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    • 1. 发明申请
    • IMPROVED PHOTOVOLTAIC CELL ASSEMBLY
    • 改进的光伏电池组件
    • WO2012033657A2
    • 2012-03-15
    • PCT/US2011/049485
    • 2011-08-29
    • DOW GLOBAL TECHNOLOGIES LLCDEGROOT, MartyLANGLOIS, Marc, Guy
    • DEGROOT, MartyLANGLOIS, Marc, Guy
    • H01L31/05
    • H01L31/0508H02S20/25H02S40/36Y02B10/12Y02E10/50
    • The present invention is premised upon an improved photovoltaic cell assembly that include at least plurality of photovoltaic cells with a photoactive portion with a top surface, a top collection structure on the top surface and an opposing conductive substrate layer on a side of the photoactive portion opposite the top surface. Also including a first conductive element with a first surface and wherein the first conductive element is bent at least once and wherein the first surface is in contact with the top collection structure and/or the top surface of a first photovoltaic ceil and the opposing conductive substrate layer of an adjacent second photovoltaic cell; further wherein at least a portion of the first surface is held in contact to the ceils by an adhesive.
    • 本发明的前提是改进的光伏电池组件,其包括至少多个光伏电池,其具有顶表面的光活性部分,顶表面上的顶部收集结构和相对的光活性部分侧面上的相对的导电基底层 顶面。 还包括具有第一表面的第一导电元件,并且其中所述第一导电元件至少弯曲一次,并且其中所述第一表面与所述顶部收集结构和/或第一光伏电池的顶表面接触,并且所述相对导电基底 相邻的第二光伏电池的层; 进一步地,其中所述第一表面的至少一部分通过粘合剂保持与所述细胞接触。
    • 2. 发明申请
    • CHALCOGENIDE-BASED MATERIALS AND IMPROVED METHODS OF MAKING SUCH MATERIALS
    • 基于氯化铝的材料和改进的制造这种材料的方法
    • WO2011115894A1
    • 2011-09-22
    • PCT/US2011/028324
    • 2011-03-14
    • DOW GLOBAL TECHNOLOGIES LLCGERBI, Jennifer E.LANGLOIS, Marc G.NILSSON, Robert T.
    • GERBI, Jennifer E.LANGLOIS, Marc G.NILSSON, Robert T.
    • H01L21/02H01L21/36
    • H01L31/0749C23C14/0623C23C14/3464C23C14/5866H01L21/02568H01L21/02614H01L21/02631
    • The present invention provides strategies for making high quality CIGS photoabsorbing materials from precursor films that incorporate a sub-stoichiometric amount of chalcogen(s). Chalcogen(s) are incorporated into the CIGS precursor film via co-sputtering with one or more other constituents of the precursor. Optional annealing also may be practiced to convert precursor into more desirable chalcopyrite crystalline form in event all or a portion of the precursor has another constitution. The resultant precursors generally are sub-stoichiometric with respect to chalcogen and have very poor electronic characteristics. The conversion of these precursors into CIGS photoabsorbing material via chalcogenizing treatment occurs with dramatically reduced interfacial void content. The resultant CIGS material displays excellent adhesion to other layers in the resultant photovoltaic devices. Ga migration also is dramatically reduced, and the resultant films have optimized Ga profiles in the top or bottom portion of the film that improve the quality of photovoltaic devices made using the films.
    • 本发明提供了从含有亚化学计量量的硫族元素的前体膜制备高品质CIGS光吸收材料的策略。 通过与前体的一种或多种其它组分的共溅射将硫族化合物并入到CIGS前体膜中。 当前体的全部或一部分具有其它结构的情况下,还可以进行任选退火以将前体转化为更理想的黄铜矿结晶形式。 所得前体通常相对于硫属元素是亚化学计量的并且具有非常差的电子特性。 通过硫属化处理将这些前体转化成CIGS光吸收材料,其界面空隙率显着降低。 所得到的CIGS材料在所得到的光伏器件中显示出对其它层的优异粘合性。 Ga迁移也显着降低,并且所得膜在膜的顶部或底部具有优化的Ga分布,其改善了使用该膜制备的光电装置的质量。
    • 5. 发明申请
    • IMPROVED PHOTOVOLTAIC CELL ASSEMBLY
    • 改进的光伏电池组件
    • WO2012033657A3
    • 2012-11-08
    • PCT/US2011049485
    • 2011-08-29
    • DOW GLOBAL TECHNOLOGIES LLCDEGROOT MARTYLANGLOIS MARC GUY
    • DEGROOT MARTYLANGLOIS MARC GUY
    • H01L31/05
    • H01L31/0508H02S20/25H02S40/36Y02B10/12Y02E10/50
    • The present invention is premised upon an improved photovoltaic cell assembly that include at least plurality of photovoltaic cells with a photoactive portion with a top surface, a top collection structure on the top surface and an opposing conductive substrate layer on a side of the photoactive portion opposite the top surface. Also including a first conductive element with a first surface and wherein the first conductive element is bent at least once and wherein the first surface is in contact with the top collection structure and/or the top surface of a first photovoltaic ceil and the opposing conductive substrate layer of an adjacent second photovoltaic cell; further wherein at least a portion of the first surface is held in contact to the ceils by an adhesive.
    • 本发明以一种改进的光伏电池组件为前提,该光伏电池组件包括至少多个具有光敏部分的光伏电池,该光敏部分具有顶表面,顶表面上的顶部收集结构和在光敏部分的相对侧上的相对导电衬底层 顶面。 还包括具有第一表面的第一导电元件,并且其中第一导电元件至少弯曲一次,并且其中第一表面与第一光伏电池的顶部收集结构和/或顶部表面以及相对的导电衬底 相邻的第二光伏电池的层; 进一步其中所述第一表面的至少一部分通过粘合剂保持与所述细胞接触。
    • 7. 发明申请
    • ACRYLATE POLYMER COATED SHEET MATERIALS AND METHOD OF PRODUCTION THEREOF
    • 丙烯酸聚合物涂层材料及其生产方法
    • WO1996031649A1
    • 1996-10-10
    • PCT/US1996004656
    • 1996-04-04
    • CATALINA COATINGS, INC.SHAW, David, G.DAWSON, EricCLINE, DanielLANGLOIS, Marc
    • CATALINA COATINGS, INC.
    • D21H19/08
    • B05D7/52B05D1/60D21H19/08D21H19/16D21H19/82Y10T428/24802Y10T428/265Y10T428/31699Y10T428/31703Y10T428/31891Y10T428/31928
    • Sheet materials according to the present invention comprise a sheet material substrate, such as for example a film or paper sheet, with a polymer base coating overlying and adhered to a surface of the sheet material substrate. The base coating comprises a radiation cured crosslinked polymer derived from at least one vapor deposited acrylate prepolymer composition having a molecular weight in the range of from about 150 to 600. A metal layer is deposited on and overlies a surface of the base coating, and a polymer top coating overlies and is adhered to a surface of the metal layer. The top coating comprises a radiation cured crosslinked polymer derived from a vapor deposited acrylate prepolymer composition having a molecular weight in the range of from about 150 to 600 and a ratio of its molecular weight to its number of acrylate groups (MW/Ac) in the range of from about 150 to 600. According to one embodiment of the invention, metallized paper sheet materials are produced with superior appearance and performance characteristics which can be tailored to specific end use applications. For example, the metallized paper can be produced with a very shiny, high gloss surface appearance, and/or a high quality metallized layer free of defects or pinholes, and/or an outer surface which is highly receptive to printing.
    • 根据本发明的片材包括片材基材,例如薄膜或纸片,聚合物基底涂层覆盖并粘附到片材基材的表面。 基底涂层包含衍生自分子量为约150至600的至少一种气相沉积的丙烯酸酯预聚物组合物的辐射固化的交联聚合物。金属层沉积在基底涂层的表面上并覆盖在基底涂层的表面上, 聚合物顶涂层覆盖并粘附到金属层的表面。 顶涂层包含辐射固化的交联聚合物,其衍生自分子量在约150至600范围内的气相沉积的丙烯酸酯预聚物组合物和其分子量与其丙烯酸酯基团数(MW / Ac)之比 范围为约150至600.根据本发明的一个实施方案,生产具有优异的外观和性能特征的金属化纸片材料,其可以针对具体的最终用途应用而定制。 例如,金属化纸可以以非常光泽,高光泽的表面外观和/或没有缺陷或针孔的高质量金属化层和/或高度接受印刷的外表面制造。
    • 9. 发明申请
    • ACRYLATE COATING METHODS
    • 丙烯酸涂料方法
    • WO1998018852A1
    • 1998-05-07
    • PCT/US1997019856
    • 1997-10-31
    • CATALINA COATINGS, INC.SHAW, David, G.CLINE, Daniel, S.DAWSON, Eric, P.LANGLOIS, Marc
    • CATALINA COATINGS, INC.
    • C08J07/06
    • B05D1/60B05D3/067B05D3/068B05D3/144C08J7/18C09D4/00C23C14/081C23C14/10C08F220/00
    • Material such as polypropylene, polyester or nylon, with high oxygen barrier properties is prepared by evaporating polyfunctional acrylate monomer with flash evaporators (43, 47, 49) and condensing the acrylate as a monomer film or by roll coating acrylate monomers onto a plastic sheet (38) in a vacuum chamber (36), using reels (37, 41). Acrylate is polymerized by irradiation by ultraviolet or electron beam (44, 48, 51, 53). A layer of metal or oxide oxygen barrier material is vapor deposited (46) over the first layer of cross-linked acrylate. An acrylate layer is applied over the metal layer. Adhesion of the acrylate layer on the plastic sheet is enhanced by reactive plasma treatment (52) of the surface immediately before deposition, the plasma treatment and coating being conducted in vacuum with less than three seconds between them. Condensation efficiency is enhanced by chilling the surface of the substrate on which the acrylate is condensed to temperatures below 0 DEG C. A backing drum (39, 40) and/or rolls (42) may be cooled to less than -15 DEG C.
    • 通过用闪蒸器(43,47,49)蒸发多官能丙烯酸酯单体并将丙烯酸酯缩合为单体膜或通过将丙烯酸酯单体辊涂到塑料片上来制备具有高氧阻隔性的材料(例如聚丙烯,聚酯或尼龙) 38)在真空室(36)中,使用卷轴(37,41)。 丙烯酸酯通过紫外线或电子束照射聚合(44,48,51,53)。 在第一交联丙烯酸酯层上蒸镀一层金属或氧化物阻氧材料(46)。 丙烯酸酯层施加在金属层上。 通过在沉积之前的表面的反应性等离子体处理(52),等离子体处理和涂覆在真空中在它们之间以不足三秒进行,增强了塑料片上丙烯酸酯层的附着力。 将丙烯酸酯缩合的基材的表面冷却至低于0℃的温度来提高冷凝效率。背衬鼓(39,40)和/或辊(42)可以冷却至小于-15℃。