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    • 1. 发明申请
    • APPARATUS AND PROCESS FOR GAS PHASE FLUIDISED BED POLYMERISATION REACTION
    • 气相流化床聚合反应装置和方法
    • WO2010037653A9
    • 2010-05-27
    • PCT/EP2009062186
    • 2009-09-21
    • INEOS EUROPE LTDDUMAS THIBAULTRAMSAY KEVIN PETER
    • DUMAS THIBAULTRAMSAY KEVIN PETER
    • B01J8/24C08F10/00
    • C08F10/00B01J8/1809B01J8/1872B01J2208/00761B01J2208/00778B01J2208/00991C08F2/34C08F2/01
    • The present invention relates to an apparatus and a process for polymerisation, and, in particular, provides an apparatus for gas phase fluidised bed polymerisation of olefins, which apparatus comprises: A) a first section which is an upright cylindrical section having a diameter, D1, and cross- sectional area, A1, and B) a second section, provided vertically above the first section and centred about a common vertical axis to the upright cylindrical first section, the base of the second section having a cylindrical cross-section of diameter D1 and being joined to the top of the first section, and the horizontal cross-sectional area of the second section above its base being greater than the cross-sectional area of the first section, characterised in that: i) D1 is greater than 4.5 metres, and ii) the second section has a maximum horizontal cross- sectional area, A2, which is between 3.2 and 6 times the cross-sectional area, A1, of the first section.
    • 本发明涉及一种用于聚合的装置和方法,并且特别地提供了一种用于烯烃气相流化床聚合的装置,该装置包括:A)第一部分,其是直径为D1的直立圆柱形部分,D1 ,和截面积A1和B)第二部分,其垂直地设置在第一部分上方并且围绕垂直的圆柱形第一部分的共同垂直轴线对中,第二部分的基部具有直径为圆柱形的横截面 D1并连接到第一部分的顶部,并且第二部分在其基部上方的水平横截面积大于第一部分的横截面积,其特征在于:i)D1大于4.5 米,并且ii)第二部分具有最大水平横截面积A 2,其在第一部分的横截面积A 1的3.2和6倍之间。
    • 6. 发明申请
    • PROCESS FOR THE PRODUCTION OF ALCOHOLS
    • 生产酒精的方法
    • WO2009010347A3
    • 2009-03-05
    • PCT/EP2008057407
    • 2008-06-12
    • INEOS EUROPE LTDBELL PETER
    • BELL PETER
    • C12P3/00C12P7/06
    • C12P3/00C01B3/382C01B2203/0233C01B2203/0238C01B2203/0405C01B2203/06C01B2203/1235C01B2203/142C12P7/02C12P7/065Y02E50/17Y02E50/32
    • The present invention relates to a process for the production of one or more C2+ alcohols. In particular, the present invention relates to a process for the production of C2+ alcohols from a methane-containing feedstock, which process comprises: a. Passing said methane- containing feedstock and carbon dioxide to a non- oxidative reforming process to produce a first product stream comprising CO, H2 and CO2, optionally in the presence of steam, but with the proviso that where steam is present in the feed to the reforming process the steam and CO2 are present in a molar ratio of less than 5: 1, b. Passing the first product stream comprising CO, H2 and CO2 to a bacterial fermentation step wherein it is converted to produce a second product stream comprising one or more C2+ alcohols in the liquid phase and a gaseous third product stream comprising CO, H2 and CO2, the fermentation step being operated to provide a conversion of CO of at least 60%, wherein CO, H2 and CO2 are recycled from the gaseous third product stream to the reforming process of step (a).
    • 本发明涉及生产一种或多种C2 +醇的方法。 具体而言,本发明涉及由含甲烷的原料生产C2 +醇的方法,该方法包括:a。 将所述含甲烷原料和二氧化碳通过非氧化重整过程,以任选地在蒸汽存在下生成包含CO,H 2和CO 2的第一产物流,但条件是在其中蒸汽存在于 重整过程中蒸汽和CO2以小于5:1的摩尔比存在,b。 将包含CO,H 2和CO 2的第一产物流传递至细菌发酵步骤,其中将其转化为产生包含液相中的一种或多种C 2+醇和包含CO,H 2和CO 2的气态第三产物流的第二产物流, 操作发酵步骤以提供至少60%的CO转化率,其中CO,H 2和CO 2从气态第三产物流循环至步骤(a)的重整工艺。
    • 10. 发明申请
    • POLYMERISATION CATALYSTS
    • 聚合催化剂
    • WO2007034149A2
    • 2007-03-29
    • PCT/GB2006003430
    • 2006-09-15
    • INEOS EUROPE LTDGIBSON VERNON CHARLESOAKES DANIEL CHARLES HOWARD
    • GIBSON VERNON CHARLESOAKES DANIEL CHARLES HOWARD
    • C08F10/00C07F7/28C08F4/64
    • C07F7/006C08F10/00C08F210/16C08F210/14C08F2500/03C08F2500/01C08F4/64075
    • A complex compound comprising the skeletal unit (A), wherein the ring C(R 1 ) -A 1 -A 2 -(A 3 ) X -C(R 2 ) -C- has delocalised unsaturation and is optionally substituted via one or more of A 1 , A 2 and A 3 by hydrogen, alkyl, aryl, halogen, or heterocyclic groups containing at least one N, S or O in a carbon ring; A 1 , A 2 and A 3 are carbon, nitrogen and, oxygen, R 1 and R 2 are hydrocarbyl, chlorine, bromine and iodine at least one of R 1 and R 2 being chlorine, bromine or iodine; x is zero or 1, 0 is oxygen, E is nitrogen, phosphorus or arsenic, Q is a divalent bridging group comprising one or more Group 14 atoms; X is a monovalent atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, y satisfies the valency of M and z is from 0 to 5. The complex can be used to polymerise olefins optionally with organo-Al or - B compounds as activator.
    • 包含骨架单元(A)的配位化合物,其中环C(R 1)-A 1 -A 2 - (A < -C(R 2)-C-具有离域不饱和度,并且任选地经由以下中的一个或多个取代:A 1, 通过氢,烷基,芳基,卤素或在碳环中含有至少一个N,S或O的杂环基团取代A 2,A 3和A 3; A 1,A 2和A 3分别是碳,氮和氧,R 1和R 2是烃基,氯,溴和碘,R 1和R 2中至少一个是氯,溴或碘; x是0或1,O是氧,E是氮,磷或砷,Q是包含一个或多个第14族原子的二价桥基; X是与M共价或离子键合的单价原子或基团; L是与M原子结合的单或双齿分子,y满足M的化合价,z为0-5。该配合物可用于任选地用有机铝化合物或-B化合物作为活化剂使烯烃聚合。