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2. 发明申请

WO2007034149A2 POLYMERISATION CATALYSTS 审中-公开
标题翻译：聚合催化剂
公开(公告)号：WO2007034149A2
公开(公告)日：2007-03-29
申请号：PCT/GB2006003430
申请日：2006-09-15
申请人： INEOS EUROPE LTD , GIBSON VERNON CHARLES , OAKES DANIEL CHARLES HOWARD
发明人： GIBSON VERNON CHARLES , OAKES DANIEL CHARLES HOWARD
IPC分类号： C08F10/00 , C07F7/28 , C08F4/64
CPC分类号： C07F7/006 , C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F4/64075
摘要： A complex compound comprising the skeletal unit (A), wherein the ring C(R 1 ) -A 1 -A 2 -(A 3 ) X -C(R 2 ) -C- has delocalised unsaturation and is optionally substituted via one or more of A 1 , A 2 and A 3 by hydrogen, alkyl, aryl, halogen, or heterocyclic groups containing at least one N, S or O in a carbon ring; A 1 , A 2 and A 3 are carbon, nitrogen and, oxygen, R 1 and R 2 are hydrocarbyl, chlorine, bromine and iodine at least one of R 1 and R 2 being chlorine, bromine or iodine; x is zero or 1, 0 is oxygen, E is nitrogen, phosphorus or arsenic, Q is a divalent bridging group comprising one or more Group 14 atoms; X is a monovalent atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, y satisfies the valency of M and z is from 0 to 5. The complex can be used to polymerise olefins optionally with organo-Al or - B compounds as activator.
摘要翻译：包含骨架单元（A）的配位化合物，其中环C（R 1）-A 1 -A 2 - （A < -C（R 2）-C-具有离域不饱和度，并且任选地经由以下中的一个或多个取代：A 1，通过氢，烷基，芳基，卤素或在碳环中含有至少一个N，S或O的杂环基团取代A 2，A 3和A 3; A 1，A 2和A 3分别是碳，氮和氧，R 1和R ^{2是烃基，氯，溴和碘，R 1和R 2中至少一个是氯，溴或碘; x是0或1，O是氧，E是氮，磷或砷，Q是包含一个或多个第14族原子的二价桥基; X是与M共价或离子键合的单价原子或基团; L是与M原子结合的单或双齿分子，y满足M的化合价，z为0-5。该配合物可用于任选地用有机铝化合物或-B化合物作为活化剂使烯烃聚合。}

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