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    • 71. 发明申请
    • REDOX FLOW BATTERY THAT REVERSIBLY CONVERTS CHEMICAL ENERGY INTO ELECTRICITY
    • REDOX流量电池可逆转化学电能
    • WO2015097270A3
    • 2015-08-27
    • PCT/EP2014079282
    • 2014-12-23
    • RHODIA OPERATIONSUNIV BORDEAUXCENTRE NAT RECH SCIENTUNIV PICARDIE
    • PAVAGEAU BERTRANDRIVOAL PHILIPPECOLIN ANNIEHAMELET STÉPHANETARASCON JEAN-MARIE
    • H01M8/18H01M8/02H01M8/04H01M8/20H01M8/22
    • H01M8/2459H01M8/0258H01M8/04186H01M8/04201H01M8/188H01M8/20H01M8/225Y02E60/528
    • The invention relates to a redox flow battery that can be used to convert chemical energy into electricity in a reversible manner, comprising: - an anolyte tank (1), containing species of a redox couple, - a catholyte tank (2), containing species of another redox couple, and - at least one electrochemical cell (10), in which a flow of anolyte (A) originating from and sent back to the anolyte tank circulates, in which a flow of catholyte (C) originating from and sent back to the catholyte tank circulates, and which is provided with two electrodes (13), which are respectively in contact with the flow of anolyte (A) and with the flow of catholyte (C), and which collect an electric charge/discharge current of the redox flow battery. The flow of anolyte and the flow of catholyte in the electrochemical cell are laminar, and, in the electrochemical cell, a laminar flow of electrolyte (E) also circulates which is inserted between the flow of anolyte (A) and the flow of catholyte (C) so as to form, at the same time, a first liquid-liquid interface between the flow of anolyte and the flow of electrolyte and a second liquid-liquid interface between the flow of catholyte and the flow of electrolyte.
    • 本发明涉及一种氧化还原液流电池,其可用于以可逆方式将化学能转化为电能,其包括:阳极电解液罐(1),其含有氧化还原对物质, - 阴极电解液罐(2),其含有物质 的另一种氧化还原对,以及 - 至少一个电化学电池(10),其中源自并发回到阳极电解液罐的阳极电解液(A)的流动循环,其中源自并发回的阴极电解液 阴极电解液罐循环,并且设置有分别与阳极电解液(A)的流动和阴极电解液(C)的流动接触的两个电极(13),并且收集电极 氧化还原液流电池。 阳极电解液的流动和电解池中的阴极电解液的流动是层流的,并且在电化学电池中,电解质(E)的层流也循环,其被插入阳极电解液(A)的流动与阴极电解液 C),以便同时形成阳极电解液的流动与电解质流之间的第一液 - 液界面和阴极电解液流与电解液流之间的第二液 - 液界面。
    • 73. 发明申请
    • APPARATUS AND METHOD FOR PRODUCT RECOVERY AND ELECTRICAL ENERGY GENERATION
    • 产品回收和电能生成的装置和方法
    • WO2015028685A1
    • 2015-03-05
    • PCT/EP2014/068635
    • 2014-09-02
    • VITO NV (VLAAMSE INSTELLING VOOR TECHNOLOGISCH ONDERZOEK NV)
    • ZHANG, YangHELSEN, Joost
    • B01D61/50B01D61/44H01M2/14H01M8/22
    • B01D61/422B01D2325/16H01M8/227
    • The present invention relates to a diffusion dialysis apparatus (15) comprising a plurality of anion exchange membranes (1,2) arranged so as to form a stack of successive cell units (16), each cell unit comprising a dialysate compartment (4) for passing a dialysate solution (7) and for collecting acid compounds recovered from a feed, a feed compartment (5) for passing a stream of the feed (6) comprising acid waste with a concentration gradient of the acid between the feed and dialysate solution, and two anion exchange membranes stacked so as to be interleaved with the dialysate compartment and the feed compartment; characterised in that the apparatus comprises an anode (12) and a cathode (13), wherein the cell units are placed between the anode and the cathode,and in that successive anion exchange membranes in the stack of successive cell units are alternately a higher proton transport anion exchange membrane (1) and a lower proton transport anion exchange membrane (2), wherein the higher proton transport AEM (1) has a first H + transport number and the lower proton transport AEM (2) has a second H + transport number, the second H + transport number being smaller than the first H + transport number, such that, in use, acid compounds from the stream of feed (6) are recovered in the dialysate compartment (4) by diffusion dialysis and electrical energy is generated from the directional migration by diffusion dialysis of protons and anions. Use of a diffusion dialysis apparatus according to the invention and a method for recovering acid (or base) compounds from a feed and generating electrical energy is provided as well.
    • 扩散透析装置技术领域本发明涉及一种扩散透析装置(15),其包括多个阴离子交换膜(1,2),其布置成形成连续细胞单元(16)的堆叠,每个细胞单元包括透析液室(4),用于 通过透析液(7)并收集从进料回收的酸性化合物,进料室(5),用于使包含酸废物的进料(6)的流在进料和透析液之间具有浓度梯度, 并且两个阴离子交换膜被堆叠以便与透析液室和进料室交错; 其特征在于,该装置包括阳极(12)和阴极(13),其中电池单元位于阳极和阴极之间,并且连续电池单元堆叠中的连续阴离子交换膜交替地是较高的质子 运输阴离子交换膜(1)和较低质子转运阴离子交换膜(2),其中较高质子转运AEM(1)具有第一H +转运数,下质子转运AEM(2)具有第二H +转运数, 第二H +传输数小于第一H +传输数,使得在使用中,来自进料流(6)的酸化合物通过扩散透析回收在透析液室(4)中,并且从定向产生电能 通过质子和阴离子的扩散透析迁移。 还提供使用根据本发明的扩散透析装置和从进料中回收酸(或碱)化合物并产生电能的方法。
    • 74. 发明申请
    • PILA DE COMBUSTIBLE
    • 燃料电池
    • WO2015025070A1
    • 2015-02-26
    • PCT/ES2014/070660
    • 2014-08-18
    • CENTRO DE INVESTIGACIONES ENERGÉTICAS, MEDIOAMBIENTALES Y TECNOLÓGICAS (CIEMAT)
    • MARTÍNEZ CHAPARRO, Antonio AlfonsoFERREIRA APARICIO, Paloma
    • H01M8/02H01M8/22
    • H01M8/04156H01M8/0232H01M8/0245H01M8/0247H01M8/2483H01M2008/1095
    • Pila de combustible que comprende un electrodo catódico(2), que comprende a su vez una capa de catalizador (4), un colector de corriente (6), una capa difusora de gas (5) intercalada entre la capa de catalizador y el colector de corriente, y una placa (7) dispuesta en contacto con el colector de corriente (6) y dotada de orificios pasantes, un electrodo anódico(3), que comprende una capa de catalizador (8),un colector de corriente,una capa difusora de gas (9), intercalada entre la capa de catalizador y el colector de corriente, y una placa distribuidora de gas dispuesta en contacto o integrada con el colector de corriente, y un electrolito de membrana polimérica(1) intercalado entre la capa de catalizador del cátodo(4) y la capa de catalizador del ánodo (8). La placa distribuidora de gas permite la evacuación del agua del ánodo de forma pasiva a través de orificios pasantes (15) sellados al paso de gas por medio de una película hidrófila (11).
    • 本发明涉及一种燃料电池,包括:阴极电极,又包括催化剂层(4),集电器(6),设置在催化剂层和集电器之间的气体扩散层(5) 和与集电体(6)接触并设置有通孔的板(7); 和阳极电极(3),其又包括设置在催化剂层和集电体之间的催化剂层(8),集电体,气体扩散层(9)和与之接触的气体分配板, 或内置于集电器中。 燃料电池还包括设置在阴极催化剂层(4)和阳极催化剂层(8)之间的聚合物膜电解质(1)。 气体分配板允许通过通过亲水膜(11)密封抵靠气体通过的通孔(15)来从阳极被动地释放水。
    • 76. 发明申请
    • CIHT POWER SYSTEM
    • CIHT电力系统
    • WO2014025443A3
    • 2014-04-03
    • PCT/US2013041938
    • 2013-05-21
    • BLACKLIGHT POWER INC
    • MILLS RANDELL L
    • H01M4/86H01M8/14H01M8/22
    • H01M8/143H01M8/00H01M8/06H01M8/0656H01M8/144H01M8/146Y02E60/366
    • An electrochemical power system is provided that generates an electromotive force (EMF) from the catalytic reaction of hydrogen to lower energy (hydrino) states providing direct conversion of the energy released from the hydrino reaction into electricity, the system comprising at least two components chosen from: H2O catalyst or a source of H2O catalyst; atomic hydrogen or a source of atomic hydrogen; reactants to form the H2O catalyst or source of H2O catalyst and atomic hydrogen or source of atomic hydrogen; and one or more reactants to initiate the catalysis of atomic hydrogen. The electrochemical power system for forming hydrinos and electricity can further comprise a cathode compartment comprising a cathode, an anode compartment comprising an anode, optionally a salt bridge, reactants that constitute hydrino reactants during cell operation with separate electron flow and ion mass transport, a source of oxygen, and a source of hydrogen. Due to oxidation-reduction cell half reactions, the hydrino-producing reaction mixture is constituted with the migration of electrons through an external circuit and ion mass transport through a separate path such as the electrolyte to complete an electrical circuit. A power source and hydride reactor is further provided that powers a power system comprising (i) a reaction cell for the catalysis of atomic hydrogen to form hydrinos, (ii) a chemical fuel mixture comprising at least two components chosen from: a source of H2O catalyst or H2O catalyst; a source of atomic hydrogen or atomic hydrogen; reactants to form the source of H2O catalyst or H2O catalyst and a source of atomic hydrogen or atomic hydrogen; one or more reactants to initiate the catalysis of atomic hydrogen; and a support to enable the catalysis, (iii) thermal systems for reversing an exchange reaction to thermally regenerate the fuel from the reaction products, (iv) a heat sink that accepts the heat from the power-producing reactions, and (v) a power conversion system.
    • 提供了一种电化学动力系统,该电化学动力系统从氢催化反应生成较低能量(分数氢)状态的电动势(EMF),从而将从分数氢反应释放的能量直接转化为电,该系统包括至少两种选自 :H 2 O催化剂或H 2 O催化剂的来源; 原子氢或原子氢的来源; 反应物以形成H 2 O催化剂或H 2 O催化剂源和原子氢或原子氢源; 和一种或多种反应物来引发原子氢的催化作用。 用于形成分数氢和电的电化学动力系统可以进一步包括阴极室,阴极室包含阴极,阳极室包含阳极,任选的盐桥,在电池操作期间用分开的电子流和离子质量传输构成分数氢反应物的反应物, 的氧气和氢的来源。 由于氧化还原单元的一半反应,产氢反应混合物由电子通过外部电路迁移并且离子质量通过诸如电解质的单独路径传输来构成,以完成电路。 还提供了动力源和氢化物反应器,其为动力系统提供动力,所述动力系统包括(i)用于催化原子氢以形成分数氢的反应单元,(ii)化学燃料混合物,其包含选自以下的至少两种组分: 催化剂或H2O催化剂; 原子氢或原子氢的来源; 反应物以形成H 2 O催化剂或H 2 O催化剂的来源以及原子氢或原子氢的来源; 一种或多种引发原子氢催化的反应物; (iii)用于逆转交换反应以使反应产物中的燃料热再生的热系统,(iv)接受来自发电反应的热量的散热器,以及(v) 电力转换系统。