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1. 发明申请

WO2016207609A1 DISAGGREGATION OF BIOMASS PYROLYSIS OIL 审中-公开
标题翻译：生物质分解油的分解
公开(公告)号：WO2016207609A1
公开(公告)日：2016-12-29
申请号：PCT/GB2016/051735
申请日：2016-06-10
申请人： FUTURE BLENDS LIMITED
发明人： GAJJELA, Sanjeev Kumar , OVEREND, Ralph Philips , WU, Zhiheng , MAYER, Zsuzsa Ajsa , CATALAN, Jose Antonio Medrano , WU, Haonan
IPC分类号： C10B53/02 , C10G3/00 , C10G27/14 , C10G21/16 , C10G53/04 , C10G53/14 , B01D11/04 , C10G31/06
CPC分类号： C10G3/44 , C10G21/16 , C10G27/14 , C10G31/06 , C10G53/04 , C10G53/14 , C10G2300/1011 , C10G2300/44 , C13K1/02 , Y02E50/14 , Y02P30/20
摘要： Described is a novel process for disaggregating biomass pyrolysis oil quantitatively into energy dense hydrophobic aromatic fraction (HAF), fermentable pyrolytic sugars and phenolics based products in a highly economical and energy efficient manner. Phase separation of the esterified pyrolysis oil after an oxidative pre-treatment and the quantitative recovery of the separate fractions is described. Phase separation uses batch as well as continuous reactor systems. The resulting HAF is an energy dense, thermally stable, water free, non-corrosive to carbon steel, and is a free flowing liquid suitable for combustion and for upgrading to transportation fuels. Pyrolytic sugars which are mainly anhydrosugars can be further converted by fermentation to ethanol or other products. Monomeric phenols are useful industrial intermediates and the organic acids in the original pyrolysis oil are mainly recovered as esters of the separation solvents.
摘要翻译：描述了一种将生物质热解油定量分解成能量密集疏水性芳香族馏分（HAF），可发酵的热解糖和酚类产品的新方法，以高度经济和节能的方式。描述了氧化预处理后的酯化热解油的相分离和单独级分的定量回收。相分离使用批次以及连续反应器系统。所得到的HAF是能量密集，热稳定，无水，对碳钢无腐蚀性的，是适用于燃烧和升级为运输燃料的自由流动液体。主要是脱水葡萄糖的热解糖可以通过发酵进一步转化成乙醇或其他产品。单体酚是有用的工业中间体，原始热解油中的有机酸主要作为分离溶剂的酯回收。

2. 发明申请

WO2014033676A1 PROCESS FOR QUALITY ENHANCEMENT IN HYDROCARBON STREAM 审中-公开
标题翻译：石油气质量提高的过程
公开(公告)号：WO2014033676A1
公开(公告)日：2014-03-06
申请号：PCT/IB2013/058152
申请日：2013-08-30
申请人： INDIAN OIL CORPORATION LIMITED
发明人： SARKAR, Mainak , ARUN, Arangarasu , GUPTA, Yamini , BUTLEY, Ganesh Vitthalrao , SAU, Madhusudan , KUMAR, Brijesh , RAJAGOPAL, Santanam , RAMADHAS, Arumugam Sakunthalai , MALHOTRA, Ravinder Kumar
IPC分类号： C10L1/02 , C10G27/04 , C10G27/10 , C10G27/14 , C10L1/18 , C10L10/08 , C10L10/12
CPC分类号： C10G67/12 , C10G27/04 , C10G27/10 , C10G27/12 , C10G27/14 , C10G45/02 , C10G2300/202 , C10G2300/307 , C10L1/026 , C10L1/1805 , C10L10/08 , C10L10/12 , C10L2200/0446 , C10L2270/026 , C10L2290/10 , C10L2290/145
摘要： The present invention discloses a process for enhancing quality of a hydrocarbon stream. More particularly, the present invention discloses a process for improvement of the combustion quality of a diesel range stream by dissolving an oxygen source in the feed stream before carrying out the oxidation, thereby enhancing the Cetane number, lubricity and reducing emission of the stream. The present invention also discloses a process for enhancing combustion quality of a hydrocarbon stream by carrying out the process in presence of an organometallic catalyst.
摘要翻译：本发明公开了一种提高烃流质量的方法。更具体地，本发明公开了一种通过在进行氧化之前将氧源溶解在进料流中来提高柴油范围流的燃烧质量的方法，从而提高了十六烷值，润滑性和减少了流的排放。本发明还公开了一种通过在有机金属催化剂存在下进行该方法来提高烃流的燃烧质量的方法。

3. 发明申请

WO0015734A9 DESULFURIZATION PROCESS 审中-公开
标题翻译：脱硫工艺
公开(公告)号：WO0015734A9
公开(公告)日：2000-08-17
申请号：PCT/US9921478
申请日：1999-09-16
申请人： JEANBLANC JAMES K
发明人： JEANBLANC JAMES K
IPC分类号： B01D53/52 , B01J19/10 , B01J19/12 , C10G27/06 , C10G27/12 , C10G27/14 , C10G32/00 , C10G53/14 , C10L5/00 , C10L9/06
CPC分类号： C10G27/12 , C10G27/14 , C10G32/00 , C10L9/06
摘要： Sulfur-containing carbonaceous materials are desulfurized by reaction with a mixture of an oxidizing agent and an oxygenated solvent such as diethyl ether under alkaline conditions at a temperature preferably ranging from ambient temperature to about 250 DEG F (121 DEG C) and a preferred pressure of about 1 atmosphere to 2 atmospheres. The use of radiation - such as X-ray, infrared, visible, microwave, or ultraviolet radiation, alpha, beta, or gamma radiation, other atomic radiation emanating from a radioactive material, or ultrasound - facilitates desulfurization. The products of the reaction are a desulfurized carbonaceous material in which the sulfur content is (for example) less than about 1 % and separated sulfur compounds.
摘要翻译：通过在碱性条件下，优选在环境温度至约250°F（121℃）的温度和优选的环境温度至约250°F（121℃）的温度下，与氧化剂和氧化溶剂如乙醚的混合物反应，将含硫的碳质材料脱硫，约1个大气压至2个大气压。使用辐射 - 例如X射线，红外线，可见光，微波或紫外线辐射，α，β或γ辐射，从放射性物质发射的其他原子辐射或超声 - 有利于脱硫。反应产物是硫含量（例如）小于约1％的脱硫碳质材料，并且分离出硫化合物。

4. 发明申请

WO00023540A1 DEEP CONVERSION COMBINING THE DEMETALLIZATION AND THE CONVERSION OF CRUDES, RESIDUES OR HEAVY OILS INTO LIGHT LIQUIDS WITH PURE OR IMPURE OXYGENATED COMPOUNDS 审中-公开
标题翻译：深度转换结合使用纯化或不纯氧化的化合物进行脱色和转化，残留或重油转化成轻液体
公开(公告)号：WO00023540A1
公开(公告)日：2000-04-27
申请号：PCT/US1999/023325
申请日：1999-10-07
IPC分类号： B01J4/00 , B01J8/04 , B01J10/00 , C10G1/02 , C10G9/00 , C10G9/36 , C10G21/02 , C10G27/14 , C10G33/06 , C10G33/08 , C10G55/04
CPC分类号： C10G21/02 , B01J4/001 , B01J2219/00006 , C10G1/02 , C10G9/00 , C10G9/36 , C10G27/14 , C10G33/06 , C10G55/04 , C10G2300/107 , C10G2300/1077 , C10G2300/201 , C10G2300/205 , C10G2300/807 , Y10S585/922 , Y10S585/923
摘要： A process for the conversion of hydrocarbons that are solid or have a high boiling temperature and may be laden with metals, sulfur or sediments, into liquids (gasolines, gas oil, fuels) with the help of a jet of gas properly superheated between 600 and 800 DEG C. The process comprises preheating a feed (5) in a heater (8) to a temperature below the selected temperature of a reactor (10). This feed is injected by injectors (4) into the empty reactor (10) (i.e., without catalyst.) The feed is treated with a jet of gas or superheated steam from superheater (2) to activate the feed. The activated products in the feed are allowed to stabilize at the selected temperature and at a selected pressure in the reactor and are then run through a series of extractors (13) to separate heavy and light hydrocarbons and to demetallize the feed. Useful products appearing in the form of water/hydrocarbon emulsions are generally demulsified in emulsion breaker (16) to form water laden with different impurities. The light phase containing the final hydrocarbons is heated in heater (98) and is separated into cuts of conventional products, according to the demand for refining by an extractor (18) similar to (13).
摘要翻译：一种将固体或具有高沸点温度的烃转化成金属，硫或沉淀物的烃转化为液体（汽油，瓦斯油，燃料）的方法，借助于600〜 800℃。该方法包括将加热器（8）中的进料（5）预热至低于反应器（10）选定温度的温度。该进料通过喷射器（4）注射到空的反应器（10）中（即，没有催化剂）。用来自过热器（2）的气体喷射或过热蒸汽处理进料以活化进料。允许进料中的活化产物在反应器中选定的温度和选择的压力下稳定，然后通过一系列萃取器（13）进行分离以分离重质烃和轻烃，并使进料脱金属。以水/碳氢化合物乳液形式出现的有用产品通常在破乳剂（16）中破乳以形成含有不同杂质的水。根据对类似于（13）的萃取器（18）的精炼需求，在加热器（98）中加热含有最终碳氢化合物的轻质相，并分离成常规产品的切割。

5. 发明申请

WO2018140620A1 OXIDATIVE DESULFURIZATION OF OIL FRACTIONS AND SULFONE MANAGEMENT USING AN FCC 审中-公开
公开(公告)号：WO2018140620A1
公开(公告)日：2018-08-02
申请号：PCT/US2018/015275
申请日：2018-01-25
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： KOSEOGLU, Omer Refa , BOURANE, Abdennour , KRESSMANN, Stephane Cyrille
IPC分类号： C10G53/04 , C10G53/14 , C10G55/06 , C10G21/16 , C10G21/20 , C10G21/22 , C10G27/04 , C10G27/12 , C10G27/14
摘要： Embodiments provide a method and apparatus for recovering components from a hydrocarbon feedstock. According to at least one embodiment, the method includes supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds and nitrogen compounds present in the hydrocarbon feedstock, separating the hydrocarbons, the oxidized sulfur compounds, and the oxidized nitrogen compounds by solvent extraction, collecting a residue stream that includes the oxidized sulfur compounds and the oxidized nitrogen compound, supplying the residue stream to a fluid catalytic cracking unit, and recycling liquid products produced by the fluid catalytic cracking unit to the oxidation reactor to selectively oxidize sulfur compounds in the liquid products, the portion of the liquids products including at least one of light cycle oils and heavy cycle oils.

6. 发明申请

WO2012068277A2 PROCESS, METHOD, AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS 审中-公开
标题翻译：用于从流体中除去重金属的方法，方法和系统
公开(公告)号：WO2012068277A2
公开(公告)日：2012-05-24
申请号：PCT/US2011/061035
申请日：2011-11-16
申请人： CHEVRON U.S.A. INC. , YEAN, Sujin
发明人： YEAN, Sujin
IPC分类号： C10G27/02 , C10G27/14 , C10G29/12 , C10G27/00
CPC分类号： C10G27/10 , C10G27/02 , C10G27/12 , C10G27/14 , C10G29/12 , C10G2300/1033 , C10G2300/205 , C10G2300/308 , C10G2300/80 , C10G2300/805
摘要： Trace amount levels of heavy metals such as mercury, arsenic, etc., in crude oil are reduced by contacting the crude oil with an oxidizing agent, extracting heavy metals into a water phase for subsequent separation from the crude oil. In one embodiment, the oxidizing agent is selected from the group of hydroperoxides, organic peroxides, inorganic peracids and salts thereof, organic peracids and salts thereof, halogens such as iodine (I 2 ), bromine (Br 2 ), and ozone. In another embodiment, at least a complexing agent selected from the group of metal halides and/or sulfur compounds can be added to facilitate the removal of heavy metals from crude oil by forming soluble heavy metal complexes in the water phase.
摘要翻译：原油中重金属如汞，砷等的痕量水平通过使原油与氧化剂接触而减少，将重金属提取到水相中以便随后从原油。在一个实施方案中，氧化剂选自氢过氧化物，有机过氧化物，无机过酸及其盐，有机过酸及其盐，卤素如碘（I 2），溴（Br 2） sub> 2 ）和臭氧。在另一个实施方案中，可以加入至少一种选自金属卤化物和/或硫化合物的络合剂，以通过在水相中形成可溶性重金属络合物来促进从原油中去除重金属。

7. 发明申请

WO2007006925A3 PROCEDE DE DEGRADATION DES HYDROCARBURES AROMATIQUES POLYCYCLIQUES UTILISANT UNE HEMOPROTEINE IMMOBILISEE 审中-公开
公开(公告)号：WO2007006925A3
公开(公告)日：2007-01-18
申请号：PCT/FR2006/001617
申请日：2006-07-06
申请人： TOTAL FRANCE , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , JAMROZIK, Claude , THOMAS, Daniel , PULVIN, Sylviane , BEDEL-CLOUTOUR, Catherine , GALARNEAU, Anne , RENARD, Gilbert , FAJULA, François , BRUNEL, Daniel , LANGELLIER, Christophe , GILSON, Jean-Pierre
发明人： JAMROZIK, Claude , THOMAS, Daniel , PULVIN, Sylviane , BEDEL-CLOUTOUR, Catherine , GALARNEAU, Anne , RENARD, Gilbert , FAJULA, François , BRUNEL, Daniel , LANGELLIER, Christophe , GILSON, Jean-Pierre
IPC分类号： C10G27/10 , C10G27/14 , C02F1/78 , C02F103/42
摘要： L'invention concerne un procédé de réduction de la teneur en hydrocarbures aromatiques polycycliques (HAP) d'un milieu liquide, lesdits HAP contenant éventuellement, dans leur structure cyclique, un ou plusieurs hétéroatomes choisis parmi N, O et S, comprenant (a) la mise en contact dudit milieu liquide avec au moins un agent oxydant approprié en présence d'au moins une hémoprotéine, choisie parmi les hémoglobines et les myoglobines, immobilisée sur ou dans des particules solides minérales finement divisées ayant une taille moyenne, déterminée par granulométrie laser, comprise entre 5 nm et 1 mm, de préférence comprise entre 10 nm et 100 μm, dans des conditions réactionnelles permettant l'oxydation des hydrocarbures aromatiques polycycliques éventuellement soufrés et/ ou azotés et/ ou oxydés par l'agent oxydant, et (b) la séparation de l’hémoprotéine immobilisée d'avec le milieu liquide.

8. 发明申请

WO2007006925A2 METHOD FOR DEGRADING POLYCYCLIC AROMATIC HYDROCARBONS BY USING AN IMMOBILIZED HEMOPROTEIN 审中-公开
标题翻译：通过使用固定化HEMOPROTEIN降解多环芳烃的方法
公开(公告)号：WO2007006925A2
公开(公告)日：2007-01-18
申请号：PCT/FR2006001617
申请日：2006-07-06
申请人： TOTAL FRANCE , CENTRE NAT RECH SCIENT , JAMROZIK CLAUDE , THOMAS DANIEL , PULVIN SYLVIANE , BEDEL-CLOUTOUR CATHERINE , GALARNEAU ANNE , RENARD GILBERT , FAJULA FRANCOIS , BRUNEL DANIEL , LANGELLIER CHRISTOPHE , GILSON JEAN-PIERRE
发明人： JAMROZIK CLAUDE , THOMAS DANIEL , PULVIN SYLVIANE , BEDEL-CLOUTOUR CATHERINE , GALARNEAU ANNE , RENARD GILBERT , FAJULA FRANCOIS , BRUNEL DANIEL , LANGELLIER CHRISTOPHE , GILSON JEAN-PIERRE
IPC分类号： C10G27/10 , C02F1/78 , C02F103/42 , C10G27/14
CPC分类号： C10G27/04 , B01J31/003 , C02F1/722 , C02F2101/32 , C10G27/12 , C10G27/14
摘要： The invention relates to a method for reducing the content of polycyclic aromatic hydrocarbons (PAH) of a liquid medium, said PAH's optionally containing, in their cyclic structure, one or more heteroatoms selected among N, O and S, comprising: (a) placing the liquid medium in contact with at least one appropriate oxidizing agent in the presence of at least one hemoprotein selected among hemoglobins and myoglobins, immobilized on or in finely divided solid mineral particles having an average size determined by laser granulometry ranging from 5 nm to 1 mm, preferably from 10 nm to 100 ?m, in reaction conditions that permit the oxidation of polycyclic aromatic hydrocarbons optionally sulfurated and/or nitrogenated and/or oxidized by the oxidizing agent, and; (b) the separation of the immobilized hemoprotein from the liquid medium.
摘要翻译：本发明涉及一种用于降低液体介质的多环芳烃（PAH）含量的方法，所述PAH在其环状结构中任选地含有一个或多个选自N，O和S的杂原子，包括：（a）将所述液体培养基在至少一种选自血红蛋白和肌红蛋白中的血红蛋白存在下与至少一种适当的氧化剂接触，固定在具有5nm至1mm的激光粒度测定的平均尺寸的细分固体矿物颗粒上，优选为10nm至100μm，在允许多环芳族烃任选被氧化剂硫化和/或氮化和/或氧化的反应条件下，（b）从液体培养基中分离固定的血液蛋白。

9. 发明申请

WO2018175143A1 PROCESS FOR OXIDATIVE DESULFURIZATION AND SULFONE DISPOSAL USING SOLVENT DEASPHALTING 审中-公开
公开(公告)号：WO2018175143A1
公开(公告)日：2018-09-27
申请号：PCT/US2018/022134
申请日：2018-03-13
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： KOSEOGLU, Omer Refa , BOURANE, Abdennour , KRESSMANN, Stephane
IPC分类号： C10G21/16 , C10G21/20 , C10G21/22 , C10G25/00 , C10G27/04 , C10G27/12 , C10G27/14 , C10G53/04 , C10G53/08 , C10G53/14 , C10G21/00
摘要： Embodiments provide a method and apparatus for upgrading a hydrocarbon feedstock. According to at least one embodiment, the method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur and nitrogen compounds present in the hydrocarbon feedstock; (b) separating the hydrocarbons and the oxidized sulfur and nitrogen compounds by solvent extraction; (c) collecting a first residue stream that includes the oxidized sulfur and oxidized nitrogen compounds; (d) supplying the first residue stream to a deasphalting unit; (e) supplying the hydrocarbons to an adsorption column to produce a high purity hydrocarbon product and a second residue stream; and (f) supplying spent adsorbent to the deasphalting unit to remove additional contaminants from the high purity hydrocarbon product in the deasphalting unit.

10. 发明申请

WO2016015045A1 INTEGRATED PROCESS TO PRODUCE ASPHALT, PETROLEUM GREEN COKE, AND LIQUID AND GAS COKING UNIT PRODUCTS 审中-公开
标题翻译：一体化生产沥青，石油绿焦，液体和气体制品单位产品
公开(公告)号：WO2016015045A1
公开(公告)日：2016-01-28
申请号：PCT/US2015/042234
申请日：2015-07-27
申请人： SAUDI ARABIAN OIL COMPANY , KOSEOGLU, Omer, Refa
发明人： KOSEOGLU, Omer, Refa
IPC分类号： C10G27/04 , C10G27/14 , C10G31/06 , C10G53/04 , C10G53/14 , C10G55/04 , C10G21/00 , C10B55/00
CPC分类号： C10G55/04 , C10B55/00 , C10B57/045 , C10G21/003 , C10G27/04 , C10G27/14 , C10G31/06 , C10G53/04 , C10G53/14 , C10G2300/202 , C10G2300/205 , C10G2300/206
摘要： An integrated process is provided to produce asphalt, high quality petroleum green coke, and liquid and gas coker unit products. Sulfur molecules contained in heavy petroleum fractions, including organosulfur molecules, and in certain embodiments organonitrogen molecules are oxidized. The polar oxidized sulfur compounds shift from the oil phase to the asphalt phase. The deasphalted/desulfurized oil phase is passed to a coker unit to produce liquid and gas coker products as an effluent stream and recover high quality petroleum green coke.
摘要翻译：提供了生产沥青，优质石油焦炭，液化气焦化装置产品的综合工艺。包含在重质石油馏分中的硫分子，包括有机硫分子，在某些实施方案中，有机硫分子被氧化。极性氧化硫化合物从油相转变为沥青相。脱沥青/脱硫油相被输送到焦化器单元以产生作为流出物流的液体和气体焦化产物并回收高质量的石油焦炭。

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