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1. 发明申请

US20080289123A1 Reactive Dyes, Their Preparation and Their Use 审中-公开
标题翻译：活性染料及其制备及其应用
公开(公告)号：US20080289123A1
公开(公告)日：2008-11-27
申请号：US11663914
申请日：2005-09-19
申请人： Georg Roentgen , Athanassios Tzikas
发明人： Georg Roentgen , Athanassios Tzikas
IPC分类号： C07C245/02 , C09D11/02 , C09B62/006 , C23C16/00
CPC分类号： C09B62/4415
摘要： Reactive dyes of formula (I) are suitable for dyeing cellulosic or amide-group-containing fibre materials.
摘要翻译：式（I）的活性染料适用于染色含纤维素或含酰胺基的纤维材料。

2. 发明授权

US07183409B2 Basic mono- and bisazo compounds 有权
标题翻译：基本单和双偶氮化合物
公开(公告)号：US07183409B2
公开(公告)日：2007-02-27
申请号：US10479779
申请日：2002-05-29
申请人： Friedrich Lehr , Reinhard Pedrazzi , Heidrun Schene
发明人： Friedrich Lehr , Reinhard Pedrazzi , Heidrun Schene
IPC分类号： C09B62/006 , C07D251/26
CPC分类号： C09B44/02 , C09B35/029 , C09B43/16
摘要： The invention relates to basic mono- and bisazo compounds according to formula (I) wherein all substituents are defined as in Claim 1, their production, their use as dyestuffs as well as material dyed with these dyestuffs.
摘要翻译：本发明涉及式（I）的基本单 - 和双偶氮化合物，其中所有取代基如权利要求1所定义，它们的制备，它们作为染料的用途以及用这些染料染色的材料。

3. 发明授权

US5696241A Sulfonated quinolone compound and method of preparation 失效
标题翻译：磺化喹诺酮化合物及其制备方法
公开(公告)号：US5696241A
公开(公告)日：1997-12-09
申请号：US784935
申请日：1997-01-15
申请人： Philomen Z. deCroos , Ronald P. Pedemonte , Thomas S. Phillips
发明人： Philomen Z. deCroos , Ronald P. Pedemonte , Thomas S. Phillips
IPC分类号： C07D215/36 , C09B62/006 , C09B62/24 , C09B62/44 , C09B62/507 , C07D215/227 , C09B62/085 , C09B62/51
CPC分类号： C07D215/36 , C09B62/0067 , C09B62/24 , C09B62/4411 , C09B62/507
摘要： Novel sulfonated quinolone compounds used in the preparation of fiber reactive dyes having the formula: ##STR1## being N-alkyl substituted-4-hydroxy-6-sulfo-2-quinolone. The alkyl group bonded to the nitrogen in the quinolone has from 1 to 4 carbon atoms which may be further substituted by an hydroxy, amino, or sulfo group. The compounds of the invention may be prepared by the sulfonation of an N-alkyl substituted-4-hydroxy-2-quinolones, ##STR2## followed by selective desulfonation to yield the compounds of interest. New monoazo fiber reactive dyes having the formulas: ##STR3## and their metal complexes, may be prepared from these sulfonated compounds by the diazotization of an amine component, selected from an unsubstituted, or a substituted benzene or naphthalene compound, containing a fiber reactive group, and coupling the diazo component to the compounds of the invention. These dyes are suitable for the dyeing and printing of native and synthetic carbonamide containing fibers, and native or regenerated or synthetic hydroxy containing fibers, especially on cellulose fibrous materials, in the presence of an alkaline agent.
摘要翻译：用于制备具有下式的纤维活性染料的新型磺化喹诺酮化合物：作为N-烷基取代的-4-羟基-6-磺基-2-喹诺酮。与喹诺酮中的氮键合的烷基具有1至4个可被羟基，氨基或磺基取代的碳原子。本发明的化合物可以通过磺化N-烷基取代的-4-羟基-2-喹诺酮，然后进行选择性脱磺酸来制备目的化合物。具有下式的新的单偶氮纤维活性染料及其金属络合物可以通过选自未取代的或取代的苯或萘的胺组分的重氮化从这些磺化化合物制备化合物，含有纤维反应性基团，并将重氮组分偶联到本发明的化合物上。这些染料适用于在碱性试剂存在下，对天然和合成含碳酰胺的纤维，天然的或再生的或合成的含羟基纤维，特别是纤维素纤维材料的染色和印刷。

4. 发明授权

US5599911A Fiber-reactive dyes having a central 1,3,5-triazine ring to which are bonded to a monoazo chromophore having another 1,3,5-triazine moiety and a second chromophore 失效
标题翻译：具有中心1,3,5-三嗪环的纤维反应性染料与具有另一个1,3,5-三嗪部分的单偶氮发色团结合，第二发色团
公开(公告)号：US5599911A
公开(公告)日：1997-02-04
申请号：US296206
申请日：1994-08-25
申请人： Rolf Deitz , Bernhard M uller , Athanassios Tzikas
发明人： Rolf Deitz , Bernhard M uller , Athanassios Tzikas
IPC分类号： C09B62/503 , C09B62/08 , C09B62/44 , C09B62/665 , D06P1/38 , C09B62/006 , C09B62/507
CPC分类号： C09B62/4403 , C09B62/08
摘要： Reactive dyes of the formula ##STR1## in which the variables have the meanings stated in the claims, are described. The dyes according to the invention are particularly suitable for dyeing cellulosic fibre materials and give dyeings with good fastness properties and a high color yield.
摘要翻译：描述了其中变量具有权利要求中所述的含义的式（1）的活性染料。根据本发明的染料特别适用于染色纤维素纤维材料，并赋予具有良好牢度性能和高颜色产率的染色。

5. 发明授权

US5276148A Phenylazobenzenes or naphthylazobenzenes having a plurality of fiber-reactive groups 失效
标题翻译：具有多个纤维反应性基团的苯基偶氮苯或萘基偶氮苯
公开(公告)号：US5276148A
公开(公告)日：1994-01-04
申请号：US886835
申请日：1992-05-22
申请人： Bernd Siegel , Manfred Patsch
发明人： Bernd Siegel , Manfred Patsch
IPC分类号： C09B62/51 , C09B62/44 , C09B62/447 , C09B62/507 , C09B62/513 , C09B62/006 , D06P1/38
CPC分类号： C09B62/4401 , C09B62/447 , C09B62/507
摘要： Reactive dyes of the formula ##STR1## where n is 0 or 1,R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,A is unsubstituted or substituted C.sub.2 -C.sub.8 -alkylene,Y is vinyl or a radical of the formula --CH.sub.2 --CH.sub.2 --Q, whereQ is a group which can be eliminated under alkaline reaction conditions,D.sup.1 is phenyl or naphthyl, where these radicals may be substituted,D.sup.2 is phenylene or naphthylene, where these radicals may be substituted, andZ is a reactive radical,with the proviso thata) n is zero when D.sup.1 is substituted by unsubstituted or substituted phenylazo or by unsubstituted or substituted naphthylazo andb) the reactive radical Z is not devised from the triazine series when n is zero and D.sup.1 is dihydroxysulfonylphenyl or trihydroxysulfonylnaphthyl,are used for dyeing and printing organic substrates containing hydroxyl groups or nitrogen atoms.
摘要翻译：其中n为0或1，R1，R2和R3的式为“IMAGE”的活性染料为氢，C1-C4-烷基或苯基，A为未取代或取代的C2-C8-亚烷基，Y为乙烯基或式为-CH 2 -CH 2 -Q，其中Q为可在碱性反应条件下除去的基团，D1为苯基或萘基，其中这些基团可以被取代，D2为亚苯基或亚萘基，其中这些基团可以被取代，和 Z是反应性基团，条件是当D1被未取代或取代的苯偶氮或未取代或取代的萘基偶氮取代时，a）n为零; b）当n为零时，并未设计出来自三嗪系列的反应性基团Z 是二羟基磺酰基苯基或三羟基磺酰基萘，用于染色和印刷含有羟基或氮原子的有机底物。

6. 发明授权

US4900812A Sulfo group-containing metal phlhalocyanine azo compound having a 6-hydroxypyrid-2-one coupling component radicals having a fiber-reactive group 失效
公开(公告)号：US4900812A
公开(公告)日：1990-02-13
申请号：US149813
申请日：1988-01-29
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B62/016 , C09B62/006 , C09B62/10 , C09B62/26 , C09B62/44 , C09B62/483 , C09B62/517
CPC分类号： C09B62/4403 , C09B62/0068 , Y10S534/01
摘要： Compounds of the formula ##STR1## and water-soluble salts thereof each cation of which is independently a non-chromophoric cation, whereinMe is cobalt, copper or nickel,Pc is the phthalocyanine radical,each R.sub.1 and R.sub.2 is independently hydrogen or C.sub.1-6 alkyl,each R.sub.4 is independently hydrogen, halo, hydroxy, C.sub.1-4 alkoxy, C.sub.1-4 alkyl, carboxy or sulfo,each R.sub.6 is hydrogen, cyano, carbamoyl or ##STR2## wherein An .crclbar. is a non-chromophoric anion,each R.sub.7 is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl, phenylethyl or carboxy,each W is linear or branched C.sub.2-6 alkylene; linear or branched C.sub.3-6 alkylene monosubstituted by hydroxy; linear or branched C.sub.2-6 alkylene interrupted by ##STR3## wherein R.sub.11 is linear or branched C.sub.1-4 alkylene,m is 0 or 1, andthe ** indicates the bond attached to the nitrogen atom of the pyridone ring, or ##STR4## wherein the ** is as set forth above, each Y is a fiber-reactive group,a is 1, 2 or 3,b is 0, 1 or 2,c is 1 or 2, with the provisos that a+b+c does not exceed 4 and that each of the four units of the phthalocyanine nucleus contains a maximum of one substituent selected from those to which a, b and c relate, andn is 0 or 1,whereineach R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.2-4 hydroxyalkyl,each R.sub.5 is independently halo, amino or an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group, andeach R.sub.12 is independently linear or branched C.sub.2-4 -alkylene,and mixtures of such compounds and salts, useful for dyeing and printing hydroxy group- or nitrogen- containing organic substrates, for example leather and fiber materials containing or consisting of natural or synthetic polyamides or of natural or regenerated cellulose, preferably textile material containing or consisting of cotton.

7. 发明授权

US4354968A Azo reactive dyestuffs having an aryl-triazinyl-aryl diazo component 失效
标题翻译：具有芳基 - 三嗪基 - 芳基重氮组分的偶氮活性染料
公开(公告)号：US4354968A
公开(公告)日：1982-10-19
申请号：US23750
申请日：1979-03-26
申请人： Erich Kramer , Horst Nickel , Karl-Heinz Schundehutte
发明人： Erich Kramer , Horst Nickel , Karl-Heinz Schundehutte
IPC分类号： C09B62/006 , C09B62/008 , C09B45/00 , C09B29/22 , C09B45/24
CPC分类号： C09B62/008 , C09B62/006
摘要： Optionally metallized azo dyestuffs which in the form of the free acid correspond to the formula ##STR1## wherein K is the radical of a benzene, naphthalene, pyrazolone, pyridone, pyrimidone, acetoacetic acid arylide or aminopyrazole coupling component;A is a non-ionic substituent;X is ##STR2## wherein W is a direct bond or a bridge member to a C atom of the benzene or naphthalene nucleus or the coupling component K;R is hydrogen or C.sub.1 -C.sub.4 -alkyl;B is a direct bond or a bridge member, especially -CO- or -SO.sub.2 -, to a C atom of Q;Q is a reactive radical;m is 0, 1 or 2;n is 0, 1 or 2;p is 0 or 1;q is 0, 1 or 2; andr is 0 or 1;and their use for the dyeing and printing of natural and regenerated cellulose fibre materials such as cotton and rayon, as well as natural and synthetic polyamide fibre materials, for example those of wool, silk, poly-.epsilon.-caprolactam or polycondensate of hexamethylene-diamine and adipic acid. The dyeings obtained, espeically those on cotton and rayon, are distinguished by good fastness properties, especially fastness to wet processing and to light.
摘要翻译：任选的以游离酸形式的金属化偶氮染料对应于下式：其中K是苯，萘，吡唑啉酮，吡啶酮，嘧啶酮，乙酰乙酸芳基化物或氨基吡唑偶联组分的基团; A是非离子取代基; X是其中W是苯或萘核的C原子或偶联组分K的直接键或桥键元素; R是氢或C 1 -C 4 - 烷基; B是Q的C原子的直接键或桥结构，特别是-CO-或-SO 2 - ; Q是反应性基团; m为0,1或2; n为0,1或2; p为0或1; q是0,1或2; r为0或1; 以及它们用于天然和再生纤维素纤维材料如棉和人造丝的染色和印花，以及天然和合成的聚酰胺纤维材料，例如羊毛，丝绸，聚ε-己内酰胺或六亚甲基二胺的缩聚物和己二酸。获得的染色，特别是在棉和人造丝上的染色，具有良好的牢度特性，特别是湿法加工和光照牢度的区别。

8. 发明授权

US4288363A Novel azo dyes having 2-amino-5-aminomethyl-7-sulfo naphthalene coupling moiety 失效
标题翻译：具有2-氨基-5-氨基甲基-7-磺基萘偶联部分的新型偶氮染料
公开(公告)号：US4288363A
公开(公告)日：1981-09-08
申请号：US23514
申请日：1979-03-23
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C301/00 , C07C303/06 , C07C309/47 , C09B29/01 , C09B29/095 , C09B43/12 , C09B62/006 , C09B62/008 , C09B62/04 , C09B62/085 , C09B62/095 , C09B62/24 , C09B62/245 , C09B62/28 , C09B62/47 , C09B62/473 , C09B62/477 , C09B62/51 , C09B62/515 , C09B63/00
CPC分类号： C09B62/006 , C09B29/0014 , C09B29/0955 , C09B62/043
摘要： Dyestuff intermediates of the formula ##STR1## wherein R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, R.sub.2 represents hydrogen or an acyl radical and Z represents hydrogen or a sulfo group, and the use thereof for the manufacture of azo dyes of the formula ##STR2## wherein D represents the radical of a coupling component, R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, and R.sub.2 represents hydrogen or an acyl radical, or of azo dyes of the formula ##STR3## wherein K is the radical of a coupling component, Z represents hydrogen or the sulfo group, and R.sub.2 represents hydrogen or an acyl radical.
摘要翻译：其中R 1表示氢，1〜8个碳原子的烷基或苯基，R 2表示氢或酰基，Z表示氢或磺基，其制备方法的用途其中D表示偶联组分的基团，R 1表示氢，1至8个碳原子的烷基或苯基，R 2表示氢或酰基，或偶氮染料其中K是偶合组分的基团，Z表示氢或磺基，R2表示氢或酰基。

9. 发明授权

US4092308A 4-Sulphomethyl substituted hydroxypyridone azo dyestuffs 失效
标题翻译： 4-磺基甲基取代的羟基吡啶酮偶氮染料
公开(公告)号：US4092308A
公开(公告)日：1978-05-30
申请号：US736930
申请日：1976-10-29
申请人： Gert Hegar
发明人： Gert Hegar
IPC分类号： C07D213/69 , C07D213/82 , C09B29/42 , C09B31/153 , C09B45/02 , C09B62/006 , C09B29/36 , C09B62/08 , C09B62/24 , C09B62/50
CPC分类号： C07D213/69 , C07D213/82 , C09B29/3621 , C09B31/153 , C09B45/025 , C09B62/006
摘要： Azo compounds of the formula ##STR1## wherein R represents a hydrogen atom, an alkyl or aryl radical, R' represents a hydrogen or halogen atom, a cyano, carboxylic amide, alkylsulphonyl, arylsulphonyl, nitro, nitroso, amino, or acylamino group, and D represents the radical of a diazo component, are valuable dyestuffs for the dyeing of textile materials.
摘要翻译：其中R表示氢原子，烷基或芳基，R'表示氢或卤素原子，氰基，羧酰胺，烷基磺酰基，芳基磺酰基，硝基，亚硝基，氨基或酰基氨基的偶氮化合物， D代表重氮组分的基团，是用于染色纺织材料的有价值的染料。

10. 发明授权

US4033943A Fiber reactive water soluble 2,4,6-triamino, 3-cyano pyridine-(5) azo dyestuffs 失效
标题翻译：纤维反应性水溶性2,4,6-三氨基，3-氰基吡啶 - （5）偶氮染料
公开(公告)号：US4033943A
公开(公告)日：1977-07-05
申请号：US551794
申请日：1975-02-21
申请人： Visvanathan Ramanathan , Angelo Della Casa , Rene DE Montmollin , Gert Hegar , Hans Ulrich Schutz
发明人： Visvanathan Ramanathan , Angelo Della Casa , Rene DE Montmollin , Gert Hegar , Hans Ulrich Schutz
IPC分类号： C07D213/74 , C07D213/82 , C07D213/85 , C09B29/42 , C09B44/08 , C09B44/10 , C09B62/006 , C09B62/008 , D06P3/06 , D06P3/14 , D06P3/66 , C09B29/36 , C09B43/12 , C09B43/16
CPC分类号： C09B44/08 , C09B29/3639 , C09B44/105 , C09B62/0067 , D06P3/06 , D06P3/148 , D06P3/66 , Y10S8/917 , Y10S8/924
摘要： Water-soluble azo dyes of the formula WHEREIN Y is a fiber-reactive group, n is 1 or 2, m is 0, 1 or 2 and the benzene rings A and B may be further substituted are disclosed. They are useful for dyeing nitrogen-containing fibers and cellulose materials and are distinguished by very bright and brilliant shades, possessing good stability, fastness to light, wet processing and fixation.
摘要翻译：公式“IMAGE”的水溶性偶氮染料是纤维反应性基团，n为1或2，m为0,1或2，苯环A和B可进一步被取代。它们可用于染色含氮纤维和纤维素材料，并且具有非常明亮和辉煌的色调，具有良好的稳定性，耐光牢度，湿法加工和固色。

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