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    • 1. 发明申请
    • Anionic monoazo dyes
    • 阴离子单偶氮染料
    • US20050256305A1
    • 2005-11-17
    • US10520964
    • 2003-07-17
    • Michael LennartzSandra Weiss
    • Michael LennartzSandra Weiss
    • C07D251/70C09B29/01C09B29/16C09B43/16D21H21/28C09B62/08
    • C09B43/16Y10S8/919
    • Anionic monoazo dyes of the formula (1) in which A represents 1- or 2-naphthyl residue, which is substituted by a total of one or two sulphonic and/or carboxylic acid groups. R1 represents hydrogen or C1-C4alkyl, each D1 and D2, independently of the other, represent either an amino acid residue resulting from removal of a hydrogen atom from the amino group of the amino acid or the residue —NR2R3, in which each R2 and R3, independently of the other, represent hydrogen, C1-C4alkyl, C2-C6alkyl which is substituted by hydroxy, halogen or cyano, phenyl which is unsubstituted or monosubstituted by hydroxy, halogen, SO3H, C1-C4alkyl or C1-C4alkoxy or alternatively, R2 and R3, together with the nitrogen atom to which they are connected, complete a saturated 5- or 6-membered ring which may contain, in addition to the nitrogen atom, one nitrogen or oxygen atom and which may be further substituted and n is 0 or 1, a process for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.
    • 式(1)的阴离子单偶氮染料其中A代表1-或2-萘基残基,其被总共一个或两个磺酸和/或羧酸基取代。 R 1表示氢或C 1 -C 4烷基,每个D 1和D 2各自独立地表示氢或C 1 -C 4烷基, / SUB>独立地代表从氨基酸的氨基或残基-NR 2 R 3取代氢原子得到的氨基酸残基, 其中每个R 2和R 3各自独立地代表氢,C 1 -C 4烷基, 被羟基,卤素或氰基取代的C 2 -C 6烷基,未被羟基,卤素取代或被羟基取代的苯基, 3个H,C 1 -C 4烷基或C 1 -C 4烷氧基或可选地 R 2和R 3 3以及它们连接的氮原子一起形成饱和的5-或6-元环,除了可以含有 氮原子,一个氮原子或氧原子,并且可以进一步被取代,并且n是0或1,它们的制备方法及其制备方法 e使用这些染料来染色天然或合成材料,特别是纸。
    • 3. 发明授权
    • Anionic acid dyes, processes for their preperation and their use
    • 阴离子染料,其制备方法及其用途
    • US5859216A
    • 1999-01-12
    • US811450
    • 1997-03-03
    • Jean-Marie AdamJean-Pierre Bacher
    • Jean-Marie AdamJean-Pierre Bacher
    • C09B1/34C09B43/16
    • C09B43/16C09B1/343
    • Anionic acid dyes of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 is C.sub.1 -C.sub.8 alkyl, substituted or unsubstituted C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl which are unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, amino, hydroxyl, ureido, halogen, carboxyl or sulfo,or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms,Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colourless organic bridge member,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,W.sub.1 is hydrogen or a radical of the formula --CO--R, in whichR is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl and A.sub.1 is as defined in claim 1.The dyes of the formula (1) are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
    • 式(1)的阴离子染料其中R 1和R 2彼此独立地是氢或取代或未取代的C 1 -C 4烷基,X 1是C 1 -C 8烷基,取代或未取代的C 5 -C 7环烷基,苯基或萘基,其是未取代的 或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,氨基,羟基,脲基,卤素,羧基或磺基取代,或者式-N(R 2)-X 1的基团是环,其可以含有其它杂原子, Y1是下式的基团:其中B1是无色有机桥连构件,R 3是氢或C 1 -C 4烷基,R 4是氢或被取代的 未取代的C1-C4烷基,W1是氢或式-CO-R的基团,其中R是取代或未取代的C1-C8烷基,C5-C7环烷基,苯基或萘基,A1如权利要求1所定义。 式(1)特别适用于染色或印花天然或合成聚酰胺纤维材料。
    • 6. 发明授权
    • Cationic imidazole azo dyes
    • 阳离子咪唑偶氮染料
    • US5708151A
    • 1998-01-13
    • US552153
    • 1995-11-02
    • Peter Mockli
    • Peter Mockli
    • C07D233/88C07D403/12C07D403/14C09B29/36C09B43/16C09B44/16C09B62/085C09B67/22D21H21/28D06P7/00D06P3/70
    • C09B43/16C09B44/16C09B62/085C09B67/0033D21H21/28
    • The cationic imidazole azo dyes of the formulae ##STR1## in which A and A.sub.1 independently of one another are each a radical of the formula ##STR2## Z is the radical of an aliphatic or aromatic diamine, R.sub.1 and R.sub.2 are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or, together with the two nitrogen atoms to which they are attached and with Z, form a 5-, 6- or 7-membered ring, X is the radical of a bridging member, n is 2, 3 or 4, Z.sub.1 is the radical of an aromatic diamine, Z.sub.2 is the radical of an aliphatic diamine, KK is the radical of a coupling component, R.sub.3 and R.sub.4 are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, R.sub.5 and R.sub.6 independently of one another are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and An.sup..crclbar. is a colorless anion, are particularly suitable for the dyeing of paper in red or violet shades having good fastness properties.
    • 其中A和A1彼此独立地分别为式(1)< IMAGE>(2)和< IMAGE>(3)的阳离子咪唑偶氮染料各自为式 是脂族或芳族二胺的基团,R 1和R 2各自为氢或取代或未取代的C 1 -C 4烷基,或与它们所连接的两个氮原子一起并与Z一起形成5-,6-或7- X是桥连基团的基团,n是2,3或4,Z 1是芳族二胺的基团,Z 2是脂族二胺的基团,KK是偶合组分的基团,R3和R4 各自为氢或取代或未取代的C1-C4烷基,R5和R6彼此独立地各自为氢或取代或未取代的C1-C4烷基或C1-C4烷氧基,An( - )为无色阴离子,特别适用于纸的染色 红色或紫色色调具有良好的坚牢度。
    • 9. 发明授权
    • AZO dyes containing a bridge member based on stibene and
morpholino-substituted triazine
    • 含有基于萜烯和吗啉取代的三嗪的桥连构件的AZO染料
    • US5554734A
    • 1996-09-10
    • US460176
    • 1995-06-02
    • Urs Lauk
    • Urs Lauk
    • C09B33/16C09B43/16C09B56/04C09B62/08D06P3/66D06P3/87
    • C09B43/16C09B56/04C09B62/082
    • Azo dyes of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl,R.sub.5 and R.sub.6 are each independently of the other hydrogen, halogen, or unsubstituted or hydroxy-substituted C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; C.sub.2 -C.sub.4 alkanoylamino which is unsubstituted or substituted in the alkyl moiety by hydroxy or C.sub.1 -C.sub.4 alkoxy, or ureido which is unsubstituted or substituted in the amino end group by one or two C.sub.1 -C.sub.4 alkyl groups,Y.sub.1 and Y.sub.2 are each independently of the other amino, N-mono- or N,N-di-C.sub.1 -C.sub.4 alkylamino which is unsubstituted or substituted in the alkyl moiety by hydroxy, sulfo, carboxy or C.sub.1 -C.sub.4 alkoxy; C.sub.5 -C.sub.7 cycloalkylamino which is unsubstituted or substituted in the. cycloalkyl ring by C.sub.1 -C.sub.4 alkyl; phenylamino or N-C.sub.1 -C.sub.4 alkyl-N-phenylamino which are each unsubstituted or substituted in the phenyl ring by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, carboxy, sulfo or halogen; or morpholino or piperidin-1-yl, andA.sub.1 and A.sub.2 are each independently of the other unsubstituted or substituted phenyl or naphthyl, are direct dyes for different substrates, especially cellulosic fibre materials. They are high-temperature stable and are therefore particularly suitable for dyeing polyester/cotton blends with a disperse dye for the polyester fibres under the conditions for dyeing polyester fibres in a single-step, one-bath process.
    • 式(1)的偶氮染料其中R1,R2,R3和R4各自独立地为氢或未取代或取代的C1-C4烷基,R5和R6各自独立地为氢,卤素或未取代或羟基 取代的C 1 -C 4烷基或C 1 -C 4烷氧基; 在烷基部分未被取代或被羟基或C 1 -C 4烷氧基取代的C 2 -C 4烷酰基氨基或在氨基端基中被一个或两个C 1 -C 4烷基取代的脲基,Y 1和Y 2各自独立地为其它氨基 未被取代或在烷基部分被羟基,磺基,羧基或C 1 -C 4烷氧基取代的N-单或N,N-二-C 1 -C 4烷基氨基; 未取代或未取代的C 5 -C 7环烷基氨基。 C1-C4烷基的环烷基环; 苯基氨基或N-C 1 -C 4烷基-N-苯基氨基,其各自未被取代或在苯环中被C1-C4烷基,C1-C4烷氧基,羧基,磺基或卤素取代; 或吗啉代或哌啶-1-基,而A1和A2各自独立地为其它未取代或取代的苯基或萘基,是用于不同底物,特别是纤维素纤维材料的直接染料。 它们是高温稳定的,因此特别适用于在单步一浴工艺中在用于染色聚酯纤维的条件下用聚酯纤维的分散染料染色聚酯/棉混纺织物。