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    • 1. 发明申请
    • Method for recycling of plating solutions
    • 电镀液回收方法
    • US20040256235A1
    • 2004-12-23
    • US10813251
    • 2004-03-30
    • Koujiro Kameyama
    • C25D021/06C25D021/16C23C028/00
    • C25D3/60C22B7/006C22B25/04C23C2/00C23C18/1617C25D21/18Y02P10/234
    • In the conventional plating process, plating solutions are newly prepared and the plating solutions used previously are dumped as industrial wastes, which is accompanied by environmental loads, effluent costs, costs for purchasing new solutions, and the like, and the present invention can recycle a foemer plating solution to prepare a new plating solution, for example, in the following order: a process for preparing a SnnullBi alloy plating solution (S1); a process for an active carbon treatment to remove the completing agent (S2); a process for removing Bi (S3); a process for a sedimenting treatment (S4); and a process for analyzing and correcting Sn plating solution. The recycling of plating solutions eliminates their effluent treatment and reduces environmental loads, effluent costs, and costs for purchasing new solutions. In the administration of the plating solution compositions, the conventional data can be utilized to facilitate the administrating operation.
    • 在传统电镀工艺中,新制备电镀液,先前使用的电镀液作为工业废弃物倾倒,伴随着环境负荷,废水成本,购买新溶液的成本等,本发明可回收 例如按照以下顺序制备新的电镀液:制备Sn-Bi合金电镀液(S1)的方法; 活性炭处理以除去完成剂的方法(S2); 一种去除Bi(S3)的方法; 沉淀处理工艺(S4); 以及用于分析和校正镀锡溶液的工艺。 电镀解决方案的回收消除了其废水处理,减少了环境负荷,污水成本以及购买新解决方案的成本。 在电镀溶液组合物的施用中,可以利用常规数据来促进给药操作。
    • 3. 发明申请
    • Electroplating solution composition control
    • 电镀液组成控制
    • US20030150734A1
    • 2003-08-14
    • US10074489
    • 2002-02-11
    • Applied Materials, Inc.
    • Rajeev BajajRamin EmamiGirish DixitHiral AjmeraRoman Mostovoy
    • C25D021/06C25D021/16C25D017/00
    • H01L21/2885C25D7/123C25D21/06C25D21/18
    • A method and apparatus for removing degraded organics from an electroplating solution by passing at least a portion of electroplating solution through a filter. The apparatus generally includes a deposition cell including a fluid inlet, a fluid reservoir, and at least one filter disposed between the reservoir and the fluid inlet. The apparatus may further include a control valve disposed between the fluid reservoir and the fluid inlet for passing at least a portion of an electroplating solution to a recovery stream including the at least one filter. Embodiments of the invention further include a method generally including the steps of providing a substrate having a seed layer disposed on a surface thereof, disposing the substrate in an electroplating solution, flowing a portion of the electroplating solution through a filter in an amount sufficient to remove an amount of organic additives from the electroplating solution equal to a calculated rate of organic additive degradation, and flowing the electroplating solution to the substrate.
    • 一种通过使至少一部分电镀溶液通过过滤器从电镀溶液中除去有机物的方法和装置。 该装置通常包括沉积池,其包括流体入口,流体储存器以及设置在储存器和流体入口之间的至少一个过滤器。 该装置还可以包括设置在流体储存器和流体入口之间的控制阀,用于将至少一部分电镀溶液传送到包括至少一个过滤器的回收流。 本发明的实施例还包括一种方法,通常包括以下步骤:提供具有设置在其表面上的种子层的基底,将基底设置在电镀溶液中,使电镀溶液的一部分通过过滤器,其量足以去除 来自电镀溶液的一定量的有机添加剂等于计算的有机添加剂降解速率,并将电镀溶液流到基底。
    • 9. 发明申请
    • Method and apparatus for reducing organic depletion during non-processing time periods
    • 在非处理时间段内减少有机物耗尽的方法和装置
    • US20030159936A1
    • 2003-08-28
    • US10085338
    • 2002-02-27
    • Applied Materials, Inc.
    • Srinivas GandikotaChris R. McGuirkDeenesh PadhiSivakami RamanathanMuhammad Atif MalikGirish A. Dixit
    • C25D021/06C25D021/16C25D017/00
    • C25D21/18C25D21/14
    • Embodiments of the invention generally provide an apparatus and method for replenishing organic molecules in an electroplating bath. The replenishment process of the present invention may occur on a real-time basis, and therefore, the concentration of organics minimally varies from desired concentration levels. The replenishment method generally includes conducting pre-processing depletion measurements in order to determine organic depletion rates per current density applied in the electroplating system. Once the organic depletion rates per current density are determined, these depletion rates may be applied to an electroplating processing recipe to calculate the volume of organic depletion per recipe step. The calculated volume of organic depletion per recipe step may then be used to determine the volume of organic molecule replenishment per unit of time that is required per recipe step in order to maintain a desired concentration of organics in the plating solution. The calculated replenishment volume may then be added to the processing recipe so that the replenishment process may occur at real-time during processing periods. The apparatus generally includes a selectively actuated valve in communicaiton with a fluid delivery line, wherein the valve is configured to fluidly isolate a plating cell during a non-processing time period. The valve may be controlled by a system controller, and thus, the fluid level in the cell may be controlled during a non-processing time period.
    • 本发明的实施方案通常提供用于在电镀浴中补充有机分子的装置和方法。 本发明的补充方法可以在实时的基础上进行,因此有机物的浓度最小化从期望的浓度水平变化。 补充方法通常包括进行预处理耗尽测量,以便确定在电镀系统中施加的每个电流密度的有机耗尽率。 一旦确定了每个电流密度的有机耗尽率,则这些耗尽率可以应用于电镀处理配方以计算每个配方步骤的有机耗尽量。 然后可以使用每个配方步骤的计算的有机耗尽体积来确定每个配方步骤所需的每单位时间的有机分子补充体积,以维持电镀溶液中所需的有机物浓度。 计算的补充量然后可以被添加到处理配方中,使得补货过程可以在处理时段期间实时发生。 该装置通常包括与流体输送管线通信的选择性致动的阀,其中阀被配置为在非处理时间段期间流体地隔离电镀槽。 阀可以由系统控制器控制,因此,可以在非处理时间段期间控制单元中的液位。