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    • 4. 发明授权
    • Microporous sheet material, method of making and articles made therewith
    • 微孔板材,制造方法和制成的制品
    • US4539256A
    • 1985-09-03
    • US583288
    • 1984-02-28
    • Gene H. Shipman
    • Gene H. Shipman
    • B29C55/00C08J5/18C08J9/228C08J9/28H01M2/14B29D27/04B32B3/10
    • B01D67/002B01D71/06B29C55/005C08J5/18C08J9/228C08J9/28H01M2/14C08J2201/0543C08J2201/0546Y10T428/249978Y10T428/249986Y10T428/249987Y10T428/24999
    • A method of making a microporous material is provided which comprises the steps of melt blending crystallizable thermoplastic polymer with a compound which is miscible with the thermoplastic polymer at the melting temperature of the polymer but phase separates on cooling at or below the crystallization temperature of the polymer, forming a shaped article of the melt blend, cooling the shaped article to a temperature at which the polymer crystallizes to cause phase separation to occur between the thermoplastic polymer and the compound to provide an article comprising a first phase comprising particles of crystallized thermoplastic polymer in a second phase of said compound, orienting the article in at least one direction to provide a network of interconnected micropores throughout. The microporous article comprises about 30 to 80 parts by weight crystallizable thermoplastic polymer and about 70 to 20 parts by weight of the compound. The oriented article has a microporous structure characterized by a multiplicity of spaced randomly dispersed, equiaxed, non-uniform shaped particles of the thermoplastic polymer which are coated with the compound. Adjacent thermoplastic particles within the article are connected to each other by a plurality of fibrils consisting of the thermoplastic polymer. The fibrils radiate in three dimensions from each particle. The compound may be removed from the sheet article. e.g., by solvent extraction. The preferred article is a sheet material.
    • 提供了一种制备微孔材料的方法,其包括以下步骤:将可结晶的热塑性聚合物与在聚合物的熔融温度下与热塑性聚合物混溶的化合物熔融共混,但是在聚合物的结晶温度或低于聚合物的结晶温度下冷却时相分离 ,形成熔融共混物的成形制品,将成型制品冷却至聚合物结晶的温度,使得在热塑性聚合物和化合物之间发生相分离,以提供包含第一相的制品,该第一相包含结晶的热塑性聚合物颗粒 所述化合物的第二阶段,使制品沿至少一个方向定向以提供整个相互连接的微孔的网络。 该微孔制品包含约30至80重量份的可结晶的热塑性聚合物和约70至20重量份的该化合物。 定向制品具有微孔结构,其特征在于涂覆有化合物的多个间隔开的无规分散的等轴不均匀成型的热塑性聚合物颗粒。 制品内相邻的热塑性颗粒通过由热塑性聚合物组成的多个原纤维相互连接。 原纤维从每个颗粒三维辐射。 化合物可以从片材制品中除去。 例如通过溶剂萃取。 优选的物品是片材。
    • 6. 发明授权
    • Method of gelling a gelation shrinkable, polymer casting solution
    • 胶凝收缩法,聚合物浇铸溶液的方法
    • US4496502A
    • 1985-01-29
    • US465548
    • 1983-02-10
    • Oleh KutowyWilliam L. ThayerSrinivasa Sourirajan
    • Oleh KutowyWilliam L. ThayerSrinivasa Sourirajan
    • B01D69/14B05D7/22B29D27/04
    • B01D69/06
    • A gelation shrinkable, polymer casting solution, that has been cast on the internal surface of a tubular support is gelled using pressure gelation by supporting the tubular support with one end higher than the other and pumping gelation liquid upwardly along the tube at a velocity in the range of the order of 10 to 100 cm/second and at a pressure of at least 10 kPa gauge at all points of contact between the gelation liquid and polymer casting solution. This achieves asymmetricity of the pore structure and ensures that the cast polymer solution is continuously in contact with the tubular support as a gelled membrane. If the tubular support is a porous, tubular support, then preferably the pressure gelation is continued until gelation liquid has passed through the cast polymer solution and the porous support removing solvent and any additives from the cast polymer solution.
    • 已经浇注在管状支撑体的内表面上的凝胶化可收缩的聚合物浇铸溶液通过使用压力凝胶化而凝胶化,其中一端高于另一端并且以一定的速度向上泵送凝胶化液体, 范围为10至100厘米/秒,并且在凝胶液和聚合物浇铸溶液之间的所有接触点处为至少10千帕量表的压力。 这实现了孔结构的不对称性,并确保浇注聚合物溶液作为凝胶膜与管状载体连续接触。 如果管状载体是多孔的管状载体,则优选继续加压凝胶,直到凝胶化液体已经通过流延聚合物溶液和多孔载体去除溶剂以及来自流延聚合物溶液的任何添加剂。
    • 7. 发明授权
    • Method of open forming an expanded polyester resin article involving a
controlled induction period
    • 开放形成涉及受控诱导期的膨胀聚酯树脂制品的方法
    • US4476076A
    • 1984-10-09
    • US291404
    • 1981-08-10
    • Glen W. Saidla
    • Glen W. Saidla
    • C08G18/30C08J9/08B29D27/04
    • C08J9/08C08G18/30
    • A method of forming a synthetic article by open forming techniques by providing a fluid composition containing a predominant quantity of synthetic resin and having a capability for delayed, substantial gas evolution. To produce reinforced articles, the composition is applied to the reinforcement at a temperature below a predetermined gas evolution temperature and is subjected to fluid spreading conditions to thoroughly wet the elements of reinforcement. Subsequently, the fluid composition reaches the predetermined temperature, the resultant gas evolution effectively expands the composition while it remains in thorough wetting contact with the reinforcement elements, and the resin then solidifies and cures to produce an intimately reinforced, expanded article. In important embodiments the preponderant gas evolution results from the reaction of an organic hydroperoxide with an isocyanate in the presence of a surfactant. The invention is especially applicable to the expansion of polyester resins but has numerous other applications.
    • 一种通过开放成型技术形成合成制品的方法,该方法通过提供含有主要量的合成树脂的流体组合物并且具有延迟,显着的气体逸出的能力。 为了生产增强制品,将组合物在低于预定气体逸出温度的温度下施加到增强材料上,并且经受流体扩散条件以彻底润湿增强材料。 随后,流体组合物达到预定温度,所产生的气体逸出有效地使组合物膨胀,同时保持与增强元件的彻底润湿接触,然后树脂固化并固化以产生紧密增强的膨胀制品。 在重要的实施方案中,主要气体逸出是由有机氢过氧化物与异氰酸酯在表面活性剂存在下的反应产生的。 本发明特别适用于聚酯树脂的膨胀,但具有许多其它应用。
    • 8. 发明授权
    • Method for manufacturing microporous membrane
    • 微多孔膜的制造方法
    • US4466931A
    • 1984-08-21
    • US405226
    • 1982-08-05
    • Gerald B. Tanny
    • Gerald B. Tanny
    • B01D39/16B01D67/00B01D69/10B29C67/20C08F2/04C08F2/46C08J9/26C08J9/28B29D27/04
    • B01D67/0006B29C67/202C08J9/28C08J2201/0543C08J2201/0546
    • The starting materials for the practice of the present invention are (1) one or more organic monomers or oligomers which upon irradiation very rapidly undergo a polymerization reaction to form a solid polymer; and (2) a liquid vehicle in which the one or more organic monomers or oligomers are soluble but in which the polymer formed is insoluble. For the manufacture of microporous membrane in accordance with the invention the monomers or oligomers are dissolved in the liquid vehicle, the resulting solution is formed into a thin layer, and the thin layer of the solution is then irradiated as with ultraviolet or electron beam radiation whereupon the rapid polymerization reaction immediately ensues and the polymer formed immediately segregates from the vehicle thereby resulting in microporous membrane from which the vehicle can be removed as by evaporation or washing. Because the radiation-induced polymerization reaction and the segregation of the polymer formed are so rapid, the membrane formed has cells and communications therebetween of very small dimensions thereby providing the microporous structure. Where ultraviolet radiation is used the solution also includes a photoinitiator.
    • 用于实施本发明的起始材料是(1)一种或多种有机单体或低聚物,其在照射时非常快速地进行聚合反应以形成固体聚合物; 和(2)一种或多种有机单体或低聚物可溶于其中形成的聚合物不溶的液态载体。 为了制造根据本发明的微多孔膜,将单体或低聚物溶解在液体载体中,将所得溶液形成为薄层,然后用紫外线或电子束辐射照射该溶液的薄层, 迅速聚合反应立即发生,形成的聚合物立即与载体分离,从而产生微孔膜,通过蒸发或洗涤可以从中除去载体。 因为辐射诱导的聚合反应和形成的聚合物的偏析如此之快,所形成的膜具有非常小尺寸的电池和通信,从而提供微孔结构。 在使用紫外线的情况下,溶液还包括光引发剂。