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    • 7. 发明申请
    • FLAME RETARDED,THEMOPLASTIC COMPOSITION, PROCESS FOR MAKING SAME AND ARTICLE CONTAINING SAME
    • 阻燃剂,塑料组合物,其制备方法和含有其的制品
    • US20120123004A1
    • 2012-05-17
    • US13145677
    • 2010-02-02
    • Jeffrey StowellRonald PirrelliSophia Dashevsky
    • Jeffrey StowellRonald PirrelliSophia Dashevsky
    • C08L75/04C08J9/00C09K21/12C08K5/527
    • C08J9/0038C08G18/48C08G2101/0008C08G2101/005C08G2350/00C08J9/145C08J2375/04C08K5/527C08L75/04
    • There is provided herein a composition comprising: (a) a flexible polyurethane foam-forming mixture and; an effective flame retarding amount of at least one non halogen-containing cyclic phosphate ester of the general formula (I): wherein R1 and R2, are the same or different, linear or branched alkyl group containing from up to about 10 carbon atoms, optionally containing heteroatom substituents, provided that R1 and R2 are not both methyl; and R3-R7 are each independently hydrogen or the same or different linear or branched alkyl group containing up to about 4 carbon atoms, optionally containing heteroatom substituents; provided that the cyclic phosphate ester is a liquid or is substantially soluble in at least one different liquid flame retardant and/or the hydroxyl-containing component of the flexible polyurethane foam-forming mixture; the cyclic phosphate ester of formula (I) contains at least 8.5 weight percent phosphorous based on the total weight of any phosphorous containing component(s); and, provided that the composition is in the absence of melamine compound. There is also provided a flame retardant additive composition comprising the cyclic phosphate ester of formula (I) and at least one different liquid flame retardant. Further, there is provided a process of making a flame retarded polyurethane foam mixture.
    • 本文提供了一种组合物,其包含:(a)柔性聚氨酯泡沫形成混合物; 有效阻燃量的至少一种通式(I)的非卤素环状磷酸酯:其中R1和R2是相同或不同的含有至多约10个碳原子的直链或支链烷基,任选地 含有杂原子取代基,条件是R1和R2不同时为甲基; 和R 3 -R 7各自独立地为氢或含有至多约4个碳原子的相同或不同的直链或支链烷基,任选含有杂原子取代基; 条件是环状磷酸酯是液体或基本上可溶于柔性聚氨酯泡沫形成混合物的至少一种不同的液体阻燃剂和/或含羟基的组分; 基于任何含磷组分的总重量,式(I)的环状磷酸酯含有至少8.5重量%的磷; 并且条件是组合物不存在三聚氰胺化合物。 还提供了包含式(I)的环状磷酸酯和至少一种不同的液体阻燃剂的阻燃添加剂组合物。 此外,提供了制造阻燃聚氨酯泡沫混合物的方法。
    • 8. 发明申请
    • PHENOLIC FOAM
    • 酚醛泡沫
    • US20110124257A1
    • 2011-05-26
    • US11991533
    • 2006-09-08
    • Vincent CoppockRuud ZeggelaarHiroo TakahashiToshiyuki Kato
    • Vincent CoppockRuud ZeggelaarHiroo TakahashiToshiyuki Kato
    • C08J9/06C08K3/26C08K5/12B32B5/18
    • C08J9/145C08J9/0066C08J9/149C08J2203/14C08J2203/142C08J2361/06C08J2361/10C08L71/08Y10T428/249953Y10T442/647
    • A phenolic foam is made by foaming and curing a formable phenolic resin composition that comprises a phenolic resin, a blowing agent, an acid catalyst and an inorganic filler. The blowing agent comprises a blend of chlorinated aliphatic hydrocarbon containing 2 to 5 carbon atoms and an aliphatic hydrocarbon containing from 3 to 6 carbon atoms mixed in a ratio of 60/40 to 95/5 parts by weight. The inorganic filler is at least one selected from a metal hydroxide, a metal oxide, a metal carbonate and metal powder. The phenolic foam has a pH of 5 or more and a water uptake less than 1 kg/m2. A phenolic foam with a higher pH value compared with conventional phenolic foam reduces corrosion risk when in contact with metallic materials. The phenolic foam maintains excellent long-term stable thermal insulation performance, low water uptake and fire resistance performance and by using the said blowing agent, does not harm the environment as an ozone or global warming depleting material.
    • 通过发泡和固化包含酚醛树脂,发泡剂,酸催化剂和无机填料的可成形酚醛树脂组合物来制备酚醛泡沫。 发泡剂包含含有2至5个碳原子的氯代脂族烃和含有3-6个碳原子的脂族烃的混合物,其混合比例为60/40至95/5重量份。 无机填料是选自金属氢氧化物,金属氧化物,金属碳酸盐和金属粉末中的至少一种。 酚醛泡沫体的pH为5以上,吸水量小于1kg / m 2。 与常规酚醛泡沫相比,具有较高pH值的酚醛泡沫体在与金属材料接触时可降低腐蚀风险。 酚醛泡沫塑料具有优异的长期稳定的隔热性能,低吸水性和耐火性能,并且通过使用所述发泡剂,不会对臭氧或全球变暖消耗材料造成危害。