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    • 2. 发明授权
    • Methods for producing a polyol and a polymer dispersed polyol
    • 制备多元醇和聚合物分散多元醇的方法
    • US06815467B2
    • 2004-11-09
    • US10197528
    • 2002-07-18
    • Yoshinori ToyotaAkio HorieHiroshi WadaKayoko SugiyamaEtsuko Akagi
    • Yoshinori ToyotaAkio HorieHiroshi WadaKayoko SugiyamaEtsuko Akagi
    • C08G1828
    • C08G65/2696C08G18/0857C08G18/4063C08G18/4072C08G18/4866C08G18/657C08G18/7607C08G65/02C08G65/2663C08G2101/0008C08G2101/005C08G2101/0083C08J2205/06
    • A method for producing a polyoxyalkylene polyol which comprises subjecting propylene oxide and ethylene oxide to ring-opening addition polymerization with an initiator in the presence of a catalyst, wherein the polyoxyalkylene polyol is a polyoxyalkylene polyol obtained by subjecting propylene oxide to ring-opening addition polymerization with an initiator in the presence of a double metal cyanide complex catalyst to form an oxypropylene block chain, subjecting ethylene oxide and propylene oxide to ring-opening addition polymerization randomly to form an oxyalkylene random chain, changing the catalyst and subjecting ethylene oxide to ring-opening addition polymerization in the presence of an alkali metal catalyst to form an oxyethylene block chain, and the polyoxyalkylene polyol is a polyoxyalkylene polyol having a hydroxyl value of from 5 to 56 mgKOH/g, a proportion of an initiator residue of at most 25 mass %, a proportion of the oxypropylene block chain of from 5 to 50 mass %, a total oxyethylene group content of from 5 to 60 mass %, and a ratio of primary hydroxyl groups among terminal hydroxyl groups of at least 60 mol %.
    • 一种聚氧化烯多元醇的制造方法,其特征在于,在催化剂的存在下,使用环氧丙烷与环氧乙烷进行开环加成聚合,其中,所述聚氧化烯多元醇是通过使环氧丙烷进行开环加成聚合得到的聚氧化烯多元醇 在双金属氰化物配合物催化剂的存在下引发剂形成氧化丙烯嵌段链,使环氧乙烷和环氧丙烷随机开环加成聚合形成氧化烯无规链,改变催化剂并使环氧乙烷进行环 - 在碱金属催化剂存在下开环加成聚合形成氧乙烯嵌段链,聚氧化烯多元醇为羟值为5〜56mgKOH / g的聚氧化烯多元醇,引发剂残基的比例为25质量%以下 %,氧丙烯嵌段链的比例为5〜50质量%,总计 氧乙烯基含量为5〜60质量%,末端羟基的伯羟基比例为60摩尔%以上。
    • 5. 发明授权
    • Solution of a polyurethane in a polyol and a process for using such a
solution in the production of polyurethane plastics
    • 聚氨酯在多元醇中的溶液以及在制备聚氨酯塑料中使用这种溶液的方法
    • US4371630A
    • 1983-02-01
    • US236949
    • 1981-02-23
    • Klaus KonigHans-Walter IllgerPeter SeifertHolger Meyborg
    • Klaus KonigHans-Walter IllgerPeter SeifertHolger Meyborg
    • C08G18/00C08G18/08C08G18/65C08G18/66C08L75/04C08G18/14C08G18/32C08G18/42
    • C08G18/0857C08L75/04Y10S521/914
    • A solution of a polyurethane in a polyol is made from (a) the reaction product of a polyisocyanate and a diprimary diol, and (b) a polyether in which the reaction product constitutes from 3 to 60 wt. % of the solution. Suitable diprimary diols have a molecular weight of from 90 to 800 and a structure at both hydroxyl groups corresponding to the general formula: ##STR1## in which R.sub.1 represents chlorine, an alkyl, cycloalkyl, aralkyl or aryl radical having from 1 to 10 carbon atoms, which carbon atoms may be substituted or interrupted by chlorine, ester groups, ether groups, amide groups, urethane groups or nitrile groups, andR.sub.2 represents hydrogen or a radical within the definition of R.sub.1.Polyethers which may be employed have at least two hydroxyl groups (at least 80% of which are secondary hydroxyl groups) and an average molecular weight of from 500 to 12,000. The disclosed solutions are particularly useful in the production of flexible polyurethane plastics which are suitable for flamecoating and high frequency bonding.
    • 聚氨酯在多元醇中的溶液由(a)多异氰酸酯与二元二元醇的反应产物和(b)反应产物构成3〜60重量%的聚醚制成。 %的解决方案。 合适的二原子二醇的分子量为90至800,并且在两个羟基上的结构对应于以下通式:其中R 1表示氯,具有1至10个碳原子的烷基,环烷基,芳烷基或芳基 ,哪些碳原子可以被氯,酯基,醚基,酰胺基,氨基甲酸酯基或腈基取代或中断,并且R 2表示氢或R 1定义中的基团。 可以使用的聚醚具有至少两个羟基(其中至少80%是仲羟基),平均分子量为500至12,000。 所公开的解决方案在生产柔性聚氨酯塑料时特别有用,这些塑料适合于熔融和高频粘合。
    • 10. 发明授权
    • Wood adhesives
    • 木材胶粘剂
    • US07056415B2
    • 2006-06-06
    • US10014053
    • 2001-12-11
    • Walter Meckel
    • Walter Meckel
    • C08G18/10C08G18/40
    • C09J175/04C08G18/0857C08G18/10C08G18/409C08G18/7664C08G18/307
    • The present invention relates to a process for bonding two or more wood substrates by using as the adhesive isocyanate-terminated prepolymers having an isocyanate content of 8 to 20 wt. % and containing the reaction product of a) at least one organic polyisocyanate with b) at least one organic polyhydroxyl compound containing the reaction products of i) organic polyisocyanates with ii) polyamines, hydrazines and/or hydrazides having primary and/or secondary amino groups dispersed in a iii) polyethers having at least two hydroxyl groups and a number average molecular weight of 500 to 12,000; and, the present invention also relates to the bonded substrates obtained by this process.
    • 本发明涉及通过使用具有异氰酸酯含量为8〜20重量%的异氰酸酯封端的预粘合剂的粘合剂来粘合两个或多个木质基材的方法。 并且含有a)至少一种有机多异氰酸酯与b)至少一种含有i)有机多异氰酸酯与ii)有机多异氰酸酯的反应产物的有机多羟基化合物与ii)具有伯和/或仲氨基的多胺,肼和/或酰肼的反应产物 分散在iii)具有至少两个羟基并且数均分子量为500至12,000的聚醚; 并且本发明还涉及通过该方法获得的粘合基材。