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1. 发明申请

US20160052867A1 POLYETHERAMINES BASED ON 1,3-DIALCOHOLS 审中-公开
标题翻译：基于1,3-二醇的聚己胺
公开(公告)号：US20160052867A1
公开(公告)日：2016-02-25
申请号：US14780603
申请日：2014-03-27
申请人： BASF SE
发明人： Sophia EBERT , Björn LUDOLPH , Christof W. WIGBERS , Steffen MAAS , Frank HUELSKOETTER , Stefano SCIALLA , Dieter BOECKH , Kevin CHRISTMAS , Amy EICHSTADT WAUN , Brian J. LOUGHNANE , Darren REES , Christian EIDAMSHAUS , Monika CHARRAK , Alexander PANCHENKO
IPC分类号： C07C217/08 , C07C213/02 , C07C41/03 , C08G59/50
CPC分类号： C07C217/08 , A61K8/45 , A61K8/86 , A61Q5/02 , A61Q19/10 , C07C41/03 , C07C211/01 , C07C211/02 , C07C211/09 , C07C211/13 , C07C213/02 , C08G59/504 , C11D1/44 , C11D3/3707
摘要： This invention relates to polyetheramines based on 1,3-dialcohols, in particular to an etheramine mixture comprising at least 90% by weight, based on the total weight of the etheramine mixture, of anamine of Formula (I) and/or (II), wherein R1-R12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R1-R6 and at least one of R7-R12 is different from H, wherein A1-A9 are independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, preferably 2-10 carbon atoms, most preferably 2-5 carbon atoms, wherein Z1-Z4 are independently selected from OH or NH2, wherein at least one of Z1-Z2 and at least one of Z3-Z4 is NH2, and wherein the sum of x+y is in the range of from 2 to 200, wherein x≧1 and y≧1; and x1+y1 is in the range of from 2 to 200, preferably 2-20, most preferably 2-10, wherein x1≧1 and y1≧1.
摘要翻译：本发明涉及基于1,3-二醇的聚醚胺，特别是涉及基于醚胺混合物的总重量至少90重量％的式（I）和/或（II）胺的胺的醚胺混合物，其中R1-R12独立地选自H，烷基，环烷基，芳基，烷基芳基或芳烷基，其中R1-R6和R7-R12中的至少一个不同于H，其中A1-A9独立地选自具有2至18个碳原子，优选2-10个碳原子，最优选2-5个碳原子的直链或支链亚烷基，其中Z1-Z4独立地选自OH或NH2，其中Z1-Z2和至少一个 Z 3 -Z 4中的一个是NH 2，并且其中x + y的总和在2至200的范围内，其中x≥1且y≥1; x1 + y1在2〜200的范围内，优选为2-20，最优选为2-10，其中x1≥1，y1≥1。

2. 发明申请

US20180354799A1 METHOD FOR POLYMER REMOVAL FROM SINGLE-WALLED CARBON NANOTUBES 审中-公开
公开(公告)号：US20180354799A1
公开(公告)日：2018-12-13
申请号：US15618242
申请日：2017-06-09
申请人： NATIONAL RESEARCH COUNCIL OF CANADA
发明人： Jianfu DING , Zhao LI , Patrick Roland Lucien MALENFANT
IPC分类号： C01B32/159 , C08F32/08 , C08F36/04
CPC分类号： C01B32/159 , B82Y30/00 , C01B2202/02 , C07C211/02 , C07D213/06 , C08F32/08 , C08F36/04
摘要： Processes for selectively dispersing semi-conducting single-walled carbon nanotubes (sc-SWCNTs) in a solvent. One process comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs, in which the amine partially displaces the conjugate polymer associated with the sc-SWNTs dispersed in the solvent. Another process comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs, with the proviso that the amine excludes EDTA. Also, a process for displacement of a conjugated polymer from the surface of semi-conducting single-walled carbon nanotubes (sc-SWCNTs) dispersed in a solvent, which comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs.

3. 发明申请

US20150246875A1 FLUOROSURFACTANTS 有权
标题翻译：氟化物
公开(公告)号：US20150246875A1
公开(公告)日：2015-09-03
申请号：US14416003
申请日：2013-07-16
申请人： MERCK PATENT GMBH
发明人： Reiner Friedrich , Gerhard Jonschker , Fanny Schooren , Christian Depner , Steffen Schellenberger
IPC分类号： C07C309/17 , C07C69/657 , C07C43/13
CPC分类号： C07C309/17 , C07C19/08 , C07C43/12 , C07C43/137 , C07C69/003 , C07C69/657 , C07C69/66 , C07C211/02 , C07C211/15 , C11D1/004
摘要： The present invention relates to novel compounds containing fluorinated end groups, to the use thereof as surface-active substances, and to compositions comprising these compounds.
摘要翻译：本发明涉及包含氟化端基的新化合物，其用作表面活性物质，以及包含这些化合物的组合物。

4. 发明申请

US20140309460A1 INCREASING THE MOLAR MASS OF POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 审中-公开
标题翻译：通过均相催化的醇醇胺化增加聚烯丙基胺的摩尔质量
公开(公告)号：US20140309460A1
公开(公告)日：2014-10-16
申请号：US14357822
申请日：2012-11-19
申请人： BASF SE
发明人： Julia Strautmann , Thomas Schaub , Stephan Hueffer , Rocco Paciello
IPC分类号： C07C209/16 , C07C211/02
CPC分类号： C07C209/16 , C07C211/02 , C08G73/0213
摘要： Process for increasing the molar mass of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, which comprises carrying out a reaction of the polyalkylenepolyamines in a reactor with elimination of water in the presence of a homogeneous catalyst and removing the water of reaction from the reaction system. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
摘要翻译：通过均相催化醇胺化来提高聚亚烷基多胺的摩尔质量的方法，其包括在均相催化剂存在下进行反应中的聚亚烷基多胺与反应器中的水反应，并从反应体系中除去反应水。可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的内聚力促进剂，树脂的交联剂/固化剂，油漆的底漆，乳液漆的湿粘合促进剂，络合剂和絮凝剂，渗透助剂木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

5. 发明授权

US08211949B2 Functionalized long-chain olefin mixtures and uses therefor 有权
标题翻译：官能化长链烯烃混合物及其用途
公开(公告)号：US08211949B2
公开(公告)日：2012-07-03
申请号：US12211583
申请日：2008-09-16
申请人： Pierre T. Varineau , Brian W. Kolthammer , Aaron W. Sanders , David A. Wilson , Kara S. Weber , Robert Kirk Thompson , Cynthia L. Rand , Thomas C. Eisenschmid
发明人： Pierre T. Varineau , Brian W. Kolthammer , Aaron W. Sanders , David A. Wilson , Kara S. Weber , Robert Kirk Thompson , Cynthia L. Rand , Thomas C. Eisenschmid
IPC分类号： C09K3/00 , C11D1/12 , C11D1/68 , C11D1/722 , C11D1/40 , C11D1/825 , C07C309/20 , C07C209/24 , C07C45/50 , C07C27/20 , B01F17/02 , B01F17/16 , B01F17/38 , B01F17/32 , B01D12/00
CPC分类号： C07C2/36 , C07C29/16 , C07C43/11 , C07C209/26 , C07C303/06 , C07C2531/24 , C08F110/02 , Y10S516/909 , Y10S516/914 , Y10S516/92 , C07C211/02 , C07C309/20 , C07C31/125
摘要： Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or to sulfates, sulfonates, sulfones, sulfides, or sulfoxides by direct sulfonation. The aldehydes may then be hydrogenated to form alcohols, or aminated to form amines or amides. The olefins starting mixture may be acquired as a byproduct of the tetramerization of ethylene in the presence of certain chromium-containing tetramerization catalysts. The functionalized mixtures, and derivatives prepared therefrom such as alkoxylates prepared from the alcohols, may be useful as surfactants that may offer improved performance in many applications, while their preparation based on a byproduct mixture reduces their cost and also reduces waste-handling issues for this non-targeted stream.
摘要翻译：长链（C10-C20）烯烃的新型混合物通过使用OXO方法转化为醛官能化，或通过直接磺化转化为硫酸盐，磺酸盐，砜，硫化物或亚砜。然后可将醛氢化形成醇，或胺化形成胺或酰胺。烯烃起始混合物可以在某些含铬四聚催化剂存在下作为乙烯四聚的副产物获得。官能化混合物和由其制备的衍生物，例如由醇制备的烷氧基化物，可用作可在许多应用中提供改进性能的表面活性剂，而其基于副产物混合物的制备降低了它们的成本，并且还减少了废物处理问题非目标流。

6. 发明申请

US20090078910A1 FUNCTIONALIZED LONG-CHAIN OLEFIN MIXTURES AND USES THEREFOR 有权
标题翻译：功能化的长链烯烃混合物及其用途
公开(公告)号：US20090078910A1
公开(公告)日：2009-03-26
申请号：US12211583
申请日：2008-09-16
申请人： Pierre T. Varineau , Brian W. Kolthammer , Aaron W. Sanders , David A. Wilson , Kara S. Weber , Robert Kirk Thompson , Cynthia L. Rand , Thomas C. Eisenschmid
发明人： Pierre T. Varineau , Brian W. Kolthammer , Aaron W. Sanders , David A. Wilson , Kara S. Weber , Robert Kirk Thompson , Cynthia L. Rand , Thomas C. Eisenschmid
IPC分类号： C09K3/00
CPC分类号： C07C2/36 , C07C29/16 , C07C43/11 , C07C209/26 , C07C303/06 , C07C2531/24 , C08F110/02 , Y10S516/909 , Y10S516/914 , Y10S516/92 , C07C211/02 , C07C309/20 , C07C31/125
摘要： Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or to sulfates, sulfonates, sulfones, sulfides, or sulfoxides by direct sulfonation. The aldehydes may then be hydrogenated to form alcohols, or aminated to form amines or amides. The olefins starting mixture may be acquired as a byproduct of the tetramerization of ethylene in the presence of certain chromium-containing tetramerization catalysts. The functionalized mixtures, and derivatives prepared therefrom such as alkoxylates prepared from the alcohols, may be useful as surfactants that may offer improved performance in many applications, while their preparation based on a byproduct mixture reduces their cost and also reduces waste-handling issues for this non-targeted stream.
摘要翻译：长链（C10-C20）烯烃的新型混合物通过使用OXO方法转化为醛官能化，或通过直接磺化转化为硫酸盐，磺酸盐，砜，硫化物或亚砜。然后可将醛氢化形成醇，或胺化形成胺或酰胺。烯烃起始混合物可以在某些含铬四聚催化剂存在下作为乙烯四聚的副产物获得。官能化混合物和由其制备的衍生物，例如由醇制备的烷氧基化物，可用作可在许多应用中提供改进性能的表面活性剂，而其基于副产物混合物的制备降低了它们的成本，并且还减少了废物处理问题非目标流。

7. 发明授权

US06492558B2 Preparation of n-butylamines 失效
标题翻译：正丁胺的制备
公开(公告)号：US06492558B2
公开(公告)日：2002-12-10
申请号：US10025539
申请日：2001-12-26
申请人： Frank Funke , Ulrich Steinbrenner , Peter Zehner , Ralf Böhling , Wolfgang Harder
发明人： Frank Funke , Ulrich Steinbrenner , Peter Zehner , Ralf Böhling , Wolfgang Harder
IPC分类号： C07C20960
CPC分类号： C07C209/70 , C07C209/60 , C07C211/02 , C07C211/09 , C07C211/07
摘要： Process for the preparation of n-butylamines where n-butenylamines are firstly prepared by reacting 1,3-butadiene in the form of a 1,3-butadiene containing mixture obtained during the cracking of petroleum fractions or during the dehydrogenation of LPG or LNG or from GTL technology with a primary amine and/or a secondary amine under hydroaminating conditions, and the resulting butenylamine(s) are then reacted in a second process stage under hydrogenating and transalkylating conditions.
摘要翻译：正丁胺的制备方法，其中首先通过在石油馏分裂化期间或在LPG或LNG的脱氢期间获得的1,3-丁二烯混合物形式的1,3-丁二烯反应制备正丁烯基胺，或在氢化条件下从具有伯胺和/或仲胺的GTL技术中获得的丁烯基胺在第二工艺阶段在氢化和烷基转移条件下反应。

8. 发明申请

US20020169319A1 Preparation of n-butylamines 失效
标题翻译：正丁胺的制备
公开(公告)号：US20020169319A1
公开(公告)日：2002-11-14
申请号：US10025539
申请日：2001-12-26
发明人： Frank Funke , Ulrich Steinbrenner , Peter Zehner , Ralf Bohling , Wolfgang Harder
IPC分类号： C07D241/04 , C07C29/24
CPC分类号： C07C209/70 , C07C209/60 , C07C211/02 , C07C211/09 , C07C211/07
摘要： Process for the preparation of n-butylamines where n-butenylamines are firstly prepared by reacting 1,3-butadiene in the form of a 1,3-butadiene-containing mixture obtained during the cracking of petroleum fractions or during the dehydrogenation of LPG or LNG or from GTL technology with a primary amine and/or a secondary amine under hydroaminating conditions, and the resulting butenylamine(s) are then reacted in a second process stage under hydrogenating and transalkylating conditions.
摘要翻译：正丁胺的制备方法，其中首先通过在石油馏分裂化期间或在LPG或LNG的脱氢过程中获得的1,3-丁二烯混合物形式的1,3-丁二烯反应制备正丁烯基胺或者在加氢胺化条件下与伯胺和/或仲胺进行GTL技术，然后在氢化和烷基转移条件下，在第二个工艺阶段使所得的丁烯胺反应。

9. 发明授权

US09481643B2 Fluorosurfactants 有权
标题翻译：含氟表面活性剂
公开(公告)号：US09481643B2
公开(公告)日：2016-11-01
申请号：US14416003
申请日：2013-07-16
申请人： MERCK PATENT GMBH
发明人： Reiner Friedrich , Gerhard Jonschker , Fanny Schooren , Christian Depner , Steffen Schellenberger
IPC分类号： C07C19/08 , C07C309/17 , C07C43/12 , C07C69/66 , C07C211/02 , C07C211/15 , C11D1/00 , C07C43/13 , C07C69/657
CPC分类号： C07C309/17 , C07C19/08 , C07C43/12 , C07C43/137 , C07C69/003 , C07C69/657 , C07C69/66 , C07C211/02 , C07C211/15 , C11D1/004
摘要： The present invention relates to novel compounds containing fluorinated end groups, to the use thereof as surface-active substances, and to compositions comprising these compounds.
摘要翻译：本发明涉及包含氟化端基的新化合物，其用作表面活性物质，以及包含这些化合物的组合物。

10. 发明授权

US09115051B2 Method for producing polyamine composition from plant 有权
标题翻译：从植物生产多胺组合物的方法
公开(公告)号：US09115051B2
公开(公告)日：2015-08-25
申请号：US14357677
申请日：2012-09-28
申请人： TOYOBO CO., LTD.
发明人： Chiaki Yamada , Hiroaki Kitazawa , Shusaku Yanagidani
IPC分类号： C07C209/86 , C07C211/02
CPC分类号： C07C209/86 , C07C211/02 , C07C211/14 , C07C211/09
摘要： A method for producing a polyamine composition with high production efficiency that has a low salt concentration includes (1) a step of treating a plant and/or a processed plant product with ethanol; (2) a step of treating the plant and/or the processed plant product with water; (3) a step of treating the plant and/or the processed plant product under an acidic condition; and (4) a step of separating and collecting a liquid fraction.
摘要翻译：一种生产效率低的具有低盐浓度的多胺组合物的方法包括（1）用乙醇处理植物和/或加工植物产物的步骤; （2）用水处理植物和/或加工的植物产品的步骤; （3）在酸性条件下处理植物和/或加工植物产物的步骤; 和（4）分离和收集液体馏分的步骤。

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