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1. 发明授权

US07057075B2 Method for producing amines by means of olefin animation in the presence of unstaturated nitrogen compounds 失效
标题翻译：在不饱和氮化合物存在下通过烯烃动画制备胺的方法
公开(公告)号：US07057075B2
公开(公告)日：2006-06-06
申请号：US10495357
申请日：2002-11-11
申请人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Reinhard Dier
发明人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Reinhard Dier
IPC分类号： C07C209/60
CPC分类号： C07C209/60 , C07C211/05
摘要： In a process for preparing alkylamines (product amines) by reacting alkenes with amines (starting amines) in the presence of a metal hydride or metal as catalyst is carried out in the process of the present invention, the reaction is carried out in the presence of a cocatalyst whose acidity is higher than that of the starting amine.
摘要翻译：在金属氢化物或金属作为催化剂存在下，通过使烯烃与胺（起始胺）反应制备烷基胺（产物胺）的方法在本发明的方法中进行，反应在其酸度高于起始胺的助催化剂。

2. 发明授权

US07053246B2 Preparation of a symmetrical secondary amine 失效
标题翻译：对称仲胺的制备
公开(公告)号：US07053246B2
公开(公告)日：2006-05-30
申请号：US10731095
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
IPC分类号： C07C29/04
CPC分类号： C07C209/64 , C07C211/14
摘要： Process for preparing a symmetrical secondary amine by reaction of a primary amine in the presence of hydrogen and a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：通过伯胺在氢气和催化剂的反应下制备对称仲胺的方法，其制备涉及将催化活性组分沉淀到单斜晶，四方晶或立方二氧化锆上。

3. 发明授权

US06916964B2 Selective hydrogenation of olefinically unsaturated carbonyl compounds 有权
标题翻译：烯属不饱和羰基化合物的选择性氢化
公开(公告)号：US06916964B2
公开(公告)日：2005-07-12
申请号：US10309181
申请日：2002-12-04
申请人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
发明人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
IPC分类号： C07B61/00 , C07C29/141 , C07C33/03 , C07C29/136 , C07C29/14 , C07C29/143 , C07C29/147
CPC分类号： C07C29/141 , C07B2200/07 , C07C33/02 , C07C33/025
摘要： The present invention relates to a continuous process for the selective hydrogenation of olefinically unsaturated carbonyl compounds to give unsaturated alcohols in particular of citral to give a mixture of geraniol and nerol, in a reactor containing a liquid phase, in which at least one catalyst is suspended, and which can additionally contain a gas phase, wherein the liquid phase and, if present, the gas phase are passed through a device in the reactor having openings or channels.
摘要翻译：本发明涉及一种用于选择性氢化烯属不饱和羰基化合物的连续方法，以在含有液相的反应器中提供不饱和醇，特别是柠檬醛，得到香叶醇和橙花醇的混合物，其中悬浮有至少一种催化剂并且其还可以包含气相，其中液相和（如果存在的话）气相通过具有开口或通道的反应器中的装置。

4. 发明授权

US06790995B2 Preparation of primary and secondary amines from nitriles 失效
标题翻译：从腈制备伯胺和仲胺
公开(公告)号：US06790995B2
公开(公告)日：2004-09-14
申请号：US10033912
申请日：2002-01-03
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C209/48 , C07C211/11 , C07C215/08
摘要： Mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) where X is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.
摘要翻译：式（I）的伯胺和式（II）的仲胺的混合物，其中X是可以未被取代或被C 1-20烷基取代的C 1-20 - 烷基，C 2-20 - 烯基或C 3-8 - 环烷基，C 3-8 - 环烷基，C 4-20 - 烷基环烷基，C 4-20 - 环烷基烷基，C 2-20烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20羟烷基，氨基，C 1-20烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基。 C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，C 3-8 - 环烷氧基，芳氧基和/或C 2-8烷氧基羰基，（III）与氢气在50-250℃下反应，压力为5-350巴，在含Pd催化剂的存在下，基于催化剂的总重量计，为0.1-10重量％的Pd 在支持上。

5. 发明授权

US06743956B1 Selective liquid phase hydrogenation of carbonyl compounds to give the corresponding alcohols in the presence of a Pt/ZnO catalyst 失效
标题翻译：在Pt / ZnO催化剂存在下，羰基化合物的选择性液相氢化得到相应的醇
公开(公告)号：US06743956B1
公开(公告)日：2004-06-01
申请号：US10309255
申请日：2002-12-04
申请人： Mathias Haake , Till Gerlach , Frank Funke
发明人： Mathias Haake , Till Gerlach , Frank Funke
IPC分类号： C07C2700
CPC分类号： C07C29/141 , C07C33/02
摘要： The present invention relates to a process for selective liquid phase hydrogenation of carbonyl compounds of the general formula I, where R1 and R2 are identical or different and are each independently hydrogen or a saturated or a mono- or polyunsaturated straight-chain or branched, optionally substituted C1-C20-alkyl radical, an optionally substituted aryl radical or an optionally substituted heterocyclic group, to give the corresponding alcohols of the general formula II where R1 and R2 are each as defined above, in the presence of hydrogen and a Pt/ZnO catalyst.
摘要翻译：本发明涉及通式I的羰基化合物的选择性液相氢化方法，其中R 1和R 2相同或不同，并且各自独立地为氢或饱和或单或多不饱和直链，链或支链，任选取代的C 1 -C 20烷基，任选取代的芳基或任选取代的杂环基，得到相应的通式II的醇，其中R 1和R 2各自如上所定义，在氢气和Pt / ZnO催化剂的存在下。

6. 发明授权

US06548704B2 Racemization of optically active amines 失效
公开(公告)号：US06548704B2
公开(公告)日：2003-04-15
申请号：US10012344
申请日：2001-12-12
申请人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
发明人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
IPC分类号： C07C2968
CPC分类号： C07C213/02 , B01J23/80 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/035 , C07B2200/07 , C07C209/68 , C07C209/88 , C07C217/08 , C07C211/07
摘要： Optically active amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 may also be hydrogen (H), with the radicals being able to bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, are racemized by reacting the optically active amine I in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, wherein the catalyst comprises the active components copper and zinc oxide and a support material.

7. 发明授权

US06525223B2 Preparation of secondary amines from nitriles 失效
标题翻译：从腈制备仲胺
公开(公告)号：US06525223B2
公开(公告)日：2003-02-25
申请号：US10026900
申请日：2001-12-27
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/11
摘要： Secondary amines of the formula (II) (X—CH2—)2NH (II) where X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl group which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycoalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino, C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl, are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 20 to 250° C. and pressures of from 60 to 350 bar in the presence of an Rh-containing catalyst comprising from 0.1 to 5% by weight, based on the total weight of the catalyst, of Rh on a support to give mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) and returning at least part of the primary amines separated from the mixtures obtained to the reaction.
摘要翻译：式（II）的仲胺，其中X是可以是未取代的或被C 1-20 - 烷基，C 3-8 - 环烷基，C 4 -C 18环烷基，C 3-8 - C 20-20烷基烷基，C 2-20 - 烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20 - 羟基烷基，氨基， C 1-20 - 烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基，C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，环烷氧基，芳氧基和/或C 2-8 - 烷氧基羰基，通过在含Rh的催化剂存在下，使式（III）的腈与20至250℃的压力和60至350巴的压力反应来制备包含基于催化剂总重量的0.1至5重量％的Rh在载体上以得到式（I）的伯胺和式（II）的仲胺的混合物，并使至少部分从获得的混合物中分离出伯胺反应。

8. 发明授权

US06525222B2 Process for preparing amines 有权
标题翻译：制备胺的方法
公开(公告)号：US06525222B2
公开(公告)日：2003-02-25
申请号：US09729458
申请日：2000-12-05
申请人： Jan Nouwen , Arthur Höhn , Horst Neuhauser , Frank Funke , Stephan Andreas Schunk , Johann-Peter Melder , Knut Eger , Michael Hesse , Joachim Wulff-Döring
发明人： Jan Nouwen , Arthur Höhn , Horst Neuhauser , Frank Funke , Stephan Andreas Schunk , Johann-Peter Melder , Knut Eger , Michael Hesse , Joachim Wulff-Döring
IPC分类号： C07C20900
CPC分类号： C07C213/02 , C07C209/26 , C07C2601/08 , C07C2602/08 , C07C2602/10 , C07C211/35 , C07C211/42 , C07C217/58
摘要： Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst, wherein the catalytically active mass of the catalyst contains, after its preparation and before the treatment with hydrogen, 22 to 45% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 5 to 50% by weight of oxygen-containing compounds of nickel, calculated as NiO, where the molar ratio of nickel to copper is greater than 1, 5 to 50% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2.
摘要翻译：通过使升高的温度下的醛或酮与选自氨，伯和仲胺的氮化合物和在催化剂存在下与氢气反应的醛或酮进行反应来制备胺，其中催化剂的催化活性物质含有其制备方法和用氢处理之前，按重量计22％至45％的锆的氧含量化合物，按ZrO2计算，按重量计为CuO的含氧化合物为铜，按CuO计为5〜50％按NiO计的含镍化合物的重量，其中镍与铜的摩尔比大于1.5至50重量％的以CoO计的含氧化合物的钴，0至5重量％按MoO3计算的含氧化合物的钼和0至10重量％的按Al2O3或MnO2计算的含铝和/或锰的含氧化合物。

9. 发明授权

US06469211B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06469211B2
公开(公告)日：2002-10-22
申请号：US09987243
申请日：2001-11-14
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/14
摘要： In a process for the continuous hydrogenation of nitrites to primary amines in the liquid phase over a suspended, activated Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, the hydrogenation is carried out in the absence of ammonia and basic alkali metal compounds or alkaline earth metal compounds.
摘要翻译：在一种基于铝合金和至少一种选自铁，钴和镍的过渡金属的悬浮活性阮内催化剂上，在液相中将亚硝酸盐连续氢化成伯胺的方法中，如果所需的一种或多种选自钛，锆，铬和锰的过渡金属，氢化在不存在氨和碱性碱金属化合物或碱土金属化合物的情况下进行。

10. 发明授权

US07183438B2 Catalysts and method for the production of amines 有权
标题翻译：用于生产胺的催化剂和方法
公开(公告)号：US07183438B2
公开(公告)日：2007-02-27
申请号：US10507602
申请日：2003-03-07
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
IPC分类号： C07C209/16 , C07C209/18 , C07C209/29 , B01J23/40 , B01J23/42
CPC分类号： C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要： Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译：公开了催化剂，其催化活性物质含有22至40重量％的以ZrO 2计算的含氧化合物的锆，1至30重量％的含氧化合物的铜，以CuO计，15至50重量％的含氧化合物的镍，以NiO计算，镍和铜之间的摩尔比大于15重量％，含氧化合物的化合物为15至50重量％作为CoO，并且在用氢处理之前少于1重量％的碱金属（以碱金属氧化物计）。还公开了一种通过使伯醇和仲醇，醛或酮与选自氨，伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法压力。

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