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1. 发明申请

US20180318819A1 NICKEL-BASED CATALYTIC COMPOSITION IN THE PRESENCE OF A SPECIFIC ACTIVATOR AND USE THEREOF IN A OLEFIN OLIGOMERSATION METHOD 审中-公开
公开(公告)号：US20180318819A1
公开(公告)日：2018-11-08
申请号：US15772374
申请日：2016-10-20
申请人： IFP Energies nouvelles
发明人： Pierre-Alain BREUIL , Emmanuel PELLIER
IPC分类号： B01J31/40 , C07C2/32
CPC分类号： B01J31/403 , B01J31/0227 , B01J31/0231 , B01J31/0237 , B01J31/0255 , B01J31/0264 , B01J31/0271 , B01J31/143 , B01J31/186 , B01J31/2247 , B01J31/24 , B01J31/2404 , B01J2231/20 , B01J2531/847 , B01J2540/10 , B01J2540/20 , B01J2540/325 , C07C2/32 , C07C11/08 , C07C11/107 , C07C2531/025 , C07C2531/14 , C07C2531/24 , C08F110/02
摘要： The invention describes a novel nickel-based composition. The invention also concerns the use of said composition as a catalytic composition in an olefin oligomerization process.

2. 发明授权

US5180872A Process for the preparation of styrene derivatives extended at the double bond by ethylene and having a double bond remaining in the extension chain formed and new styrene derivatives extended with ethylene 失效
标题翻译：制备苯乙烯衍生物的方法在乙烯双酚键上延伸，并且在延伸链形成的双键和新的苯乙烯衍生物中扩展乙烯
公开(公告)号：US5180872A
公开(公告)日：1993-01-19
申请号：US704751
申请日：1991-05-23
申请人： Karl-Heinz A. O. Starzewski
发明人： Karl-Heinz A. O. Starzewski
IPC分类号： B01J31/22 , B01J31/18 , B01J31/24 , C07B37/02 , C07B61/00 , C07C2/04 , C07C15/44 , C07C17/26 , C07C17/275 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , C07C49/813 , C08F4/26 , C08F12/00 , C08F12/08
CPC分类号： C07C49/813 , B01J31/1875 , B01J31/2247 , B01J31/2295 , B01J31/24 , B01J31/2404 , C07B37/02 , C07C15/44 , C07C17/275 , C07C2/04 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , B01J2531/847 , B01J31/2291 , C07C2531/22
摘要： The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20.degree.to 160.degree. C. and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula ##STR1## in which R.sup.19 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, vinyl or chlorine and R.sup.38 denotes C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl, C.sub.2 -C.sub.7 -acyl, flourine, chlorine or bromine andm assumes values of 4-104,with the exception of compounds wherein R.sup.19 denotes hydrogen and R.sup.38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.
摘要翻译：标题化合物可以通过苯乙烯衍生物与乙烯在携带磷 - 氧螯合配体的镍催化剂存在下，在20至160℃的温度和1至200巴的乙烯压力下反应来制备。苯乙烯衍生物用乙烯延伸，其结构式为：其中R 19表示氢，C 1 -C 4烷基，乙烯基或氯，R 38表示C 1 -C 4烷基，C 2 -C 4链烯基，C 2 -C 7酰基，氯或溴，m为4-104的值，除了其中R 19表示氢，R 38表示异丁基或苯甲酰基，m为4的化合物是新的。

3. 发明授权

US4293727A Process for the oligomerization of ethylene 失效
标题翻译：乙烯低聚方法
公开(公告)号：US4293727A
公开(公告)日：1981-10-06
申请号：US179076
申请日：1980-08-18
申请人： David L. Beach , James J. Harrison
发明人： David L. Beach , James J. Harrison
IPC分类号： C07C2/32 , B01J31/00 , B01J31/18 , B01J31/22 , B01J31/24 , C07B61/00 , C07C1/00 , C07C2/36 , C07C11/02 , C07C67/00 , C07F15/04 , C08F110/02 , C07C2/02
CPC分类号： B01J31/2404 , B01J31/1895 , B01J31/2247 , C07C2/36 , C07F15/04 , C08F110/02 , B01J2231/20 , B01J2531/847 , B01J2540/32 , C07C2531/24
摘要： Ethylene is oligomerized by contacting ethylene under oligomerization conditions with a nickel ylide defined by the following Formula I: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about one to about 24 carbon atoms, preferably from about one to about 10 carbon atoms; aryl radicals having from about six to about 20 carbon atoms, preferably from about six to about 10 carbon atoms; alkenyl radicals having from about two to about 30 carbons atoms, preferably from about two to about 20 carbon atoms; cycloalkyl radicals having from about three to about 40 carbon atoms, preferably from about three to about 30 carbon atoms; aralkyl and alkaryl radicals having from about six to about 40 carbon atoms, preferably from about six to about 30 carbon atoms; a halogen radical selected from the group consisting of fluorine, chlorine, bromine and iodine, preferably chlorine; a hydroxyl group; an alkoxy or aryloxy group; and a hydrocarbyl group, such as defined above, carrying halogen, hydroxyl or alkoxy or aryloxy; provided that at least one, preferably from about one to about four, of each of R.sub.1 to R.sub.8 is a sulfonato group (--SO.sub.3.sup.-) or an alkyl, aryl, alkenyl, cycloalkyl, aralkyl or alkaryl group carrying a sulfonato group; M is sulfur or oxygen, preferably oxygen; E is phosphorus, arsenic, antimony or nitrogen, preferably phosphorus; and F is phosphorus, arsenic or antimony, preferably phosphorus. This process is characterized by a relatively high reaction rate at low temperatures and pressures and results in the production of relatively high proportions of desirable trimer, tetramer, pentamer, and higher olefinic products.
摘要翻译：乙烯通过在低聚条件下与乙烯接触，通过下列通式I所定义的镍叶立德使其低聚：其中R1，R2，R3，R4，R5，R6，R7和R8是相同或不同的成员，的氢，具有约1至约24个碳原子，优选约1至约10个碳原子的烷基; 具有约6至约20个碳原子，优选约6至约10个碳原子的芳基; 具有约2至约30个碳原子，优选约2至约20个碳原子的烯基; 具有约3至约40个碳原子，优选约3至约30个碳原子的环烷基; 具有约6至约40个碳原子，优选约6至约30个碳原子的芳烷基和烷芳基; 选自氟，氯，溴和碘的卤素，优选氯; 羟基; 烷氧基或芳氧基; 和如上所定义的含有卤素，羟基或烷氧基或芳氧基的烃基; 条件是R 1至R 8中的至少一个，优选约1至约4个为磺酸基（-SO 3 - ）或带有磺酸基的烷基，芳基，烯基，环烷基，芳烷基或烷芳基; M是硫或氧，优选氧; E是磷，砷，锑或氮，优选磷; F是磷，砷或锑，优选磷。该方法的特征在于在低温和低压下的相对较高的反应速率，并导致产生相对较高比例的所需三聚体，四聚体，五聚物和更高级烯烃产物。

4. 发明授权

US3686351A Alpha-olefin production 失效
标题翻译： ALPHA-OLEFIN生产
公开(公告)号：US3686351A
公开(公告)日：1972-08-22
申请号：US3686351D
申请日：1971-07-16
申请人： SHELL OIL CO
发明人： MASON RONALD F
IPC分类号： B01J31/26 , C07C2/36 , C07C3/10
CPC分类号： B01J31/146 , B01J31/2221 , B01J31/2247 , B01J31/28 , B01J31/30 , B01J2231/20 , B01J2531/847 , C07C2/36 , C07C2527/128 , C07C2531/14 , C07C2531/24
摘要： Ethylene is oligomerized to linear, alpha-olefins by reacting ethylene in liquid phase solution in the presence of a catalyst composition produced by contacting in the presence of ethylene (1) a simple divalent nickel salt (2) a boron hydride reducing agent (3) a phosphinooacetic acid or alkali metal salt thereof.
摘要翻译：在乙烯存在下（1）单价二价镍盐（2）硼氢化物还原剂（3）的存在下，使乙烯在液相溶液中反应生成的催化剂组合物，使乙烯低聚成线性α-烯烃，膦酰乙酸或其碱金属盐。

5. 发明授权

US09228061B2 Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts 有权
标题翻译：含锆的络合物和缩合反应催化剂，制备催化剂的方法和含有催化剂的组合物
公开(公告)号：US09228061B2
公开(公告)日：2016-01-05
申请号：US14125962
申请日：2012-09-06
申请人： Kurt Brandstadt , Simon Cook , Keith Hall , Gary Diamond , Loren Lower , Avril Surgenor , Richard Taylor , James Tonge , Ming-Shin Tzou
发明人： Kurt Brandstadt , Simon Cook , Keith Hall , Gary Diamond , Loren Lower , Avril Surgenor , Richard Taylor , James Tonge , Ming-Shin Tzou
IPC分类号： C08G77/08 , B01J31/22 , C08L83/04 , C08K5/00
CPC分类号： C08G77/08 , B01J31/2234 , B01J31/2239 , B01J31/2247 , B01J31/226 , B01J2231/14 , B01J2531/48 , C08K5/0091 , C08L83/04
摘要： A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
摘要翻译：组合物能够通过缩合反应固化。该组合物使用新的缩合反应催化剂。新的缩合反应催化剂用于代替常规的锡催化剂。组合物可以反应以形成胶，凝胶，橡胶或树脂。

6. 发明申请

US20150306588A1 NOVEL NICKEL-BASED CATALYTIC COMPOSITION, AND ITS USE IN A PROCESS FOR THE OLIGOMERIZATION OF OLEFINS 有权
标题翻译：新型的镍基催化组合物及其在烯烃低级化过程中的应用
公开(公告)号：US20150306588A1
公开(公告)日：2015-10-29
申请号：US14694052
申请日：2015-04-23
申请人： IFP ENERGIES NOUVELLES , UNIVERSITEIT VAN AMSTERDAM
发明人： Pierre BOULENS , Pierre-Alain BREUIL , Joost REEK , Helene OLIVIER-BOURBIGOU
IPC分类号： B01J31/18 , C07F15/04 , B01J31/14 , C07C2/32
CPC分类号： B01J31/1845 , B01J31/0267 , B01J31/143 , B01J31/2247 , B01J2231/20 , B01J2531/0213 , B01J2531/847 , C07C2/32 , C07C2/34 , C07C2527/02 , C07C2531/18 , C07C2531/24 , C07F15/045 , C07C11/08
摘要： The invention describes a nickel-based composition. The invention also concerns the use of said composition as a catalytic composition in an olefin oligomerization process.
摘要翻译：本发明描述了一种镍基组合物。本发明还涉及在烯烃低聚方法中使用所述组合物作为催化组合物。

7. 发明申请

US20150252055A1 COMPOUNDS OF CHIRAL AROMATIC SPIROKETAL DIPHOSPHINE LIGANDS, PREPARATION METHODS AND USES THEREOF 有权
标题翻译：化合物，其制备方法及其用途
公开(公告)号：US20150252055A1
公开(公告)日：2015-09-10
申请号：US14415857
申请日：2013-01-29
申请人： SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES
发明人： Kuiling Ding , Xiaoming Wang , Zhaobin Han , Xubin Wang , Zheng Wang
IPC分类号： C07D493/10 , C07D495/20 , C07D491/20 , C07F9/6561
CPC分类号： C07D493/10 , B01J31/2247 , B01J31/2409 , B01J2231/32 , B01J2531/0238 , B01J2531/0261 , B01J2531/824 , C07B53/00 , C07C227/32 , C07D491/20 , C07D493/20 , C07D495/20 , C07F9/6561 , C07F9/65616 , C07F15/0033 , C07C229/34
摘要： Disclosed are aromatic spiroketal diphosphine ligands, preparation methods and uses thereof. The ligands have the structure of formula (I), in which R1, R2, R3, R4, R5, R6, R7, R8, X and n are defined as such described in the specification. The aromatic spiroketal diphosphine ligands are prepared from aromatic spiroketal compounds. Also disclosed are the preparation methods of aromatic spiroketal compounds. The preparation methods are simple and can produce racemic or chiral aromatic spiroketal diphosphine ligands. The ligands can be used as catalysts of asymmetrical catalytic reactions having economical practicability and industry application prospect.
摘要翻译：公开了芳族螺旋二膦配体，其制备方法和用途。配体具有式（I）的结构，其中R1，R2，R3，R4，R5，R6，R7，R8，X和n如说明书中所述定义。芳族螺缩酮二膦配体由芳族螺缩酮化合物制备。还公开了芳族螺缩酮化合物的制备方法。制备方法简单，可制备外消旋或手性芳香族螺二酮二膦配体。该配体可用作具有经济实用性和工业应用前景的不对称催化反应催化剂。

8. 发明申请

US20140296467A1 Iron(II) Containing Complex and Condensation Reaction Catalysts, Methods for Preparing the Catalysts, and Compositions Containing the Catalysts 有权
标题翻译：含有复合和缩合反应催化剂的铁（II），制备催化剂的方法和含有催化剂的组合物
公开(公告)号：US20140296467A1
公开(公告)日：2014-10-02
申请号：US14236757
申请日：2012-10-04
申请人： Dow Corning Corporation
发明人： Kurt Brandstadt , Simon Cook , Gary Diamond , Keith Hall , Loren Lower , Avril Surgenor , Richard Taylor , James Tonge , Ming-Shin Tzou , Thomas Galbraith , James Shoemaker
IPC分类号： C08G77/38
CPC分类号： C08G77/08 , B01J31/18 , B01J31/1805 , B01J31/2208 , B01J31/2213 , B01J31/223 , B01J31/2234 , B01J31/2243 , B01J31/2247 , B01J31/226 , B01J2531/0252 , B01J2531/842 , B01J2540/22 , B01J2540/225 , C08K5/0091 , C08L83/04
摘要： A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
摘要翻译：组合物能够通过缩合反应固化。该组合物使用新的缩合反应催化剂。新的缩合反应催化剂用于代替常规的锡催化剂。组合物可以反应以形成胶，凝胶，橡胶或树脂。

9. 发明授权

US08283276B2 Coordination complex system comprising tautomeric ligands 有权
标题翻译：包含互变异构配体的配位复合体系
公开(公告)号：US08283276B2
公开(公告)日：2012-10-09
申请号：US12744293
申请日：2008-11-19
申请人： Joost Nikolaas Hendrik Reek , Frederic William Patureau , Mark Kuil , Albertus Jacobus Sandee , Jurjen Meeuwissen
发明人： Joost Nikolaas Hendrik Reek , Frederic William Patureau , Mark Kuil , Albertus Jacobus Sandee , Jurjen Meeuwissen
IPC分类号： B01J31/00 , C07F15/00 , C07C231/12 , C07C67/303 , C07C45/69 , C07C5/10 , C07D209/08 , C08G69/08
CPC分类号： C07F15/008 , B01J31/2247 , B01J2231/321 , B01J2231/643 , B01J2231/645 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07B2200/11 , C07C45/50 , C07C45/505 , C07C45/55 , C07C67/303 , C07C231/12 , C07C69/34 , C07C47/228 , C07C47/02 , C07C233/47 , C07C233/05
摘要： The invention relates to a coordination complex system comprising a ligand having the formula: R1—SO2—NH—P (XR2)2 (1a); or R1—SO2—N═PH (XR2)2 (1b); or R1—SO(OH)═N—P(XR2)2 (1c); wherein X is independently O, S, NH, or a bond; R1 and R2 are independently selected from hydrogen and substituted or unsubstituted alkyl or aryl; wherein at least one equivalent of the ligand is complexed to an equivalent of a metal selected from a transition metal and lanthanide. The invention also relates to the use of said coordination complexes as catalysts in the hydroformylation, hydrogenation, transfer hydrogenation, hydrocyanation, polymerization, isomerization, carbonylation, cross-coupling, metathesis, CH activation, allylic substitution, aldol condensation, or Michael addition.
摘要翻译：本发明涉及包含具有下式的配体的配位络合物体系：R1-SO2-NH-P（XR2）2（1a）; 或R1-SO2-N = PH（XR2）2（1b）; 或R1-SO（OH）= N-P（XR2）2（1c）; 其中X独立地为O，S，NH或键; R 1和R 2独立地选自氢和取代或未取代的烷基或芳基; 其中至少一当量的配体与选自过渡金属和镧系元素的金属的当量络合。本发明还涉及所述配位络合物在加氢甲酰化，氢化，转移氢化，氢氰化，聚合，异构化，羰基化，交叉偶联，复分解，CH活化，烯丙基取代，醛醇缩合或迈克尔加成中的用途。

10. 再颁专利

USRE37106E1 Process for the preparation of styrene derivatives extended at the double bond by ethylene and having a double bond remaining in the extension chain formed and new styrene derivatives extended with ethylene 失效
标题翻译：通过乙烯制备在双键延伸的苯乙烯衍生物和形成的延伸链中保留双键并且用乙烯延伸的新的苯乙烯衍生物的方法
公开(公告)号：USRE37106E1
公开(公告)日：2001-03-20
申请号：US08394538
申请日：1995-02-22
申请人： Karl-Heinz Aleksander Ostoja Starzewski
发明人： Karl-Heinz Aleksander Ostoja Starzewski
IPC分类号： C10L116
CPC分类号： C07C49/813 , B01J31/1875 , B01J31/2247 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2531/847 , C07B37/02 , C07C2/04 , C07C15/44 , C07C17/275 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , C07C2531/22
摘要： The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20° to 160° C. and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula in which R19 denotes hydrogen, C1-C4-alkyl, vinyl or chlorine and R38 denotes C1-C4-alkyl, C2-C4-alkenyl, C2-C7-acyl, flourine, chlorine or bromine and m assumes values of 4-104, with the exception of compounds wherein R19 denotes hydrogen and R38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.
摘要翻译：标题化合物可以通过苯乙烯衍生物与乙烯在携带磷 - 氧螯合配体的镍催化剂存在下，在20℃至160℃的温度和1至200巴的乙烯压力下反应来制备。乙烯延伸的苯乙烯衍生物，其中R 19表示氢，C 1 -C 4 - 烷基，乙烯基或氯，R 38表示C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 7 - 酰基，芴，氯或溴，并表示值的4-104，除了其中R 19表示氢并且R 38表示异丁基或苯甲酰基，m表示数值4的化合物，是新的。

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