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1. 发明授权

US5274131A 2-chloropropionaldehyde trimer and production process thereof 失效
标题翻译： 2-氯丙醛三聚体及其制备方法
公开(公告)号：US5274131A
公开(公告)日：1993-12-28
申请号：US781101
申请日：1991-10-22
申请人： Takashi Wakasugi , Tadashi Miyakawa , Naka Tonouchi , Takashi Yamauchi , Makoto Ishizuka
发明人： Takashi Wakasugi , Tadashi Miyakawa , Naka Tonouchi , Takashi Yamauchi , Makoto Ishizuka
IPC分类号： C07C45/55 , C07C45/63 , C07D323/04 , C07D323/06
CPC分类号： C07D323/04 , C07C45/55 , C07C45/63
摘要： A novel compound, a 2-chloropropionaldehyde trimer and a process of producing a 2-chloropropionaldehyde trimer by adding concentrated sulfuric acid to an organic solvent containing 2-chloropropionaldehyde and stirring the mixture at a temperature of from -5.degree. C. to 15.degree. C. to carry out the reaction.

2. 发明授权

US4169110A Condensation and trimerization of aldehydes 失效
标题翻译：醛的缩合和三聚
公开(公告)号：US4169110A
公开(公告)日：1979-09-25
申请号：US12426
申请日：1970-02-18
申请人： John M. Holovka , Edward Hurley, Jr.
发明人： John M. Holovka , Edward Hurley, Jr.
IPC分类号： C07C41/56 , C07C43/303 , C07C45/55 , C07C45/74 , C07C47/21 , C07D323/06 , C07C47/20
CPC分类号： C07C47/21 , C07C41/56 , C07C43/303 , C07C45/55 , C07C45/74 , C07D323/06
摘要： Group VIII metal salts such as iridium chloride and rhodium chloride are used as catalysts in the condensation reactions of aldehydes to produce acetals and alpha,beta-unsaturated aldehydes. These catalysts are also useful in the conversion of aldehydes to trioxanes. Materials of this type are widely used in the formation of resins, preservatives, dyes, and chemical intermediates.
摘要翻译： VIII族金属盐如氯化铱和氯化铑被用作醛类缩醛反应产生缩醛和α，β-不饱和醛的催化剂。这些催化剂也可用于将醛转化为三恶烷。这种材料广泛用于树脂，防腐剂，染料和化学中间体的形成。

3. 发明授权

US3883309A Apparatus for the generation of gaseous formaldehyde from formaldehyde polymer 失效
标题翻译：用于从甲醛聚合物产生气态甲醛的装置
公开(公告)号：US3883309A
公开(公告)日：1975-05-13
申请号：US27887472
申请日：1972-08-08
申请人： KANEBO LTD
发明人： ISHIZAWA KAZUTOMO , NAGATA YASUNORI , IKUI HISAKAZU
IPC分类号： B01D1/00 , B01D3/34 , B01D19/00 , C07C45/55 , C07C47/045 , B01J7/00 , C07C47/04
CPC分类号： B01D19/0068 , B01D1/0082 , B01D3/34 , B01D19/00 , C07C45/55 , Y10S422/901 , C07C47/04
摘要： A process and an apparatus for generating gaseous formaldehyde from a dispersion of formaldehyde polymer in a liquid carrier are provided. The dispersion is continuously fed from a mixing tank to an evaporator in a manner such that said dispersion flows into the evaporator in the state of overflow, where the dispersion is heated to evaporate gaseous formaldehyde. The liquid carrier collected on the bottom is continuously discharged while the free surface of the liquid carrier is maintained at a stated range of height by a liquid level controlling means. The liquid carrier discharged therefrom is cooled, and then made to circulate to the mixing tank where the formaldehyde polymer is replenished thereto and the resulting dispersion is fed to the evaporator repeatedly.
摘要翻译：提供了一种用于从液体载体中的甲醛聚合物分散体产生气态甲醛的方法和装置。将分散体从混合罐连续地供给到蒸发器，使得所述分散体以溢出的状态流入蒸发器，其中分散体被加热以蒸发气态甲醛。收集在底部的液体载体被连续排出，而液体载体的自由表面通过液位控制装置保持在规定的高度范围。将从其排出的液体载体冷却，然后使其循环到混合罐中，在其中补充甲醛聚合物，并将所得的分散体反复进料至蒸发器。

4. 发明授权

US656061A Process of producing formaldehyde vapors. 失效
标题翻译：生产甲醛的方法。
公开(公告)号：US656061A
公开(公告)日：1900-08-14
申请号：US1896613270
申请日：1896-11-24
申请人： USINES DU RHONE ANCIENNEMENT GILLIARD P MONNET ET CARTIER SOC CHIMIQUE DES
发明人： TRILLAT JEAN JOSEPH AUGUSTE
CPC分类号： C07C45/55

5. 发明授权

US08283276B2 Coordination complex system comprising tautomeric ligands 有权
标题翻译：包含互变异构配体的配位复合体系
公开(公告)号：US08283276B2
公开(公告)日：2012-10-09
申请号：US12744293
申请日：2008-11-19
申请人： Joost Nikolaas Hendrik Reek , Frederic William Patureau , Mark Kuil , Albertus Jacobus Sandee , Jurjen Meeuwissen
发明人： Joost Nikolaas Hendrik Reek , Frederic William Patureau , Mark Kuil , Albertus Jacobus Sandee , Jurjen Meeuwissen
IPC分类号： B01J31/00 , C07F15/00 , C07C231/12 , C07C67/303 , C07C45/69 , C07C5/10 , C07D209/08 , C08G69/08
CPC分类号： C07F15/008 , B01J31/2247 , B01J2231/321 , B01J2231/643 , B01J2231/645 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07B2200/11 , C07C45/50 , C07C45/505 , C07C45/55 , C07C67/303 , C07C231/12 , C07C69/34 , C07C47/228 , C07C47/02 , C07C233/47 , C07C233/05
摘要： The invention relates to a coordination complex system comprising a ligand having the formula: R1—SO2—NH—P (XR2)2 (1a); or R1—SO2—N═PH (XR2)2 (1b); or R1—SO(OH)═N—P(XR2)2 (1c); wherein X is independently O, S, NH, or a bond; R1 and R2 are independently selected from hydrogen and substituted or unsubstituted alkyl or aryl; wherein at least one equivalent of the ligand is complexed to an equivalent of a metal selected from a transition metal and lanthanide. The invention also relates to the use of said coordination complexes as catalysts in the hydroformylation, hydrogenation, transfer hydrogenation, hydrocyanation, polymerization, isomerization, carbonylation, cross-coupling, metathesis, CH activation, allylic substitution, aldol condensation, or Michael addition.
摘要翻译：本发明涉及包含具有下式的配体的配位络合物体系：R1-SO2-NH-P（XR2）2（1a）; 或R1-SO2-N = PH（XR2）2（1b）; 或R1-SO（OH）= N-P（XR2）2（1c）; 其中X独立地为O，S，NH或键; R 1和R 2独立地选自氢和取代或未取代的烷基或芳基; 其中至少一当量的配体与选自过渡金属和镧系元素的金属的当量络合。本发明还涉及所述配位络合物在加氢甲酰化，氢化，转移氢化，氢氰化，聚合，异构化，羰基化，交叉偶联，复分解，CH活化，烯丙基取代，醛醇缩合或迈克尔加成中的用途。

6. 发明授权

US5414139A Process for the manufacture of monochloroacetaldehyde trimer and chloral 失效
标题翻译：一氯乙醛三聚体和氯醛的制备方法
公开(公告)号：US5414139A
公开(公告)日：1995-05-09
申请号：US214123
申请日：1994-03-15
申请人： Takashi Wakasugi , Tadashi Miyakawa , Fukuichi Suzuki
发明人： Takashi Wakasugi , Tadashi Miyakawa , Fukuichi Suzuki
IPC分类号： B01J23/06 , B01J23/14 , C07B61/00 , C07C45/55 , C07C45/63 , C07D323/06 , C07C45/53 , C07C45/61
CPC分类号： C07D323/06 , C07C45/55 , C07C45/63
摘要： A process for manufacturing monochloroacetaldehyde trimer and chloral together by effectively utilizing a raw material acetaldehyde or para-aldehyde. The process comprises a step of chlorinating acetaldehyde or para-aldehyde to produce a chlorinated liquid of which the major component is monochloroacetaldehyde, a step comprising adding chloral to said chlorinated liquid and distilling the mixture to obtain a fraction of which the major components are monochloroacetaldehyde and chloral, a step of trimerizing monochloroacetaldehyde by reacting said fraction in the presence of a trimerization catalyst and separating the MCA trimer by filtration, and a step of chlorinating other fractions from said distillation step and the filtrate from said trimerization step to produce chloral. According to this process all raw material aldehydes and components derived from aldehydes which have not been consumed for the production of MCA trimer can be easily converted into chloral which is useful as an industrial chemical. The process is also free from the problem of the waste water treatment.
摘要翻译：通过有效利用原料乙醛或对醛制备单氯乙醛三聚物和氯醛的方法。该方法包括氯化乙醛或对醛以产生其主要成分为一氯乙醛的氯化液体的步骤，该步骤包括向所述氯化液体中加入氯醛并蒸馏该混合物，得到主要成分为一氯乙醛的馏分，氯醛，通过在三聚催化剂存在下使所述级分反应并通过过滤分离MCA三聚体，以及从所述蒸馏步骤氯化其它级分的步骤和来自所述三聚步骤的滤液以产生氯醛的步骤，使一氯乙醛三聚。根据该方法，所有原料醛和源自未用于生产MCA三聚体的醛的组分可以容易地转化成可用作工业化学品的氯醛。该过程也没有废水处理的问题。

7. 发明授权

US5386055A Depolymerization process 失效
标题翻译：解聚过程
公开(公告)号：US5386055A
公开(公告)日：1995-01-31
申请号：US105885
申请日：1993-08-11
申请人： Sunggyu Lee , Mehmet A. Gencer , Kathy L. Fullerton , Fouad O. Azzam
发明人： Sunggyu Lee , Mehmet A. Gencer , Kathy L. Fullerton , Fouad O. Azzam
IPC分类号： C08J11/10 , B01J3/00 , B29B17/04 , C07B37/06 , C07C4/22 , C07C17/087 , C07C17/367 , C07C45/55 , C07C67/333 , C07C68/06 , C10G1/10 , C07C1/00
CPC分类号： C10G1/10 , B01J3/008 , C07B37/06 , C07C17/087 , C07C17/367 , C07C4/22 , C07C45/55 , C07C67/333 , C07C68/06 , Y02P20/544
摘要： A process for depolymerizing polymers by selective, partial oxidation at supercritical or near supercritical conditions for water and wherein supercritical water or water near supercritical conditions is used as a solvent and reforming agent, is used to produce relatively high yields of the monomers originally used to produce the polymers. The invention provides an environmentally friendly process for recycling polymeric waste materials to generate valuable polymer feedstock in a closed oxidation process which is free of hazardous stack emissions. The polymers which can be recycled in accordance with the process can include typical amounts of conventional additive and other impurities without significantly affecting the overall conversion.
摘要翻译：通过在超临界或近超临界条件下用于水的选择性，部分氧化解聚聚合物的方法，其中使用超临界条件下的超临界水或水作为溶剂和重整剂用于产生相对高的原始用于生产的单体的产率聚合物。本发明提供了一种环境友好的方法，用于回收聚合物废料以在封闭的氧化过程中生成有价值的聚合物原料，该氧化方法不含有危险的堆排放物。根据该方法可再循环的聚合物可以包括常规添加剂和其它杂质的典型量，而不会显着影响整体转化率。

8. 发明授权

US3413353A 2-(4-trifluoromethylphenyl)-indan-1, 3-diones 失效
标题翻译： 2-（4-三氟甲基苯基） - 茚满-1,3-二酮
公开(公告)号：US3413353A
公开(公告)日：1968-11-26
申请号：US48261765
申请日：1965-08-25
申请人： WYBE T. NAUTA
发明人： NAUTA WYBE T
IPC分类号： A61K31/02 , A61K31/12 , C07C45/27 , C07C45/48 , C07C45/55 , C07C45/59 , C07C49/697 , C07C49/755 , C07C69/76 , C07C205/45 , C07C255/49 , C07D307/87
CPC分类号： C07C205/45 , C07C45/27 , C07C45/48 , C07C45/55 , C07C45/59 , C07C49/697 , C07C49/755 , C07C47/55

9. 发明授权

US3268591A Production of monomeric formaldehyde 失效
标题翻译：生产单体甲醛
公开(公告)号：US3268591A
公开(公告)日：1966-08-23
申请号：US26974663
申请日：1963-04-01
申请人： TENNECO CHEM
发明人： SLOAN KENNETH T , REYNOLDS RICHARD E
IPC分类号： C07C45/55 , C07C45/81
CPC分类号： C07C45/81 , C07C45/55 , C07C47/04

10. 发明授权

US2615048A Process of producing chlorinated acetaldehydes utilizing chlorinated acetaldehydes as diluents 失效
标题翻译：使用氯化乙醛作为稀释剂生产氯化乙醛的方法
公开(公告)号：US2615048A
公开(公告)日：1952-10-21
申请号：US5545248
申请日：1948-10-20
申请人： FMC CORP
发明人： PIANFETTI JOHN A , PORTER DAVID J
IPC分类号： C07C45/55 , C07C45/63
CPC分类号： C07C45/55 , C07C45/63 , C07C47/16 , C07C47/14

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