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1. 发明授权

US6011071A Ether compound and process for producing the same 失效
标题翻译：醚化合物及其制备方法
公开(公告)号：US6011071A
公开(公告)日：2000-01-04
申请号：US952075
申请日：1997-11-17
申请人： Yasuyuki Fujii , Hisakazu Furugaki , Katsumi Kita , Hideharu Morimoto , Mitsuru Uno , Yasushi Kajihara
发明人： Yasuyuki Fujii , Hisakazu Furugaki , Katsumi Kita , Hideharu Morimoto , Mitsuru Uno , Yasushi Kajihara
IPC分类号： A61K8/33 , A61K8/58 , A61K8/81 , A61K31/08 , A61Q1/14 , A61Q19/10 , C07C41/01 , C07C41/05 , C07C43/04 , C07C43/10 , C07C43/11 , C07C43/184
CPC分类号： C07C43/184 , A61K8/33 , A61K8/585 , A61K8/8111 , A61Q1/14 , A61Q19/10 , C07C41/01 , C07C43/04 , C07C43/10 , C07C43/11 , C07C2101/14
摘要： To provide a novel ether compound which is useful such as an oil agent and a surfactant having the formula (I): R.sup.1 --O--(AO).sub.n --R.sup.2, wherein R.sup.1 is an alpha-branched alkyl group or an alkyl group having two or more branched chains or a cycloalkyl having 5 to 7 carbon atoms, R.sup.2 is an alkyl or alkenyl each being either branched or straight, each having 10 to 30 carbon atoms, A is an alkylene having 2 to 12 carbon atoms, n is a number from 0 to 30, A's being same as or different from one another.
摘要翻译： PCT No.PCT / JP96 / 01315 Sec。 371日期：1997年11月17日 102（e）日期1997年11月17日PCT提交1996年5月17日PCT公布。 WO96 / 36583 PCT出版物日期1996年11月21日提供一种有用的新型醚化合物，例如油剂和具有式（I）的表面活性剂：R1-O-（AO）n-R2，其中R1是α-支链烷基或具有2个以上支链或5〜7个碳原子的环烷基的烷基，R 2为分支或直链的烷基或烯基，各自具有10〜30个碳原子，A为碳原子数2〜12的亚烷基，n为0〜30的数，A相同或不同。

2. 发明授权

US5914430A Process for producing ether compound 失效
标题翻译：生产醚化合物的方法
公开(公告)号：US5914430A
公开(公告)日：1999-06-22
申请号：US675923
申请日：1996-07-05
申请人： Yasuyuki Fujii , Hisakazu Furugaki , Katsumi Kita , Mitsuru Uno , Eiko Tamura , Hiromasa Matsumoto
发明人： Yasuyuki Fujii , Hisakazu Furugaki , Katsumi Kita , Mitsuru Uno , Eiko Tamura , Hiromasa Matsumoto
IPC分类号： C07C41/01 , C08G65/30 , C08G65/331 , C08G65/338 , C07C43/11
CPC分类号： C07C41/01 , C08G65/30 , C08G65/331 , C08G65/338 , C07C2101/14
摘要： Ether compounds, which are useful as solvents, cosmetics, detergents, lubricants, emulsifiers and so on, are produced by reacting (a) a hydroxy compound with a carbonyl compound of (b) a carbonyl compound under hydrogen atmosphere in the presence of a catalyst with ease and at a low cost. The reaction is carried out while removing out produced water by using a dehydrating agent during the reaction; by distilling off the water by azeotropic dehydration and the like; or by blowing gases such as hydrogen gas to flow through the reaction system.
摘要翻译：可用作溶剂，化妆品，洗涤剂，润滑剂，乳化剂等的醚化合物通过（a）羟基化合物与（b）羰基化合物的羰基化合物在氢气氛下在催化剂存在下反应来制备轻松，低成本。反应在反应期间通过使用脱水剂除去生成的水进行反应; 通过共沸脱水等蒸馏除去水分; 或通过吹入气体如氢气流过反应体系。

3. 发明授权

US5409705A Phosphobetaine and detergent and cosmetic containing the same 失效
标题翻译：磷酸甜菜碱和洗涤剂和化妆品含有相同的含量
公开(公告)号：US5409705A
公开(公告)日：1995-04-25
申请号：US796337
申请日：1991-11-22
申请人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
发明人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
IPC分类号： C07F9/09 , C07F9/655 , C07H11/04 , C07H15/04 , C08B31/06 , C11D1/88 , C11D3/22 , C11D3/36 , C07C69/76 , A61K7/06 , C07H15/00
CPC分类号： C11D3/364 , A61K8/55 , A61Q19/00 , C07F9/091 , C07F9/65515 , C07H11/04 , C07H15/04 , C08B31/066 , C11D1/886 , C11D3/228 , A61Q19/10 , A61Q5/00 , A61Q5/006 , A61Q5/02
摘要： A novel phosphobetaine is disclosed. This compound is very excellence in that it exerts a conditioning effect of imparting a good feel to the skin or hair, is excellent in humidifying properties, is available at a low price, and thus it is highly usable in detergents, cosmetics, a bathing preparation and the like. A detergent composition, a cosmetic, and a bathing preparation each containing the phosphobetaine are also disclosed.
摘要翻译：公开了一种新的磷酸甜菜碱。该化合物非常优异地发挥赋予皮肤或毛发良好感觉的调理效果，加湿性优异，可以低价位获得，因此其可用于洗涤剂，化妆品，洗浴用品等等。还公开了含有磷酸甜菜碱的洗涤剂组合物，化妆品和洗浴剂。

4. 发明授权

US5929283A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5929283A
公开(公告)日：1999-07-27
申请号：US935539
申请日：1997-09-23
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C215/06
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译：本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可具有-OH并且具有1-24个碳原子的烷基或烯基，A表示亚烷基或亚烯基，可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子，y1是-COOH，-SO3H或-OSO3H，y2表示-OH，-OSO3H或-OCO-A-COOH，n表示 0或1的数，p为1-8的整数，或其盐或季铵化产物，以及含有这种化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

5. 发明授权

US5723655A Amine compound and detergent composition containing the same 失效
标题翻译：胺化合物和含有它的洗涤剂组合物
公开(公告)号：US5723655A
公开(公告)日：1998-03-03
申请号：US750981
申请日：1997-01-07
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita
IPC分类号： C07C229/16 , C07C233/36 , C07C309/14 , C07C309/17 , C07D303/36 , C11D1/10 , C11D1/28 , C11D3/33 , C11D3/34 , C07C229/26 , C07C229/30 , C07C235/10
CPC分类号： A61K8/466 , A61K8/44 , C07C229/16 , C07C233/36 , C07C309/14 , C07C309/17 , C07D303/36 , C11D1/10 , C11D1/28 , C11D3/33 , C11D3/349 , A61K2800/75 , A61Q19/10 , A61Q5/02 , C11D3/3472
摘要： The present invention relates to an amine compound represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent individually a linear or branched C.sub.1 -C.sub.24 alkyl or alkenyl group which may be substituted by a hydroxyl group, X.sup.1 represents a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by a hydroxyl, sulfonic or carboxyl group, Y.sup.1 represents a carboxyl or sulfonic group, or a sulfuric acid residue, Y.sup.2 represents a hydroxyl group, a sulfuric acid residue or a group --OCO--X.sup.1 --COOH, Z represents a sulfoalkyl group or a group obtained by removing an amino group from an amino acid or a salt thereof, and n represents a number of 0 or 1, or a salt or quaternized product thereof, an intermediate useful for the preparation thereof, and detergent compositions containing such an amine compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP95 / 00988 Sec。 371日期：1996年1月7日 102（e）日期1996年1月7日PCT提交1995年5月23日PCT公布。公开号WO96 / 01805 日期：1996年1月25日本发明涉及由以下通式（1）表示的胺化合物：其中R 1和R 2分别表示可被取代的直链或支链C 1 -C 24烷基或链烯基通过羟基，X1表示可以被羟基，磺酸或羧基取代的C1-C6亚烷基或亚烯基，Y1表示羧基或磺酸基，或硫酸残基，Y2表示羟基，硫酸酸残基或基团-OCO-X1-COOH，Z表示磺基烷基或通过从氨基酸或其盐除去氨基获得的基团，n表示0或1的数，或者是盐或季铵化的其制品，可用于其制备的中间体和含有这种胺化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

6. 发明授权

US5801270A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5801270A
公开(公告)日：1998-09-01
申请号：US646338
申请日：1996-06-13
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C229/00 , C11D1/04 , C11D1/46
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01923 Sec。 371日期：1996年6月13日 102（e）1996年6月13日PCT 1994年11月14日PCT PCT。出版物WO95 / 16664 日期：1995年6月22日本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可以具有-OH并具有1-24的烷基或烯基碳原子，A表示可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子的亚烷基或亚烯基，Y 1是-COOH，-SO 3 H或-OSO 3 H，Y 2表示-OH，-OSO 3 H 或-OCO-A-COOH，n表示0或1的数，p表示1-8的整数，或其盐或季铵化产物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉悦的感觉。

7. 发明授权

US5756784A Amides, method for preparing the amides, and detergent compositions containing the amides 失效
公开(公告)号：US5756784A
公开(公告)日：1998-05-26
申请号：US646767
申请日：1996-05-08
申请人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
IPC分类号： A61K8/42 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C07C233/05 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/30 , C07C305/06 , C07C309/15 , C11D1/52 , C11D3/32
CPC分类号： C11D3/32 , A61K8/42 , A61Q19/00 , A61Q19/10 , A61Q5/02 , C07C231/02 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/24 , C07C303/32 , C07C309/15 , C11D1/528 , A61Q5/12
摘要： An amide represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are C1-C24 alkyl, etc.; B is C2-C10 alkylene, etc.; A.sup.1 and A.sup.2 are C1-C6 alkylene, etc.; Y.sup.1 and Y.sup.2 are ##STR2## wherein R.sup.3, R.sup.4, and R.sup.5 are C1-C4 alkyl, etc., and X.sup.1 is halogen; or a salt of the amide and detergent compositions containing the amide or salt are mild to the skin or hair, provide a pleasant sensation to the skin or hair, and have excellent latherability and emulsion stability. These compounds are useful as components of various detergents and cosmetic compositions, emulsifiers, and conditioners.

8. 发明授权

US5885955A Amides, method for preparing the amides, and detergent compositions containing the amides 失效
标题翻译：酰胺，制备酰胺的方法和含有酰胺的洗涤剂组合物
公开(公告)号：US5885955A
公开(公告)日：1999-03-23
申请号：US967918
申请日：1997-11-12
申请人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
IPC分类号： A61K8/42 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C07C233/05 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/30 , C07C305/06 , C07C309/15 , C11D1/52 , C11D3/32 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/66
CPC分类号： C11D3/32 , A61K8/42 , A61Q19/00 , A61Q19/10 , A61Q5/02 , C07C231/02 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/24 , C07C303/32 , C07C309/15 , C11D1/528 , A61Q5/12
摘要： An amide represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are C1-C24 alkyl, etc.; B is C2-C10 alkylene, etc.; A.sup.1 and A.sup.2 are C1-C6 alkylene, etc.; Y.sup.1 and Y.sup.2 are ##STR2## wherein R.sup.3, R.sup.4, and R.sup.5 are C1-C4 alkyl, etc., and X.sup.1 is halogen; or a salt of the amide and detergent compositions containing the amide or salt are mild to the skin or hair, provide a pleasant sensation to the skin or hair, and have excellent latherability and emulsion stability. These compounds are useful as components of various detergents and cosmetic compositions, emulsifiers, and conditioners.
摘要翻译：由下式（1）表示的酰胺：其中R 1和R 2是C 1 -C 24烷基等; B是C 2 -C 10亚烷基等; A1和A2是C1-C6亚烷基等; Y 1和Y 2是其中R 3，R 4和R 5是C 1 -C 4烷基等，且X 1是卤素; 或含有酰胺或盐的酰胺和洗涤剂组合物的盐对皮肤或毛发温和，对皮肤或毛发提供愉快的感觉，并且具有优异的起泡性和乳液稳定性。这些化合物可用作各种洗涤剂和化妆品组合物，乳化剂和调理剂的组分。

9. 发明授权

US5714457A 2-hydroxypropanediamine derivative and detergent composition containing the same 失效
标题翻译： 2-羟基丙二胺衍生物和含有它们的洗涤剂组合物
公开(公告)号：US5714457A
公开(公告)日：1998-02-03
申请号：US569128
申请日：1996-01-11
申请人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
发明人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
IPC分类号： A61K8/41 , A61K8/44 , A61K8/68 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/13 , C07C309/14 , C07C309/17 , C11D1/02 , C11D1/10 , C11D1/28 , C11D1/92
CPC分类号： A61Q19/00 , A61K8/41 , A61K8/416 , A61K8/44 , A61K8/68 , A61Q5/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/14 , C07C309/17 , C11D1/10 , C11D1/28 , C11D3/0094 , A61K2800/75 , A61Q19/10 , A61Q5/02
摘要： The present invention relates to a 2-hydroxypropanediamine derivative represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 mean individually a linear or branched C.sub.6 -C.sub.36 alkyl or alkenyl group, X denotes a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by at least one hydroxyl, sulfonic or carboxyl group and has 1-6 carbon atoms, y.sup.1 is a sulfonic group, a sulfuric acid residue or a carboxyl group, y.sup.2 means a hydroxyl group, a sulfuric acid residue or ##STR2## and n stands for 0 or 1, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01129 Sec。 371日期1996年1月11日 102（e）日期1996年1月11日PCT提交1994年7月11日PCT公布。出版物WO95 / 01955 日本1 9月19日本发明涉及由以下通式（1）表示的2-羟基丙二胺衍生物：其中R 1和R 2分别表示直链或支链C 6 -C 36烷基或链烯基，X 表示可以被至少一个羟基，磺酸或羧基取代并具有1-6个碳原子的C1-C6亚烷基或亚烯基，y1是磺酸基，硫酸残基或羧基，y2表示羟基基团，硫酸残基或，n表示0或1，或其盐或季铵化物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

10. 发明授权

US06437196B1 Process for producing glyceryl ether 有权
标题翻译：甘油醚的制备方法
公开(公告)号：US06437196B1
公开(公告)日：2002-08-20
申请号：US09646749
申请日：2000-09-22
申请人： Tetsuya Miyajima , Mitsuru Uno
发明人： Tetsuya Miyajima , Mitsuru Uno
IPC分类号： C07C4103
CPC分类号： C07C41/26 , C07C43/13
摘要： A process for producing a glyceryl ether which contains a markedly small amount of organohalogen compounds and therefore can be used even for cosmetics and body detergents. The process comprises reacting an alcohol with an &agr;-epihalohydrin in the presence of an acid catalyst, subjecting the reaction mixture to ring closure to convert it into the corresponding glycidyl ether and then hydrolyzing the glycidyl ether, wherein: (a) the hydrolysis is effected at 140 to 230° C. in the presence of a salt formed from a strongly basic compound and a weakly acidic compound, or (b) the reaction mixture after the hydrolysis is heated at 100 to 230° C. in the presence of a salt formed from a strongly basic compound and a weakly acidic compound.
摘要翻译：一种生产含有显着少量有机卤素化合物的甘油醚的方法，因此甚至可用于化妆品和身体洗涤剂。该方法包括在酸催化剂存在下使醇与α-表卤醇反应，使反应混合物闭环以将其转化为相应的缩水甘油醚，然后水解缩水甘油醚，其中：（a）进行水解在由强碱性化合物和弱酸性化合物形成的盐的存在下，在140〜230℃下，或（b）将水解后的反应混合物在盐酸存在下在100〜230℃下加热由强碱性化合物和弱酸性化合物形成。

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