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1. 发明授权

US5885955A Amides, method for preparing the amides, and detergent compositions containing the amides 失效
标题翻译：酰胺，制备酰胺的方法和含有酰胺的洗涤剂组合物
公开(公告)号：US5885955A
公开(公告)日：1999-03-23
申请号：US967918
申请日：1997-11-12
申请人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
IPC分类号： A61K8/42 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C07C233/05 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/30 , C07C305/06 , C07C309/15 , C11D1/52 , C11D3/32 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/66
CPC分类号： C11D3/32 , A61K8/42 , A61Q19/00 , A61Q19/10 , A61Q5/02 , C07C231/02 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/24 , C07C303/32 , C07C309/15 , C11D1/528 , A61Q5/12
摘要： An amide represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are C1-C24 alkyl, etc.; B is C2-C10 alkylene, etc.; A.sup.1 and A.sup.2 are C1-C6 alkylene, etc.; Y.sup.1 and Y.sup.2 are ##STR2## wherein R.sup.3, R.sup.4, and R.sup.5 are C1-C4 alkyl, etc., and X.sup.1 is halogen; or a salt of the amide and detergent compositions containing the amide or salt are mild to the skin or hair, provide a pleasant sensation to the skin or hair, and have excellent latherability and emulsion stability. These compounds are useful as components of various detergents and cosmetic compositions, emulsifiers, and conditioners.
摘要翻译：由下式（1）表示的酰胺：其中R 1和R 2是C 1 -C 24烷基等; B是C 2 -C 10亚烷基等; A1和A2是C1-C6亚烷基等; Y 1和Y 2是其中R 3，R 4和R 5是C 1 -C 4烷基等，且X 1是卤素; 或含有酰胺或盐的酰胺和洗涤剂组合物的盐对皮肤或毛发温和，对皮肤或毛发提供愉快的感觉，并且具有优异的起泡性和乳液稳定性。这些化合物可用作各种洗涤剂和化妆品组合物，乳化剂和调理剂的组分。

2. 发明授权

US5714457A 2-hydroxypropanediamine derivative and detergent composition containing the same 失效
标题翻译： 2-羟基丙二胺衍生物和含有它们的洗涤剂组合物
公开(公告)号：US5714457A
公开(公告)日：1998-02-03
申请号：US569128
申请日：1996-01-11
申请人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
发明人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
IPC分类号： A61K8/41 , A61K8/44 , A61K8/68 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/13 , C07C309/14 , C07C309/17 , C11D1/02 , C11D1/10 , C11D1/28 , C11D1/92
CPC分类号： A61Q19/00 , A61K8/41 , A61K8/416 , A61K8/44 , A61K8/68 , A61Q5/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/14 , C07C309/17 , C11D1/10 , C11D1/28 , C11D3/0094 , A61K2800/75 , A61Q19/10 , A61Q5/02
摘要： The present invention relates to a 2-hydroxypropanediamine derivative represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 mean individually a linear or branched C.sub.6 -C.sub.36 alkyl or alkenyl group, X denotes a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by at least one hydroxyl, sulfonic or carboxyl group and has 1-6 carbon atoms, y.sup.1 is a sulfonic group, a sulfuric acid residue or a carboxyl group, y.sup.2 means a hydroxyl group, a sulfuric acid residue or ##STR2## and n stands for 0 or 1, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01129 Sec。 371日期1996年1月11日 102（e）日期1996年1月11日PCT提交1994年7月11日PCT公布。出版物WO95 / 01955 日本1 9月19日本发明涉及由以下通式（1）表示的2-羟基丙二胺衍生物：其中R 1和R 2分别表示直链或支链C 6 -C 36烷基或链烯基，X 表示可以被至少一个羟基，磺酸或羧基取代并具有1-6个碳原子的C1-C6亚烷基或亚烯基，y1是磺酸基，硫酸残基或羧基，y2表示羟基基团，硫酸残基或，n表示0或1，或其盐或季铵化物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

3. 发明授权

US5801270A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5801270A
公开(公告)日：1998-09-01
申请号：US646338
申请日：1996-06-13
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C229/00 , C11D1/04 , C11D1/46
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01923 Sec。 371日期：1996年6月13日 102（e）1996年6月13日PCT 1994年11月14日PCT PCT。出版物WO95 / 16664 日期：1995年6月22日本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可以具有-OH并具有1-24的烷基或烯基碳原子，A表示可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子的亚烷基或亚烯基，Y 1是-COOH，-SO 3 H或-OSO 3 H，Y 2表示-OH，-OSO 3 H 或-OCO-A-COOH，n表示0或1的数，p表示1-8的整数，或其盐或季铵化产物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉悦的感觉。

4. 发明授权

US5756784A Amides, method for preparing the amides, and detergent compositions containing the amides 失效
公开(公告)号：US5756784A
公开(公告)日：1998-05-26
申请号：US646767
申请日：1996-05-08
申请人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tetsuya Miyajima , Tomohito Kitsuki , Katsumi Kita
IPC分类号： A61K8/42 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C07C233/05 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/30 , C07C305/06 , C07C309/15 , C11D1/52 , C11D3/32
CPC分类号： C11D3/32 , A61K8/42 , A61Q19/00 , A61Q19/10 , A61Q5/02 , C07C231/02 , C07C233/36 , C07C233/47 , C07C303/22 , C07C303/24 , C07C303/32 , C07C309/15 , C11D1/528 , A61Q5/12
摘要： An amide represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are C1-C24 alkyl, etc.; B is C2-C10 alkylene, etc.; A.sup.1 and A.sup.2 are C1-C6 alkylene, etc.; Y.sup.1 and Y.sup.2 are ##STR2## wherein R.sup.3, R.sup.4, and R.sup.5 are C1-C4 alkyl, etc., and X.sup.1 is halogen; or a salt of the amide and detergent compositions containing the amide or salt are mild to the skin or hair, provide a pleasant sensation to the skin or hair, and have excellent latherability and emulsion stability. These compounds are useful as components of various detergents and cosmetic compositions, emulsifiers, and conditioners.

5. 发明授权

US5929283A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5929283A
公开(公告)日：1999-07-27
申请号：US935539
申请日：1997-09-23
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C215/06
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译：本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可具有-OH并且具有1-24个碳原子的烷基或烯基，A表示亚烷基或亚烯基，可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子，y1是-COOH，-SO3H或-OSO3H，y2表示-OH，-OSO3H或-OCO-A-COOH，n表示 0或1的数，p为1-8的整数，或其盐或季铵化产物，以及含有这种化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

6. 发明授权

US5723655A Amine compound and detergent composition containing the same 失效
标题翻译：胺化合物和含有它的洗涤剂组合物
公开(公告)号：US5723655A
公开(公告)日：1998-03-03
申请号：US750981
申请日：1997-01-07
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita
IPC分类号： C07C229/16 , C07C233/36 , C07C309/14 , C07C309/17 , C07D303/36 , C11D1/10 , C11D1/28 , C11D3/33 , C11D3/34 , C07C229/26 , C07C229/30 , C07C235/10
CPC分类号： A61K8/466 , A61K8/44 , C07C229/16 , C07C233/36 , C07C309/14 , C07C309/17 , C07D303/36 , C11D1/10 , C11D1/28 , C11D3/33 , C11D3/349 , A61K2800/75 , A61Q19/10 , A61Q5/02 , C11D3/3472
摘要： The present invention relates to an amine compound represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent individually a linear or branched C.sub.1 -C.sub.24 alkyl or alkenyl group which may be substituted by a hydroxyl group, X.sup.1 represents a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by a hydroxyl, sulfonic or carboxyl group, Y.sup.1 represents a carboxyl or sulfonic group, or a sulfuric acid residue, Y.sup.2 represents a hydroxyl group, a sulfuric acid residue or a group --OCO--X.sup.1 --COOH, Z represents a sulfoalkyl group or a group obtained by removing an amino group from an amino acid or a salt thereof, and n represents a number of 0 or 1, or a salt or quaternized product thereof, an intermediate useful for the preparation thereof, and detergent compositions containing such an amine compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP95 / 00988 Sec。 371日期：1996年1月7日 102（e）日期1996年1月7日PCT提交1995年5月23日PCT公布。公开号WO96 / 01805 日期：1996年1月25日本发明涉及由以下通式（1）表示的胺化合物：其中R 1和R 2分别表示可被取代的直链或支链C 1 -C 24烷基或链烯基通过羟基，X1表示可以被羟基，磺酸或羧基取代的C1-C6亚烷基或亚烯基，Y1表示羧基或磺酸基，或硫酸残基，Y2表示羟基，硫酸酸残基或基团-OCO-X1-COOH，Z表示磺基烷基或通过从氨基酸或其盐除去氨基获得的基团，n表示0或1的数，或者是盐或季铵化的其制品，可用于其制备的中间体和含有这种胺化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

7. 发明授权

US5409705A Phosphobetaine and detergent and cosmetic containing the same 失效
标题翻译：磷酸甜菜碱和洗涤剂和化妆品含有相同的含量
公开(公告)号：US5409705A
公开(公告)日：1995-04-25
申请号：US796337
申请日：1991-11-22
申请人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
发明人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
IPC分类号： C07F9/09 , C07F9/655 , C07H11/04 , C07H15/04 , C08B31/06 , C11D1/88 , C11D3/22 , C11D3/36 , C07C69/76 , A61K7/06 , C07H15/00
CPC分类号： C11D3/364 , A61K8/55 , A61Q19/00 , C07F9/091 , C07F9/65515 , C07H11/04 , C07H15/04 , C08B31/066 , C11D1/886 , C11D3/228 , A61Q19/10 , A61Q5/00 , A61Q5/006 , A61Q5/02
摘要： A novel phosphobetaine is disclosed. This compound is very excellence in that it exerts a conditioning effect of imparting a good feel to the skin or hair, is excellent in humidifying properties, is available at a low price, and thus it is highly usable in detergents, cosmetics, a bathing preparation and the like. A detergent composition, a cosmetic, and a bathing preparation each containing the phosphobetaine are also disclosed.
摘要翻译：公开了一种新的磷酸甜菜碱。该化合物非常优异地发挥赋予皮肤或毛发良好感觉的调理效果，加湿性优异，可以低价位获得，因此其可用于洗涤剂，化妆品，洗浴用品等等。还公开了含有磷酸甜菜碱的洗涤剂组合物，化妆品和洗浴剂。

8. 发明申请

US20060252946A1 Production process for glycidyl ether adduct and catalyst used for the process 审中-公开
标题翻译：用于该方法的缩水甘油醚加合物和催化剂的制备方法
公开(公告)号：US20060252946A1
公开(公告)日：2006-11-09
申请号：US11482749
申请日：2006-07-10
申请人： Atsushi Nagasawa , Mitsuru Uno , Tomohito Kitsuki
发明人： Atsushi Nagasawa , Mitsuru Uno , Tomohito Kitsuki
IPC分类号： C07D301/27 , C07H1/00
CPC分类号： C11D1/72 , B01J21/10 , B01J23/002 , B01J23/06 , B01J2523/00 , B01J2523/22 , B01J2523/31 , B01J2523/27
摘要： Provided is a catalyst for adding a glycidyl ether to an active hydrogen-containing organic compound, comprising a complex oxide of magnesium and at least one element other than magnesium selected from the group consisting of the elements in the third period and the fourth period in the periodic table. Also provided is a process for producing a glycidyl ether adduct, which comprises subjecting an active hydrogen-containing organic compound and a glycidyl ether to an addition reaction in the presence of the above-mentioned catalyst. In the addition reaction between the active hydrogen-containing organic compound and the glycidyl ether, use of the catalyst of the present invention enables inhibition of an excess addition reaction of the glycidyl ether which is a successive reaction, and a mono- or di-(alkyl, alkenyl or phenyl) ether product in which one or two glycidyl ethers are added is selectively produced by adjusting the mole ratio of the active hydrogen-containing organic compound to the glycidyl ether to a specific range. Accordingly, the mono- or di-(alkyl, alkenyl or phenyl) ether product can be obtained at a high productivity with a high purity.
摘要翻译：提供了一种用于向含活性氢的有机化合物中加入缩水甘油醚的催化剂，其包含镁和至少一种除镁以外的元素的复合氧化物，所述复合氧化物选自第三周期和第四周期中的元素组周期表。还提供了一种制备缩水甘油醚加合物的方法，其包括在上述催化剂存在下使含活性氢的有机化合物和缩水甘油醚进行加成反应。在含活性氢的有机化合物和缩水甘油醚之间的加成反应中，使用本发明的催化剂可以抑制作为连续反应的缩水甘油醚的过量加成反应，以及单 - 或二烷基，烯基或苯基）醚产物，其中加入一个或两个缩水甘油醚是通过将含活性氢的有机化合物与缩水甘油醚的摩尔比调整到特定范围来选择性地制备的。因此，可以以高纯度的高生产率获得单 - 或二 - （烷基，烯基或苯基）醚产物。

9. 发明授权

US06207845B1 Aluminum compounds and use thereof 有权
标题翻译：铝化合物及其用途
公开(公告)号：US06207845B1
公开(公告)日：2001-03-27
申请号：US09403765
申请日：1999-11-01
申请人： Munehisa Okutsu , Tomohito Kitsuki , Katsumi Kita
发明人： Munehisa Okutsu , Tomohito Kitsuki , Katsumi Kita
IPC分类号： C07F506
CPC分类号： B01J31/143 , B01J31/0212 , B01J31/0225 , B01J2231/40 , B01J2231/48 , C07C41/03 , C07C309/04 , C07C309/30 , C07C309/31 , C07C309/35 , C07C309/42 , C07F5/061 , C07F5/069 , C07C43/135 , C07C43/137 , C07C43/13
摘要： An aluminum compounds represented by the following general formula (1): Al(R1—SO3)1(R2)m(R3)n (1) wherein R1 is a hydrocarbon group which may be substituted, R2 is a hydrocarbon group which may be substituted, an aliphatic hydrocarbonoxy group which may be substituted, or a halogen atom, R3 is an aromatic hydrocarbonoxy group which may be substituted, and 1, m and n are independently a number of 0 to 3, with the proviso that 1+m+n equals 3, and 1 is not 0, an acid catalyst comprising the aluminum compound, and a process for producing an ester, acetal, ketal, ether or alkyl glycoside making use of the catalyst. The catalyst is suitable for use in a variety of acid-catalyzed reactions of alcohols, i.e., reactions with carbonyl compounds, such as esterification, transesterification, acetalization and ketalization, etherification, ring-opening reactions of epoxy compounds, etc. in addition to the above-described respective reactions, is not deactivated by alcoholysis, has a sufficient activity, can easily control a reaction catalyzed thereby and scarcely causes side reactions. Consequently, the use of the catalyst permits the production of the intended product at a high yield from starting materials used in an almost equimolar proportion.
摘要翻译：由以下通式（1）表示的铝化合物：其中R1是可被取代的烃基，R2是可被取代的烃基，可被取代的脂族烃氧基或卤素原子，R3是可以被取代的芳族烃氧基，并且1，m和n独立地为0-3的数，条件是1 + m + n等于3，并且1不为0，包含铝化合物的酸催化剂，以及利用催化剂生产酯，缩醛，缩酮，醚或烷基糖苷的方法。该催化剂适用于各种酸催化的醇反应，即与羰基化合物的反应，如酯化，酯交换，缩醛化和缩酮化，醚化，环氧化合物的开环反应等除了上述各自的反应之外，不通过醇解使其失活，具有足够的活性，可以容易地控制ar 因此催化，并且几乎不引起副反应。因此，使用催化剂允许以几乎等摩尔比例使用的起始材料从高产率生产所需产品。

10. 发明授权

US06372923B1 Process for preparing alcohol derivatives 失效
标题翻译：醇衍生物的制备方法
公开(公告)号：US06372923B1
公开(公告)日：2002-04-16
申请号：US09583777
申请日：2000-05-31
申请人： Mitsuru Uno , Munehisa Okutsu , Tomohito Kitsuki
发明人： Mitsuru Uno , Munehisa Okutsu , Tomohito Kitsuki
IPC分类号： C07D30128
CPC分类号： C07D303/22 , C07B41/00
摘要： The present invention provides a process for preparing an alcohol derivative, where the alcohol derivative is an ester, acetal, ketal, ether glycoside, or alkyl glycoside, by reacting an alcohol with a carbonyl compound, alcohol, olefin, epoxy compound or saccharide, where C2-4 vicinal alkylene oxides are excluded, in the presence of (A) an aluminum alkoxide and (B) sulfuric acid or phosphoric acid.
摘要翻译：本发明提供一种醇衍生物的制备方法，其中醇衍生物为酯，缩醛，缩酮，醚糖苷或烷基糖苷，通过醇与羰基化合物，醇，烯烃，环氧化合物或糖反应，其中在（A）烷氧基铝和（B）硫酸或磷酸的存在下，不排除C2-4连位烯化氧。

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