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1. 发明授权

US5728839A Metal complexes with heterocycles carbenes 失效
标题翻译：金属络合物与杂环碳烯
公开(公告)号：US5728839A
公开(公告)日：1998-03-17
申请号：US581029
申请日：1995-12-29
申请人： Wolfgang A. Herrmann , Martina Elison , Jakob Fischer , Christian Kocher , Karl Ofele
发明人： Wolfgang A. Herrmann , Martina Elison , Jakob Fischer , Christian Kocher , Karl Ofele
IPC分类号： B01J31/18 , B01J31/22 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F7/02
CPC分类号： C07F15/0086 , B01J31/2265 , B01J31/2273 , B01J31/2295 , C07F15/002 , C07F15/0033 , C07F15/0046 , C07F15/006 , C07F15/0073 , B01J2231/54 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828
摘要： A complex of the formula �L.sub.a M.sub.b X.sub.c !.sup.n (A).sub.n I as described in the application useful as homogenous catalysts.
摘要翻译：本申请中所述的式[LaMbXc] n（A）n I的络合物可用作均匀的催化剂。

2. 发明授权

US5663451A Process for preparing aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US5663451A
公开(公告)日：1997-09-02
申请号：US581399
申请日：1995-12-29
申请人： Wolfgang A. Herrmann , Martina Elison , Jakob Fischer , Christian Kocher
发明人： Wolfgang A. Herrmann , Martina Elison , Jakob Fischer , Christian Kocher
IPC分类号： B01J31/02 , B01J31/18 , B01J31/22 , C07B61/00 , C07C45/50 , C07C47/02
CPC分类号： C07C45/50 , B01J31/2265 , B01J31/2273 , B01J2231/321 , B01J2531/822 , B01J2531/845 , B01J2531/96
摘要： A process for the hydroformylation of olefins and olefinically unsaturated compounds in the presence of cobalt or rhodium complexes which contain, as complexing ligands, heterocyclic carbenes and, if desired, further ligands.
摘要翻译：在钴或铑络合物的存在下，烯烃和烯属不饱和化合物的加氢甲酰化的方法，其包含作为络合配体的杂环卡宾，以及如果需要的话，还包含其它配体。

3. 发明授权

US5703269A Process for preparing aromatic olefins 失效
标题翻译：芳烃烯烃的制备方法
公开(公告)号：US5703269A
公开(公告)日：1997-12-30
申请号：US581397
申请日：1995-12-29
申请人： Wolfgang A. Herrmann , Jakob Fischer , Martina Elison , Christian Kocher
发明人： Wolfgang A. Herrmann , Jakob Fischer , Martina Elison , Christian Kocher
IPC分类号： B01J31/18 , B01J31/22 , C07B37/04 , C07B61/00 , C07C2/86 , C07C15/52 , C07C17/266 , C07C41/30 , C07C43/20 , C07C45/68 , C07C47/52 , C07C49/76 , C07C67/343 , C07C69/618 , C07C69/732 , C07C69/734 , C07C69/738 , C07C205/06 , C07C205/56 , C07C229/44 , C07C303/22 , C07C315/04 , C07C9/734
CPC分类号： B01J31/2265 , B01J31/2273 , C07B37/04 , C07C17/266 , C07C201/12 , C07C227/16 , C07C41/30 , C07C45/68 , C07C67/343 , B01J2231/4261 , B01J2531/824
摘要： The preparation of aromatic olefins from haloaromatics and olefins (Heck reaction) is carried out in the presence of palladium complexes as catalysts, which complexes contain heterocyclic carbenes as ligands.
摘要翻译：从卤代芳烃和烯烃（Heck反应）制备芳族烯烃在钯配合物作为催化剂存在下进行，该络合物含有杂环卡宾作为配体。

4. 发明授权

US6025496A Process for preparing heterocyclic carbenes 失效
标题翻译：制备杂环卡宾的方法
公开(公告)号：US6025496A
公开(公告)日：2000-02-15
申请号：US155065
申请日：1998-11-02
申请人： Wolfgang A. Herrmann , Christian Kocher , Lukas Goossen
发明人： Wolfgang A. Herrmann , Christian Kocher , Lukas Goossen
IPC分类号： C07D233/10 , C07D233/06 , C07D233/12 , C07D233/14 , C07D233/16 , C07D233/20 , C07D249/08 , C07D401/06 , C07F9/6506
CPC分类号： C07D233/06 , C07D233/20 , C07D249/08 , C07D401/14 , C07F9/65061
摘要： A process for preparing heterocyclic carbenes of the ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are individually saturated or unsaturated, straight chain, branched or cyclic, unsubstituted or substituted C.sub.1 -C.sub.10 alkyl, C.sub.2 -C.sub.5 alkylidene, C.sub.2 -C.sub.5 alkylidine, C.sub.7 -C.sub.19 aralkyl or C.sub.6 -C.sub.14 alkyl groups, R.sup.3 and R.sup.4 can also stand for hydrogen or form jointly anellated, substituted or unsubstituted groups with between 3 and 7 carbon atoms and X stands for carbon or nitrogen, R.sup.3 being dropped if X is nitrogen comprising reacting azolium salts with a deprotonizing reagent in pure liquid ammonia or in pure organic amine or a mixture of liquid ammonia or an organic amine and an organic polar-aprotic solvent which are a plurality of temperature-sensitive carbenes are produced under mild reaction conditions at temperatures of between -75 and 0.degree. C.
摘要翻译： PCT No.PCT / EP97 / 01296 Sec。 371日期：1998年11月2日 102（e）1998年11月2日日期PCT 1997年3月14日PCT公布。出版物WO97 / 34875 日期：1997年9月25日制备其中R 1，R 2，R 3和R 4分别为饱和或不饱和的直链，支链或环状，未取代或取代的C 1 -C 10烷基，C 2 -C 5亚烷基， C5烷基化烷基，C7-C19芳烷基或C6-C14烷基，R3和R4也可以代表氢或形成具有3-7个碳原子的联合的，有取代或未取代的基团，X代表碳或氮，R3如果 X是氮，其包括在纯液氨或纯有机胺或液态氨或有机胺和有机极性非质子溶剂的混合物中在纯液氨或脱氨基化试剂中反应，其为多种温度敏感的碳烯，温和在-75至0℃的温度下的反应条件

5. 发明授权

US5466644A Reactivation of water-soluble hydroformylation catalysts 失效
标题翻译：水溶性加氢甲酰化催化剂的再活化
公开(公告)号：US5466644A
公开(公告)日：1995-11-14
申请号：US378861
申请日：1995-01-19
申请人： Werner Konkol , Helmut Bahrmann , Wolfgang A. Herrmann , Christian Kohlpaintner
发明人： Werner Konkol , Helmut Bahrmann , Wolfgang A. Herrmann , Christian Kohlpaintner
IPC分类号： B01J27/185 , B01J27/28 , B01J31/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C27/20 , C07C27/22 , C07C45/50 , C07C45/85 , C07C47/02 , B01J38/62
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/2404 , B01J31/2447 , C07C45/50 , C07C45/85 , B01J2231/321 , B01J2531/822 , B01J2531/96 , Y02P20/584
摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.
摘要翻译：一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物，由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯（-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。

6. 发明授权

US07084222B2 Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效
标题翻译：钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法
公开(公告)号：US07084222B2
公开(公告)日：2006-08-01
申请号：US10489921
申请日：2002-09-19
申请人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
发明人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
IPC分类号： C08F4/80 , C07F15/00
CPC分类号： C07D239/04 , C07D233/02 , C07F15/0046 , C08G61/08
摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.
摘要翻译：本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法，在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。

7. 发明授权

US5616734A Process for the catalytic oxidation of aromatic compounds 失效
标题翻译：芳香族化合物的催化氧化方法
公开(公告)号：US5616734A
公开(公告)日：1997-04-01
申请号：US378231
申请日：1995-01-25
申请人： Wolfgang A. Herrmann , Joao D. G. Correia , Richard Fischer , Waldemar Adam , Jianhua Lin , Chantu R. Saha-Moller , Masao Shimizu
发明人： Wolfgang A. Herrmann , Joao D. G. Correia , Richard Fischer , Waldemar Adam , Jianhua Lin , Chantu R. Saha-Moller , Masao Shimizu
IPC分类号： B01J31/12 , C07B61/00 , C07C27/00 , C07C37/60 , C07C39/07 , C07C39/225 , C07C46/04 , C07C46/06 , C07C50/02 , C07C50/10 , C07C50/28 , C07C51/285 , C07C63/331 , C07D311/74 , C07C50/04
CPC分类号： C07C46/04 , C07C37/60 , C07C46/06 , C07C50/10
摘要： The invention relates to the use of compounds of the formula IR.sup.1.sub.a Re.sub.b O.sub.c (I),where a is from 1 to 6, b is from 1 to 4 and c is from 1 to 14 and the sum of a, b and c is in accordance with the valence of from 5 to 7 of the rhenium, with the proviso that c is not greater than 3.multidot.b, and where R.sup.1 is identical or different and is an aliphatic hydrocarbon radical having from 1 to 10 carbon atoms, an aromatic hydrocarbon radical having from 6 to 10 carbon atoms or an arylalkyl radical having from 7 to 9 carbon atoms, with the radicals R.sup.1 being able, if desired, to be identically or differently substituted independently of one another and, in the case of .sigma.-bonded radicals, at least one hydrogen atom still being bonded to the carbon atom in the .alpha. position, as catalysts for the oxidation of electron-rich aromatic compounds and their derivatives and to a process for the oxidation of electron-rich aromatic compounds which comprises oxidizing electron-rich C.sub.6 -C.sub.22 -aryl compounds and their derivatives in the presence of a catalyst of the formula I and a peroxide-containing compound.
摘要翻译：本发明涉及式Ⅰ化合物R1aRebOc（Ⅰ）的用途，其中a为1至6，b为1至4，c为1至14，a，b和c的和为铼的价数为5至7，条件是c不大于3xb，并且其中R1相同或不同，是具有1至10个碳原子的脂族烃基，具有从 6至10个碳原子或具有7至9个碳原子的芳基烷基，如果需要，基团R1能够彼此相同或不同地取代，并且在σ-键合基团的情况下，至少一个氢原子仍然与α位上的碳原子键合，作为用于氧化富含电子的芳族化合物及其衍生物的催化剂，以及氧化富含电子的芳族化合物的方法，其包括将富含电子的C6- C22-芳基化合物及其衍生物在式I催化剂和含过氧化物的化合物存在下进行。

8. 发明授权

US5565398A Sulfonated 2,2'-bis (Diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5565398A
公开(公告)日：1996-10-15
申请号：US552289
申请日：1995-11-02
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/50 , B01J31/00 , C07F15/00
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m--C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译：其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。

9. 发明授权

US5481045A Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5481045A
公开(公告)日：1996-01-02
申请号：US240902
申请日：1994-05-11
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/50 , C07C47/11
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 -SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译：其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。

10. 发明授权

US5342985A Organic derivatives of rhenium oxides and their preparation and use for the metathesis of olefins 失效
标题翻译：铼氧化物的有机衍生物及其制备和用于烯烃复分解的用途
公开(公告)号：US5342985A
公开(公告)日：1994-08-30
申请号：US569614
申请日：1990-08-20
申请人： Wolfgang A. Herrmann , Werner Wagner , Ursula Volkhardt
发明人： Wolfgang A. Herrmann , Werner Wagner , Ursula Volkhardt
IPC分类号： B01J31/12 , B01J31/22 , C07C6/04 , C07C6/06 , C07C17/00 , C07C45/67 , C07C67/333 , C07C67/475 , C07F13/00 , C07F7/08 , C07F7/18
CPC分类号： B01J31/2265 , B01J31/122 , C07C17/00 , C07C45/673 , C07C6/04 , C07C6/06 , C07C67/333 , C07C67/475 , C07F13/00 , B01J2231/543 , B01J2531/74 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/20 , C07C2523/26 , C07C2531/12 , C07C2531/34 , C07C2531/36 , C07C2531/38
摘要： The invention relates to a process for the metathesis of olefins which comprises reacting an olefin of the formula YCZ.dbd.CZ--(CX.sub.2).sub.n R.sup.2 (II) whereinn is an integer from 1 to 28,X represents H or F,Y represents H or alkyl having from 1 to 10 carbon atoms andZ represents H or a non-aromatic hydrocarbon group having from 1 to 6 carbon atoms and R.sup.2 represents H, alkyl, halogen, COOR.sup.3 or OR.sup.4, wherein R.sup.3 and R.sup.4 represent alkyl having from 1 to 15 carbon atoms or phenyl which is unsubstituted or contains from 1 to 3 substituents or wherein R.sup.4 is trialkylsilyl R.sup.5 Si, wherein R.sup.5 represents alkyl having from 1 to 5 carbon atoms, at a catalyst comprising an oxidic carrier charged with a rhenium compound as defined hereinbefore.
摘要翻译：本发明涉及烯烃复分解方法，该方法包括使式YCZ = CZ-（CX2）nR2（Ⅱ）的烯烃反应，其中n为1至28的整数，X代表H或F，Y代表H或具有1至10个碳原子的烷基，Z表示H或具有1至6个碳原子的非芳族烃基，R 2表示H，烷基，卤素，COOR 3或OR 4，其中R 3和R 4表示具有1至15个碳原子的烷基原子或苯基，其未被取代或含有1至3个取代基或其中R 4为三烷基甲硅烷基R 5 Si，其中R 5表示具有1至5个碳原子的烷基，该催化剂包含负载有上文定义的铼化合物的氧化载体。

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