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1. 发明授权

US5466644A Reactivation of water-soluble hydroformylation catalysts 失效
标题翻译：水溶性加氢甲酰化催化剂的再活化
公开(公告)号：US5466644A
公开(公告)日：1995-11-14
申请号：US378861
申请日：1995-01-19
申请人： Werner Konkol , Helmut Bahrmann , Wolfgang A. Herrmann , Christian Kohlpaintner
发明人： Werner Konkol , Helmut Bahrmann , Wolfgang A. Herrmann , Christian Kohlpaintner
IPC分类号： B01J27/185 , B01J27/28 , B01J31/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C27/20 , C07C27/22 , C07C45/50 , C07C45/85 , C07C47/02 , B01J38/62
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/2404 , B01J31/2447 , C07C45/50 , C07C45/85 , B01J2231/321 , B01J2531/822 , B01J2531/96 , Y02P20/584
摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.
摘要翻译：一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物，由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯（-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。

2. 发明授权

US5312951A 3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbornadiene, process for the preparation thereof and process for the hydroformylation of olefinnically unsaturated compounds 失效
标题翻译： 3,4-二甲基-2,5,6-三（对磺酸苯基）-1-膦酰基降冰片二烯，其制备方法和烯烃不饱和化合物的加氢甲酰化方法
公开(公告)号：US5312951A
公开(公告)日：1994-05-17
申请号：US78975
申请日：1993-06-17
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Christian Kohlpaintner , Helmut Bahrmann
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Christian Kohlpaintner , Helmut Bahrmann
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6568 , C07F15/00 , C07F9/02
CPC分类号： B01J31/248 , C07C45/50 , C07F15/008 , C07F9/65683 , B01J2231/321 , B01J2531/822
摘要： The chemical compound 3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbernadiene, a process for the preparation thereof and a process for the hydroformylation of olefinically unsaturated compounds with the use of catalysts which contain the aforementioned chemical compound.
摘要翻译：化合物3,4-二甲基-2,5,6-三（对磺酸苯基）-1-膦酰苯二烯，其制备方法以及烯属不饱和化合物的加氢甲酰化方法，其中使用含有上述化合物。

3. 发明授权

US5347045A Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5347045A
公开(公告)日：1994-09-13
申请号：US66553
申请日：1993-05-25
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/50 , C07C309/35
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译：其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。

4. 发明授权

US5565398A Sulfonated 2,2'-bis (Diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5565398A
公开(公告)日：1996-10-15
申请号：US552289
申请日：1995-11-02
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/50 , B01J31/00 , C07F15/00
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m--C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译：其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。

5. 发明授权

US5481045A Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5481045A
公开(公告)日：1996-01-02
申请号：US240902
申请日：1994-05-11
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/50 , C07C47/11
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 -SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译：其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。

6. 发明授权

US5041228A Process for separating mixtures of substances contained in an aqueous or aqueous/organic solution 失效
标题翻译：用于分离水或水/有机溶液中所含物质的混合物的方法
公开(公告)号：US5041228A
公开(公告)日：1991-08-20
申请号：US373097
申请日：1989-06-28
申请人： W. A. Herrmann , Jurgen Kulpe , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Thomas Muller , Helmut Bahrmann
发明人： W. A. Herrmann , Jurgen Kulpe , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Thomas Muller , Helmut Bahrmann
IPC分类号： B01D15/08 , C07F15/00
CPC分类号： C07F15/008 , B01D15/34 , Y02P20/584
摘要： Mixtures of substances containing metal complex compounds, organoelemental ligands, and/or other components are separated according to the invention by chromatography on stationary supports in an aqueous or aqueous/organic medium.
摘要翻译：根据本发明，通过在水性或水/有机介质中的固定载体上的色谱分离含有金属络合物，有机配体和/或其它组分的物质的混合物。

7. 发明授权

US4578523A Process for the preparation of aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4578523A
公开(公告)日：1986-03-25
申请号：US738822
申请日：1985-05-29
申请人： Helmut Bahrmann , Boy Cornils , Werner Konkol , Wolfgang Lipps
发明人： Helmut Bahrmann , Boy Cornils , Werner Konkol , Wolfgang Lipps
IPC分类号： C07C45/50
CPC分类号： C07C45/50
摘要： A novel process for the preparation of aldehydes by reacting olefins with carbon monoxide and hydrogen in the presence of a catalyst system comprised of rhodium in metallic form or as a compound and a water-soluble quaternary ammonium salt of a mono, di or trisulfonated arylphosphine.
摘要翻译：一种用于通过烯烃与一氧化碳和氢气在由金属形式的铑或作为化合物和单，二或三磺化芳基膦的水溶性季铵盐的催化剂体系存在下反应来制备醛的新方法。

8. 发明授权

US4808757A Process for the preparation of aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4808757A
公开(公告)日：1989-02-28
申请号：US193956
申请日：1988-05-13
申请人： Boy Cornils , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Helmut Bahrmann , Heinz-Dieter Hahn
发明人： Boy Cornils , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Helmut Bahrmann , Heinz-Dieter Hahn
IPC分类号： C07C47/02 , B01J31/00 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： A process for the preparation of aldehydes by hydroformylation of olefins in the presence of an aqueous solution containing rhodium as a catalyst. The aqueous solution preferably contains rhodium in a concentration of 450 to 800 weight-ppm and sulfonated or carboxylated triarylphosphines as complex ligands in a concentration of 25 to 30% by weight, both based on the aqueous solution.
摘要翻译：在含有铑作为催化剂的水溶液存在下通过烯烃的加氢甲酰化来制备醛的方法。该水溶液优选含有浓度为450-800重量ppm的铑和基于水溶液的25-30重量％浓度的磺化或羧化三芳基膦作为络合配体。

9. 发明授权

US4795727A Rhodium catalysts and methods of preparation and use thereof 失效
标题翻译：铑催化剂及其制备方法及用途
公开(公告)号：US4795727A
公开(公告)日：1989-01-03
申请号：US47663
申请日：1987-05-08
申请人： Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Werner Konkol , Ernst Wiebus
发明人： Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Werner Konkol , Ernst Wiebus
IPC分类号： C07B61/00 , B01J31/00 , B01J31/02 , B01J31/20 , B01J31/24 , B01J37/04 , C07C45/00 , C07C45/50 , C07C47/02 , C07C47/06 , C07C47/07 , C07C67/00 , C07F9/50 , B01J31/22
CPC分类号： C07C45/50
摘要： A process for the preparation of a rhodium catalyst comprising dissolving a carboxylic acid salt of rhodium in a solvent taken from the class consisting of aliphatic, cycloaliphatic, aromatic hydrocarbons and mixtures thereof. The carboxylic acid has 2 to 18 carbon atoms. This salt is reacted with carbon monoxide and hydrogen to form a rhodium hydridrocarbonyl which is reacted with an aqueous solution of a triaryl phosphine. The aqueous solution may be present during the initial reaction of the rhodium salt or may be added thereafter. A catalyst which is the product of the foregoing process is also disclosed, as is a method of producing aldehydes using the catalyst.
摘要翻译：一种制备铑催化剂的方法，包括将铑的羧酸盐溶解在从脂族，脂环族，芳族烃及其混合物组成的溶剂中。羧酸具有2至18个碳原子。该盐与一氧化碳和氢气反应形成与三芳基膦水溶液反应的铑氢化羰基。水溶液可以在铑盐的初始反应期间存在，或者可以在其后加入。还公开了作为上述方法的产物的催化剂，以及使用该催化剂生产醛的方法。

10. 发明授权

US4731485A Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom 失效
标题翻译：用铑催化剂加氢甲酰化和从中分离铑的方法
公开(公告)号：US4731485A
公开(公告)日：1988-03-15
申请号：US9734
申请日：1987-02-02
申请人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
发明人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
IPC分类号： C07C45/50
CPC分类号： C07C45/50
摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.
摘要翻译：一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。还阐述了在络合剂和增溶剂存在下制备醛的方法。增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。

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