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1. 发明授权

US6136238A Device and process for producing plastic components, especially polyurethane moldings 失效
标题翻译：用于生产塑料部件，特别是聚氨酯模制品的装置和工艺
公开(公告)号：US6136238A
公开(公告)日：2000-10-24
申请号：US142445
申请日：1998-09-04
申请人： Werner Rasshofer , Henry Muller , Achim Symannek
发明人： Werner Rasshofer , Henry Muller , Achim Symannek
IPC分类号： B29C33/38 , B29C44/00 , B29K75/00 , B29K105/04 , C08G18/66 , C22C38/00 , C22C38/22 , C22C38/24 , C22C38/30 , C22C38/52 , B29C41/38 , B29C44/02
CPC分类号： C08G18/6696 , B29C33/38 , C08G2101/0033 , C08G2125/00
摘要： The present invention relates to a process for preparing solid, microcellular or expanded plastic molded items, characterized in that said molded items are produced in molds in which the internal surfaces consist of steel with the percentage composition:a) Fe: having a wt % greater than 0 wt % and less than 100 wt %;b) at least one element selected from the group consisting of W, Mo, or V, wherein if W is selected, W is present from a range greater than 0 wt % to 40 wt %; wherein if Mo is selected, Mo is present from a range greater than 0 wt % to 12 wt %; and if V is selected, V is present from a range greater than 0 wt % to 5 wt %;c) at least one element selected from the group consisting of Cr, Al, wherein if Cr is selected, Cr is present in a concentration of greater than 0 wt % to 15 wt %; and if Al is selected, Al is present in a concentration of greater than 0 wt % to 15 wt %;d) optionally, carbon at a concentration ranging from 0.1 to 1.5 wt %;e) optionally, cobalt at a concentration ranging from 0.1 to 10 wt %; andf) optionally, nitrogen in a nitriding layer at a concentration ranging from greater than 0 wt % to 10 wt %.
摘要翻译： PCT No.PCT / EP97 / 00952 Sec。 371日期：1998年9月4日 102（e）1998年9月4日PCT PCT 1997年2月27日提交PCT公布。第WO97 / 34021号公报日期：1997年9月18日本发明涉及一种制备固体，微孔或膨胀塑料模塑制品的方法，其特征在于，所述模制品在模具中制造，其中内表面由具有百分比组成的钢组成：a）Fe：重量％大于0重量％且小于100重量％; b）选自W，Mo或V中的至少一种元素，其中如果选择W，W存在于大于0重量％至40重量％的范围内; 其中如果选择Mo，则Mo在大于0重量％至12重量％的范围内存在; 并且如果选择V，则V从大于0重量％至5重量％的范围存在; c）选自Cr，Al中的至少一种元素，其中如果选择Cr，则Cr以大于0wt％至15wt％的浓度存在; 并且如果选择Al，则Al以大于0重量％至15重量％的浓度存在; d）任选地，浓度为0.1至1.5重量％的碳; e）任选地，浓度为0.1至10重量％的钴; 和f）任选地，氮化层中的氮浓度范围为大于0重量％至10重量％。

2. 发明授权

US5705594A Polyamine crosslinking agent formulation and its preparation 失效
标题翻译：多胺交联剂配方及其制备
公开(公告)号：US5705594A
公开(公告)日：1998-01-06
申请号：US767564
申请日：1996-12-16
申请人： Klaus Konig , Otto Neuner , Werner Rasshofer
发明人： Klaus Konig , Otto Neuner , Werner Rasshofer
IPC分类号： C07D251/34 , C08G59/50 , C08J3/24 , C08K5/3492 , C08L63/00 , C08L73/02 , C08L79/02 , C08G18/08 , C08G18/10
CPC分类号： C08G59/5086 , C07D251/34
摘要： Liquid polyamine crosslinking agent formulations based on trimerized toluylene 2,4- and/or 2,6-diisocyanate, with formation of an isocyanurate structure and hydrolysis of the isocyanate groups to amine groups, are described. The novel crosslinking agent formulations have a content of 40 to 80% of the total weight of the solids content of the crosslinking agent formulation of 1,3,5-tris-(3-amino-4-methyl-phenyl,2-methyl-3-aminophenyl) isocyanurate (I) which is not further condensed, and a content of not more than 1.0% of the total weight of the crosslinking agent formulations of toluylene-2,4- and/or -2,6-diamine (III). For the preparation, toluylene diisocyanate is trimerized, to form the isocyanurate structure, until 10 to 25% of the NCO groups have been reacted. The toluylene diisocyanate which has not undergone condensation is then distilled off, the bottom product formed by this operation is taken up directly in a solvent A and the 30 to 70% strength by weight solution formed by this procedure is metered into a hydrolysis in water/N,N-dialkyl-carboxylic acid amide in the presence of a catalytic amount of a basic catalyst. After the hydrolysis, the crosslinking agent formulations are brought to a solids content of 35 to 60% of the total weight of the formulation by distilling off a portion of the solvents and adding a solvent B.
摘要翻译：描述了基于三聚甲苯2,4-和/或2,6-二异氰酸酯的液态多胺交联剂制剂，其形成异氰脲酸酯结构和将异氰酸酯基团水解为胺基。新型交联剂配方的含量为交联剂配方的1,3,5-三（3-氨基-4-甲基 - 苯基，2-甲基 - 苯基） - 苯胺的固体含量的总重量的40-80％ 3-氨基苯基）异氰脲酸酯（I），其不再进一步缩合，并且不大于甲苯-2,4-和/或-2,6-二胺（III）的交联剂配方的总重量的1.0重量％）。为了制备，将甲苯二异氰酸酯进行三聚，形成异氰脲酸酯结构，直到10〜25％的NCO基团都已反应。然后蒸馏除去未进行冷凝的甲苯二异氰酸酯，将通过该操作形成的底部产物直接溶于溶剂A中，并将通过该方法形成的30-70重量％的重量浓度的溶液计量加入水/ N，N-二烷基 - 羧酸酰胺在催化量的碱性催化剂存在下反应。水解后，通过蒸馏掉一部分溶剂并加入溶剂B使交联剂配方的固体含量达到制剂总重量的35至60％。

3. 发明授权

US5069857A Process for the production of molded articles by deep-drawing prefabricated polyurethane(urea) parts or by pressing fragmented polyurethane(urea) material 失效
标题翻译：通过深冲预制的聚氨酯（尿素）部件或压制片断的聚氨酯（尿素）材料来生产模制品的方法
公开(公告)号：US5069857A
公开(公告)日：1991-12-03
申请号：US605600
申请日：1990-10-29
申请人： Joachim Wagner , Thomas Elsner , Werner Rasshofer , Jurgen Faehndrich , Eberhard Jurgens
发明人： Joachim Wagner , Thomas Elsner , Werner Rasshofer , Jurgen Faehndrich , Eberhard Jurgens
IPC分类号： B29C51/08 , B29C43/00 , B29C51/00 , B29C67/24 , B29K75/00
CPC分类号： B29C51/002 , B29C43/003 , B29C67/246 , B29K2075/00
摘要： The invention is directed to a process for the production of molded articles by deep-drawing a prefabricated polyurethane(urea) part produced from a polyisocyanate polyaddition product having a specific gravity of at least 0.8 g/cm.sup.3. The part is placed inside a deep-drawing mold and pressed at a temperature of up to 230.degree. C. and a pressure of up to 1,000 bar. After the deep-drawing process, the part is subjected to a dwell time of at least 10 seconds at a temperature of up to 230.degree. C. and a pressure of up to 1,000 and is immediately thereafter removed from the mold.
摘要翻译：本发明涉及通过深冲压由比重至少为0.8g / cm 3的多异氰酸酯加聚产物制成的预制聚氨酯（尿素）部分来生产模制品的方法。将该部件放置在深拉模具内并在高达230℃的温度和高达1,000巴的压力下压制。在深拉伸工艺之后，该部件在高达230℃的温度和至多1000的压力下进行至少10秒的停留时间，并立即从模具中取出。

4. 发明授权

US4902825A N,N'-bis(trans-4-isocyanatocyclohexyl)urea, a process for its preparation and its use 失效
标题翻译： N，N'-双（反式-4-异氰酸根合环己基）脲，其制备方法及其用途
公开(公告)号：US4902825A
公开(公告)日：1990-02-20
申请号：US255915
申请日：1988-10-11
申请人： Andreas Ruckes , Werner Rasshofer , Richard Kopp , Gerhard Grogler
发明人： Andreas Ruckes , Werner Rasshofer , Richard Kopp , Gerhard Grogler
IPC分类号： C07C67/00 , C07C239/00 , C07C275/26 , C08G18/46 , C08G18/50 , C08G18/78 , C08G18/80
CPC分类号： C08G18/8045 , C07C275/26 , C08G18/4615 , C08G18/4623 , C08G18/5048 , C08G18/7825
摘要： The present invention relates to N,N'-bis-(4-isocyanatocyclohexyl)urea obtained from the reaction with water of cyclohexane-1,4-diisocyanate having a high trans isomer content. This invention further relates to the process for preparing the N,N'-bis(4-isocyanatocyclohexyl)urea and to its use in the synthesis of polyurethanes.
摘要翻译：本发明涉及由与反式异构体含量高的环己烷-1,4-二异氰酸酯与水的反应得到的N，N'-双（4-异氰酸根合环己基）脲。本发明还涉及制备N，N'-双（4-异氰酸根合环己基）脲的方法及其在合成聚氨酯中的用途。

5. 发明授权

US4724252A Polyamines and a process for their production from polyisocyanates 失效
标题翻译：多胺及其由多异氰酸酯制备的方法
公开(公告)号：US4724252A
公开(公告)日：1988-02-09
申请号：US895629
申请日：1986-08-11
申请人： Werner Rasshofer
发明人： Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/10 , C08G18/18 , C08G18/20 , C08G18/50 , C08G18/83
CPC分类号： C08G18/5021 , C08G18/10 , C08G18/1858 , C08G18/2027 , C08G18/2063
摘要： Polyamines containing aromatically bound primary amino groups are prepared in a single stage process by hydrolyzing an isocyanate in the presence of a compound containing an amidine and/or guanidine group and a water-miscible, aprotic-dipolar solvent. This hydrolysis is carried out at from 20.degree. to 210.degree. C. with the reactants being in substantially homogeneous phase. The isocyanate starting material contains aromatically bound NCO groups and has NCO content of from 0.5 to 40 wt. %. The compound containing amidine and/or guanidine groups functions as a catalyst and is used in a quantity of at least 0.001 parts by weight for every 100 parts by weight of isocyanate. The water-miscible solvent is used in a quantity of at least 10 parts by weight for every 100 parts by weight of polyisocyanate. The polyamines thus-produced are particularly useful in the production of polyurethanes.
摘要翻译：通过在含有脒和/或胍基和水混溶性非质子偶极溶剂的化合物的存在下水解异氰酸酯，在单阶段方法中制备含芳香结合的伯氨基的多胺。该水解在20至210℃下进行，反应物基本上是均匀的相。异氰酸酯原料含有芳香结合的NCO基团，并且NCO含量为0.5〜40wt。％。含有脒和/或胍基的化合物用作催化剂，并且对于每100重量份的异氰酸酯，其用量至少为0.001重量份。该水混溶性溶剂的使用量相对于每100重量份多异氰酸酯至少为10重量份。如此生产的聚胺在聚氨酯的生产中特别有用。

6. 发明授权

US4677136A Process for the production of polyisocyanate compositions containing urea and/or biuret groups, the polyisocyanate compositions obtained by this process, and their use for the production of plastics by the isocyanate polyaddition process 失效
标题翻译：用于生产含有脲和/或缩二脲基团的多异氰酸酯组合物的方法，通过该方法获得的多异氰酸酯组合物及其通过异氰酸酯加聚方法生产塑料的用途
公开(公告)号：US4677136A
公开(公告)日：1987-06-30
申请号：US884831
申请日：1986-07-11
申请人： Werner Rasshofer , Reiner Paul
发明人： Werner Rasshofer , Reiner Paul
IPC分类号： C08G18/00 , C08G18/12 , C08G18/30 , C08G18/65 , C08G18/78 , C08G18/14
CPC分类号： C08G18/7818 , C08G18/12 , C08G18/302 , C08G2120/00
摘要： The present invention is directed to a process for the production of polyisocyanates containing urea and/or biuret groups by reacting organic polyisocyanates with a mixture of water, high molecular weight isocyanate reactive compounds and optionally low molecular weight isocyanate reactive compounds. The present invention is further directed to the products obtained by this process and their use for the production of polyisocyanate polyaddition productions, especially for the preparation of molded articles by the RIM process.
摘要翻译：本发明涉及通过使有机多异氰酸酯与水，高分子量异氰酸酯反应性化合物和任选的低分子量异氰酸酯反应性化合物的混合物反应来生产含有脲和/或缩二脲基团的多异氰酸酯的方法。本发明还涉及通过该方法获得的产品及其用于生产多异氰酸酯加聚物的用途，特别是通过RIM方法制备模塑制品。

7. 发明授权

US4554340A Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效
标题翻译：具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途
公开(公告)号：US4554340A
公开(公告)日：1985-11-19
申请号：US703059
申请日：1985-02-19
申请人： Rudolf Heusch , Werner Rasshofer , Wolfgang Reichmann , Adolf Richartz
发明人： Rudolf Heusch , Werner Rasshofer , Wolfgang Reichmann , Adolf Richartz
IPC分类号： C08G18/32 , C08G18/66
CPC分类号： C08G18/667 , C08G18/3206 , C08G18/6674 , C08G2120/00 , C08G2130/00
摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-- number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.
摘要翻译：具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和在聚氨酯生产中已知的添加剂。此外，使用这些多元醇混合物制备的聚氨酯。

8. 发明授权

US4500656A Process for the preparation of a cellular polyurethane 失效
标题翻译：制备细胞聚氨酯的方法
公开(公告)号：US4500656A
公开(公告)日：1985-02-19
申请号：US594054
申请日：1984-03-28
申请人： Werner Rasshofer , Ernst-Christoph Prolingheuer
发明人： Werner Rasshofer , Ernst-Christoph Prolingheuer
IPC分类号： C08G18/32 , C08G18/65 , C08G18/14
CPC分类号： C08G18/3296 , C08G18/6535 , Y10S521/904
摘要： The present invention relates to a process for the preparation of a cellular polyurethane by the reaction of(A) a polyisocyanate with(B) an isocyanate reactive component containing(1) at least one component having a molecular weight of about 60-2000 and a functionality of 2 to 8, containing isocyanate reactive groups,(2) optionally at least one component having a molecular weight of about 2000 to 12,000 and a functionality of 2 to 8 containing isocyanate reactive groups.(3) about 0.1 to 30 parts, based on 100 parts of (B1)+(B2), of a liquid adduct of an amine and carbon dioxide, and(4) optionally water, blowing agents, foam stabilizers, catalysts and other auxiliary agents and additives,characterized in that the liquid adduct of amine and carbon dioxide is liquid at 20.degree. C., optionally contains water, and is an adduct of carbon dioxide and an amine having at least one amino group and containing at least one primary, secondary or tertiary hydroxyl group, which amine may be solid or liquid at 20.degree. C.
摘要翻译：本发明涉及通过（A）多异氰酸酯与（B）异氰酸酯反应性成分的反应制备细胞聚氨酯的方法，所述异氰酸酯反应性成分含有（1）至少一种分子量为约60-2000的成分和含有异氰酸酯反应性基团的官能度为2至8，（2）任选地至少一种分子量为约2000至12,000且官能度为2至8的含异氰酸酯反应性基团的组分。（3）约0.1至30份，基于100份（B1）+（B2）的胺和二氧化碳的液体加合物，和（4）任选的水，发泡剂，泡沫稳定剂，催化剂和其它助剂试剂和添加剂，其特征在于胺和二氧化碳的液体加合物在20℃下为液体，任选地含有水，并且是二氧化碳和具有至少一个氨基并且含有至少一个伯，二羟基或叔羟基，该胺在20℃下可以是固体或液体。

9. 发明授权

US4390640A Process for the production of optionally-foamed polyurethanes 失效
标题翻译：用于生产任选发泡聚氨酯的方法
公开(公告)号：US4390640A
公开(公告)日：1983-06-28
申请号：US342303
申请日：1982-01-25
申请人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
发明人： Werner Rasshofer , Geza Avar , Hans-Albrecht Freitag , Gerhard Grogler , Richard Kopp
IPC分类号： C08G18/00 , C08G18/22 , C08G18/24 , C08J9/02 , C08G18/14
CPC分类号： C08G18/246
摘要： This invention relates to a process for the production of polyurethanes, particularly polyurethane foam moldings having a compact skin and a cellular core, using special tin activators.
摘要翻译：本发明涉及使用特殊的锡活化剂来生产聚氨酯的方法，特别是具有紧密表皮和细胞芯的聚氨酯泡沫塑料模制品。

10. 发明授权

US5616623A Process for the decompostion of polyurethane plastics 失效
标题翻译：聚氨酯塑料分解工艺
公开(公告)号：US5616623A
公开(公告)日：1997-04-01
申请号：US560565
申请日：1995-11-20
申请人： Thomas Munzmay , Peter Fuhrmann , Franz Lamla , Walter Meckel , Werner Rasshofer
发明人： Thomas Munzmay , Peter Fuhrmann , Franz Lamla , Walter Meckel , Werner Rasshofer
IPC分类号： C08J11/18 , C08G18/83 , C08J11/24 , C08J11/04
CPC分类号： C08J11/24 , C08G18/831 , C08J2375/04 , Y02W30/706
摘要： A process for the decomposition of polyurethane plastic waste materials in which a compound containing at least two isocyanate-reactive hydrogen atoms (e.g., glycol) and polyurethane plastic, together with 2 to 20 times the amount of previously regenerated material, are treated in a mixing and comminution device.
摘要翻译：一种分解聚氨酯塑料废料的方法，其中含有至少两种异氰酸酯反应性氢原子的化合物（例如二醇）和聚氨酯塑料以及先前再生材料量的2至20倍的化合物在混合和粉碎装置。

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