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    • 1. 发明授权
    • Production of rigid polyurethane foams
    • 生产刚性聚氨酯泡沫
    • US5552450A
    • 1996-09-03
    • US229255
    • 1994-04-18
    • Werner HinzRolf HennUwe KeppelerBernd Guettes
    • Werner HinzRolf HennUwe KeppelerBernd Guettes
    • C08G18/48C08G18/66C08G65/26C08G65/28C08G65/333C08G18/00
    • C08G18/4845C08G18/4812C08G18/6666C08G65/26C08G65/33348C08G2101/0025C08G2101/0041
    • A process for the production of rigid polyurethane foams involves reactinga) organic and/or modified organic polyisocyanates withb) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and, if desired,c) low-molecular-weight chain extenders and/or cross-linking agents,in the presence ofd) blowing agents,e) catalysts and, if desired,f) assistants and/or additives,where the relatively high-molecular-weight compounds (b) containing at least two reactive hydrogen atoms are polyoxypropylene-polyols and/or polyoxyethylene-polyoxy-propylene-polyols containing up to 20% by weight, based on the weight of the alkylene oxide units, of pendant oxyethylene units containing secondary hydroxyl groups and having a functionality of from 3.8 to 4.1, a hydroxyl number of from 385 to 410 mg of KOH/g and a viscosity of from 1700 to 2400 mPa.multidot.s at 25.degree. C., and which can be prepared by anionic polymerization of 1,2-propylene oxide and, if desired, ethylene oxide on an initiator molecule mixture comprising sucrose, pentaerythritol and diethylene glycol.
    • 用于生产刚性聚氨酯泡沫的方法包括使a)有机和/或改性的有机多异氰酸酯与b)至少一种含有至少两个反应性氢原子的相对高分子量化合物反应,如果需要,c) 分子量增链剂和/或交联剂,在d)发泡剂的存在下,e)催化剂,如果需要,f)助剂和/或添加剂,其中相对高分子量的化合物(b) 含有至少两个反应性氢原子的是聚氧丙烯 - 多元醇和/或聚氧乙烯 - 聚氧丙烯 - 多元醇,其含有基于烯化氧单元重量的至多20重量%的含有仲羟基的侧面氧乙烯单元并具有 官能度为3.8至4.1,羟基数为385至410mg KOH / g,25℃时粘度为1700至2400 mPax,可通过1,2-环氧丙烷的阴离子聚合制备 如果需要, 包含蔗糖,季戊四醇和二甘醇的引发剂分子混合物上的氧化亚苯基。
    • 3. 发明授权
    • Polyoxypropylene-polyols and polyoxypropylene-polyoxyethylene-polyols
containing hydroxyl groups
    • 含有羟基的聚氧丙烯 - 多元醇和聚氧丙烯 - 聚氧乙烯 - 多元醇
    • US5340916A
    • 1994-08-23
    • US966228
    • 1992-10-26
    • Rolf HennWerner HinzLudwig SchusterKlaus Vorspohl
    • Rolf HennWerner HinzLudwig SchusterKlaus Vorspohl
    • C08G18/48C08G65/26C08G65/28C07C43/10C08G65/08
    • C08G18/4816C08G18/4829C08G65/2606C08G2101/0025C08G2101/005C08G2105/02Y10S521/902
    • The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.multidot.s at 23.degree. C. and prepared by anionic polymerization of 1,2-propylene oxide or ethylene oxide and 1,2-propylene oxide onto an initiator molecule mixture containing, based on the total weight,a1) from 40 to 80% by weight of a hexanetetrol,a2) from 1 to 30% by weight of a hexanetriol,a3) from 0 to 35% by weight of glycerol anda4) from 0 to 15% by weight of sorbitol or mannitol, or a mixture thereof,b) optionally, a low-molecular-weight chain extender and/or crosslinking agent withc) an organic, modified or unmodified polyisocyanate; in the presence ofd) a blowing agent,e) a catalyst and, optionally,f) assistants and/or additives, and novel polyoxypropylene-polyols and polyoxyethylene-polyoxypropylene-polyols which can be used for this purpose.
    • 本发明涉及通过使a)具有仲羟基的聚氧丙烯或聚氧乙烯 - 聚氧丙烯 - 多元醇,具有官能度的官能度的方法,通过多异氰酸酯加聚方法制备含有氨基甲酸酯基团或聚氨酯和异氰脲酸酯基团的硬质泡沫的方法, 3.5至4.3,羟值为350至650,在23℃下的粘度为500至2500mPax,并通过将1,2-环氧丙烷或环氧乙烷和1,2-环氧丙烷阴离子聚合制备到 包含基于总重量的起始分子混合物,a1)为40至80重量%的己烷四醇,a2)1至30重量%的己烷三醇,a3)0至35重量%的甘油和 a4)0至15重量%的山梨糖醇或甘露醇或其混合物,b)任选的低分子量增链剂和/或交联剂,c)有机,改性或未改性的多异氰酸酯; 在d)发泡剂的存在下,e)可以用于此目的的催化剂和任选的f)助剂和/或添加剂,以及新的聚氧丙烯 - 多元醇和聚氧乙烯 - 聚氧丙烯 - 多元醇。
    • 4. 发明授权
    • Preparation of hard foams containing urethane groups or urethane and
isocyanurate groups by polyisocyanate polyaddition, and
polyoxyalkylene-polyols which are suitable therefor
    • 通过聚异氰酸酯聚合物制备含有尿素组合或尿酸酯和异氰酸酯基团的硬脂酸酯,以及适用于其的多羟基亚烷基多元醇
    • US5192813A
    • 1993-03-09
    • US694621
    • 1991-05-02
    • Rolf HennWerner HinzLudwig SchusterKlaus Vorspohl
    • Rolf HennWerner HinzLudwig SchusterKlaus Vorspohl
    • C08G18/48C08G65/26C08G65/28
    • C08G18/4816C08G18/4829C08G65/2606C08G2101/0025C08G2101/005C08G2105/02Y10S521/902
    • The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydoxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.s at 23.degree. C. and prepared by anionic polymerization of 1,2-propylene oxide or ethylene oxide and 1,2-propylene oxide onto an initiator molecule mixture containing, based on the total weight,a1) from 40 to 80% by weight of a hexanetetrol,a2) from 1 to 30% by weight of a hexanetriol,a3) from 0 to 35% by weight of glycerol anda4) from 0 to 15% by weight of sorbitol or mannitol, or a mixture thereof,b) optionally, a low-molecular-weight chain extender and/or crosslinking agent withc) an organic, modified or unmodified polyisocyanate; in the presence ofd) a blowing agent,e) a catalystand, optionally,f) assistants and/or additives,and novel polyoxypropoylene-polyols and polyoxyethylene-polyoxypropylene-polyols which can be used for this purpose.
    • 本发明涉及通过使a)具有仲羟基的聚氧丙烯或聚氧乙烯 - 聚氧丙烯 - 多元醇,具有官能度的官能度的方法,通过多异氰酸酯加聚方法制备含有氨基甲酸酯基团或聚氨酯和异氰脲酸酯基团的硬质泡沫的方法, 3.5至4.3,羟基数为350至650,在23℃下的粘度为500至2,500mPa.s,并通过1,2-环氧丙烷或环氧乙烷和1,2-丙烯的阴离子聚合制备 氧化物引入到基于总重量的基于总重量的起始分子混合物,a1)为40至80重量%的己烷四丁醇,a2)1至30重量%的己烷三醇,a3)0至35重量% 甘油和a4)0至15重量%的山梨糖醇或甘露醇或其混合物,b)任选的低分子扩链剂和/或交联剂,c)有机,改性或未改性的多异氰酸酯; 在d)发泡剂的存在下,e)可以用于该目的的催化剂和任选的f)助剂和/或添加剂,以及新的聚氧亚丙基 - 多元醇和聚氧乙烯 - 聚氧丙烯 - 多元醇。
    • 5. 发明授权
    • Preparation of flexible, soft polyurethane foams having viscoelastic,
structure-borne soundproofing properties, and polyoxyalkylene-polyol
mixtures which can be used for this purpose
    • 制备具有粘弹性,结构隔音性能的柔性,软质聚氨酯泡沫,以及可用于此目的的聚氧化烯 - 多元醇混合物
    • US5420170A
    • 1995-05-30
    • US619265
    • 1990-11-28
    • Heinz-Dieter LutterReinhard LeppkesPeter HornWalter DeckerVolker HaaseWerner Hinz
    • Heinz-Dieter LutterReinhard LeppkesPeter HornWalter DeckerVolker HaaseWerner Hinz
    • C08G18/48C08G18/66
    • C08G18/4804C08G18/4841C08G18/6674C08G2101/0008C08G2101/0058C08G2101/0083C08G2350/00Y10S521/914
    • The present invention relates to a process for the preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties in a temperature range of from -20.degree. C. to +80.degree. C. by reactinga) a polyoxyalkylene-polyol mixture containingai) block polyoxypropylene-polyoxyethylene-polyol mixture having a hydroxyl number of from 14 to 65 and containing from 2 to 9% by weight of terminal ethylene oxide units, based on the weight of the polyoxypropylene units, prepared by anionic polymerization, at elevated temperatures, of 1,2-propyleneoxide onto an initiator molecule mixture having a mean functionality of from 2.3 to 2.8, comprising water and glycerol and/or trimethylolpropane, and polymerization of acylene oxide onto the resultant polyoxypropylene adduct, andaii) one or more difunctional and/or trifunctional polyoxypropylene-polyoxyethylene-polyol containing from 60 to 85% by weight of oxyethylene units, based on the total weight of polymerized alkylene oxide units, and having a hydroxyl number of from 20 to 80, andb) if desired low-molecular-weight chain extenders withc) organic and/or modified organic polyisocyanates in the presence ofd) catalysts,e) blowing agents, preferably water, and, if desired,f) auxiliaries and/or additives,and to the polyoxyalkylene-polyol mixtures (a) which can be used for this purpose.
    • 本发明涉及一种制备柔软的软质聚氨酯泡沫的方法,该泡沫在-20℃至+ 80℃的温度范围内具有粘弹性结构的隔音性能,通过使a)聚氧化烯 - 多元醇混合物 含有ai)嵌段聚氧丙烯 - 聚氧乙烯 - 多元醇混合物,羟基数为14至65,并含有2至9重量%的末端环氧乙烷单元,基于通过阴离子聚合制备的聚氧丙烯单元的重量,在升高的 温度,1,2-环氧丙烷至平均官能度为2.3至2.8的引发剂分子混合物,包含水和甘油和/或三羟甲基丙烷,以及将芳族氧化物聚合到所得聚氧丙烯加合物上,以及aii)一种或多种双官能 和/或含有60至85重量%的氧化乙烯单元的三官能聚氧丙烯 - 聚氧乙烯 - 多元醇,基于聚合的Al的总重量 环氧乙烷单元,羟值为20至80,和b)如果需要,在d)催化剂存在下,c)有机和/或改性有机多异氰酸酯的低分子增链剂,e)发泡剂, 如果需要,f)助剂和/或添加剂,以及可用于该目的的聚氧化烯 - 多元醇混合物(a)。
    • 8. 发明授权
    • Apparatus for manipulating rod-shaped articles of the tobacco processing
industry
    • 用于操纵烟草加工业的棒状制品的装置
    • US4781204A
    • 1988-11-01
    • US27486
    • 1987-03-18
    • Karl-Heinz BarbeWerner HinzJorg Ziolkowski
    • Karl-Heinz BarbeWerner HinzJorg Ziolkowski
    • A24C5/32A24C5/60B23K26/08
    • B23K26/0823A24C5/606
    • Filter cigarettes which are transported sideways at the periphery of a rotating drum-shaped conveyor are engaged by successive rolling surfaces of a pair of coaxial rotary rolling members which rotate at the peripheral speed of the conveyor but in the opposite direction so that the cigarettes are caused to roll about their respective axes and cease to advance with the conveyor. The periphery of the conveyor is formed with flutes which receive the freshly rolled cigarettes, and the rolling of cigarettes is abruptly terminated by arresting members which orbit adjacent the path of movement of the cigarettes at the peripheral speed of the conveyor and in the same direction. A laser is used to make holes in successive cigarettes while the cigarettes roll about their respective axes.
    • 在旋转的鼓形输送机的周边侧面运输的过滤香烟由一对同轴旋转滚动构件的连续滚动表面接合,所述滚动表面以传送器的圆周速度旋转,但是沿相反的方向旋转,从而引起香烟 绕其各自的轴线滚动并停止与输送机一起前进。 输送机的周边形成有容纳新鲜卷起的香烟的槽纹,并且通过阻止沿着输送机的圆周速度和相同方向在香烟运动路径附近轨道运动的构件,香烟的滚动突然终止。 激光用于连续卷烟中的孔,而香烟围绕它们各自的轴线滚动。
    • 9. 发明授权
    • Method and apparatus for joining coaxial rod-shaped articles
    • 用于连接同轴棒状物品的方法和装置
    • US4445519A
    • 1984-05-01
    • US346760
    • 1982-02-08
    • Werner HinzGerhard Tolasch
    • Werner HinzGerhard Tolasch
    • A24C5/47A24C5/08A24C5/10
    • A24C5/471
    • Groups of coaxial filter rod sections and plain cigarettes are delivered onto the peripheral surface of a rotary drum in such orientation that each group extends in parallelism with the axis of the drum and overlies the adhesive coated outer side of a discrete uniting band which adheres to the surface by suction and is formed on the drum in such a way that its leader overlies a groove in the surface. The cigarettes of each group are attracted to the drum by suction, and the sections of the groups are mechanically urged against the leaders of the respective bands by claws which are retractible into and extendable from the drum by one or more stationary cams, followers which track the cams and gears which receive motion from the followers and rotate discs having eccentric pins coupling them to the respective claws. The claws are disengaged from the respective sections, and the ports in the surface of the drums cease to attract the cigarettes and the bands before the groups reach a rolling gap wherein they rotate about their respective axes and convolute the bands around the respective sections and the adjacent end portions of the cigarettes. The claws prevent misorientation or separation of sections from the drum when the latter is driven at a high peripheral speed so that the sections tend to fly away under the action of gravity and/or centrifugal force.
    • 同轴过滤杆部分和平卷烟组以这样的方向输送到旋转鼓的圆周表面上,每个组与滚筒的轴线平行地延伸,并且覆盖粘附到分离的联合带的粘合剂涂覆的外侧 通过抽吸而形成在滚筒上,使得其引导件覆盖在表面中的凹槽。 每组的香烟通过抽吸被吸引到鼓上,并且这些组的部分通过爪被机械地推靠在相应带的前端,所述爪通过一个或多个固定凸轮可追回到滚筒中并可从滚筒延伸,跟踪器跟踪 凸轮和齿轮接收来自跟随器的运动并旋转具有将它们连接到相应爪的偏心销的盘。 爪从相应的部分脱离,并且鼓的表面中的端口停止吸引香烟和带之前的组达到滚动间隙,其中它们围绕其相应的轴线旋转并将带卷绕在相应的部分周围,并且 香烟的相邻端部。 当后者以高圆周速度被驱动时,爪防止部分与鼓的错位或分离,使得部分倾向于在重力和/或离心力的作用下飞走。
    • 10. 发明授权
    • Apparatus for severing paper webs or the like
    • 用于切断纸幅等的装置
    • US4334449A
    • 1982-06-15
    • US207962
    • 1980-11-18
    • Werner HinzNikolaus Hausler
    • Werner HinzNikolaus Hausler
    • A24C5/47B26D1/62A24C5/58
    • B26D1/626A24C5/473Y10T83/4827Y10T83/4836
    • An apparatus which subdivides an adhesive-coated web of paper or imitation cork into a succession of uniting bands which are draped around groups of coaxial cigarettes and filter plugs to form filter cigarettes has two drums rotating in opposite directions about parallel axes. One of the drums is a suction drum and serves to advance the leader of the web toward the nip of the two drums where the leader is severed to yield successive uniting bands. The suction drum has a number of equidistant axially parallel peripheral grooves each disposed in front of a cutting edge. The other drum carries detachable knives with cutting edges extending beyond the periphery of the other drum so that they can penetrate into the oncoming grooves during travel past the nip. The drums are rotated by mating gears and the radius of the cylinder which is formed by the cutting edges of the knives exceeds the radius of the pitch circle of the gear which drives the other drum. The cutting edges of the suction drum form a cylinder with a radius which is equal to or somewhat smaller than the radius of the pitch circle of the gear serving to drive the suction drum. The cutting edges of the knives define epicycloidal paths during travel toward, during penetration into and during withdrawal from the corresponding grooves. Those portions of the paths which are disposed in the respective grooves resemble loops with zeniths located in the interior of the grooves or at the entrances to such grooves. This ensures that expansion or contraction of the drums cannot result in clashing of the cooperating cutting edges.
    • 将粘合剂涂布的纸幅或仿软木塞细分成一系列联合带,其围绕同轴卷烟和过滤嘴盖组成以形成过滤嘴香烟具有两个相对于平行轴相反方向旋转的滚筒。 其中一个鼓是吸鼓,并用于将卷筒纸的前导件朝着两个滚筒的辊隙前进,导纱器被切断以产生连续的联合带。 抽吸鼓具有多个等距的轴向平行的周向槽,每个周向槽设置在切削刃的前方。 另一个鼓带有可拆卸的刀具,切割刃延伸超过另一个鼓的周边,使得它们在行进通过辊隙期间能够穿透到迎面而来的槽中。 鼓通过配合齿轮旋转,并且由刀的切割刃形成的圆筒的半径超过驱动另一个滚筒的齿轮的节圆的半径。 抽吸鼓的切割刃形成圆柱体,其半径等于或略小于用于驱动抽吸滚筒的齿轮的节圆的半径。 刀具的切割刃在穿过相对应的槽期间和在从相应的凹槽退出时在行进期间限定了外部路径。 设置在相应凹槽中的路径部分类似于具有位于凹槽内部或入口处的天顶的环路。 这确保鼓的膨胀或收缩不会导致协作的切割边缘的冲突。