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    • 7. 发明授权
    • Extended engine coolant lifetime through polymeric polycarboxylate secondary silicate stabilization
    • 通过聚合多羧酸酯二次硅酸盐稳定化延长发动机冷却剂寿命
    • US06203719B1
    • 2001-03-20
    • US08781848
    • 1997-01-10
    • David E. TurcotteFrances E. Lockwood
    • David E. TurcotteFrances E. Lockwood
    • C09K500
    • C23F11/08C09K5/10C09K5/20
    • The present invention provides corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges. The addition of selected polymeric polycarboxylates not only significantly reduces glycol based coolant cavitation erosion-corrosion, heat rejecting aluminum corrosion, and hard water precipitates and scale, it has been discovered that polymeric polycarboxylates in combination with siloxane stabilized silicates enhance secondary silicate stabilization leading to improvement in aluminum corrosion protection and coolant life when utilized with selected amounts of the above-identified additives. The formulations are particularly suitable for automotive applications.
    • 本发明提供了用于抑制矿物垢和金属腐蚀的腐蚀抑制配方和组合物,特别是在含水液体存在下铝的气穴腐蚀。 聚合多羧酸盐,唑类,硝酸盐,磷酸盐,稳定的硅酸盐和过渡金属化合物的混合物的组合提供了抗水溶液中铝的气穴腐蚀的协同保护作用,降低了腐蚀速率,并且在相对低的浓度和变化的pH下是有效的 范围。 选择的聚合物多羧酸盐的添加不仅显着地减少了基于乙二醇的冷却剂空蚀腐蚀腐蚀,耐热铝腐蚀和硬水沉淀物和水垢,已经发现聚硅氧烷聚硅氧烷与硅氧烷稳定的硅酸盐结合增强了次级硅酸盐稳定性,从而改善了 当与所选量的上述添加剂一起使用时,防腐蚀和冷却剂寿命。 配方特别适用于汽车应用。