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    • 1. 发明授权
    • Anti-spotting and anti-filming hard surface cleaning formulations and methods
    • 防斑和防晒硬表面清洁配方及方法
    • US06315835B1
    • 2001-11-13
    • US09559257
    • 2000-04-27
    • Charles O. KeroboMichael C. WelchRichard J. HollandSonia J. PattersonSuzanne M. Gessner
    • Charles O. KeroboMichael C. WelchRichard J. HollandSonia J. PattersonSuzanne M. Gessner
    • B08B300
    • C11D3/28C11D1/72C11D1/722C11D3/2068C11D3/3765C11D3/3788
    • Cleaning formulations and methods are provided by which solid deposition is inhibited on hydrophobic hard surfaces typically encountered in bathroom and outdoor environments without detrimentally affecting the appearance of such surfaces. The formulations most preferably include an aqueous mixture of an organically solvated nonionic copolymer, a polyacrylic acid homopolymer and a nonionic surfactant. Optionally, a hydrotrope may also be present in the formulation. Most preferably, the formulations of this invention have a pH between about 4.0 to about 7.0, most preferably around neutral (i.e., about 7.0). In specific embodiments, the formulations include an aqueous mixture of (a) a graft copolymer of polyalkylene oxide with vinyl ester, the graft copolymer having a molecular weight within the range of about 5,000 to 50,000, (b) at least one polycarboxylate selected from the group consisting of acrylic acid/maleic acid copolymers, having a molecular weight within the range of about 1,000 to 100,000 and polyacrylic acid having a molecular weight of from about 1,000 to about 100,000, (c) at least one nonionic surfactant selected from the group consisting of alcohol alkoxylates, alcohol block alkoxylates, and polyoxyethylene/polyoxypropylene triblock surfactants, and (d) one or more water soluble organic solvents.
    • 提供清洁配方和方法,在浴室和室外环境中通常遇到的疏水性硬表面上固体沉积被抑制,而不会不利地影响这些表面的外观。 制剂最优选包括有机溶剂化非离子共聚物,聚丙烯酸均聚物和非离子表面活性剂的水性混合物。 任选地,水溶助长剂也可以存在于制剂中。 最优选地,本发明的制剂具有约4.0至约7.0之间的pH,最优选约中性(即约7.0)。 在具体实施方案中,制剂包括(a)聚环氧烷与乙烯基酯的接枝共聚物的水性混合物,接枝共聚物的分子量在约5,000至50,000范围内,(b)至少一种选自以下的聚羧酸盐 由丙烯酸/马来酸共聚物组成的分子量在约1,000至100,000范围内的聚丙烯酸和分子量为约1,000至约100,000的聚丙烯酸,(c)至少一种选自以下的非离子表面活性剂: 醇烷氧基化物,醇嵌段烷氧基化物和聚氧乙烯/聚氧丙烯三嵌段表面活性剂,和(d)一种或多种水溶性有机溶剂。