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    • 6. 发明申请
    • (METH)ACRYLATE COPOLYMER AND METHOD FOR PRODUCING SAME
    • (METH)丙烯酸酯共聚物及其生产方法
    • US20150252129A1
    • 2015-09-10
    • US14426293
    • 2013-10-02
    • NIPPON SHOKUBAI CO., LTD.
    • Masato NakanoYuki Sano
    • C08F220/06
    • C08F220/06C02F5/00C02F5/10C02F5/105C08F2/38C08F216/14C23F11/10C23F11/173C23F14/02C08F216/1466
    • Provided is a copolymer having excellent calcium ion trapping ability, calcium carbonate dispersing capacity, and gel resistance. A (meth)acrylic acid-based copolymer contains, as essential structural units, a structural unit (a) derived from a monomer represented by the following formula (1) in an amount of 2% by mole or more and 9% by mole or less, and a structural unit (b) derived from a (meth)acrylic acid (salt) in an amount of 91% by mole or more and 98% by mole or less, relative to 100% by mole of structural units derived from all monomers, wherein the copolymer contains a sulfonic acid (salt) group at least one end of the main chain and has a weight average molecular weight of 7000 to 100000, wherein R2 represents a hydrogen atom or a methyl group; and X and Y each independently represent a hydroxyl group or a sulfonic acid (salt) group (at least one of X and Y represents a sulfonic acid (salt) group).
    • 提供了具有优异的钙离子捕获能力,碳酸钙分散能力和凝胶电阻的共聚物。 (甲基)丙烯酸系共聚物作为必要结构单元包含由下式(1)表示的单体衍生的结构单元(a),其含量为2摩尔%以上且9摩尔%,或者 相对于衍生自全部的结构单元的100摩尔%,衍生自(甲基)丙烯酸(盐)的结构单元(b)的含量为91摩尔%以上且98摩尔%以下 单体,其中所述共聚物在主链的至少一个末端含有磺酸(盐)基团,其重均分子量为7000〜100000,其中R2表示氢原子或甲基; X和Y各自独立地表示羟基或磺酸(盐)基(X和Y中的至少一个表示磺酸(盐)基)。