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    • 4. 发明授权
    • Novel product and process
    • 新产品和工艺
    • US4703099A
    • 1987-10-27
    • US909543
    • 1986-09-22
    • Dale F. Regelman
    • Dale F. Regelman
    • C07D295/02C08G18/02C08G18/16C08G18/79C08G18/08
    • C07D295/02C07C255/00C07C265/00C07C265/12C08G18/022C08G18/168C08G18/791C08G2105/02Y10S521/902
    • Disclosed are novel compositions capable of catalytically trimerizing organic isocyanates said compositions comprising solutions of the reaction products obtained by reacting in an inert solvent in substantially equimolar proportions electron-rich ketene-aminals with electron-poor olefins having the respective formulae (I) and (II) ##STR1## The variously substituted electron-rich ketene-aminals (I), as the name implies, have high electron density associated with the double bond because of the two tertiary amine groups while the electron-poor olefins (II) have the opposite situation due to the presence of electron withdrawing substituents R.sub.9 and R.sub.10.Also disclosed is an improved process for trimerizing organic isocyanates using the above catalyst compositions including the preparation of polyisocyanurate polymers and isocyanurate-modified polyisocyanates.
    • 公开了能够催化三聚有机异氰酸酯的新型组合物,所述组合物包含通过在惰性溶剂中基本上等摩尔比例的富含电子的乙烯酮 - 胺与具有各自式(I)和(II)的电子不足烯烃反应而获得的反应产物的溶液 (I)如下所述,不同取代的富电子酮乙烯酮(I)由于两个叔胺基团而具有与双键相关的高电子密度,而电子 由于吸电子取代基R9和R10的存在,α-烯烃(II)具有相反的情况。 还公开了使用上述催化剂组合物三聚有机异氰酸酯的改进方法,包括制备聚异氰脲酸酯聚合物和异氰脲酸酯改性的多异氰酸酯。
    • 6. 发明授权
    • Amidinium salts
    • 脒盐
    • US4567257A
    • 1986-01-28
    • US571391
    • 1984-01-16
    • Dale F. Regelman
    • Dale F. Regelman
    • C07D295/02C08G18/02C07C123/00C07D295/12
    • C07D295/02C08G18/025
    • Disclosed is a novel class of amidinium salts having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 when taken individually are independently selected from lower-alkyl, aralkyl and cycloalkyl, and, when taken together with the respective nitrogen atoms to which they are attached, R.sub.1 together with R.sub.2, and R.sub.3 together with R.sub.4 independently represent heterocyclic groups having 5 to 7 ring atoms, R.sub.5, R.sub.6, R.sub.7, and R.sub.8 are independently selected from hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl.The amidinium salts are very active catalysts for converting organic isocyanates to products containing isocyanurate and carbodiimide linkages.
    • 公开了一类新的具有下式的脒鎓盐:其中R 1,R 2,R 3和R 4分别独立地选自低级烷基,芳烷基和环烷基,并且当与各自的氮原子一起 R 1和R 2一起连接,R 3与R 4一起独立地表示具有5至7个环原子的杂环基,R 5,R 6,R 7和R 8独立地选自氢,低级烷基,芳基,芳烷基和环烷基。 脒鎓盐是将有机异氰酸酯转化为含有异氰脲酸酯和碳二亚胺键的产物的非常活泼的催化剂。
    • 8. 发明授权
    • Novel polyamides from ketene-aminals
    • 来自乙烯酮的新型聚酰胺
    • US4338428A
    • 1982-07-06
    • US292872
    • 1981-08-14
    • Louis M. AlberinoDale F. Regelman
    • Louis M. AlberinoDale F. Regelman
    • C08G18/67C08G18/32C08G18/38C08G69/08
    • C08G18/678C08G2120/00
    • Novel polyketene-aminal polyamides are disclosed which have the following recurring unit ##STR1## wherein R is a divalent hydrocarbon radical, R.sub.1, R.sub.2, R.sub.3, and R.sub.4 when taken separately are independently selected from the group consisting of lower alkyl, aralkyl, and cycloalkyl, and when taken together as R.sub.1 with R.sub.2 and R.sub.3 with R.sub.4 with the respective nitrogen atoms to which they are attached represent independently a heterocyclic group having from 5 to 7 ring atoms.The polyamides are prepared by reacting together the appropriate diisocyanate [R(NCO).sub.2 ] and appropriate ketene-aminal to form the polymer directly without the evolution of any by-products or volatiles.The novel polymers are thermoplastic and can be formed or shaped using any of the techniques known to those skilled in the thermoplastic polymer art.
    • 公开了具有以下重复单元的新型聚烯酮 - 酰胺聚酰胺,其中R是二价烃基,R 1,R 2,R 3和R 4分开独立地选自低级烷基,芳烷基和环烷基 并且当R 1和R 3与R 4与它们所连接的相应氮原子一起作为R 1独立地表示具有5至7个环原子的杂环基时。 聚酰胺通过使合适的二异氰酸酯[R(NCO)2]和适当的乙烯酮 - 胺反应而直接形成聚合物而制备,而不会产生任何副产物或挥发物。 新型聚合物是热塑性的并且可以使用热塑性聚合物领域的技术人员已知的任何技术形成或成型。
    • 10. 发明授权
    • Isocyanurate preparation
    • 异氰脲酸盐制剂
    • US4632989A
    • 1986-12-30
    • US737837
    • 1985-05-28
    • Dale F. Regelman
    • Dale F. Regelman
    • C07D251/34C07D295/02C08G18/02C08G18/16C08G18/79
    • C07D295/02C07C255/00C07C265/00C07C265/12C08G18/022C08G18/168C08G18/791
    • Disclosed are novel compositions capable of catalytically trimerizing organic isocyanates said compositions comprising solutions of the reaction products obtained by reacting in an inert solvent in substantially equimolar proportions electron-rich ketene-aminals with electron-poor olefins having the respective formulae (I) and (II) ##STR1## The variously substituted electron-rich ketene-aminals (I), as the name implies, have high electron density associated with the double bond because of the two tertiary amine groups while the electron-poor olefins (II) have the opposite situation due to the presence of electron withdrawing substituents R.sub.9 and R.sub.10.Also disclosed is an improved process for trimerizing organic isocyanates using the above catalyst compositions including the preparation of polyisocyanurate polymers and isocyanurate-modified polyisocyanates.
    • 公开了能够催化三聚有机异氰酸酯的新型组合物,所述组合物包含通过在惰性溶剂中基本上等摩尔比例的富含电子的乙烯酮 - 胺与具有各自式(I)和(II)的电子不足烯烃反应而获得的反应产物的溶液 (I)如下所述,不同取代的富电子酮乙烯酮(I)由于两个叔胺基团而具有与双键相关的高电子密度,而电子 由于吸电子取代基R9和R10的存在,α-烯烃(II)具有相反的情况。 还公开了使用上述催化剂组合物三聚有机异氰酸酯的改进方法,包括制备聚异氰脲酸酯聚合物和异氰脲酸酯改性的多异氰酸酯。