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    • 3. 发明授权
    • Monocarboxylic acid based antifreeze composition for diesel engines
    • 用于柴油机的单羧酸基防冻组合物
    • US06676847B2
    • 2004-01-13
    • US09851368
    • 2001-05-08
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • C09K750
    • C23F11/08C09K5/20
    • The present invention relates to a carboxylic acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic carboxylic organic acid, azoles, low levels of molybdates, a nitrite salt and/or nitrate salt and/or siloxane stabilized silicate, and combinations thereof, polyvinylpyrrolidone, provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的羧酸基防冻剂冷却剂制剂,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元羧酸有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐和/或硅氧烷稳定的硅酸盐的混合物及其组合,聚乙烯吡咯烷酮的组合​​提供了协同的保护作用 防止铝在水性液体中的气穴腐蚀降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 4. 发明授权
    • Monocarboxylic acid based antifreeze composition for diesel engines
    • 用于柴油机的单羧酸基防冻组合物
    • US06290870B1
    • 2001-09-18
    • US09513323
    • 2000-02-25
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • C09K500
    • C09K5/20C23F11/08
    • The present invention relates to an acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic aliphatic organic acid, azoles, low levels of molybdates, a combination of nitrite and/or nitrate salts, polyvinylpyrrolidone, a hydroxide salt, silicates and/or siloxane stabilized silicates with transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的酸性防冻剂冷却剂配方,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元脂族有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐的组合,聚乙烯吡咯烷酮,氢氧化物盐,硅酸盐和/或硅氧烷稳定化的硅酸盐与过渡金属的组合 化合物对水溶液中铝的气穴腐蚀提供协同的保护作用,降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 5. 发明授权
    • Acid based antifreeze composition
    • 酸性防冻剂组成
    • US07407599B2
    • 2008-08-05
    • US10755713
    • 2004-01-12
    • David E. TurcotteMichael DituroAlden W. OlsenArnold L. Coffey, Jr.Carl R. Stephens
    • David E. TurcotteMichael DituroAlden W. OlsenArnold L. Coffey, Jr.Carl R. Stephens
    • C09K5/00
    • C23F11/08C09K5/20
    • The present invention relates to a carboxylic acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic carboxylic organic acid, azoles, low levels of molybdates, a nitrite salt and/or nitrate salt and/or siloxane stabilized silicate, and combinations thereof, polyvinylpyrrolidone, provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的羧酸基防冻剂冷却剂制剂,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元羧酸有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐和/或硅氧烷稳定的硅酸盐的混合物及其组合,聚乙烯吡咯烷酮的组合​​提供了协同的保护作用 防止铝在水性液体中的气穴腐蚀降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 7. 发明授权
    • Apparatus for intimately contacting particulate solids with a heavy
liquid
    • 用于使颗粒状固体与重质液体紧密接触的装置
    • US4610218A
    • 1986-09-09
    • US714714
    • 1985-03-21
    • Steven W. JohnsonAlden W. Olsen
    • Steven W. JohnsonAlden W. Olsen
    • B01J8/08B01J8/12C10L9/10B05B17/00B05C13/02
    • B01J8/085B01J8/12C10L9/10
    • An apparatus for intimately contacting particulate solids with a heavy liquid, said apparatus comprising:(a) a contacting vessel;(b) a particulate solids inlet in communication with an upper end of the contacting vessel;(c) a generally conical deflector positioned in the contacting vessel beneath the particulate solids inlet;(d) an inlet control to control the flow of the particulate solids into the contacting vessel and prevent the discharge of gaseous materials from the contacting vessel;(e) a particulate solids outlet in communication with a lower end of the contacting vessel;(f) an outlet control to control the flow of particulate solids from the contacting vessel so that a bed of particulate solids is maintained in a lower portion of the contacting vessel; and,(g) spray nozzles positioned in the contacting vessel to spray heavy liquid onto the particulate solids as they fall downwardly to the bed of particulate solids.The spray nozzles are positioned so that no spray is directed toward the inner walls of the contacting vessel.
    • 一种用于使颗粒状固体与重质液体紧密接触的装置,所述装置包括:(a)接触容器; (b)与所述接触容器的上端连通的颗粒状固体入口; (c)定位在颗粒状固体入口下方的接触容器中的大致圆锥形的偏转器; (d)入口控制以控制颗粒状固体进入接触容器的流动并防止气态物质从接触容器排出; (e)与接触容器的下端连通的颗粒状固体出口; (f)出口控制器,用于控制来自接触容器的颗粒固体的流动,使得颗粒固体床保持在接触容器的下部; 和(g)定位在接触容器中的喷嘴,当它们向下落到颗粒状固体床时,将重质液体喷射到颗粒状固体上。 喷嘴被定位成使得没有喷雾被引导到接触容器的内壁。