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1. 发明授权

US06284812B1 Thermally stable rigid foams based on isocyanate and having low brittleness and low thermal conductivity 有权
标题翻译：基于异氰酸酯的热稳定的刚性泡沫体，具有低脆性和低热导率
公开(公告)号：US06284812B1
公开(公告)日：2001-09-04
申请号：US09159798
申请日：1998-09-24
申请人： Udo Rotermund , Renate Hempel , Holger Seifert , Werner Schmiade
发明人： Udo Rotermund , Renate Hempel , Holger Seifert , Werner Schmiade
IPC分类号： C08G1804
CPC分类号： C08J9/14 , C08G18/6607 , C08G2101/0025 , C08G2101/0058 , C08J2203/14 , C08J2203/142 , C08J2375/04
摘要： Thermally stable rigid foams based on isocyanate can be produced by reacting a) polyisocyanates with b) compounds containing at least two hydrogen atoms which can react with isocyanate groups, c) water, in the presence of d) physically acting blowing agents, in the presence or absence of e) catalysts and auxiliaries and/or additives, wherein the component b) comprises bi) at least one polyether alcohol having a functionality of at least 1.5 and a hydroxyl number of from 10 to 100 mg KOH/g in an amount of from 0.2 to 80% by mass, based on b), and bii)at least one polyester alcohol in an amount of from 5 to 90% by mass, based on b), the water c) is present in an amount of at most 2% by mass, based on the sum of the components b) to e), and the component d) used comprises hydrocarbons and/or fluorine-containing hydrocarbons in an amount of from 5 to 30% by mass, based on the sum of the components b) to e).
摘要翻译：基于异氰酸酯的热稳定的硬质泡沫可以通过使多异氰酸酯与b）含有至少两个可与异氰酸酯基团反应的氢原子的化合物，c）在存在或不存在的情况下在d）物理作用的发泡剂存在下，）催化剂和助剂和/或添加剂，其中组分b）包含至少一种官能度为至少1.5，羟基数为10至100mg KOH / g的聚醚醇，其量为0.2至80％基于b），andbii）基于b）的至少一种聚酯醇的量为5〜90质量％，水c）的含量为至多2质量％，基于基于组分b）至e）的总和，并且使用的组分d）基于组分b）至e的总和，含有5至30质量％的烃和/或含氟烃）。

2. 发明授权

US5684092A Production of rigid foams based on isocyanate 失效
标题翻译：生产基于异氰酸酯的硬质泡沫
公开(公告)号：US5684092A
公开(公告)日：1997-11-04
申请号：US755069
申请日：1996-11-22
申请人： Holger Seifert , Renate Hempel , Gottfried Knorr , Udo Rotermund
发明人： Holger Seifert , Renate Hempel , Gottfried Knorr , Udo Rotermund
IPC分类号： C08J9/02 , C08G18/00 , C08G18/08 , C08G18/28 , C08G18/65 , C08J9/14 , C08K3/00
CPC分类号： C08J9/149 , C08G18/282 , C08J9/141 , C08G2101/0025 , C08J2375/04
摘要： In a process for producing rigid foams based on isocyanate, the blowing agent used is a mixture of at least one low-boiling hydrocarbon having from 3 to 7 carbon atoms, low molecular weight monohydric alcohols containing primary or secondary hydroxyl groups and having from 1 to 4 carbon atoms, and, if desired, the carbon dioxide formed from water and isocyanate. The rigid foams can be used as insulation material.
摘要翻译：在用于生产基于异氰酸酯的刚性泡沫的方法中，所用的发泡剂是至少一种具有3-7个碳原子的低沸点烃，含有伯或仲羟基的低分子量一元醇的混合物，并且具有1至 4个碳原子，如果需要，由水和异氰酸酯形成的二氧化碳。刚性泡沫可以用作绝缘材料。

3. 发明授权

US06495652B1 Prepolymers containing isocyanate groups and a method for the production thereof 有权
标题翻译：含有异氰酸酯基团的预聚物及其制备方法
公开(公告)号：US06495652B1
公开(公告)日：2002-12-17
申请号：US09673046
申请日：2000-10-09
申请人： Michael Reichelt , Udo Rotermund , Renate Hempel , Peter Falke , Peter von Malotki , Holger Seifert
发明人： Michael Reichelt , Udo Rotermund , Renate Hempel , Peter Falke , Peter von Malotki , Holger Seifert
IPC分类号： C08G1876
CPC分类号： C09K3/1021 , C08G18/10 , C08G18/5006 , C08G18/7664 , C08G2101/0008 , C08G2101/0025 , C08G2101/0083 , C08G18/6674
摘要： Prepolymers which contain isocyanate groups, have an NCO content of at least 30.0% by weight and can be prepared by reacting an isocyanate mixture consisting predominantly of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates and having a proportion of two-ring isomers of not more than 74% by weight with at least 4-functional polyols or a mixture of polyols having a mean functionality of at least 4, where the polyols or polyol mixtures have a hydroxyl number of from 200 to 1650 mg KOH/g and a number average molecular weight of less than 1100 g/mol. The present invention also provides a process for preparing these prepolymers containing isocyanate groups, provides for their use for producing polyurethanes and provides a process for producing polyurethanes by reacting at least one novel prepolymer containing isocyanate groups, if desired in admixture with further organic and/or modified organic isocyanates (a), with compounds having at least two reactive hydrogen atoms (b) in the presence of, if desired, blowing agents (c), catalysts (d) and, if desired, further auxiliaries and/or additives (e).
摘要翻译：含有异氰酸酯基的预聚物的NCO含量至少为30.0重量％，可以通过使主要由二苯基甲烷二异氰酸酯和聚苯基聚亚甲基多异氰酸酯组成的异氰酸酯混合物与二苯基聚亚甲基多异氰酸酯的比例为不超过74％的双环异构体比例重量与至少4-官能多元醇或平均官能度至少为4的多元醇的混合物，其中多元醇或多元醇混合物的羟值为200至1650mg KOH / g，数均分子量小于 1100g / mol。本发明还提供了制备这些含有异氰酸酯基团的预聚物的方法，提供了它们用于生产聚氨酯的方法，并且提供了通过使至少一种含有异氰酸酯基团的新型预聚物（如果需要）与另外的有机和/或如果需要，发泡剂（c），催化剂（d）和（如果需要的话）其它助剂和/或添加剂（e）的存在下，改性有机异氰酸酯（a），具有至少两个反应性氢原子的化合物（b））。

4. 发明授权

US5895792A Production of rigid polyurethane foams 失效
标题翻译：生产刚性聚氨酯泡沫
公开(公告)号：US5895792A
公开(公告)日：1999-04-20
申请号：US935911
申请日：1997-09-23
申请人： Udo Rotermund , Renate Hempel , Holger Seifert , Werner Wiegmann
发明人： Udo Rotermund , Renate Hempel , Holger Seifert , Werner Wiegmann
IPC分类号： C08J9/12 , C08G18/06 , C08G18/48 , C08G18/50
CPC分类号： C08G18/5033 , C08G18/482 , C08G2101/0025 , C08G2101/0033 , C08G2101/005 , C08G2101/0058 , C08G2101/0083
摘要： In a process for producing rigid polyurethane foams having improved heat distortion resistance and reduced thermal conductivity by reactinga) polyisocyanates withb) compounds containing hydrogen atoms reactive toward isocyanates, in the presence ofc) water, and, if desired,d) physically acting blowing agents ande) catalysts and known auxiliaries and/or additives, the compounds b) containing hydrogen atoms reactive toward isocyanates are a polyol mixture comprisingb1) a polyol which can be prepared by addition of ethylene oxide and/or propylene oxide onto a hexitol or a hexitol mixture, with the total hexitol content of the polyol mixture being from 15 to 30% by weight, based on the polyol mixture, andb2) a polyol which can be prepared by addition of ethylene oxide and/or propylene oxide onto one or more aromatic amines, with the total amine content of the polyol mixture being from 1 to 10% by weight, based on the polyol mixture, and the amount of the polyol mixture in the component b) is from 60 to 100 parts by mass per 100 parts by mass of the component b).
摘要翻译：在制备具有改善的耐热变形性和降低热导率的硬质聚氨酯泡沫体的方法中，通过使a）多异氰酸酯与b）在c）水和（如果需要）d）的存在下，对含有氢原子的异氰酸酯反应的化合物d）发泡剂和e）催化剂和已知的助剂和/或添加剂，包含对异氰酸酯具有反应性的氢原子的化合物b）是多元醇混合物，其包含b1）可以通过在己糖醇中加入环氧乙烷和/或环氧丙烷制备的多元醇或己糖醇混合物，其中多元醇混合物的总己糖醇含量为基于多元醇混合物的15至30重量％，和b2）可通过将环氧乙烷和/或环氧丙烷加成到一个上制备的多元醇或更多的芳族胺，多元醇混合物的总胺含量基于多元醇混合物为1至10重量％，并且组分中的多元醇混合物的量 b）相对于100质量份组分b）为60〜100质量份。

5. 发明授权

US5624969A Production of rigid foams based on isocyanate 失效
公开(公告)号：US5624969A
公开(公告)日：1997-04-29
申请号：US677744
申请日：1996-07-10
申请人： Holger Seifert , Renate Hempel , Gottfried Knorr , Udo Rotermund
发明人： Holger Seifert , Renate Hempel , Gottfried Knorr , Udo Rotermund
IPC分类号： C08J9/02 , C08G18/00 , C08G18/08 , C08G18/28 , C08G18/65 , C08J9/14
CPC分类号： C08J9/149 , C08G18/282 , C08J9/141 , C08G2101/0025 , C08J2375/04
摘要： In a process for producing rigid foams based on isocyanate, the blowing agent used is a mixture of at least one low-boiling hydrocarbon having from 3 to 7 carbon atoms, low molecular weight monohydric alcohols containing primary or secondary hydroxyl groups and having from 1 to 4 carbon atoms, and, if desired, the carbon dioxide formed from water and isocyanate. The rigid foams can be used as insulation material.

6. 发明授权

US6040349A Production of rigid polyurethanes foams with reduced density 失效
标题翻译：生产刚性聚氨酯发泡体，密度降低
公开(公告)号：US6040349A
公开(公告)日：2000-03-21
申请号：US38388
申请日：1998-03-11
申请人： Gottfried Knorr , Udo Rotermund , Eva Baum , Holger Seifert , Werner Wiegmann
发明人： Gottfried Knorr , Udo Rotermund , Eva Baum , Holger Seifert , Werner Wiegmann
IPC分类号： C08J9/08 , C08G18/48 , C08G18/50 , C08G18/66 , C08J9/14 , C08G18/32
CPC分类号： C08J9/141 , C08G18/482 , C08G18/5033 , C08G2101/0025 , C08G2101/005 , C08J2375/12
摘要： A process for producing rigid polyurethane foams with reduced density by reactinga) organic and/or modified organic polyisocyanates withb) at least one higher-molecular-weight compound having at least two reactive hydrogen atoms and, if desired,c) low-molecular-weight chain extenders and/or crosslinkers in the presence ofd) blowing agents,e) catalysts and, if desired,f) other auxiliaries and/or additives,is described, which comprises using, as blowing agent (d), a mixture of cyclopentane with at least one compound which is homogeneously miscible with cyclopentane selected from the class consisting of the alkanes and/or alkenes having 3 or 4 carbon atoms in the molecule and with the carbon dioxide produced from water and isocyanate, and using, as higher-molecular-weight compound (b) having at least two reactive hydrogen atoms, polyethers which contain aromatics and nitrogen.The use of the rigid foams produced in this way as insulating material is also described.
摘要翻译：通过使a）有机和/或改性的有机多异氰酸酯与b）至少一种具有至少两个反应性氢原子的高分子量化合物，如果需要，c）低分子量在d）发泡剂和e）催化剂的存在下，重量增链剂和/或交联剂，e）催化剂，如果需要，f）其它助剂和/或添加剂，其包括使用作为发泡剂（d）的混合物的环戊烷与至少一种与分子中具有3或4个碳原子的烷烃和/或烯烃与由水和异氰酸酯生成的二氧化碳类型的环戊烷可均匀混溶的化合物，并且使用较高的 - 具有至少两个反应性氢原子的分子量化合物（b），含有芳烃和氮的聚醚。还描述了以这种方式制造的刚性泡沫作为绝缘材料的用途。

7. 发明申请

US20100016461A1 RIGID POLYURETHANE FOAMS 有权
标题翻译：刚性聚氨酯泡沫塑料
公开(公告)号：US20100016461A1
公开(公告)日：2010-01-21
申请号：US12522002
申请日：2008-01-09
申请人： Holger Seifert , Johann Klassen , Louis Du Rieu , Werner Wiegmann , Guenter Matzke
发明人： Holger Seifert , Johann Klassen , Louis Du Rieu , Werner Wiegmann , Guenter Matzke
IPC分类号： C08G18/72
CPC分类号： C08G18/7664 , C08G18/4804 , C08G18/797
摘要： The invention relates to rigid polyurethane foams which can be produced by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reacted toward isocyanate groups in the presence of c) blowing agents, wherein the polyisocyanate a) used is a mixture of diphenylmethane diisocyanate and polyphenylenepolymethylene polyisocyanates comprising a1) 30-35% by weight of diphenylmethane diisocyanate, a2) 21-28% by weight of polyphenylenepolymethylene polyisocyanate having three aromatic rings, a3) 8-13% by weight of polyphenylenepolymethylene polyisocyanate having four aromatic rings, a4) 24-41% by weight of polyphenylenepolymethylene polyisocyanate having five or more aromatic rings, where the percentages by weight of the components a1) to a4) are based on the total weight of the components a1) to a4) and add up to 100% by weight.
摘要翻译：本发明涉及硬质聚氨酯泡沫体，其可通过使a）多异氰酸酯与b）在c）发泡剂存在下与至少两个氢原子反应的化合物反应而制备，其中使用的多异氰酸酯a）是混合物二苯基甲烷二异氰酸酯和聚亚苯基多亚甲基多异氰酸酯，其包含a1）30-35重量％的二苯基甲烷二异氰酸酯，a2）21-28重量％的具有三个芳环的聚亚苯基多亚甲基多异氰酸酯，a3）8-13重量％的具有四个芳环的聚苯基聚亚甲基多异氰酸酯，a4）24-41重量％的具有五个或更多个芳环的聚亚苯基多亚甲基多异氰酸酯，其中组分a1）至a4）的重量百分比基于组分a1）至a4的总重量），并加起来 100重量％。

8. 发明授权

US6100308A Preparation of polyurethanes having improved curing 失效
标题翻译：改进固化的聚氨酯的制备
公开(公告)号：US6100308A
公开(公告)日：2000-08-08
申请号：US900497
申请日：1997-07-25
申请人： Bernd Guettes , Stefan Dinsch , Gottfried Knorr , Holger Seifert
发明人： Bernd Guettes , Stefan Dinsch , Gottfried Knorr , Holger Seifert
IPC分类号： C08J9/12 , C08G18/50 , C08G18/65 , C08G101/00 , C08G18/48
CPC分类号： C08G18/5033 , C08G2101/0025 , C08G2101/0041 , C08G2101/0083
摘要： Polyurethanes having improved curing are prepared by reactinga) organic and/or modified organic diisocyanates and/or polyisocyanates withb) polyether polyols based on aromatic amines, able to be prepared by reacting specific amine combinations and, if desired, further coinitiators in a stage wise molecular addition of alkylene oxide, and also, if desired, further relatively high molecular weight compounds containing at least two reactive hydrogen atoms and, if desired,c) low molecular weight chain extenders and/or crosslinkers in the presence ofd) blowing agents,e) catalysts and, if desired,f) further auxiliaries and/or additives,wherein the specific amine combination used is a mixture of amines of the diphenylmethane series consisting of from 5 to 20% by weight of 4-ring amine, from 15 to 30% by weight of 3-ring amine, from 20 to 35% by weight of amines having more than 4 rings and from 25 to 50% by weight of 2-ring amine, wherein the proportions add up to 100% by weight, in combination with further aromatic amines.
摘要翻译：具有改进的固化的聚氨酯通过使a）有机和/或改性的有机二异氰酸酯和/或多异氰酸酯与b）基于芳族胺的聚醚多元醇反应制备，所述聚醚多元醇可以通过使特定的胺组合反应制备，如果需要，并且如果需要，还含有至少两个反应性氢原子的进一步相对高分子量化合物，如果需要，c）在d）发泡剂存在下的低分子量增链剂和/或交联剂，e）催化剂，如果需要，f）其它助剂和/或添加剂，其中所用的特定胺组合是由5至20重量％的4-环胺组成的二苯基甲烷系列的胺的混合物，15 至30重量％的3-环胺，20至35重量％的具有多于4个环的胺和25至50重量％的2-环胺，其中所述比例加至100重量％在公司与进一步的芳香胺混合。

9. 发明授权

US5492941A Polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface, process for their production, and their use as shoe or shoe sole material 失效
公开(公告)号：US5492941A
公开(公告)日：1996-02-20
申请号：US500212
申请日：1995-07-10
申请人： Peter Falke , Holger Seifert , Marion Heinz
发明人： Peter Falke , Holger Seifert , Marion Heinz
IPC分类号： C08J9/00 , C08J9/34
CPC分类号： C08J9/0061 , C08J9/34 , C08J2375/04 , C08J2433/00
摘要： The invention relates to polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface which comprise crosslinked poly(meth)acrylic acid, poly(meth)acrylic acid salts and/or poly(meth)acrylamides, to a process for their production, and to their use as shoe or shoe sole material.

10. 发明授权

US5488070A Polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface, process for their production, and their use as shoe or shoe sole material 失效
标题翻译：具有多孔芯和压实表面的聚氨酯基，紧凑的模制品或模制品，用于生产的方法，以及作为鞋底鞋底材料的用途
公开(公告)号：US5488070A
公开(公告)日：1996-01-30
申请号：US394877
申请日：1995-02-27
申请人： Peter Falke , Holger Seifert , Marion Heinz
发明人： Peter Falke , Holger Seifert , Marion Heinz
IPC分类号： C08J9/00 , C08J9/34
CPC分类号： C08J9/0061 , C08J9/34 , C08J2375/04 , C08J2433/00
摘要： The invention relates to polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface which comprise crosslinked poly(meth)acrylic acid, poly(meth)acrylic acid salts and/or poly(meth)acrylamides, to a process for their production, and to their use as shoe or shoe sole material.
摘要翻译：本发明涉及具有多孔芯和压实表面的聚氨酯基，紧密的模制品或模制品，其包含交联的聚（甲基）丙烯酸，聚（甲基）丙烯酸盐和/或聚（甲基）丙烯酰胺，他们的生产，以及作为鞋或鞋底材料的用途。

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