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1. 发明授权

US5492941A Polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface, process for their production, and their use as shoe or shoe sole material 失效
公开(公告)号：US5492941A
公开(公告)日：1996-02-20
申请号：US500212
申请日：1995-07-10
申请人： Peter Falke , Holger Seifert , Marion Heinz
发明人： Peter Falke , Holger Seifert , Marion Heinz
IPC分类号： C08J9/00 , C08J9/34
CPC分类号： C08J9/0061 , C08J9/34 , C08J2375/04 , C08J2433/00
摘要： The invention relates to polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface which comprise crosslinked poly(meth)acrylic acid, poly(meth)acrylic acid salts and/or poly(meth)acrylamides, to a process for their production, and to their use as shoe or shoe sole material.

2. 发明授权

US5488070A Polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface, process for their production, and their use as shoe or shoe sole material 失效
标题翻译：具有多孔芯和压实表面的聚氨酯基，紧凑的模制品或模制品，用于生产的方法，以及作为鞋底鞋底材料的用途
公开(公告)号：US5488070A
公开(公告)日：1996-01-30
申请号：US394877
申请日：1995-02-27
申请人： Peter Falke , Holger Seifert , Marion Heinz
发明人： Peter Falke , Holger Seifert , Marion Heinz
IPC分类号： C08J9/00 , C08J9/34
CPC分类号： C08J9/0061 , C08J9/34 , C08J2375/04 , C08J2433/00
摘要： The invention relates to polyurethane-based, compact moldings or moldings having a cellular core and a compacted surface which comprise crosslinked poly(meth)acrylic acid, poly(meth)acrylic acid salts and/or poly(meth)acrylamides, to a process for their production, and to their use as shoe or shoe sole material.
摘要翻译：本发明涉及具有多孔芯和压实表面的聚氨酯基，紧密的模制品或模制品，其包含交联的聚（甲基）丙烯酸，聚（甲基）丙烯酸盐和/或聚（甲基）丙烯酰胺，他们的生产，以及作为鞋或鞋底材料的用途。

3. 发明授权

US5916480A Storage-stable emulsions for producing fine-celled rigid foams based on isocyanate 有权
标题翻译：用于生产基于异氰酸酯的细胞刚性泡沫的储存稳定的乳液
公开(公告)号：US5916480A
公开(公告)日：1999-06-29
申请号：US159976
申请日：1998-09-24
申请人： Udo Rotermund , Marion Heinz , Anja Biedermann , Renate Hempel , Werner Wiegmann
发明人： Udo Rotermund , Marion Heinz , Anja Biedermann , Renate Hempel , Werner Wiegmann
IPC分类号： C08J9/00 , B01F17/34 , C08G18/00 , C08G18/28 , C08G18/34 , C08G18/40 , C08G18/42 , C08G18/66 , C08G101/00 , C08J9/14 , C08K3/00
CPC分类号： C08J9/141 , C08G18/6607 , C08G2101/0025 , C08G2101/0058 , C08J2205/10 , C08J2375/04
摘要： Blowing agent-containing emulsions comprisea) compounds containing hydrogen atoms which are reactive toward isocyanates,b) blowing agents,c) catalysts, auxiliaries and/or additives which are customary in polyurethane chemistry, wherein the blowing agents b) are present as an emulsion in the components a) and c), and polyester alcohols having the following structure are used as emulsification aids: ##STR1## where m=0-15n=0-1o=0-15p=0-1q=0-15r=0-1s=0-15t=0-1u=0-10v=0-15x=1-5y=1-4 or mixtures of 1-3 where r+n.noteq.0z=0-3z.sub.i =0.1-3R.sub.1 is an aliphatic structure without OH groups, based on the structure of polyhydric alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol and dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,3-butanediol, trimethylolpropane, trimethylol ethane, glycerol, pentaerythritol, where these substances can also be used as any mixture with one another in the esterification and R.sub.1 can therefore also be a mixture of the corresponding structures,R.sub.2 is the radical of a polycarboxylic acid without COOH groups, eg. adipic acid, terephthalic acid, o-phthalic acid,R.sub.3 is an alcohol radical like R.sub.1.
摘要翻译：含发泡剂的乳液包括a）含有对异氰酸酯具有反应性的氢原子的化合物，b）发泡剂，c）在聚氨酯化学中常用的催化剂，助剂和/或添加剂，其中发泡剂b）作为乳液存在在组分a）和c）中，具有以下结构的聚酯醇用作乳化助剂：其中m = 0-15n = 0-1 o = 0-15 p = 0-1 q = 0-15 r = 0-1 s = 0-15 t = 0-1 u = 0-10 v = 0-15 x = 1-5 y = 1-4或1-3的混合，其中r + n NOTEQUAL 0 z = 0-3 zi = 0.1-3 R1是不含OH基团的脂肪族结构，基于多元醇的结构，优选乙二醇，二甘醇，三甘醇，1,2-丙二醇和二丙二醇，1,4-丁二醇， 6-己二醇，新戊二醇，1,3-丁二醇，三羟甲基丙烷，三羟甲基乙烷，甘油，季戊四醇，其中这些物质也可以作为彼此在酯化中的任何混合物使用，因此，因此是相应结构的混合物，R2是不含COOH基团的多元羧酸的基团，例如。己二酸，对苯二甲酸，邻苯二甲酸，R3是如R1的醇基。

4. 发明授权

US06274642B1 Storage-stable, blowing agent-containing emulsions for producing rigid foams based on isocyanate 有权
标题翻译：用于生产基于异氰酸酯的刚性泡沫的储存稳定的含发泡剂的乳液
公开(公告)号：US06274642B1
公开(公告)日：2001-08-14
申请号：US09160109
申请日：1998-09-24
申请人： Udo Rotermund , Anja Biedermann , Renate Hempel , Werner Wiegmann , Marion Heinz
发明人： Udo Rotermund , Anja Biedermann , Renate Hempel , Werner Wiegmann , Marion Heinz
IPC分类号： C08J914
CPC分类号： C08J9/141 , C08G18/4018 , C08G18/4288 , C08G18/4816 , C08G18/4841 , C08G18/4845 , C08G18/5024 , C08G18/6674 , C08G2101/0025 , C08J2205/10 , C08J2375/04
摘要： Storage-stable, blowing agent-containing halogen-free emulsions for producing rigid foams based on isocyanate comprise a) compounds containing hydrogen atoms which are reactive toward isocyanate groups, b) water, c) physically acting, halogen-free blowing agents and, if desired, d) auxiliaries and/or additives which are customary in polyurethane chemistry, wherein the component a) comprises polyether alcohols having a functionality of greater than 1.5 and a hydroxyl number of from 10 to 100 mg KOH/g in an amount of from 0.2% by mass to 80% by mass, based on the mass of the component a), and the halogen-free, physically acting blowing agents c) used are hydrocarbons having from 3 to 10 carbon atoms.
摘要翻译：用于制备基于异氰酸酯的刚性泡沫的储存稳定的含发泡剂的无卤乳液包括a）含有对异氰酸酯基团具有反应性的氢原子的化合物，b）水，c）物理作用的，无卤素的发泡剂，如果需要，d）在聚氨酯化学中通常的助剂和/或添加剂，其中组分a）包含官能度大于1.5，羟值为10至100mg KOH / g的聚醚醇，其量为0.2重量％基于组分a）的质量计，质量至80质量％，并且所用的无卤物理作用的发泡剂c）是具有3至10个碳原子的烃。

5. 发明授权

US5880168A Open-celled rigid foams based on isocyanate 有权
标题翻译：基于异氰酸酯的开孔刚性泡沫
公开(公告)号：US5880168A
公开(公告)日：1999-03-09
申请号：US159924
申请日：1998-09-24
申请人： Marion Heinz , Werner Wiegmann , Udo Rotermund , Anja Biedermann , Michael Reichelt
发明人： Marion Heinz , Werner Wiegmann , Udo Rotermund , Anja Biedermann , Michael Reichelt
IPC分类号： C08J9/02 , C08G18/28 , C08G18/48 , C08G18/66 , C08G101/00 , C08J9/14 , C08G18/34
CPC分类号： C08J9/149 , C08G18/482 , C08G18/6607 , C08G18/6696 , C08J9/141 , C08G2101/0025 , C08G2101/0058 , C08G2330/50 , C08J2203/14 , C08J2203/142 , C08J2205/05 , C08J2205/10 , C08J2375/04 , F25D2201/1262 , F25D2201/14
摘要： In a process for producing open-celled rigid foams by reactinga) polyisocyanates withb) compounds containing hydrogen atoms which are reactive toward isocyanates, in the presence ofc) water,d) if desired, organic compounds acting as physical blowing agents,e) catalysts, auxiliaries and/or additives,the compounds containing reactive hydrogen atoms used are substances having the structure I: ##STR1## where m is 0-15n is 0-1o is 0-15p is 0-1q is 0-15r is 0-1s is 0-15t is 0-1u is 0-10v is 0-15x is 1-5y is 1-4 or mixtures of 1-3 where r+n.noteq.0z is 0-3z.sub.i is 0.1-3R.sub.1 is an aliphatic structure without OH groups based on the structure of polyhydric alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol and dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,3-butanediol, trimethylolpropane, trimethylolethane, glycerol, pentaerythritol, where these substances can also be used in the esterification as any mixture among one another and R.sub.1 can therefore also be a mixture of the corresponding structures,R.sub.2 is the radical of a polycarboxylic acid without COOH groups, eg. adipic acid, terephthalic acid, o-phthalic acid,R.sub.3 is an alcohol radical like R.sub.1.
摘要翻译：在一种生产开孔刚性泡沫的方法中，通过使a）多异氰酸酯与b）在c）水存在下，含有对异氰酸酯反应的氢原子的化合物，d）如果需要，作为物理发泡剂的有机化合物，e ）催化剂，助剂和/或添加剂，含有反应性氢原子的化合物是具有结构I的物质：0-1 q是0-15 r是0-1 s是0-15 t是0-1 u是0 -10 v是0-15 x是1-5 y是1-4或1-3的混合物，其中r + n是等于0 z是0-3 zi是0.1-3 R1是没有OH基团的脂肪族结构，基于多元醇的结构，优选乙二醇，二甘醇，三甘醇，1,2-丙二醇和二丙二醇，1,4-丁二醇，1,6-己二醇，新戊二醇，1,3-丁二醇，三羟甲基丙烷，三羟甲基乙烷，甘油，季戊四醇，其中这些物质也可以在酯化中用作彼此和R1之间的任何混合物，因此可以是 o是相应结构的混合物，R2是不含COOH基团的多元羧酸的基团，例如。己二酸，对苯二甲酸，邻苯二甲酸，R3是如R1的醇基。

6. 发明授权

US07390867B2 Isocyanate adducts 有权
标题翻译：异氰酸酯加合物
公开(公告)号：US07390867B2
公开(公告)日：2008-06-24
申请号：US10735426
申请日：2003-12-12
申请人： Marion Heinz , Udo Rotermund , Peter Huntemann , Udo Schilling
发明人： Marion Heinz , Udo Rotermund , Peter Huntemann , Udo Schilling
IPC分类号： C08G18/48 , C08J9/32
CPC分类号： C08G18/0885 , C08G18/4816 , C08G18/6674 , C08G18/7671 , C08G2101/00 , C08K7/28
摘要： The invention relates to isocyanate adducts which can be prepared by reacting at least one polyisocyanate with compounds having at least two hydrogen atoms which are reactive toward isocyanate groups and have a crystalline content of less than 10 J/g determined by differential scanning calorimetry in accordance with DIN 51 004 at 20 K/min from room temperature to 250° C. using a nitrogen flow of 3 l/h as carrier gas and an aromatics content reported as carbon atoms in aromatic rings of less than 31% by weight, based on the total weight of the isocyanate adducts.
摘要翻译：本发明涉及异氰酸酯加合物，其可以通过使至少一种多异氰酸酯与具有至少两个对异氰酸酯基反应的氢原子的化合物与通过差示扫描量热法测定的结晶含量小于10J / g的化合物反应来制备， DIN 51 004以20K /分钟从室温至250℃，使用3升/小时的氮气流作为载气，芳族环中报道的芳族化合物含量小于31重量％，基于异氰酸酯加合物的总重量。

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