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    • 6. 发明授权
    • Prepolymers containing isocyanate groups and a method for the production thereof
    • 含有异氰酸酯基团的预聚物及其制备方法
    • US06495652B1
    • 2002-12-17
    • US09673046
    • 2000-10-09
    • Michael ReicheltUdo RotermundRenate HempelPeter FalkePeter von MalotkiHolger Seifert
    • Michael ReicheltUdo RotermundRenate HempelPeter FalkePeter von MalotkiHolger Seifert
    • C08G1876
    • C09K3/1021C08G18/10C08G18/5006C08G18/7664C08G2101/0008C08G2101/0025C08G2101/0083C08G18/6674
    • Prepolymers which contain isocyanate groups, have an NCO content of at least 30.0% by weight and can be prepared by reacting an isocyanate mixture consisting predominantly of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates and having a proportion of two-ring isomers of not more than 74% by weight with at least 4-functional polyols or a mixture of polyols having a mean functionality of at least 4, where the polyols or polyol mixtures have a hydroxyl number of from 200 to 1650 mg KOH/g and a number average molecular weight of less than 1100 g/mol. The present invention also provides a process for preparing these prepolymers containing isocyanate groups, provides for their use for producing polyurethanes and provides a process for producing polyurethanes by reacting at least one novel prepolymer containing isocyanate groups, if desired in admixture with further organic and/or modified organic isocyanates (a), with compounds having at least two reactive hydrogen atoms (b) in the presence of, if desired, blowing agents (c), catalysts (d) and, if desired, further auxiliaries and/or additives (e).
    • 含有异氰酸酯基的预聚物的NCO含量至少为30.0重量%,可以通过使主要由二苯基甲烷二异氰酸酯和聚苯基聚亚甲基多异氰酸酯组成的异氰酸酯混合物与二苯基聚亚甲基多异氰酸酯的比例为不超过74%的双环异构体比例 重量与至少4-官能多元醇或平均官能度至少为4的多元醇的混合物,其中多元醇或多元醇混合物的羟值为200至1650mg KOH / g,数均分子量小于 1100g / mol。 本发明还提供了制备这些含有异氰酸酯基团的预聚物的方法,提供了它们用于生产聚氨酯的方法,并且提供了通过使至少一种含有异氰酸酯基团的新型预聚物(如果需要)与另外的有机和/或 如果需要,发泡剂(c),催化剂(d)和(如果需要的话)其它助剂和/或添加剂(e)的存在下,改性有机异氰酸酯(a),具有至少两个反应性氢原子的化合物(b) )。