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    • 3. 发明授权
    • Process for producing polyamide acid having siloxane bonds and polyimide
having siloxane bonds and isoindoloquinazolinedione rings
    • 具有硅氧烷键的聚酰胺酸的制造方法和具有硅氧烷键和异吲哚喹啉二酮环的聚酰亚胺的制造方法
    • US4847358A
    • 1989-07-11
    • US86892
    • 1987-08-18
    • Mitsumasa KojimaTakayuki SaitoToul KikuchiShun-ichiro UchimuraHidetaka SatouDaisuke Makino
    • Mitsumasa KojimaTakayuki SaitoToul KikuchiShun-ichiro UchimuraHidetaka SatouDaisuke Makino
    • C08G73/10
    • C08G73/106
    • There are disclosed a process for producing a polyamide acid having at least one siloxane bond, which comprises carrying out the reaction of:(a) a tetracarboxylic dianhydride having at least one siloxane bond of the formula: ##STR1## wherein R represents a monovalent hydrocarbon group and m is an integer of 1 or more;(b) a diamine; and(c) a diaminoamide compound of the formula (II): ##STR2## wherein Ar represents an aromatic residue, Y represents SO.sub.2 or CO, and one amino group and Y--YNH.sub.2 are positioned in ortho-position to each other,and optinal presence of(d) an aromatic tetracarboxylic dianhydride;with the total amount of the diamine and the diaminoamide compound and the total amount of the tetracarboxylic dianhydride of the formula (I) and the aromatic tetracarboxylic dianhydride optionally contained being substantially equal moles;and a process for producing a polyimide having at least one siloxane bond and at least one isoindoloquinazolinedione ring, which comprises further heating the resulting polyamide acid to dehydration ring closure.
    • 公开了一种制备具有至少一个硅氧烷键的聚酰胺酸的方法,该方法包括进行以下反应:(a)具有至少一个具有下式的硅氧烷键的四羧酸二酐:其中R表示 一价烃基,m为1以上的整数, (b)二胺; 和(c)式(II)的二氨基酰胺化合物:其中Ar表示芳族残基,Y表示SO 2或CO,一个氨基和Y-YNH 2彼此相邻位置 ,和(d)芳族四羧酸二酐的选择性存在; 二胺和二氨基酰胺化合物的总量和式(I)的四羧酸二酐和任选地含有的芳族四羧酸二酐的总量基本相等; 以及生产具有至少一个硅氧烷键和至少一个异吲哚喹啉二酮环的聚酰亚胺的方法,其包括进一步将所得聚酰胺酸加热至脱水闭环。