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1. 发明授权

US5831129A Preparation, with heterogeneous catalysis, of N-hydroxyalkyl-substituted aminoalkynes 失效
标题翻译：用非均相催化制备N-羟烷基取代的氨基炔烃
公开(公告)号：US5831129A
公开(公告)日：1998-11-03
申请号：US944976
申请日：1997-10-07
申请人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz , Thomas Ruhl
发明人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz , Thomas Ruhl
IPC分类号： B01J23/72 , C07B61/00 , C07C213/02 , C07C215/08 , C07C217/08 , C07C209/02
CPC分类号： C07C213/02
摘要： N-Hydroxyalkyl-substituted aminoalkynes of the formula I ##STR1## are prepared by reacting an alkyne with a 1-oxa-3-azaheterocyclo-alkane in a reaction with heterogeneous catalysis by a catalyst which comprises a compound of a metal of the first or second sub-group.
摘要翻译：通过使炔与1-氧杂-3-氮杂环烷烃反应，通过催化剂与非均相催化反应制备式I的N-羟基烷基取代的氨基炔，所述催化剂包含：第一或第二子组。

2. 发明授权

US5840986A Preparation with heterogeneous catalysis of N-alkyl-substituted aminoalkynes 失效
标题翻译：用N-烷基取代的氨基炔的多相催化制备
公开(公告)号：US5840986A
公开(公告)日：1998-11-24
申请号：US923557
申请日：1997-09-04
申请人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
发明人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
IPC分类号： C07D295/04 , B01J31/26 , C07C209/60 , C07C211/08 , C07C211/23 , C07C211/25 , C07C211/26 , C07C211/43 , C07C211/54 , C07C209/26
CPC分类号： C07C209/60
摘要： A process for preparing N-alkyl-substituted aminoalkynes by reacting an alkyne with a carbonyl compound and an amine with heterogeneous catalysis in which an unsupported copper acetylide derived from malachite is used as the catalyst. The N-alkyl-substituted aminoalkyne have a wide variety of uses including their use as precursors for pharmaceuticals, their use in electroplating processes and their use as corrosion inhibitors.
摘要翻译：通过使炔与羰基化合物和胺与非均相催化反应制备N-烷基取代的氨基炔烃的方法，其中使用源自孔雀石的未负载的乙炔化铜作为催化剂。 N-烷基取代的氨基炔具有多种用途，包括它们作为药物前体的用途，它们在电镀方法中的应用及其作为腐蚀抑制剂的用途。

3. 发明授权

US5962700A Butyrolactone-preparation process 失效
标题翻译：丁内酯制备工艺
公开(公告)号：US5962700A
公开(公告)日：1999-10-05
申请号：US11607
申请日：1998-02-12
申请人： Marc Heider , Thomas Ruhl , Jochem Henkelmann , Susanne Stutz , Thomas Preiss , Heinz Rutter , Martin Schafer , Arthur Hohn
发明人： Marc Heider , Thomas Ruhl , Jochem Henkelmann , Susanne Stutz , Thomas Preiss , Heinz Rutter , Martin Schafer , Arthur Hohn
IPC分类号： C07D307/33 , B01J31/20 , C07B61/00 , C07D307/58 , C07D315/00 , C07F7/08
CPC分类号： C07D315/00
摘要： A process for the preparation of butyrolactones of the formula I ##STR1## where the substituents R.sup.1 and R.sup.2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert: substituents, is described in which an alkyne of the formula IIR.sup.1 --C.tbd.C--R.sup.2 IIwhere the substituents have the meanings indicated above, is reacted under reducing conditions at elevated pressure and elevated temperature with carbon monoxide CO and hydrogen in the presence of a transition metal catalyst or with carbon monoxide and water in the presence of a transition metal catalyst.
摘要翻译： PCT No.PCT / EP96 / 03472 Sec。 371日期1998年2月12日 102（e）日期1998年2月12日PCT 1996年8月6日PCT PCT。公开号WO97 / 07111 日期1997年2月27日描述了制备式I的丁内酯的方法，其中取代基R 1和R 2是氢，烷基或羟基烷基，或芳基和三烷基甲硅烷基，如果适用的话带有惰性：取代基，其中描述了炔其中取代基具有上述含义的式IIR1-C 3BOND C-R2II在还原条件下在升高的压力和升高的温度下与一氧化碳CO和氢在过渡金属催化剂或一氧化碳和水的存在下反应过渡金属催化剂的存在。

4. 发明授权

US5808160A Preparation of hydroxy-alkyl-substituted aminoalkynes with heterogenous catalysis 失效
标题翻译：用异源催化制备羟烷基取代的氨基炔
公开(公告)号：US5808160A
公开(公告)日：1998-09-15
申请号：US847486
申请日：1997-04-25
申请人： Thomas Ruhl , Thomas Preiss , Jochem Henkelmann
发明人： Thomas Ruhl , Thomas Preiss , Jochem Henkelmann
IPC分类号： B01J31/26 , C07B61/00 , C07C213/02 , C07C213/08 , C07C215/08 , C07C215/12 , C07C215/24 , C07C217/08 , C07C217/46 , C07C213/00
CPC分类号： C07C213/02
摘要： Hydroxyalkyl-substituted aminoalkynes of the general formula I ##STR1## where at least one of the substituents R.sup.1, R.sup.4 or R.sup.5 is hydroxyalkyl are prepared in a reaction with heterogeneous catalysis.
摘要翻译：其中至少一个取代基R 1，R 4或R 5是羟基烷基的通式I（I）的羟烷基取代的氨基炔与多异构催化反应制备。

5. 发明授权

US06316680B1 Isolation of &agr;-ethynyl carbinols by distillation 失效
标题翻译：通过蒸馏分离α-乙炔基甲醇
公开(公告)号：US06316680B1
公开(公告)日：2001-11-13
申请号：US09455161
申请日：1999-12-06
申请人： Ralf-Thomas Rahn , Harald Rust , Thomas Rühl , Jochem Henkelmann , Susanne Stutz
发明人： Ralf-Thomas Rahn , Harald Rust , Thomas Rühl , Jochem Henkelmann , Susanne Stutz
IPC分类号： C07C2726
CPC分类号： C07C29/80 , C07C33/042 , C07C33/048
摘要： In a process for isolating &agr;-ethynyl carbinols from the liquid reaction mixture from the addition of acetylene onto &agr;,&bgr;-unsaturated carbonyl compounds by distillation, the distillation is carried out continuously, the feed stream is introduced into the middle section of a distillation column (K), the major part of the water is distilled off azeotropically together with the solvent at the top of the column, and the &agr;-ethynyl carbinol target product is taken off below the feed point to the column.
摘要翻译：在通过蒸馏从乙炔加入到α，β-不饱和羰基化合物中的液体反应混合物中分离α-乙炔基甲醇的方法中，蒸馏连续进行，将进料流引入蒸馏塔的中间部分（K）中，将大部分水与塔顶部的溶剂一起共沸蒸馏，并将α-乙炔基甲醇目标产物从柱的进料点以下取出。

6. 发明授权

US06828468B2 Preparation of higher &agr;, &bgr;-unsaturated alcohols 失效
标题翻译：制备较高级的α，β-不饱和醇
公开(公告)号：US06828468B2
公开(公告)日：2004-12-07
申请号：US10138338
申请日：2002-05-06
申请人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
发明人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
IPC分类号： C07C3304
CPC分类号： C07C49/203 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0225 , C07C29/17 , C07C29/42 , C07C45/62 , C07C45/676 , C07C33/02 , C07C33/048 , C07C49/04
摘要： Higher &agr;,&bgr;-unsaturated alcohols are prepared by monoethynylation of a ketone by the NH3/KOH method, if desired hydrogenation of the acetylene alcohol in the presence of hydrogen over a Pd-containing thin layer catalyst, purifying distillation of the hydrogenation product, preferably in a dividing wall column with recirculation of the unreacted ketone to the ethynylation step, and, if desired, preparation of higher alcohols having in each case 5 more carbon atoms in the chain by reacting the alcohols prepared by monoethynylation and, if desired, partial hydrogenation with alkyl acetoacetates diketene in a Carroll reaction to form ketones and using these as starting materials for the steps ethynylation, optional hydrogenation and fractional distillation.
摘要翻译：如果需要在氢气存在下在含Pd的薄层催化剂上氢化乙炔醇，纯化氢化产物的蒸馏，优选的是通过NH 3 / KOH方法将酮单异构化制备较高级的α，β-不饱和醇在具有未反应酮再循环至乙炔化步骤的分隔壁塔中，并且如果需要，通过使通过单异丁烯基化制备的醇和如果需要的话进行部分氢化制备在各种情况下在链中多出5个碳原子的高级醇在Carroll反应中使用烷基乙酰乙酸酯双烯酮形成酮，并将其用作步骤乙炔化，任选的氢化和分馏的起始原料。

7. 发明授权

US5723685A Preparation of monovinyl ethers 失效
标题翻译：单乙烯基醚的制备
公开(公告)号：US5723685A
公开(公告)日：1998-03-03
申请号：US548739
申请日：1995-10-26
申请人： Marc Heider , Thomas Ruhl , Herbert Helfert , Martin Schmidt-Radde , Jochem Henkelmann
发明人： Marc Heider , Thomas Ruhl , Herbert Helfert , Martin Schmidt-Radde , Jochem Henkelmann
IPC分类号： B01J23/02 , B01J31/02 , B01J31/12 , C07B61/00 , C07C41/06 , C07C41/08 , C07C43/178 , C07C41/00
CPC分类号： C07C41/08 , C07C41/54
摘要： The preparation of monovinyl ethers of the general formula I ##STR1## in which A stands for a chemical bond or for a methylene or ethylene group, the radicals R.sup.1 and R.sup.2 independently stand for hydrogen, alkyl, cycloalkyl, or aryl groups or R.sup.1 and R.sup.2 together form a C.sub.3 -C.sub.5 alkylene bridging member, by the reaction of a diol of the general formula II ##STR2## in which the variables have the above meanings, with acetylene in the presence of a base, in which the reaction is carried out at 150.degree.-250.degree. C. under an acetylene partial pressure of 5-25 bar until 40-80% of the diol has been converted, at which point the reaction is stopped and the monovinyl ether of the formula I is isolated.
摘要翻译：制备通式I的单乙烯基醚（I）其中A代表化学键或亚甲基或亚乙基，基团R 1和R 2分别代表氢，烷基，环烷基或芳基或 R 1和R 2一起形成C 3 -C 5亚烷基桥连体，通过其中变量具有上述含义的通式II的二醇（II）与乙炔在碱的存在下反应，其中反应在150-250℃，乙炔分压为5-25巴下进行，直到二醇的40-80％转化为止，此时反应停止，式I的单乙烯基醚是孤立的

8. 发明授权

US5646293A Preparation of N-alkenylazoles 失效
标题翻译： N-链烯基唑的制备
公开(公告)号：US5646293A
公开(公告)日：1997-07-08
申请号：US675588
申请日：1996-07-03
申请人： Jochem Henkelmann , Marc Heider , Thomas Ruhl
发明人： Jochem Henkelmann , Marc Heider , Thomas Ruhl
IPC分类号： B01J31/02 , C07B61/00 , C07D233/56 , C07D233/58 , C07D235/06 , C07D249/08 , C07D521/00 , C07D235/08 , C07D235/18
CPC分类号： C07D235/06 , C07D231/12 , C07D233/56 , C07D249/08
摘要： A process for preparing N-alkenylazoles of the general formula I ##STR1## where X is CH--R.sup.6 or nitrogen,R.sup.1 and R.sup.2 are hydrogen or C.sub.1 - to C.sub.8 -alkyl,R.sup.3,R.sup.4,R.sup.5 and R.sup.6 are hydrogen, C.sub.1 - to C.sub.40 -alkyl, C.sub.2 - to C.sub.40 -alkenyl, C.sub.3 - to C.sub.20 -cycloalkyl, C.sub.4 - to C.sub.20 -alkylcycloalkyl, C.sub.4 - to C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 - to C.sub.20 -alkylaryl or C.sub.7 - to C.sub.20 -aralkyl, or aryl, C.sub.7 - to C.sub.20 -alkylaryl or C.sub.7 - to C.sub.20 -aralkyl which are mono- to pentasubstituted by C.sub.1 - to C.sub.8 -alkyl, C.sub.1 - to C.sub.8 -alkoxy or halogen, or R.sup.3 and R.sup.4 or R.sup.4 and R.sup.5 or R.sup.5 and R.sup.6 together are a C.sub.2 - to C.sub.10 -alkylene chain which is unsubstituted or mono- to hexasubstituted by C.sub.1 - to C.sub.8 -alkylby reaction of azoles of the general formula II ##STR2## where X, R.sup.3, R.sup.4 and R.sup.5 have the abovementioned meanings, with an alkenyl carboxylate of the general formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings and R.sup.7 is hydrogen, C.sub.1 - to C.sub.40 -alkyl, C.sub.3 - to C.sub.20 -cycloalkyl, C.sub.4 - to C.sub.20 -alkylcycloalkyl, aryl, C.sub.7 - to C.sub.20 -alkylaryl, C.sub.7 - to C.sub.20 -aralkyl, or aryl or C.sub.7 - to C.sub.20 -aralkyl which is mono- to trisubstituted by C.sub.1 - to C.sub.8 -alkyl, at from 0.degree. to 180.degree. C. and from 0.01 to 10 bar, which comprises carrying out the reaction in the presence of a base and of a quaternary salt, is described.
摘要翻译：制备通式I（I）的N-烯基唑的方法，其中X是CH-R6或氮，R1和R2是氢或C1-至C8-烷基，R3，R4，R5和R6是氢， C 1至C 40 - 烷基，C 2至C 40 - 烯基，C 3 -C 20 - 环烷基，C 4至C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20烷基芳基或C 7 -C 20 - 芳烷基，或被C 1〜C 8 - 烷基，C 1 -C 8 - 烷氧基或卤素单 - 五取代的芳基，C 7〜C 20 - 烷基芳基或C 7〜C 20 - 芳烷基，或者R 3和R 4或R 4和R 5或R 5 和R6一起是C2至C10亚烷基链，其未被取代或被C 1 -C 8 - 烷基单取代或被六取代的通式II（II）的唑类，其中X，R 3，R 4和R 5 具有上述含义，具有通式III（III）的烯基羧酸酯，其中R 1和R 2具有上述含义，并且R 7是氢，C 1至C 40烷基，C 3 -C 20环烷基，C 4至 C20-烷基环烷基，芳基，C7-至C20-烷基芳基，C7-至C20-芳基烷基或芳基或被C 1 -C 8烷基单取代三取代的C 7 -C 20 - 芳烷基，其中0至180℃和0.01至10巴，其包括在存在下进行反应的碱和季盐。

9. 发明授权

US06369282B1 Preparation of alkynediols 失效
标题翻译：炔二醇的制备
公开(公告)号：US06369282B1
公开(公告)日：2002-04-09
申请号：US09577127
申请日：2000-05-24
申请人： Alois Kindler , Thomas Preiss , Jochem Henkelmann
发明人： Alois Kindler , Thomas Preiss , Jochem Henkelmann
IPC分类号： C07C3118
CPC分类号： C07C29/42 , C07C33/044 , C07C33/046
摘要： The process for preparing alkynediols of the formula (I) R1R2C(OH)—C≡C—C(OH)R1R2 (I) where R1, R2 are each independently H, or a C1-20-hydrocarbon radical which may be substituted by one or more C1-6-alkyls and/or be interrupted by nonadjacent heteroatoms and/or contain C—C double or triple bonds, by reacting compounds of the formula (II) R1—C(═O)—R2 (II) with acetylene in a polar aprotic solvent is carried out in the presence of basic alkali metal salts as catalysts.
摘要翻译：制备式（I）的炔二醇的方法，其中R 1，R 2各自独立地为H，或可被一个或多个C 1-6 - 烷基取代和/或被不相邻的杂原子中断的C 1-20烃基和/ 或含有CC双键或三键，通过使式（II）化合物与极性非质子溶剂中的乙炔反应，在碱性碱金属盐作为催化剂的存在下进行。

10. 发明授权

US5936126A Process for reacting an organic compound in the presence of a supported ruthenium catalyst 失效
标题翻译：在负载型钌催化剂存在下使有机化合物反应的方法
公开(公告)号：US5936126A
公开(公告)日：1999-08-10
申请号：US877819
申请日：1997-06-18
申请人： Thomas Ruhl , Boris Breitscheidel , Jochem Henkelmann , Wolfgang Reif , Helmuth Menig , Sabine Weiguny
发明人： Thomas Ruhl , Boris Breitscheidel , Jochem Henkelmann , Wolfgang Reif , Helmuth Menig , Sabine Weiguny
IPC分类号： B01J23/46 , B01J35/10 , C07B35/02 , C07B61/00 , C07C29/141 , C07C29/149 , C07C29/20 , C07C31/12 , C07C31/125 , C07C31/135 , C07C31/20 , C07C35/08 , C07C35/21 , C07C209/72 , C07C211/35 , C07C211/36
CPC分类号： C07C29/149 , B01J23/462 , C07C209/72 , C07C29/141 , C07C29/20 , C07C2101/14
摘要： A process for the hydrogenation of an aromatic compound, in which at least one hydroxyl group is attached to an aromatic core, or an aromatic compound, in which at least one amino group is attached to an aromatic core, in the presence of a catalyst containing, as active metal, ruthenium and optionally one or more other Group IB, VIIB, or VIIIB metals, applied to a macroporous support.
摘要翻译：一种芳香化合物的氢化方法，其中至少一个羟基连接到芳族核心上，或其中至少一个氨基连接到芳族核心上的芳族化合物，在含有，作为活性金属，钌和任选的一种或多种其它IB，VIIB或VIIIB族金属，应用于大孔载体。

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