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1. 发明授权

US5831129A Preparation, with heterogeneous catalysis, of N-hydroxyalkyl-substituted aminoalkynes 失效
标题翻译：用非均相催化制备N-羟烷基取代的氨基炔烃
公开(公告)号：US5831129A
公开(公告)日：1998-11-03
申请号：US944976
申请日：1997-10-07
申请人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz , Thomas Ruhl
发明人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz , Thomas Ruhl
IPC分类号： B01J23/72 , C07B61/00 , C07C213/02 , C07C215/08 , C07C217/08 , C07C209/02
CPC分类号： C07C213/02
摘要： N-Hydroxyalkyl-substituted aminoalkynes of the formula I ##STR1## are prepared by reacting an alkyne with a 1-oxa-3-azaheterocyclo-alkane in a reaction with heterogeneous catalysis by a catalyst which comprises a compound of a metal of the first or second sub-group.
摘要翻译：通过使炔与1-氧杂-3-氮杂环烷烃反应，通过催化剂与非均相催化反应制备式I的N-羟基烷基取代的氨基炔，所述催化剂包含：第一或第二子组。

2. 发明授权

US5840986A Preparation with heterogeneous catalysis of N-alkyl-substituted aminoalkynes 失效
标题翻译：用N-烷基取代的氨基炔的多相催化制备
公开(公告)号：US5840986A
公开(公告)日：1998-11-24
申请号：US923557
申请日：1997-09-04
申请人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
发明人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
IPC分类号： C07D295/04 , B01J31/26 , C07C209/60 , C07C211/08 , C07C211/23 , C07C211/25 , C07C211/26 , C07C211/43 , C07C211/54 , C07C209/26
CPC分类号： C07C209/60
摘要： A process for preparing N-alkyl-substituted aminoalkynes by reacting an alkyne with a carbonyl compound and an amine with heterogeneous catalysis in which an unsupported copper acetylide derived from malachite is used as the catalyst. The N-alkyl-substituted aminoalkyne have a wide variety of uses including their use as precursors for pharmaceuticals, their use in electroplating processes and their use as corrosion inhibitors.
摘要翻译：通过使炔与羰基化合物和胺与非均相催化反应制备N-烷基取代的氨基炔烃的方法，其中使用源自孔雀石的未负载的乙炔化铜作为催化剂。 N-烷基取代的氨基炔具有多种用途，包括它们作为药物前体的用途，它们在电镀方法中的应用及其作为腐蚀抑制剂的用途。

3. 发明授权

US5962700A Butyrolactone-preparation process 失效
标题翻译：丁内酯制备工艺
公开(公告)号：US5962700A
公开(公告)日：1999-10-05
申请号：US11607
申请日：1998-02-12
申请人： Marc Heider , Thomas Ruhl , Jochem Henkelmann , Susanne Stutz , Thomas Preiss , Heinz Rutter , Martin Schafer , Arthur Hohn
发明人： Marc Heider , Thomas Ruhl , Jochem Henkelmann , Susanne Stutz , Thomas Preiss , Heinz Rutter , Martin Schafer , Arthur Hohn
IPC分类号： C07D307/33 , B01J31/20 , C07B61/00 , C07D307/58 , C07D315/00 , C07F7/08
CPC分类号： C07D315/00
摘要： A process for the preparation of butyrolactones of the formula I ##STR1## where the substituents R.sup.1 and R.sup.2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert: substituents, is described in which an alkyne of the formula IIR.sup.1 --C.tbd.C--R.sup.2 IIwhere the substituents have the meanings indicated above, is reacted under reducing conditions at elevated pressure and elevated temperature with carbon monoxide CO and hydrogen in the presence of a transition metal catalyst or with carbon monoxide and water in the presence of a transition metal catalyst.
摘要翻译： PCT No.PCT / EP96 / 03472 Sec。 371日期1998年2月12日 102（e）日期1998年2月12日PCT 1996年8月6日PCT PCT。公开号WO97 / 07111 日期1997年2月27日描述了制备式I的丁内酯的方法，其中取代基R 1和R 2是氢，烷基或羟基烷基，或芳基和三烷基甲硅烷基，如果适用的话带有惰性：取代基，其中描述了炔其中取代基具有上述含义的式IIR1-C 3BOND C-R2II在还原条件下在升高的压力和升高的温度下与一氧化碳CO和氢在过渡金属催化剂或一氧化碳和水的存在下反应过渡金属催化剂的存在。

4. 发明授权

US06316680B1 Isolation of &agr;-ethynyl carbinols by distillation 失效
标题翻译：通过蒸馏分离α-乙炔基甲醇
公开(公告)号：US06316680B1
公开(公告)日：2001-11-13
申请号：US09455161
申请日：1999-12-06
申请人： Ralf-Thomas Rahn , Harald Rust , Thomas Rühl , Jochem Henkelmann , Susanne Stutz
发明人： Ralf-Thomas Rahn , Harald Rust , Thomas Rühl , Jochem Henkelmann , Susanne Stutz
IPC分类号： C07C2726
CPC分类号： C07C29/80 , C07C33/042 , C07C33/048
摘要： In a process for isolating &agr;-ethynyl carbinols from the liquid reaction mixture from the addition of acetylene onto &agr;,&bgr;-unsaturated carbonyl compounds by distillation, the distillation is carried out continuously, the feed stream is introduced into the middle section of a distillation column (K), the major part of the water is distilled off azeotropically together with the solvent at the top of the column, and the &agr;-ethynyl carbinol target product is taken off below the feed point to the column.
摘要翻译：在通过蒸馏从乙炔加入到α，β-不饱和羰基化合物中的液体反应混合物中分离α-乙炔基甲醇的方法中，蒸馏连续进行，将进料流引入蒸馏塔的中间部分（K）中，将大部分水与塔顶部的溶剂一起共沸蒸馏，并将α-乙炔基甲醇目标产物从柱的进料点以下取出。

5. 发明授权

US06828468B2 Preparation of higher &agr;, &bgr;-unsaturated alcohols 失效
标题翻译：制备较高级的α，β-不饱和醇
公开(公告)号：US06828468B2
公开(公告)日：2004-12-07
申请号：US10138338
申请日：2002-05-06
申请人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
发明人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
IPC分类号： C07C3304
CPC分类号： C07C49/203 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0225 , C07C29/17 , C07C29/42 , C07C45/62 , C07C45/676 , C07C33/02 , C07C33/048 , C07C49/04
摘要： Higher &agr;,&bgr;-unsaturated alcohols are prepared by monoethynylation of a ketone by the NH3/KOH method, if desired hydrogenation of the acetylene alcohol in the presence of hydrogen over a Pd-containing thin layer catalyst, purifying distillation of the hydrogenation product, preferably in a dividing wall column with recirculation of the unreacted ketone to the ethynylation step, and, if desired, preparation of higher alcohols having in each case 5 more carbon atoms in the chain by reacting the alcohols prepared by monoethynylation and, if desired, partial hydrogenation with alkyl acetoacetates diketene in a Carroll reaction to form ketones and using these as starting materials for the steps ethynylation, optional hydrogenation and fractional distillation.
摘要翻译：如果需要在氢气存在下在含Pd的薄层催化剂上氢化乙炔醇，纯化氢化产物的蒸馏，优选的是通过NH 3 / KOH方法将酮单异构化制备较高级的α，β-不饱和醇在具有未反应酮再循环至乙炔化步骤的分隔壁塔中，并且如果需要，通过使通过单异丁烯基化制备的醇和如果需要的话进行部分氢化制备在各种情况下在链中多出5个碳原子的高级醇在Carroll反应中使用烷基乙酰乙酸酯双烯酮形成酮，并将其用作步骤乙炔化，任选的氢化和分馏的起始原料。

6. 发明申请

US20120328685A1 SYSTEM FOR PROTECTING GOODS DURING TRANSPORT 审中-公开
标题翻译：运输过程中保护物品的系统
公开(公告)号：US20120328685A1
公开(公告)日：2012-12-27
申请号：US13534781
申请日：2012-06-27
申请人： Susanne Stutz , Claus Kaiser , Jürgen Weiser , Daniel Bihlmeyer , Stefan Schaffert
发明人： Susanne Stutz , Claus Kaiser , Jürgen Weiser , Daniel Bihlmeyer , Stefan Schaffert
IPC分类号： B65D81/28 , A01P15/00 , B67C3/22 , A01N25/34
CPC分类号： B60P7/0876 , B65D88/542 , B65D90/046 , B65D2590/046
摘要： A system for protecting stored goods in a container (10), comprises a cage-like structure (20) formed by at least one pesticide treated net (22), capable of enclosing the stored goods, wherein the cage like structure (20), further comprises means for suspending the pesticide treated nets (14, 28, 30, 32, 34), and means for opening and closing the cage-like structure (26) on at least one section (24) of the at least one net (22). The system is particularly useful for the transport of tobacco, coffee, dried fruits, cocoa, nuts, tea, cereals, vegetables, spices and animals.
摘要翻译：一种用于保护储存在容器（10）中的储存物品的系统，包括由能够封闭储存货物的至少一个农药处理网（22）形成的笼状结构（20），其中笼状结构（20），进一步包括用于悬挂经过处理的农药网（14,28,30,32,34）的装置，以及用于在至少一个网的至少一个部分（24）上打开和关闭笼状结构（26）的装置（ 22）。该系统特别适用于运输烟草，咖啡，干果，可可，坚果，茶叶，谷物，蔬菜，香料和动物。

7. 发明授权

US08434623B2 Inorganic particles comprising an organic coating that can be hydrophilically/hydrophobically temperature controlled 失效
标题翻译：包含能够亲水/疏水控制温度的有机涂层的无机颗粒
公开(公告)号：US08434623B2
公开(公告)日：2013-05-07
申请号：US13054702
申请日：2009-07-17
申请人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
发明人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
IPC分类号： B03D3/00
CPC分类号： H01F1/44 , B03C1/015 , H01F1/0054
摘要： The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the following steps: (A) contacting of the mixture comprising the at least one first material and at least one second material with at least one selective hydrophobicizing agent in the presence of a suspension medium so that an adduct is formed from the at least one hydrophobicizing agent and the at least one first material but not with the at least one second material, (B) contacting of the adduct from step (A) with at least one magnetic particle which is functionalized on the surface with at least one polymeric compound having a transition temperature LCST (lower critical solution temperature) at a temperature at which the polymeric compound has hydrophobic character so that the adduct from step (A) and the at least one functionalized magnetic particle agglomerate, (C) if appropriate addition of further suspension medium to the mixture obtained in step (B), (D) separation of the agglomerate present in the suspension from step (B) or (C) from the suspension by application of a magnetic field, (E) dissociation of the agglomerate separated off in step (D) by setting of a temperature at which the polymeric compound has hydrophilic character in order to obtain the at least one first material.
摘要翻译：本发明涉及从包含该至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法，其包括以下步骤：（A）使包含至少一种第一材料和/ 材料和至少一种第二材料与至少一种选择性疏水剂在悬浮介质的存在下进行，使得加合物由至少一种疏水剂和至少一种第一材料形成，但不与至少一种第二材料形成，（B）将来自步骤（A）的加合物与至少一种在表面上官能化的磁性颗粒与至少一种具有转变温度LCST（较低临界溶解温度）的聚合化合物在聚合物具有疏水性，使得步骤（A）和至少一种官能化磁性颗粒附聚物的加合物，（C）如果适当添加的另外的悬浮介质加入到步骤（B）中获得的混合物中，（D）通过施加磁场从悬浮液中分离存在于步骤（B）或（C）的悬浮液中的附聚物，（E）在步骤（D）中通过设定聚合物具有亲水特性的温度来分离聚集体，以获得至少一种第一材料。

8. 发明申请

US20120114727A1 INSECTICIDAL SHEET-LIKE STRUCTURE FOR PROTECTING HUMANS AND DOMESTIC ANIMALS 审中-公开
标题翻译：用于保护人体和国内动物的杀虫面板结构
公开(公告)号：US20120114727A1
公开(公告)日：2012-05-10
申请号：US13382711
申请日：2010-07-05
申请人： Hartmut Leininger , Susanne Stutz , Ulrich Karl
发明人： Hartmut Leininger , Susanne Stutz , Ulrich Karl
IPC分类号： A01N43/36 , A01P7/04 , A01N25/08
CPC分类号： A01N43/36 , A01N43/56 , A01N53/00 , C08G18/6266 , C08G18/792 , D01F1/10 , D06M13/395 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/31 , D06M15/643 , D06M16/00 , D21H21/36 , A01N25/34 , A01N2300/00
摘要： A sheet-like structure, in particular a net, finished with an insecticidal mixture comprising a) chlorfenapyr and b) one or more pyrethroids from the group consisting of alpha-cypermethrin (b1), deltamethrin (b2), permethrin (b3) and lambda-cyhalothrin (b4), in an amount of (in each case relative to the sheet-like structure) a) 50 to 150 mg/m2 chlorfenapyr; b1) 50 to 150 mg/m2 alpha-cypermethrin; b2) 15 to 45 mg/m2 deltamethrin; b3) 50 to 750 mg/m2 permethrin; b4) 5 to 30 mg/m2 lambda-cyhalothrin, is suitable for controlling harmful insects in buildings and for protecting humans and domestic animals from such harmful insects and from vector-transmitted diseases which are transmitted by the harmful insects.
摘要翻译：具有杀虫混合物的片状结构，特别是一种杀虫混合物，其包含a）chlorfenapyr和b）一种或多种来自由α-氯氰菊酯（b1），溴氰菊酯（b2），氯菊酯（b3）和λ - 氯沙芬（b4），其量（在每种情况下相对于片状结构）a）50至150mg / m 2氯芬太尼; b1）50〜150mg / m2α-氯氰菊酯; b2）15〜45mg / m2溴氰菊酯; b3）50〜750mg / m2氯菊酯; b4）5〜30mg / m2λ-氯氟氰菊酯，适用于防治建筑物中的有害昆虫，并保护人类和家畜免受有害昆虫和由有害昆虫传播的载体传播疾病。

9. 发明申请

US20110120954A1 SELECTIVE MATERIALS SEPARATION USING MODIFIED MAGNETIC PARTICLES 有权
标题翻译：使用改性磁性颗粒的选择性材料分离
公开(公告)号：US20110120954A1
公开(公告)日：2011-05-26
申请号：US13054713
申请日：2009-07-15
申请人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
发明人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
IPC分类号： B03C1/01 , B01D39/00
CPC分类号： H01F1/44 , B03C1/015 , B82Y25/00 , H01F1/0045
摘要： The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.
摘要翻译：本发明涉及一种本发明的方法，用于从包含该至少一种第一材料和至少一种第二材料的混合物中分离至少一种第一材料，其包括以下步骤：（A）接触至少一种磁性颗粒和至少一种双功能分子或两者的加合物与混合物包含至少一种第一材料和至少一种第二材料，使得加合物由至少一个磁性颗粒形成，通式（I）的双官能化合物）和所述至少一种第一材料，（B）步骤（A）中获得的加合物的悬浮液在合适的悬浮介质中，（C）通过施用将来自步骤（B）的悬浮液中存在的加合物与悬浮液（D）如果合适，在步骤（C）中分离的加合物的解离以获得至少一种第一材料。相应的加合物和这种加合物用于分离材料混合物的用途。

10. 发明授权

US08519196B2 C10 alkanolalkoxylate mixtures and use thereof as novel low-foaming wetting agents 有权
标题翻译： C10链烷醇烷氧基化物混合物及其作为新型低泡润湿剂的用途
公开(公告)号：US08519196B2
公开(公告)日：2013-08-27
申请号：US10575760
申请日：2004-10-14
申请人： Markus Klumpe , Juergen Tropsch , Rolf-Dieter Kahl , Roland Boehn , Susanne Stutz , Ralf Noerenberg
发明人： Markus Klumpe , Juergen Tropsch , Rolf-Dieter Kahl , Roland Boehn , Susanne Stutz , Ralf Noerenberg
IPC分类号： C11D3/20
CPC分类号： C11D3/0026 , C07C43/11 , C11D1/72 , C11D1/722 , C11D1/8255
摘要： The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH (I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.
摘要翻译：烷氧基化物混合物包括式（I）的烷氧基化物：C 5 H 11 CH（C 3 H 7）CH 2 O（B）p（A）n（B）m（A）qH（I）其中A是亚乙基氧基，B各自独立地是C3- 10-亚烷基氧基或其混合物，基团A和B以所述顺序以嵌段的形式存在，p为0至10的数，n为大于0至20的数，m为大于0至 20，q是大于0至10的数，p + n + m + q至少为1，70至99重量％的烷氧基化物A1，其中C5H11为n-C5H11，1〜30％为其中C5H11是C2H5CH（CH3）CH2和/或CH3CH（CH3）CH2CH2）的烷氧基化物A2的重量存在于混合物中。

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