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1. 发明授权

US06828468B2 Preparation of higher &agr;, &bgr;-unsaturated alcohols 失效
标题翻译：制备较高级的α，β-不饱和醇
公开(公告)号：US06828468B2
公开(公告)日：2004-12-07
申请号：US10138338
申请日：2002-05-06
申请人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
发明人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
IPC分类号： C07C3304
CPC分类号： C07C49/203 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0225 , C07C29/17 , C07C29/42 , C07C45/62 , C07C45/676 , C07C33/02 , C07C33/048 , C07C49/04
摘要： Higher &agr;,&bgr;-unsaturated alcohols are prepared by monoethynylation of a ketone by the NH3/KOH method, if desired hydrogenation of the acetylene alcohol in the presence of hydrogen over a Pd-containing thin layer catalyst, purifying distillation of the hydrogenation product, preferably in a dividing wall column with recirculation of the unreacted ketone to the ethynylation step, and, if desired, preparation of higher alcohols having in each case 5 more carbon atoms in the chain by reacting the alcohols prepared by monoethynylation and, if desired, partial hydrogenation with alkyl acetoacetates diketene in a Carroll reaction to form ketones and using these as starting materials for the steps ethynylation, optional hydrogenation and fractional distillation.
摘要翻译：如果需要在氢气存在下在含Pd的薄层催化剂上氢化乙炔醇，纯化氢化产物的蒸馏，优选的是通过NH 3 / KOH方法将酮单异构化制备较高级的α，β-不饱和醇在具有未反应酮再循环至乙炔化步骤的分隔壁塔中，并且如果需要，通过使通过单异丁烯基化制备的醇和如果需要的话进行部分氢化制备在各种情况下在链中多出5个碳原子的高级醇在Carroll反应中使用烷基乙酰乙酸酯双烯酮形成酮，并将其用作步骤乙炔化，任选的氢化和分馏的起始原料。

2. 发明授权

US06956141B1 Method for preparing acetylene alcohols and their secondary products 失效
标题翻译：乙炔醇及其次要产物的制备方法
公开(公告)号：US06956141B1
公开(公告)日：2005-10-18
申请号：US09913979
申请日：2000-02-22
申请人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
发明人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
IPC分类号： C07C29/17 , C07C29/42 , C07C33/042 , C07C33/04 , C07C33/044 , C07C33/046
CPC分类号： C07C29/42 , C07C29/172 , Y02P20/582 , C07C33/044 , C07C33/042 , C07C31/20
摘要： A process for preparing at least one unsaturated alcohol (B) comprises the steps (I) to (III) below: (I) reaction of at least one alkali metal hydroxide or alkaline earth metal hydroxide with at least one alcohol (A) in at least one organic solvent (L) to give a mixture (G-I) comprising at least the alcohol (A), the solvent (L) and an alkoxide (AL); (II) reaction of at least one carbonyl compound of the formula R—CO—R′ with at least one alkyne of the formula R″—C≡C—H and the mixture (G-I) obtained in step (I) to give a mixture (G-II) comprising at least the alcohol (A), the solvent (L) and an unsaturated alcohol (B); (III) distillation of the mixture (G-II) obtained in step (II) to give the alcohol or alcohols (B) and a mixture (G-III) comprising the solvent (L) and the alcohol (A), wherein the solvent (L) obtained in step (III) and the alcohol (A) obtained in step (III) are recycled as a mixture to step (I).
摘要翻译：一种制备至少一种不饱和醇（B）的方法包括下列步骤（I）至（III）：（I）至少一种碱金属氢氧化物或碱土金属氢氧化物与至少一种醇（A）在至少一种有机溶剂（L），得到至少包含醇（A），溶剂（L）和醇盐（AL）的混合物（GI）（II）至少一种式R-CO-R'的羰基化合物与至少一种式R'-C≡CH的炔和步骤（I）中获得的混合物（GI）的反应，得到混合物至少包含醇（A），溶剂（L）和不饱和醇（B）的化合物（G-II）; （II）中获得的混合物（G-II）的蒸馏（III），得到醇或醇（B）和包含溶剂（L）和醇（A）的混合物（G-III），其中将步骤（III）中获得的溶剂（L）和步骤（III）中获得的醇（A）作为步骤（I）的混合物再循环。

3. 发明授权

US06297407B1 Method for producing alkyne diols 失效
标题翻译：炔二醇的制备方法
公开(公告)号：US06297407B1
公开(公告)日：2001-10-02
申请号：US09744437
申请日：2001-01-24
申请人： Alois Kindler , Melanie Brunner , Christian Tragut , Jochem Henkelmann
发明人： Alois Kindler , Melanie Brunner , Christian Tragut , Jochem Henkelmann
IPC分类号： C07C3118
CPC分类号： C07C29/42 , C07C33/042 , C07C33/044
摘要： The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence of a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.
摘要翻译：本发明涉及一种在含有伯醇和/或仲醇的醇钾的碱存在下，通过酮与炔烃在有机溶剂中反应制备炔烃的方法。产生炔二醇，同时形成从反应混合物中沉淀的加合物，其由炔一醇和/或炔二醇和碱组成。选择反应伴侣的化学计量，使得形成包含球形表面的凝胶状加合物，由此在整个反应期间反应混合物保持敏感。

4. 发明授权

US06716937B2 Method for the single-step production of polytetrahydrofuran and tetrahydrofuran copolymers 失效
标题翻译：单步生产聚四氢呋喃和四氢呋喃共聚物的方法
公开(公告)号：US06716937B2
公开(公告)日：2004-04-06
申请号：US10312851
申请日：2003-01-02
申请人： Gerd Bohner , Thomas Domschke , Rolf-Hartmuth Fischer , Martin Haubner , Christoph Sigwart , Ulrich Steinbrenner , Christian Tragut
发明人： Gerd Bohner , Thomas Domschke , Rolf-Hartmuth Fischer , Martin Haubner , Christoph Sigwart , Ulrich Steinbrenner , Christian Tragut
IPC分类号： C08F244
CPC分类号： C08G65/30 , C08G65/20
摘要： A process for the single-stage preparation of polytetrahydrofuran and/or tetrahydrofuran copolymers having a mean molecular weight of from 650 to 5000 dalton by polymerization of tetrahydrofuran over a heterogeneous acid catalyst in the presence of at least one telogen and/or comonomer selected from the group consisting of alpha,omega-diols, water, polytetrahydrofuran having a molecular weight of from 200 to 700 dalton and cyclic ethers comprises a) separating off the catalyst and/or downstream products of the catalyst suspended and/or dissolved in the output from the polymerization, b) fractionating the resulting catalyst-free output from the polymerization in at least one distillation step to give a distillation residue comprising the polymerization product and at least one tetrahydrofuran fraction and returning at least part of the tetrahydrofuran fraction to the polymerization and c) separating low molecular weight polytetrahydrofuran and/or tetrahydrofuran copolymers having a mean molecular weight of from 200 to 700 dalton from the distillation residue from work-up step b) and isolating polytetrahydrofuran and/or tetrahydrofuran copolymers having a mean molecular weight of from 650 to 5000 dalton.
摘要翻译：一种通过在多相酸催化剂的存在下，在四氢呋喃和/或共聚单体的存在下，通过四氢呋喃聚合，单分级制备平均分子量为650-5000道尔顿的聚四氢呋喃和/或四氢呋喃共聚物的方法，该共聚单体选自由α，ω-二醇，水，分子量为200至700道尔顿的聚四氢呋喃和环醚组成的组包括：a）将催化剂和/或催化剂的下游产物分离出悬浮和/或溶解在聚合物的输出中 b）在至少一个蒸馏步骤中将所得无催化剂的产物从聚合中分馏，得到包含聚合产物和至少一种四氢呋喃馏分的蒸馏残余物，并将至少部分四氢呋喃馏分返回到聚合反应中，分子量的四氢呋喃和/或四氢呋喃共聚物来自后处理步骤b）的蒸馏残余物的200至700道尔顿的颗粒重量，并分离平均分子量为650-5000道尔顿的聚四氢呋喃和/或四氢呋喃共聚物。

5. 发明申请

US20110251425A1 PROCESS FOR PREPARING AROMATIC ISOCYANATES 有权
标题翻译：制备异构体异氰酸酯的方法
公开(公告)号：US20110251425A1
公开(公告)日：2011-10-13
申请号：US13057869
申请日：2009-08-06
申请人： Ulrich Penzel , Torsten Mattke , Andreas Wolfert , Johannes Jocobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
发明人： Ulrich Penzel , Torsten Mattke , Andreas Wolfert , Johannes Jocobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
IPC分类号： C07C263/10 , B01J19/00
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the liquid phase, if appropriate in the presence of at least one inert medium, in which the amine and the phosgene are first mixed in a mixing chamber (1) to give a reaction mixture and the reaction mixture is fed to a reactor, the amine being added through an orifice (3) arranged coaxially to the mixing chamber (1) and the phosgene being added through feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1), or the phosgene being added through the orifice (3) arranged coaxially to the mixing chamber and the amine through the feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1). At least one plane (9) is arranged upstream and at least one plane (7) downstream of the orifice (3) arranged coaxially to the mixing chamber (1) in main flow direction of the reaction mixture. The mean residence time of the reaction mixture in the mixing chamber (1) is not more than 20 ms.
摘要翻译：本发明涉及通过使相应的胺与液相中的光气反应制备异氰酸酯的方法，如果合适的话，在至少一种惰性介质存在下，其中胺和光气首先在混合室（1）中混合，得到反应混合物并将反应混合物加入到反应器中，通过与混合室（1）同轴布置的孔口（3）加入胺，并且通过进料孔（5）在至少两个平面中添加光气（7,9），其与所述混合室（1）的轴线（11）成直角排列，或者通过所述孔（3）加入的光气通过所述孔（3）同轴地配置到所述混合室，所述胺通过所述进料孔（5）在与所述混合室（1）的轴线（11）成直角布置的至少两个平面（7,9）中。至少一个平面（9）布置在上游，并且孔（3）下游的至少一个平面（7）在反应混合物的主流动方向上与混合室（1）同轴布置。反应混合物在混合室（1）中的平均停留时间不超过20ms。

6. 发明授权

US06423861B1 Method of producing dimethyl sulfite 失效
标题翻译：生产二甲基亚硫酸盐的方法
公开(公告)号：US06423861B1
公开(公告)日：2002-07-23
申请号：US09889580
申请日：2001-07-31
申请人： Klaus Halbritter , Hans-Josef Sterzel , Christian Tragut , Eva Freudenthaler
发明人： Klaus Halbritter , Hans-Josef Sterzel , Christian Tragut , Eva Freudenthaler
IPC分类号： C07C30100
CPC分类号： C07C301/00
摘要： Dimethyl sulfite is prepared by transesterification of a cyclic alkylene sulfite of at least 2 carbon atoms with methanol, in the presence or absence of a catalyst, by a process which is carried out continuously in a column.
摘要翻译：在存在或不存在催化剂的情况下，通过在柱中连续进行的方法，通过使具有至少2个碳原子的环状亚烷基亚硫酸酯与甲醇进行酯交换来制备亚硫酸二甲酯。

7. 发明授权

US06387222B1 Continuous isolation of a high-melting material by distillation 有权
标题翻译：通过蒸馏连续分离高熔点材料
公开(公告)号：US06387222B1
公开(公告)日：2002-05-14
申请号：US09538503
申请日：2000-03-30
申请人： Christian Tragut , Gerd Kaibel
发明人： Christian Tragut , Gerd Kaibel
IPC分类号： B01D342
CPC分类号： B01D3/141 , B01D3/14 , B01D3/146 , C07C29/80 , Y10S203/20 , C07C31/12 , C07C31/20
摘要： A method of distillation for separating a material which is solid at ambient temperature from a lower boiling and lower melting point material, and the apparatus.
摘要翻译：一种蒸馏方法，用于将环境温度下为固体的材料与较低沸点和较低熔点的材料以及该装置分离。

8. 发明授权

US08829232B2 Process for preparing aromatic isocyanates 有权
标题翻译：制备芳族异氰酸酯的方法
公开(公告)号：US08829232B2
公开(公告)日：2014-09-09
申请号：US13057869
申请日：2009-08-06
申请人： Ulrich Penzel , Torsten Mattke , Andreas Wölfert , Johannes Jacobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
发明人： Ulrich Penzel , Torsten Mattke , Andreas Wölfert , Johannes Jacobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
IPC分类号： C07C263/00 , C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the liquid phase, if appropriate in the presence of at least one inert medium, in which the amine and the phosgene are first mixed in a mixing chamber (1) to give a reaction mixture and the reaction mixture is fed to a reactor, the amine being added through an orifice (3) arranged coaxially to the mixing chamber (1) and the phosgene being added through feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1), or the phosgene being added through the orifice (3) arranged coaxially to the mixing chamber and the amine through the feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1). At least one plane (9) is arranged upstream and at least one plane (7) downstream of the orifice (3) arranged coaxially to the mixing chamber (1) in main flow direction of the reaction mixture. The mean residence time of the reaction mixture in the mixing chamber (1) is not more than 20 ms.
摘要翻译：本发明涉及通过使相应的胺与液相中的光气反应制备异氰酸酯的方法，如果合适的话，在至少一种惰性介质存在下，其中胺和光气首先在混合室（1）中混合，得到反应混合物并将反应混合物加入到反应器中，通过与混合室（1）同轴设置的孔口（3）加入胺，通过进料孔（5）在至少两个平面中加入光气（7,9），其与所述混合室（1）的轴线（11）成直角排列，或者通过所述孔（3）加入的光气通过所述孔（3）同轴地配置到所述混合室，所述胺通过所述进料孔（5）在与所述混合室（1）的轴线（11）成直角布置的至少两个平面（7,9）中。至少一个平面（9）布置在上游，并且孔（3）下游的至少一个平面（7）在反应混合物的主流动方向上与混合室（1）同轴布置。反应混合物在混合室（1）中的平均停留时间不超过20ms。

9. 发明授权

US07001490B2 Purification of ammonia by distillation 失效
标题翻译：通过蒸馏纯化氨
公开(公告)号：US07001490B2
公开(公告)日：2006-02-21
申请号：US09767820
申请日：2001-01-24
申请人： Karl-Heinz Wostbrock , Gerd Kaibel , Christian Tragut , Gabriele Anken
发明人： Karl-Heinz Wostbrock , Gerd Kaibel , Christian Tragut , Gabriele Anken
IPC分类号： B01D3/14 , B01D3/42 , C01C1/02
CPC分类号： B01D3/141 , B01D3/146 , C01C1/024 , Y10S203/20
摘要： Crude ammonia is separated into a low boiler fraction, a high boiler fraction and an intermediate-boiling pure fraction by continuous fractional distillation in a distillation apparatus configured either as a dividing wall column or as a system of thermally coupled distillation columns. In the process of the present invention, the low boiler fraction is taken off at the top of the distillation apparatus. The intermediate-boiling pure fraction is obtained at a side offtake which is preferably provided with droplet precipitators. In addition, the gas loading of the distillation column is restricted so that the operating pressure is in the range from 2 to 30 bar and the F factor does not exceed 2.0 Pa0.5.
摘要翻译：在作为分隔壁塔或作为热偶联蒸馏塔的系统的蒸馏装置中，通过连续分馏将粗氨分离成低沸点馏分，高沸点馏分和中间沸点纯馏分。在本发明的方法中，低沸点馏分在蒸馏装置的顶部取出。中间沸腾的纯馏分在优选设置有液滴沉淀器的一侧获得。此外，限制蒸馏塔的气体负载，使得操作压力在2至30巴的范围内，F因子不超过2.0Pa±0.5。

10. 发明授权

US06686506B1 Process for the preparation of organic disulfides 有权
标题翻译：制备有机二硫化物的方法
公开(公告)号：US06686506B1
公开(公告)日：2004-02-03
申请号：US09831914
申请日：2001-05-25
申请人： Werner Hesse , Hans-Josef Sterzel , Christian Tragut
发明人： Werner Hesse , Hans-Josef Sterzel , Christian Tragut
IPC分类号： C07C31900
CPC分类号： C07C319/24 , C07C321/14
摘要： The invention relates to a process for the preparation of organic disulfides by oxidation of mercaptans with sulfur dissolved in an organic disulfide using an amine as catalyst, where the mercaptans are used as “crude mercaptan stream” from a reaction of alcohols with hydrogen sulfide over a catalyst suitable for mercaptan synthesis. Furthermore, the invention relates to the use of the organic disulfides for the preparation of alkanesulfonic acids.
摘要翻译：本发明涉及一种通过使用胺作为催化剂将硫溶解在有机二硫化物中的硫醇硫化制备有机二硫化物的方法，其中硫醇用作“硫醇粗品”的醇与硫化氢的反应，适用于硫醇合成的催化剂。此外，本发明涉及有机二硫化物用于制备链烷磺酸的用途。

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