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1. 发明授权

US5131917A Fiber reactive red dye composition 失效
标题翻译：纤维反应性红色染料组合物
公开(公告)号：US5131917A
公开(公告)日：1992-07-21
申请号：US620784
申请日：1990-12-03
申请人： Tetsuya Miyamoto , Yutaka Kayane , Sadanobu Kikkawa , Kingo Akahori
发明人： Tetsuya Miyamoto , Yutaka Kayane , Sadanobu Kikkawa , Kingo Akahori
IPC分类号： C09B62/44 , C09B62/51 , C09B67/22
CPC分类号： C09B62/51 , C09B62/4413 , C09B67/0052 , Y10S8/917 , Y10S8/918 , Y10S8/919 , Y10S8/924 , Y10S8/926
摘要： A reactive dye composition comprising a monoazo compound of the following formula (I) in the free acid form, ##STR1## and at least one member selected from monoazo compounds of the following formulas (II) to (IV) in each free acid form, ##STR2## wherein Z, Z' and Z'" are each --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Z.sub.1, --CH.sub.2 CH.sub.2 Z.sub.2 or --CH.sub.2 CH.sub.2 Z.sub.3, respetively, in which Z.sub.1, Z.sub.2 and Z.sub.3 are each a group capable of being split by the action of an alkali, Z" is --CH.dbd.CH.sub.2, and any one of X and Y is sulfo, and the other is hydrogen, exhibits superior dye performance such as solubility, storage stability and build-up property, and is useful for dyeing or printing fiber materials such as cellulose fiber in a red color excellent in various fastness properties.
摘要翻译：一种活性染料组合物，其包含游离酸形式的下式（I）的单偶氮化合物，和每种游离酸中选自下式（II）至（IV）的单偶氮化合物中的至少一种：（IV）其中Z，Z'和Z“'各自为-CH = CH 2或-CH 2 CH 2 Z 1，-CH 2 CH 2 Z 2或-CH 2 CH 2 Z 3，分别代替 Z 1，Z 2和Z 3各自是能够被碱作用的基团，Z“是-CH = CH 2，X和Y中的任一个是磺基，而另一个是氢，表现出优异的染料性能例如溶解性，储存稳定性和积聚性，并且可用于以各种牢度性能优异的红色染色或印刷纤维素纤维如纤维素纤维。

2. 发明授权

US5116956A Polyazo dye compounds having vinylsulfone type and pyridinium type fiber reactive groups 失效
标题翻译：具有乙烯基砜型和吡啶类型纤维反应性基团的聚氨酯染料化合物
公开(公告)号：US5116956A
公开(公告)日：1992-05-26
申请号：US524743
申请日：1990-05-17
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/44
CPC分类号： C09B62/4415
摘要： A polyazo compound of the following formula, ##STR1## wherein X is ##STR2## --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5, in which R.sub.1 is hydrogen or alkyl, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, A is phenylene, naphthylene or alkylene, Z is a fiber-reactive group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, Y is pyridinio, and F is polyazo dye moiety carrying a fiber-reactive group like that represented by Z, which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

3. 发明授权

US5112959A Polyazo dye compounds having plural vinylsulfone type fiber reactive groups in one molecule 失效
标题翻译：在一个分子中具有多种乙烯基纤维素类型的纤维反应组的聚氨基染料化合物
公开(公告)号：US5112959A
公开(公告)日：1992-05-12
申请号：US526708
申请日：1990-05-22
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/513
CPC分类号： C09B62/513
摘要： A polyazo compound of the following formula, ##STR1## wherein A is phenylene, naphthylene or alkylene, X is --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5 in which R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthylene or benzyl, Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, R.sub.1 is hydrogen or alkyl, and F is polyazo dye moiety carrying a fiber reactive group like that represented by Z. This compound is useful for the dyeing or printing of fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

4. 发明授权

US5488098A Monoazo compounds having vinylsulfone type fiber reactive group and method for dyeing or printing fiber materials using the same 失效
标题翻译：具有乙烯基砜型纤维反应性基团的单偶氮化合物和使用其的纤维材料的染色或印花方法
公开(公告)号：US5488098A
公开(公告)日：1996-01-30
申请号：US193646
申请日：1994-02-07
申请人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Takeshi Washimi
发明人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Takeshi Washimi
IPC分类号： C09B62/085 , C09B62/44 , C09B62/51 , D06P1/384
CPC分类号： C09B62/4413 , C09B62/51
摘要： A monoazo compound of the following formula, ##STR1## wherein D is phenylene or naphthylene; X is halogeno, pyridinio or ##STR2## B is --OR.sub.3, --SR.sub.4, ##STR3## in which R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, r is 0 or 1, and E is O, SO, SO.sub.2, CH.sub.2 or NR.sub.8, in which R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl; R, R.sub.1, R.sub.2 and R.sub.7 are each hydrogen or alkyl; A.sub.1, A.sub.2 and A.sub.3 are each phenylene, naphthylene or alkylene; Z.sub.1, Z.sub.2 and Z.sub.3 are each --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a splittable group; and p is 0 or 1; which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.
摘要翻译：下式的单偶氮化合物，其中D是亚苯基或亚萘基; X是卤素，吡啶鎓或B是-OR 3，-SR 4，其中R 3，R 4，R 5和R 6各自是氢，烷基，苯基，萘基或苄基，r是0或1，E是 O，SO，SO 2，CH 2或NR 8，其中R 8是氢或C 1 -C 4烷基; R，R 1，R 2和R 7各自为氢或烷基; A1，A2和A3各自为亚苯基，亚萘基或亚烷基; Z 1，Z 2和Z 3各自为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y为可裂解基团; p为0或1; 该化合物可用于染色或印刷纤维材料以获得染色或印刷成具有优异的各种牢度性能的颜色的产品，具有优异的聚集性能。

5. 发明授权

US5359040A Monoazo compounds having naphthylazonaphtylamino group and use therefor for dyeing or printing fiber materials 失效
标题翻译：具有萘氮杂萘基氨基的单偶氮化合物，用于染色或印刷纤维材料
公开(公告)号：US5359040A
公开(公告)日：1994-10-25
申请号：US963553
申请日：1992-10-20
申请人： Kingo Akahori , Masayuki Miki , Takeshi Washimi , Yutaka Kayane
发明人： Kingo Akahori , Masayuki Miki , Takeshi Washimi , Yutaka Kayane
IPC分类号： C07D251/54 , C09B62/085 , C09B62/51 , D06P1/384
CPC分类号： C09B62/51
摘要： A monoazo compound represented by the following formula (I) in the free acid form: ##STR1## wherein X is an alkylamino, C.sub.5 -C.sub.7 cycloalkylamino, piperidino, pyrrolidino or morpholino group which is unsubstituted or substituted with a substituent other than sulfo, R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, R.sub.1 and R.sub.2 independently of one another are each hydrogen, methoxy, ethoxy, methyl, ethyl, chloro, bromo, nitro, carboxy or sulfo, Z is vinyl or -CH.sub.2 CH.sub.2 Y in which Y is a group which is split by the action of an alkali and p is 0 or 1. This compound is a reactive dye suitable for dyeing or printing fiber materials containing hydroxyl group and/or amide group in red color. This compound is high in dissolvability and can give dyed or printed products excellent in dyeability such as build-up property and various fastnesses.
摘要翻译：由游离酸形式的下式（I）表示的单偶氮化合物：其中X是未被取代或被取代基以外的取代基取代的烷基氨基，C 5 -C 7环烷基氨基，哌啶子基，吡咯烷子基或吗啉代基磺基，R为氢或未取代或取代的C 1 -C 4烷基，R 1和R 2各自独立地为氢，甲氧基，乙氧基，甲基，乙基，氯，溴，硝基，羧基或磺基，Z为乙烯基或-CH2CH2Y Y是通过碱的作用而分裂的基团，p是0或1.该化合物是适用于染色或印刷含有红色的羟基和/或酰胺基的纤维材料的活性染料。该化合物的溶解性高，可以赋予染色性，印染性等优异的染色性，例如聚集性和各种坚牢度。

6. 发明授权

US5266696A 1-aminoanthraquinone dye compound having fiber reactive group through sulfur or oxygen atom at 4-position and imparting red color 失效
标题翻译：具有纤维反应性基团的1-氨基蒽醌染料化合物，通过硫或氧原子在4位上赋予红色
公开(公告)号：US5266696A
公开(公告)日：1993-11-30
申请号：US836825
申请日：1992-02-19
申请人： Kingo Akahori , Naoki Harada , Yutaka Kayane , Takashi Omura
发明人： Kingo Akahori , Naoki Harada , Yutaka Kayane , Takashi Omura
IPC分类号： C09B62/024 , C09B62/44 , C09B62/505 , C07D251/70 , C09B62/06 , D06P1/382 , D06P1/384
CPC分类号： C09B62/024 , C09B62/4409 , C09B62/505
摘要： Anthraquinone compounds of the formula, ##STR1## wherein R is hydrogen, alkyl or the like, R.sub.1 and R.sub.2 are each hydrogen, halogen or sulfo, l is 1 or 2, X is sulfo or the like or --V--A--(W).sub.m --Z, and Y is --V.sub.1 --A.sub.1 --U, wherein V and V.sub.1 are each --O-- or --S--, A and A.sub.1 are each a divalent group such as ##STR2## W is --NH-- or the like, Z is hydrogen or a fiber reactive group, and U is hydrogen, a fiber reactive group or a fiber reactive group-containing group, provided that at least one of Z and U is or has a fiber reactive group, which is useful for dyeing or printing fiber materials such as cotton to give a dyed or printed product having excellent fastness properties, particularly those such as light fastness and perspiration-light fastness.
摘要翻译：下式的蒽醌化合物，其中R是氢，烷基等，R 1和R 2各自为氢，卤素或磺基，l为1或2，X为磺基等或-VA-（W）mZ ，Y为-V1-A1-U，其中V和V1各自为-O-或-S-，A和A1各自为二价基团，例如W为-NH-等，Z为氢或纤维反应性基团，U为氢，纤维反应性基团或含纤维反应性基团，条件是Z和U中的至少一个为或具有纤维反应性基团，其可用于染色或印刷纤维材料例如棉，以得到具有优异坚牢性的染色或印刷产品，特别是耐光牢度和耐汗牢度等。

7. 发明授权

US6136970A Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：不对称二恶嗪化合物及其染色或印花方法
公开(公告)号：US6136970A
公开(公告)日：2000-10-24
申请号：US967617
申请日：1992-10-29
申请人： Kazufumi Yokogawa , Takahiko Fujisaki , Miyao Takahashi , Shigeru Kawabata , Naoki Harada , Kingo Akahori , Yutaka Kayane , Takashi Omura
发明人： Kazufumi Yokogawa , Takahiko Fujisaki , Miyao Takahashi , Shigeru Kawabata , Naoki Harada , Kingo Akahori , Yutaka Kayane , Takashi Omura
IPC分类号： C07D265/34 , C09B19/00 , C09B62/002 , C09B62/02 , C09B62/44 , C09B62/503 , C07D498/04
CPC分类号： C09B62/5033 , C09B62/0025 , C09B62/021 , C09B62/4405
摘要： An asymmetric dioxazine compound represented by the following formula (I) in the free acid form: ##STR1## wherein A.sub.1 and A.sub.2 independently of one another are each sulfo, halo, alkyl or alkoxy, X.sub.1 and X.sub.2 independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R.sub.1 is hydrogen or unsubstituted or substituted alkyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m.noteq.n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.
摘要翻译：由游离酸形式的下式（I）表示的不对称二嗪类化合物：其中A1和A2彼此独立地各自为磺基，卤素，烷基或烷氧基，X 1和X 2彼此独立地为氢，卤素，烷基，烷氧基或苯氧基，R 1是氢或未取代或取代的烷基，R 2和R 3彼此独立地各自为氢，烷基，烷氧基，卤素或未取代或取代的氨基，Z为纤维反应性基团，m和n独立地为一个另外每个都为0或1，条件是m注意n和L为1或2.该化合物适用于将纤维素纤维，天然和合成聚酰胺纤维，聚氨酯纤维，皮革等及其混合纱线染色和印刷到获得染色或印刷的产品，颜色快速到轻，湿和氯，具有优异的积聚和水平的染色性能。

8. 发明授权

US5235046A Triazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：三氮唑化合物和使用该方法染色或印刷纤维材料的方法
公开(公告)号：US5235046A
公开(公告)日：1993-08-10
申请号：US793096
申请日：1991-11-18
申请人： Kingo Akahori , Masayuki Miki , Yutaka Kayane , Takeshi Washimi
发明人： Kingo Akahori , Masayuki Miki , Yutaka Kayane , Takeshi Washimi
IPC分类号： C09B62/04 , C09B62/085 , C09B62/503 , C09B62/505 , C09B62/51 , C09B62/513 , C09B62/515 , D06P1/38 , D06P1/384 , D06P3/66
CPC分类号： C09B62/503
摘要： A triazine compound which is useful for dyeing or printing materials containing hydroxyl group and/or amide group, and which has the following formula (I) or salts thereof ##STR1## wherein R represents hydrogen or unsubstituted or substituted alkyl; R.sub.1 represents hydrogen, an alkyl unsubstituted or substituted by carboxy, sulfo, alkoxy, halogeno, sulfato or hydroxy, or --Y--SO.sub.2 Z.sub.3 ; R.sub.2 represents hydrogen or unsubstituted or substituted alkyl; A represents unsubstituted or substituted phenylene or naphthylene; Y represents a divalent group which is C.sub.2 -C.sub.7 alkylene and so on; Z.sub.1, Z.sub.2 and Z.sub.3 independently of one another are each --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Z' wherein Z' is a group capable of being split by the action of an alkali; and F is any one of the dye residue which is anthraquinone, azo, disazo, trisazo or phthalocyanine nucleus and so on, and a process for dyeing or printing fiber materials which comprises using said triazine compounds or salts thereof.

9. 发明授权

US5488101A Trisazo compounds, method for dyeing fiber materials, paper or leather using the same and inks containing the same 失效
标题翻译：三唑类化合物，纤维材料的染色方法，使用其的纸或皮革以及含有它们的油墨
公开(公告)号：US5488101A
公开(公告)日：1996-01-30
申请号：US894561
申请日：1992-06-05
申请人： Kazuya Ogino , Kingo Akahori , Naoki Harada , Yutaka Kayane , Hideo Kawashita , Mituhiro Ohta
发明人： Kazuya Ogino , Kingo Akahori , Naoki Harada , Yutaka Kayane , Hideo Kawashita , Mituhiro Ohta
IPC分类号： C09B33/22 , C09B35/46 , C09B62/513 , C09D11/02 , C09D11/03 , C09D11/328 , D06P1/06 , D06P1/384 , D06P3/32 , D06P3/66
CPC分类号： C09D11/328 , C09B35/465 , C09B62/513 , Y10S8/917 , Y10S8/918 , Y10S8/919 , Y10S8/924
摘要： Herein is provided a trisazo compound represented by formula (I) in the free acid form: ##STR1## wherein Q.sub.1 is an unsubstituted or substituted phenylene or naphthylene group, Q.sub.2 is an unsubstituted or substituted phenyl or naphthyl group, Z is --SO.sub.2 CH.sub.2 CH.sub.2 OH or --SO.sub.2 CH.sub.2 CH.sub.2 SO.sub.3 H group, and L is 0 or 1. The trisazo compound provided herein is excellent in solubility and gives deep colored dyed product or image when used in dyeing or printing, so that it is useful as a dye and an ink. Herein are also provided a method for dyeing fiber materials, paper or leather by using said trisazo compound, and an ink containing said trisazo compound.
摘要翻译：本发明提供由游离酸形式的式（I）表示的三偶氮化合物：其中Q1是未取代或取代的亚苯基或亚萘基，Q2是未取代或取代的苯基或萘基， Z为-SO 2 CH 2 CH 2 OH或-SO 2 CH 2 CH 2 SO 3 H基团，L为0或1.本文提供的三偶氮化合物在染色或印刷中使用时溶解度优异，并产生深色染色产品或图像，因此可用作染料和墨水。本发明还提供了一种通过使用所述三偶氮化合物和含有所述三偶氮化合物的油墨对纤维材料，纸或皮革进行染色的方法。

10. 发明授权

US4975094A Anthrapyridone compounds having vinylsulfone type fiber reactive group through triazinyl bridging group 失效
标题翻译：通过三嗪基桥连基团具有乙烯基砜型纤维反应性基团的蒽并吡啶酮化合物
公开(公告)号：US4975094A
公开(公告)日：1990-12-04
申请号：US390278
申请日：1989-08-07
申请人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Naoki Harada , Takashi Omura
发明人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Naoki Harada , Takashi Omura
IPC分类号： C09B62/44 , C09B62/505
CPC分类号： C09B62/505 , C09B62/4403
摘要： Anthrapyridone compounds of the formula, ##STR1## wherein R.sub.1 is hydrogen, benzoyl, acetyl or alkyloxycarbonyl, R.sub.2 is hydrogen or alkyl, R.sub.3 is hydrogen, halogen, sulfo, phenoxy, phenylthio or alkoxy, R.sub.4 is hydrogen, halogen or sulfo, R.sub.5 and R.sub.6 are each hydrogen or alkyl, V is --O--, --S-- or ##STR2## in which R.sub.7 is hydrogen, acetyl or alkyl, B is phenylene or naphthylene, D is vinyl or --CH.sub.2 CH.sub.2 L such as --CH.sub.2 CH.sub.2 OSO.sub.3 H, A is a divalent group, and X is halogen, quaternary ammonium, pyridinio, amino or a ##STR3## like group, which are useful for dyeing or printing fiber materials with superior dyeing performance.

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