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    • 1. 发明授权
    • Base coating composition for decorated moldings, top clear coating composition for decorated moldings, and decorated moldings
    • 用于装饰模制品的基础涂料组合物,用于装饰模制品的顶部透明涂料组合物和装饰模塑品
    • US07419723B2
    • 2008-09-02
    • US10859606
    • 2004-06-03
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • A61Q19/00B32B27/00B32B27/40C08C19/00C08F8/00C08F8/30C08F8/42C08F283/04C08F283/06C08J3/00C08K5/24C08L75/00C08L83/00C08L83/04
    • C08J7/045C08G18/289C08G18/4063C08G18/6283C09D175/04Y10S524/906Y10S525/939Y10T428/31551Y10T428/31605
    • It is an object of the present invention to provide a base coating composition for decorated moldings containing silver plating layer and a top clear coating composition for decorated moldings containing silver plating layer, and decorated moldings obtainable by using these compositions; the compositions and moldings are to be excellent in silver deposition tendency, basecoat film smoothness, adhesion and/or film appearance.A base coating composition for decorated moldings containing silver plating layer comprisinga main composition for base coating comprising an acrylic polyol (A1), an organic-modified polydimethylsiloxane (A2) and an epoxysilane (A3) represented by the chemical scheme (1): in the scheme, R1 represents a methyl, methoxy or ethoxy group and R2 and R3 are the same or different and each represents a methoxy or ethoxy group, and a curing agent for base coating comprising a polyisocyanate, wherein the base coating composition for decorated moldings is a two-package curing type urethane coating composition, in the main composition for base coating, the (A2)/(A1) ratio is 0.02/100 to 0.20/100 on the solid weight basis and the (A3)/(A1) ratio is 1.5/100 to 5.5/100 on the solid weight basis, and the equivalent ratio between the NCO groups in the curing agent for base coating and the OH groups in the acrylic polyol (A1), namely the NCO/OH equivalent ratio, is 1.5 to 3.0.
    • 本发明的目的是提供一种含有银镀层的装饰成型品的基底涂料组合物和用于装有银镀层的模制品的顶部透明涂料组合物,以及使用这些组合物可获得的装饰成型品; 组合物和成型品的银沉积趋势,底涂膜的平滑性,粘合性和/或膜外观优异。 包含银镀层的装饰成型品的基底涂料组合物,其包含由化学方案(1)表示的丙烯酸多元醇(A1),有机改性的聚二甲基硅氧烷(A2)和环氧硅烷(A3))的基础涂料的主要组合物:在 方案R 1表示甲基,甲氧基或乙氧基,R 2和R 3相同或不同,并且各自表示甲氧基 (A2)/(A1)组合物的基础涂料用固化剂,其中,所述(A2)/(A1)组合物包含多异氰酸酯,其中所述装饰成型用基底涂料组合物为双包装固化型聚氨酯涂料组合物, 比例为固体重量的0.02 / 100〜0.20 / 100,固化重量的(A3)/(A1)比为1.5 / 100〜5.5 / 100,固化剂中的NCO基的当量比 对于基础涂层和丙烯酸多元醇(A1)中的OH基,即NCO / OH当量比为1.5 到3.0。
    • 2. 发明申请
    • Clear coating composition, method of forming multilayer coating film and inmold decoration product
    • 透明涂料组合物,多层涂膜成型方法及模塑装饰产品
    • US20060014024A1
    • 2006-01-19
    • US11147398
    • 2005-06-08
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • C08G18/00B32B27/00
    • C08G18/62C08G18/289C08G18/792C09D175/04Y10T428/31551Y10T428/31605
    • It is an object of the present invention to provide a clear coating composition which inhibits a corrosion reaction by containing a rust preventive agent in a clear layer on a silver-plating layer and preventing a corrosive substance such as chlorine ion from contacting with the surface of the silver-plating layer, and develops beautiful silver-plating design for a long time, and an inmold decoration product comprising a silver-plating layer. A clear coating composition used in forming a multilayer coating film comprising a silver-plating layer, said multilayer coating film being obtainable by forming a base coating film layer, a silver-plating layer and a clear coating film layer in succession on a plastic substrate, wherein said clear coating composition is a two-package polyurethane coating composition comprising a main material containing acrylic polyol and a curing agent containing a polyisocyanate compound, the equivalence ratio of an NCO group in said polyisocyanate compound to an OH group in said acrylic polyol (NCO/OH) ranges from 0.8/1 to 1.2/1, and the clear coating composition contains a rust preventive agent in the proportions of 1.0 to 13.0 parts (on a basis of solids weight) with respect to 100 parts by weight of the total of the acrylic polyol and the rust preventive agent.
    • 本发明的目的是提供一种透明的涂料组合物,其通过在银镀层上的透明层中含有防锈剂来抑制腐蚀反应,并防止诸如氯离子的腐蚀性物质与 镀银层,并且长时间地形成美丽的镀银设计,以及包括镀银层的嵌入式装饰产品。 用于形成包含镀银层的多层涂膜的透明涂料组合物,所述多层涂膜可以通过在塑料基材上连续形成基底涂膜层,镀银层和透明涂膜层获得, 其中所述透明涂料组合物是包含含有丙烯酸多元醇的主要材料和含有多异氰酸酯化合物的固化剂的双组分聚氨酯涂料组合物,所述多异氰酸酯化合物中的NCO基团与所述丙烯酸多元醇中的OH基团的当量比(NCO / OH)为0.8 / 1〜1.2 / 1,透明涂料组合物含有比例为1.0〜13.0份(基于固体重量)的防锈剂,相对于100重量份 丙烯酸多元醇和防锈剂。
    • 3. 发明申请
    • Base coating composition for decorated moldings, top clear coating composition for decorated moldings, and decorated moldings
    • 用于装饰模制品的基础涂料组合物,用于装饰模制品的顶部透明涂料组合物和装饰模塑品
    • US20050009983A1
    • 2005-01-13
    • US10859606
    • 2004-06-03
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • B05D7/24C08G18/28C08G18/40C08G18/62C08J7/04C09D133/14C09D175/04C09D183/04C08K3/00
    • C08J7/045C08G18/289C08G18/4063C08G18/6283C09D175/04Y10S524/906Y10S525/939Y10T428/31551Y10T428/31605
    • It is an object of the present invention to provide a base coating composition for decorated moldings containing silver plating layer and a top clear coating composition for decorated moldings containing silver plating layer, and decorated moldings obtainable by using these compositions; the compositions and moldings are to be excellent in silver deposition tendency, basecoat film smoothness, adhesion and/or film appearance. A base coating composition for decorated moldings containing silver plating layer comprising a main composition for base coating comprising an acrylic polyol (A1), an organic-modified polydimethylsiloxane (A2) and an epoxysilane (A3) represented by the chemical scheme (1): in the scheme, R1 represents a methyl, methoxy or ethoxy group and R2 and R3 are the same or different and each represents a methoxy or ethoxy group, and a curing agent for base coating comprising a polyisocyanate, wherein the base coating composition for decorated moldings is a two-package curing type urethane coating composition, in the main composition for base coating, the (A2)/(A1) ratio is 0.02/100 to 0.20/100 on the solid weight basis and the (A3)/(A1) ratio is 1.5/100 to 5.5/100 on the solid weight basis, and the equivalent ratio between the NCO groups in the curing agent for base coating and the OH groups in the acrylic polyol (A1), namely the NCO/OH equivalent ratio, is 1.5 to 3.0.
    • 本发明的目的是提供一种含有银镀层的装饰成型品的基底涂料组合物和用于装有银镀层的模制品的顶部透明涂料组合物,以及使用这些组合物可获得的装饰成型品; 组合物和成型品的银沉积趋势,底涂膜的平滑性,粘合性和/或膜外观优异。 包含银镀层的装饰成型品的基底涂料组合物,其包含由化学方案(1)表示的丙烯酸多元醇(A1),有机改性的聚二甲基硅氧烷(A2)和环氧硅烷(A3))的基础涂料的主要组合物:在 该方案中,R 1表示甲基,甲氧基或乙氧基,R 2和R 3相同或不同,各自表示甲氧基或乙氧基,以及用于底涂层的固化剂,其包含多异氰酸酯, 其中,用于装饰成型品的基础涂料组合物是双包装固化型聚氨酯涂料组合物,在基础涂料的主要组合物中,(A2)/(A1)比为固体重量的0.02 / 100至0.20 / 100, 基于固体重量的(A3)/(A1)比为1.5 / 100〜5.5 / 100,底涂层用固化剂中的NCO基与丙烯酸多元醇(A1)中的OH基的当量比, 即NCO / OH当量比为1.5〜3.0。
    • 5. 发明申请
    • Coating with both primer and base coating function, method of producing inmold decoration products and inmold decoration product
    • 具有底漆和底漆涂层功能的涂层,生产嵌体装饰产品的方法和模塑装饰产品
    • US20060003107A1
    • 2006-01-05
    • US11165530
    • 2005-06-24
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • Tatsuya ItakuraTakashi YamamotoManabu YamaokaToshihiko Uchiyama
    • B05D1/36
    • B05D7/57B05D5/068C23C18/2086C23C18/285
    • It is an object of the present invention to provide a coating with both primer and base coating function for an inmold decoration product, which can attain an inmold decoration product which secures adequately the adhesion between a polyolefin substrate and a coating film layer without forming a primer coating film layer and also has excellent properties in a precipitating property of silver, smoothness of a silver-plating layer and coating film appearance, a method of producing inmold decoration products formed by using this base coating composition and an inmold decoration product. A coating with both primer and base coating function for an inmold decoration product, used in a method of producing inmold decoration products obtained by forming a multilayer coating film comprising a silver-plating layer, said multilayer coating film being obtainable by forming a coating film layer with both primer and base coating function, a silver-plating layer and a top clear coating film layer on a polyolefin substrate, wherein said coating with both primer and base coating function comprises a main material (a) based on acrylic polyol (a1), a chlorinated polyolefin modified acrylic resin (a2) and a chlorinated polyolefin resin (a3), and a polyisocyanate curing agent (b), the % by weight of the solids of said (a1), (a2) and (a3) are 40 to 80%, 5 to 45% and 1 to 35%, respectively, and the main material (a) contains cyclohexane in an amount 5 to 45 parts by weight per 100 parts by weight of the solids in the main material.
    • 本发明的一个目的是提供一种具有底漆和底涂层功能的涂层,用于包覆模塑装饰产品,其可以获得一种可以充分确保聚烯烃基材和涂膜层之间的粘合性而不形成底漆的模塑装饰产品 并且还具有优异的银沉淀性,镀银层的光滑性和涂膜外观,通过使用该基础涂料组合物和嵌入式装饰产品形成的嵌入式装饰产品的方法。 一种包含底漆和底涂层的涂层功能,用于通过形成包含镀银层的多层涂膜而获得的包覆模制装饰产品的方法中所用的嵌体模塑装饰产品,所述多层涂膜可通过形成涂膜层 具有底漆和底涂层功能,聚烯烃基材上的镀银层和顶部透明涂膜层,其中所述底漆和底涂层功能的涂层包括基于丙烯酸多元醇(a1)的主要材料(a), (a1),(a2)和(a3)的固体的重量%的氯化聚烯烃改性丙烯酸树脂(a2)和氯化聚烯烃树脂(a3)和多异氰酸酯固化剂(b)分别为40〜 80%,5〜45%和1〜35%,主要材料(a)含有相对于主要材料中的固体100重量份为5〜45重量份的环己烷。
    • 6. 发明授权
    • Method of partially plating article or synthetic resin
    • 部分电镀制品或合成树脂的方法
    • US4170524A
    • 1979-10-09
    • US809713
    • 1977-06-24
    • Noriaki NakajyoToshihiko Uchiyama
    • Noriaki NakajyoToshihiko Uchiyama
    • C23C18/16C23C18/20C23C18/31C23C18/34C25D5/56H05K3/18C25D5/02
    • C23C18/1605C23C18/1653H05K3/182
    • Partial plating of a synthetic resin article is accomplished with a beautiful appearance and good adhesion of the plated coating regardless of the shape and size of the article or geometry of the intended coating by a method having the steps of (a) producing an article to be plated by uniting a first member, or members, of a conducting resin with a second member, or members, of a nonconducting resin such that the surface of the first member in the produced article is partially exposed and that the exposed portion of the surface alone gives a region, or regions, to be plated, (b) forming a metal coating exclusively on the exposed portion of the first member by chemical plating, and (c) effecting electroplating on the metal coating.
    • 合成树脂制品的部分电镀是通过具有以下步骤的方法实现的:具有美观的外观和镀覆涂层的良好粘合性,而不管制品的形状和尺寸或预期涂层的几何形状,具有以下步骤:(a)生产制品 通过将导电树脂的第一构件或构件与不导电树脂的第二构件或构件结合在一起,使得所制造的制品中的第一构件的表面部分地暴露,并且单独的表面的暴露部分 给出要镀覆的区域或区域,(b)通过化学镀在第一构件的暴露部分上专门形成金属涂层,和(c)对金属涂层进行电镀。
    • 10. 发明申请
    • Metod for forming brilliant coating film and coated article showing metallic effect
    • Metod用于形成辉光涂膜和涂层制品,显示金属效果
    • US20070104874A1
    • 2007-05-10
    • US10556439
    • 2004-05-28
    • Takeshi OgawaSatoru IharaToshihiko UchiyamaMasanobu InoueSeigo MiyazoeRyuichi Shiraga
    • Takeshi OgawaSatoru IharaToshihiko UchiyamaMasanobu InoueSeigo MiyazoeRyuichi Shiraga
    • B05D3/02B05D1/36
    • B05D7/542B05D5/068B05D7/572
    • There is provided a method for forming a brilliant coating film with an excellent brilliant appearance by using aqueous first and second base coating compositions without preheating the applied first base coating composition. In the method, the aqueous first base coating composition is applied to a substrate to form a first base coating, the aqueous second base coating composition is applied to the first base coating to form a second base coating, a clear coating composition is applied to the second base coating to form a clear coating, and then the uncured coatings formed are simultaneously heated and cured, under controlling the solid contents of the first and second base coating compositions and the ratio therebetween, or the brilliant pigment mass concentrations of the base coating compositions and the ratio therebetween, or the mass ratio, the evaporation rate, and the solubility parameter of a solvent contained in the first base coating composition.
    • 提供了一种通过使用水性第一和第二基础涂料组合物形成具有优异外观的辉光涂层的方法,而不预加所施加的第一底涂层组合物。 在该方法中,将水性第一基础涂料组合物施加到基底上以形成第一基底涂层,将水性第二基础涂料组合物施加到第一基底涂层以形成第二基底涂层,将透明涂料组合物施用于 第二基底涂层以形成透明涂层,然后在控制第一和第二基础涂料组合物的固体含量和它们之间的比例的同时加热和固化所形成的未固化的涂层,或者基础涂料组合物的辉光颜料质量浓度 以及第一基础涂料组合物中所含溶剂的比例,质量比,蒸发速率和溶解度参数。