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    • 1. 发明授权
    • Integrated circuit having selectivity deposited silicon oxide spacer layer formed therein
    • 在其中形成有选择性淀积的氧化硅间隔层的集成电路
    • US06329717B1
    • 2001-12-11
    • US08616140
    • 1996-03-14
    • Syun-Ming JangChen-Hua YuLung ChenLin-June Wu
    • Syun-Ming JangChen-Hua YuLung ChenLin-June Wu
    • H01L2348
    • H01L21/76801
    • A method for selectively depositing a silicon oxide insulator spacer layer between multi-layer patterned metal stacks within an integrated circuit. Formed upon a semiconductor substrate is a silicon oxide insulator substrate layer which is formed through a Plasma Enhanced Chemical Vapor Deposition (PECVD) process. Upon the silicon oxide insulator substrate layer are formed multi-layer patterned metal stacks. The multi-layer patterned metal stacks have a top barrier metal layer formed from titanium nitride and a lower-lying conductor metal layer formed from an aluminum containing alloy. Formed selectively upon the portions of the silicon oxide insulator substrate layer exposed through the multi-layer patterned metal stacks and upon the edges of the aluminum containing alloy exposed through the multi-layer patterned metal stacks is a silicon oxide insulator spacer layer. The silicon oxide insulator spacer layer is formed through an ozone assisted Chemical Vapor Deposition (CVD) process employing Tetra Ethyl Ortho Silicate as the silicon source material. The silicon oxide insulator spacer layer is formed for a deposition time not exceeding an incubation time for forming the silicon oxide insulator spacer layer upon the top barrier metal layer formed from titanium nitride.
    • 一种用于在集成电路内的多层图案化金属堆叠之间选择性地沉积氧化硅绝缘体间隔层的方法。 形成在半导体衬底上的是通过等离子体增强化学气相沉积(PECVD)工艺形成的氧化硅绝缘体衬底层。 在氧化硅绝缘体衬底层形成多层图案化的金属叠层时。 多层图案化的金属堆叠具有由氮化钛形成的顶部阻挡金属层和由含铝合金形成的下部导体金属层。 在通过多层图案化的金属堆叠暴露的氧化硅绝缘体基底层的部分上并且通过多层图案化的金属堆叠暴露的含铝合金的边缘上选择性地形成氧化硅绝缘体间隔层。 氧化硅绝缘体间隔层通过使用四乙基正硅酸盐作为硅源材料的臭氧辅助化学气相沉积(CVD)工艺形成。 形成氧化硅绝缘体间隔层,用于在由氮化钛形成的顶部阻挡金属层上形成氧化硅绝缘体间隔层的沉积时间不超过孵育时间。
    • 2. 发明授权
    • Method for selectively depositing silicon oxide spacer layers
    • 选择性沉积氧化硅间隔层的方法
    • US5518959A
    • 1996-05-21
    • US518706
    • 1995-08-24
    • Syun-Ming JangChen-Hua YuLung ChenLin-June Wu
    • Syun-Ming JangChen-Hua YuLung ChenLin-June Wu
    • H01L21/768H01L21/283
    • H01L21/76801
    • A method for selectively depositing a silicon oxide insulator spacer layer between multi-layer patterned metal stacks within an integrated circuit. Formed upon a semiconductor substrate is a silicon oxide insulator substrate layer which is formed through a Plasma Enhanced Chemical Vapor Deposition (PECVD) process. Upon the silicon oxide insulator substrate layer are formed multi-layer patterned metal stacks. The multi-layer patterned metal stacks have a top barrier metal layer formed from titanium nitride and a lower-lying conductor metal layer formed from an aluminum containing alloy. Formed selectively upon the portions of the silicon oxide insulator substrate layer exposed through the multi-layer patterned metal stacks and upon the edges of the aluminum containing alloy exposed through the multi-layer patterned metal stacks is a silicon oxide insulator spacer layer. The silicon oxide insulator spacer layer is formed through an ozone assisted Chemical Vapor Deposition (CVD) process employing Tetra Ethyl Ortho Silicate as the silicon source material. The silicon oxide insulator spacer layer is formed for a deposition time not exceeding an incubation time for forming the silicon oxide insulator spacer layer upon the top barrier metal layer formed from titanium nitride.
    • 一种用于在集成电路内的多层图案化金属堆叠之间选择性地沉积氧化硅绝缘体间隔层的方法。 形成在半导体衬底上的是通过等离子体增强化学气相沉积(PECVD)工艺形成的氧化硅绝缘体衬底层。 在氧化硅绝缘体衬底层形成多层图案化金属叠层时。 多层图案化的金属堆叠具有由氮化钛形成的顶部阻挡金属层和由含铝合金形成的下部导体金属层。 在通过多层图案化的金属堆叠暴露的氧化硅绝缘体基底层的部分上并且通过多层图案化的金属堆叠暴露的含铝合金的边缘上选择性地形成氧化硅绝缘体隔离层。 氧化硅绝缘体间隔层通过使用四乙基正硅酸盐作为硅源材料的臭氧辅助化学气相沉积(CVD)工艺形成。 形成氧化硅绝缘体间隔层,用于在由氮化钛形成的顶部阻挡金属层上形成氧化硅绝缘体间隔层的沉积时间不超过孵育时间。
    • 3. 发明授权
    • Sacrificial etchback layer for improved spin-on-glass planarization
    • 牺牲回蚀层,用于改进旋涂玻璃平面化
    • US5631197A
    • 1997-05-20
    • US520595
    • 1995-08-30
    • Chen-Hua YuSyun-Ming JangLung ChenYuan-Chang Huang
    • Chen-Hua YuSyun-Ming JangLung ChenYuan-Chang Huang
    • H01L21/3105H01L21/465
    • H01L21/31053
    • A method for forming a sacrificial planarization layer over an SOG layer which provide a more planar final surface. A substrate is provided with a first insulating layer formed on its surface. A spin-on-glass (SOG) layer is formed over the first insulating layer. The SOG layer has a greater thickness towards the outer edge compared to the central area of the substrate. Next a sacrificial layer is formed over the SOG layer. The sacrificial layer, preferably formed of silicon oxide material, is formed so that the layer has a greater thickness towards the outside of the wafer than in the central area. Next, the sacrificial layer is etched away and portions of the SOG layer are etched. The etch rates of the sacrificial layer, the SOG layer and the first insulating layer are approximately equal so that the planar top SOG surface is transferred to the final top surface after the etch. The resulting surface is planar because the additional sacrificial layer thickness in the outside periphery compensated for the thinner SOG in on the periphery and the faster etch rate on the periphery.
    • 一种用于在SOG层上形成牺牲平坦化层的方法,其提供更平面的最终表面。 衬底上设有形成在其表面上的第一绝缘层。 在第一绝缘层上形成旋涂玻璃(SOG)层。 与衬底的中心区域相比,SOG层具有比外边缘更大的厚度。 接下来,在SOG层上形成牺牲层。 优选由氧化硅材料形成的牺牲层被形成为使得该层具有比在中心区域更大于晶片外部的厚度。 接下来,蚀刻掉牺牲层并蚀刻SOG层的部分。 牺牲层,SOG层和第一绝缘层的蚀刻速率大致相等,使得在蚀刻之后,平面顶部SOG表面被转移到最终的顶表面。 所得到的表面是平面的,因为在外围的额外牺牲层厚度补偿了周边较薄的SOG,并且外围蚀刻速率更快。
    • 7. 发明授权
    • Use of PE-SiON or PE-Oxide for contact or via photo and for defect reduction with oxide and w chemical-mechanical polish
    • 使用PE-SiON或PE氧化物进行接触或通过照相和氧化物和化学机械抛光剂进行缺陷还原
    • US06458689B2
    • 2002-10-01
    • US09818714
    • 2001-03-28
    • Chen-Hua YuSyun-Ming JangTsu ShihAnthony YenJih-Chuyng Twu
    • Chen-Hua YuSyun-Ming JangTsu ShihAnthony YenJih-Chuyng Twu
    • H01L214763
    • H01L21/0276H01L21/31144H01L21/3144H01L21/3145H01L21/7684Y10S438/97
    • A method forming a protective (SiON or PE-Ox) dielectric anti-reflective coating (DARC) over a dielectric layer after a chemical-mechanical polish dielectric layer planarization process and before a chemical-mechanical polish of a conductive layer used in a contact or via plug formation. A dielectric layer is chemical-mechanical polished thereby creating microscratches in the dielectric layer. The invention's protective SiON or PE-OX DARC layer is formed over the dielectric layer whereby the protective SiON or PE-OX DARC layer fills in the microscratches. A first opening is etched in he protective layer and the dielectric layer. A conductive layer is formed over the protective layer and fills the first opening. The conductive layer is chemical-mechanical polished to remove the conductive layer from over the protective layer and to form an interconnect filling the first opening. The protective SiON or PE-OX DARC layer is used as a CMP stop thereby preventing microscratches in the dielectric layer.
    • 在化学机械抛光介质层平坦化工艺之后和用于接触的导电层的化学机械抛光之前,在电介质层上形成保护性(SiON或PE-Ox)电介质抗反射涂层(DARC)的方法或 通过插塞形成。 电介质层被化学机械抛光,从而在电介质层中形成微细结构。 本发明的保护性SiON或PE-OX DARC层形成在电介质层上,由此保护性SiON或PE-OX DARC层填充在微细凹槽中。 在其保护层和电介质层中蚀刻第一开口。 导电层形成在保护层上并填充第一开口。 导电层被化学机械抛光以从保护层上方移除导电层并形成填充第一开口的互连。 使用保护性SiON或PE-OX DARC层作为CMP阻挡层,从而防止电介质层中的微细纹。
    • 8. 发明授权
    • Ozone-teos method for forming with attenuated surface sensitivity a silicon oxide dielectric layer upon a thermally oxidized silicon substrate layer
    • 用于在热氧化硅衬底层上形成具有衰减表面灵敏度的氧化硅介电层的臭氧陶瓷方法
    • US06245691B1
    • 2001-06-12
    • US09086770
    • 1998-05-29
    • Syun-Ming JangChen-Hua Yu
    • Syun-Ming JangChen-Hua Yu
    • H01L2131
    • H01L21/02164C23C16/0218C23C16/0272C23C16/402H01L21/02271H01L21/02304H01L21/31612H01L21/31662
    • A method for forming a silicon oxide dielectric layer within a microelectronics fabrication. There is first provided a silicon substrate layer employed within a microelectronics fabrication. There is then formed employing the silicon substrate a thermal silicon oxide layer through thermal oxidation of the silicon substrate layer. There is then formed upon the thermal silicon oxide layer a second silicon oxide layer formed through use of a thermal chemical vapor deposition (CVD) method employing ozone as an oxidant and tetraethylorthosilicate (TEOS) as a silicon source material. The thermal chemical vapor deposition (CVD) method also employs a reactor chamber pressure of from about 40 to about 80 torr. The second silicon oxide layer is formed with an attenuated surface sensitivity of the second silicon oxide layer with respect to the thermal silicon oxide layer. The method is particularly desirable when forming trench isolation regions within isolation trenches within silicon semiconductor substrates employed within integrated circuit microelectronics fabrications.
    • 一种在微电子制造中形成氧化硅介电层的方法。 首先提供在微电子制造中使用的硅衬底层。 然后通过硅衬底层的热氧化形成硅衬底热硅氧化物层。 然后在热氧化硅层上形成第二氧化硅层,该第二氧化硅层通过使用以臭氧作为氧化剂的热化学气相沉积(CVD)方法和作为硅源材料的原硅酸四乙酯(TEOS)形成。 热化学气相沉积(CVD)方法也采用约40至约80托的反应室压力。 第二氧化硅层形成有相对于热氧化硅层的第二氧化硅层的衰减的表面灵敏度。 当在集成电路微电子学制造中使用的硅半导体衬底内的隔离沟槽内形成沟槽隔离区域时,该方法是特别需要的。
    • 9. 发明授权
    • Shallow trench isolation process employing a BPSG trench fill
    • 采用BPSG沟槽填充的浅沟槽隔离工艺
    • US6010948A
    • 2000-01-04
    • US244879
    • 1999-02-05
    • Chen-Hua YuSyun-Ming Jang
    • Chen-Hua YuSyun-Ming Jang
    • H01L21/762
    • H01L21/76224
    • A process for creating BPSG filled, shallow trench isolation regions, in a semiconductor substrate, has been developed. The process features the use of a BPSG layer with about 4 to 4.5 weight percent B.sub.2 O.sub.3, and about 4 to 4.5 weight percent P.sub.2 O.sub.5, in silicon oxide. This BPSG composition, when subjected to a high temperature anneal procedure, results in softening, or reflowing, of the BPSG layer, eliminating seams or voids, in the BPSG layer, that may have been present after BPSG deposition. The removal rate of BPSG, is lower than the removal rate of silicon oxide layer, in buffered HF solutions, thus allowing several buffered HF procedures to be performed without recessing of BPSG in the shallow trench. In addition this composition of BPSG performs as a gettering material for mobile ions, thus contributing to yield and reliability improvements, when used at the isolation region for MOSFET devices.
    • 已经开发了用于在半导体衬底中产生BPSG填充的浅沟槽隔离区的工艺。 该方法的特征在于在氧化硅中使用具有约4至4.5重量%的B 2 O 3和约4至4.5重量%的P 2 O 5的BPSG层。 当经过高温退火过程时,该BPSG组合物导致BPSG层的软化或回流,消除了在BPSG沉积后可能存在的BPSG层中的接缝或空隙。 BPSG的去除率低于缓冲HF溶液中氧化硅层的去除率,从而允许在浅沟槽中不进行BPSG的凹陷而执行几个缓冲的HF程序。 此外,BPSG的这种组合作为移动离子的吸气材料,当在MOSFET器件的隔离区域使用时,有助于提高产量和可靠性。