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    • 4. 发明授权
    • Post chemical mechanical polish (CMP) planarizing substrate cleaning method employing enhanced substrate hydrophilicity
    • 后化学机械抛光(CMP)平面化基板清洗方法采用增强的基板亲水性
    • US06376377B1
    • 2002-04-23
    • US09541487
    • 2000-04-03
    • Weng ChangYing-Ho ChenJih-Churng TwuSyun-Ming Jang
    • Weng ChangYing-Ho ChenJih-Churng TwuSyun-Ming Jang
    • H01L21302
    • H01L21/76826H01L21/02074H01L21/3212H01L21/76801H01L21/76807H01L21/76825H01L21/76888
    • Within a method for removing from over a substrate a chemical mechanical polish (CMP) residue layer there is first provided a substrate. There is then formed over the substrate: (1) a chemical mechanical polish (CMP) substrate layer having an aperture formed therein; (2) a chemical mechanical polish (CMP) planarized patterned layer formed within the aperture within the chemical mechanical polish (CMP) substrate layer; and (3) a chemical mechanical polish (CMP) residue layer formed upon at least one of the chemical mechanical polish substrate layer and the chemical mechanical polish (CMP) planarized patterned layer, where at least one of the chemical mechanical polish (CMP) substrate layer and the chemical mechanical polish (CMP) planarized patterned layer has a first aqueous contact angle. There is then treated the at least one of the chemical mechanical polish (CMP) substrate layer and the chemical mechanical polish (CMP) planarized patterned layer having the first aqueous contact angle to provide at least one of a hydrophilic chemical mechanical polish (CMP) substrate layer and a hydrophilic chemical mechanical polish (CMP) planarized patterned layer having a second aqueous contact angle less than the first aqueous contact angle. Finally, there is then removed the chemical mechanical polish (CMP) residue layer from the at least one of the hydrophilic chemical mechanical polish (CMP) substrate layer and the hydrophilic chemical mechanical polish (CMP) planarized patterned layer with an aqueous cleaner composition.
    • 在用于从衬底上除去化学机械抛光(CMP)残留层的方法中,首先提供衬底。 然后在衬底上形成:(1)其中形成有孔的化学机械抛光(CMP)衬底层; (2)化学机械抛光(CMP)平面化图案层,其形成在化学机械抛光(CMP)衬底层内的孔内; 化学机械抛光(CMP)残留层形成在至少一个化学机械抛光衬底层和化学机械抛光(CMP)平面化图案层上,其中化学机械抛光(CMP)衬底 层和化学机械抛光(CMP)平面化图案层具有第一水接触角。 然后,处理具有第一水接触角的化学机械抛光(CMP)衬底层和化学机械抛光(CMP)平坦化图案化层中的至少一个以提供亲水化学机械抛光(CMP)衬底中的至少一个 层和亲水化学机械抛光(CMP)平面化图案层,其具有小于第一水接触角的第二水接触角。 最后,用水性清洁剂组合物从亲水化学机械抛光(CMP)衬底层和亲水化学机械抛光(CMP)平坦化图案化层中的至少一个去除化学机械抛光(CMP)残留层。
    • 7. 发明授权
    • Method for forming a self-aligned copper structure with improved
planarity
    • 用于形成具有改善的平面度的自对准铜结构的方法
    • US6080656A
    • 2000-06-27
    • US387436
    • 1999-09-01
    • Tsu ShihYing-Ho ChenJih-Churng TwuSyun-Ming Jang
    • Tsu ShihYing-Ho ChenJih-Churng TwuSyun-Ming Jang
    • H01L21/768H01L21/4763H01L21/44
    • H01L21/7684H01L21/76879
    • A method for forming a copper structure with reduced dishing, using a self-aligned copper electroplating process. The process begins by providing a semiconductor structure having a dielectric layer thereover, wherein the dielectric layer has a trench therein. A barrier layer is formed over the dielectric layer, a seed layer is formed on the barrier layer, and an insulating layer is formed on the seed layer. The insulating layer is patterned so as to expose the seed layer on the bottom and sidewalls of the trench, preferably using the trench photo mask. A copper layer is selectively electroplated onto the exposed seed layer on the bottom and sidewalls of the trench, while the insulating layer prevents copper deposition outside of the trench. The copper layer, the insulating layer, and the seed layer are planarized, stopping at the dielectric layer. Because of the self-aligned copper geometry, the copper suffers reduced dishing.
    • 一种使用自对准铜电镀工艺形成具有减少凹陷的铜结构的方法。 该过程开始于提供其上具有介电层的半导体结构,其中介电层在其中具有沟槽。 在电介质层上形成阻挡层,在阻挡层上形成种子层,在籽晶层上形成绝缘层。 图案化绝缘层,以便优选地使用沟槽光掩模来暴露沟槽的底部和侧壁上的晶种层。 选择性地将铜层电镀到沟槽的底部和侧壁上的暴露种子层上,同时绝缘层防止在该沟槽外部的铜沉积。 铜层,绝缘层和种子层被平坦化,停留在电介质层。 由于自对准的铜几何形状,铜损坏了凹陷。
    • 8. 发明授权
    • Reduction of Cu line damage by two-step CMP
    • 通过两步CMP减少Cu线损伤
    • US06620725B1
    • 2003-09-16
    • US09395287
    • 1999-09-13
    • Shau-Lin ShueMing-Hsing TsaiWen-Jye TsaiYing-Ho ChenTsu ShihJih-Churng TwuSyun-Ming Jang
    • Shau-Lin ShueMing-Hsing TsaiWen-Jye TsaiYing-Ho ChenTsu ShihJih-Churng TwuSyun-Ming Jang
    • H01L214763
    • H01L21/7684H01L21/3212
    • A process for performing CMP in two steps is described. After trenches have been formed and over-filled with copper, in a first embodiment of the invention a hard pad is used initially to remove most of the copper until a point is reached where dishing effects would begin to appear. A soft pad is then substituted and CMP continued until all copper has been removed, except in the trenches. In a second embodiment, CMP is initiated using a pad to which high-pressure is applied and which rotates relatively slowly. As before, this combination is used until the point is reached where dishing effects would begin to appear. Then, relatively low pressure in combination with relatively high rotational speed is used until all copper has been removed, except in the trenches. Both of these embodiments result in trenches which are just-filled with copper, with little or no dishing effects, and with all traces of copper removed everywhere except in the trenches themselves.
    • 描述用于在两个步骤中执行CMP的过程。 在沟槽已经形成并且用铜过度填充之后,在本发明的第一实施例中,最初使用硬焊盘去除大部分铜,直到达到一个点,其中凹陷效应将开始出现。 然后取代软焊盘,继续CMP直到除了沟槽中除去所有的铜。 在第二实施例中,使用施加高压并且相对缓慢地旋转的衬垫来启动CMP。 如前所述,使用这种组合,直到达到点,其中凹陷效应将开始出现。 然后,除了沟槽之外,使用相对较低的压力结合相对高的转速直到除去所有的铜。 这两个实施例都导致刚好填充铜的沟槽,几乎没有凹陷效应,并且除了沟槽本身之外,所有痕迹的铜都被去除。
    • 10. 发明授权
    • Gap filling of shallow trench isolation by ozone-tetraethoxysilane
    • 通过臭氧四乙氧基硅烷进行浅沟隔离的间隙填充
    • US6100163A
    • 2000-08-08
    • US226277
    • 1999-01-07
    • Syun-Ming JangYing-Ho ChenChen-Hua Yu
    • Syun-Ming JangYing-Ho ChenChen-Hua Yu
    • H01L21/762H01L21/76
    • H01L21/76224
    • A method for filling a trench within a silicon substrate. There is first provided a silicon substrate having a trench formed therein. There is then oxidized thermally the silicon substrate to form within the trench a thermal silicon oxide trench liner layer. There is then treated the thermal silicon oxide trench liner layer by exposure to a plasma formed from a gas composition which upon plasma activation simultaneously supplies an active nitrogen containing species and an active oxygen containing species to form a plasma treated thermal silicon oxide trench liner layer. There is then formed upon the plasma treated thermal silicon oxide trench liner layer a conformal silicon oxide intermediate layer formed through a plasma enhanced chemical vapor deposition (PECVD) method employing a silane silicon source material. Finally, there is then formed upon the conformal silicon oxide intermediate layer a gap filling silicon oxide trench fill layer through an ozone assisted sub-atmospheric pressure thermal chemical vapor deposition (SACVD) method employing an ozone oxidant and a tetra-ethyl-ortho-silicate (TEOS) silicon source material.
    • 一种用于在硅衬底内填充沟槽的方法。 首先提供其中形成有沟槽的硅衬底。 然后将硅衬底热氧化以在沟槽内形成热氧化硅沟槽衬垫层。 然后通过暴露于由气体组合物形成的等离子体来处理热氧化硅沟槽衬里层,其在等离子体激活时同时提供含活性氮的物质和含活性氧的物质以形成等离子体处理的热氧化硅沟槽衬里层。 然后在等离子体处理的热氧化硅沟槽衬垫层上形成通过使用硅烷硅源材料的等离子体增强化学气相沉积(PECVD)方法形成的共形氧化硅中间层。 最后,通过使用臭氧氧化剂和四乙基原硅酸盐的臭氧辅助亚大气压热化学气相沉积(SACVD)方法,在保形氧化硅中间层上形成填充氧化硅沟槽填充层的间隙 (TEOS)硅源材料。