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1. 发明申请

US20080269426A1 Method for Producing a Polyalkenyl Amine 审中-公开
标题翻译：聚烯基胺的制备方法
公开(公告)号：US20080269426A1
公开(公告)日：2008-10-30
申请号：US11917816
申请日：2006-06-23
申请人： Stefan Bitterlich , Thomas Wettling , Peter Spang , Helmut Schmidtke , Klaus Diehl , Andreas Bode , Matthias Frauenkron , Marc Walter , Erich K. Fehr
发明人： Stefan Bitterlich , Thomas Wettling , Peter Spang , Helmut Schmidtke , Klaus Diehl , Andreas Bode , Matthias Frauenkron , Marc Walter , Erich K. Fehr
IPC分类号： C08F8/30 , C08F8/32
CPC分类号： C10L1/2383 , B01D3/14 , B01D5/0069 , C08F8/00 , C08F8/32 , C10M133/54 , C10M149/02 , C10M2215/26 , C08F10/00 , C08F10/10
摘要： The present invention relates to a process for preparing a polyalkenylamine, in which the solvent used for the reaction is exchanged for a different solvent.
摘要翻译：本发明涉及一种制备聚烯烃的方法，其中用于反应的溶剂被换成不同的溶剂。

2. 发明授权

US07753970B2 Polyalkene amines with improved applicational properties 有权
标题翻译：聚烯烃胺具有改进的应用性能
公开(公告)号：US07753970B2
公开(公告)日：2010-07-13
申请号：US10550910
申请日：2004-03-31
申请人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich K. Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
发明人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich K. Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
IPC分类号： C08L23/26
CPC分类号： C10L1/238 , C08F8/32 , C08L39/00 , C09D11/03 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/2383 , C10L1/2387 , C10L10/14 , C10M133/06 , C10M133/08 , C10M133/40 , C10M133/48 , C10M133/50 , C10M133/54 , C10M141/04 , C10M2203/022 , C10M2203/106 , C10M2215/04 , C10M2215/042 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10N2220/023 , C08F10/10
摘要： The present invention relates to polyalkene amine formulations comprising at least one polyalkene amine in a solvent, having improved performance properties, especially improved low temperature properties; a process for preparing such formulations and the use of these formulations in fuel and lubricant compositions, in particular fuels, for improving the intake system-cleaning action of such fuels.
摘要翻译：本发明涉及在溶剂中包含至少一种聚烯烃胺的聚烯烃胺配方，具有改进的性能特性，特别是改进的低温性能; 制备这种制剂的方法以及这些制剂在燃料和润滑剂组合物，特别是燃料中的用途，以改善这种燃料的进气系统清洁作用。

3. 发明申请

US20070094922A1 Polyalkene amines with improved applicational properties 有权
标题翻译：聚烯烃胺具有改进的应用性能
公开(公告)号：US20070094922A1
公开(公告)日：2007-05-03
申请号：US10550910
申请日：2004-03-31
申请人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
发明人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
IPC分类号： C10L1/22 , C07C211/13
CPC分类号： C10L1/238 , C08F8/32 , C08L39/00 , C09D11/03 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/2383 , C10L1/2387 , C10L10/14 , C10M133/06 , C10M133/08 , C10M133/40 , C10M133/48 , C10M133/50 , C10M133/54 , C10M141/04 , C10M2203/022 , C10M2203/106 , C10M2215/04 , C10M2215/042 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10N2220/023 , C08F10/10
摘要： The present invention relates to polyalkene amine formulations comprising at least one polyalkene amine in a solvent, having improved performance properties, especially improved low temperature properties; a process for preparing such formulations and the use of these formulations in fuel and lubricant compositions, in particular fuels, for improving the intake system-cleaning action of such fuels.
摘要翻译：本发明涉及在溶剂中包含至少一种聚烯烃胺的聚烯烃胺配方，具有改进的性能特性，特别是改进的低温性能; 制备这种制剂的方法以及这些制剂在燃料和润滑剂组合物，特别是燃料中的用途，以改善这种燃料的进气系统清洁作用。

4. 发明申请

US20080214762A1 Method for the Production of High-Grade Polyisobutene 审中-公开
标题翻译：高级聚异丁烯生产方法
公开(公告)号：US20080214762A1
公开(公告)日：2008-09-04
申请号：US11994417
申请日：2006-07-11
申请人： Andreas Bode , Uwe Rachwalsky , Friedrich Sauer , Eckard Schauss , Marco-Christian Volland , Thomas Wettling
发明人： Andreas Bode , Uwe Rachwalsky , Friedrich Sauer , Eckard Schauss , Marco-Christian Volland , Thomas Wettling
IPC分类号： C08F4/14 , C08F10/10
CPC分类号： B01F3/1221 , B01F7/00758 , B01J19/1806 , C08F110/10 , C08F2/01 , C08F4/14 , C08F2500/03
摘要： The present invention relates to a process for preparing polyisobutenes by polymerizing isobutene in the presence of a Lewis acid catalyst in liquid organic phase, terminating the reaction by admixing the organic phase with an aqueous terminator in a dynamic mixer which has a rotationally symmetric mixing chamber formed from one circumferential wall and two end walls, and a mixing rotor driven such that it rotates therein, the organic phase being introduced through a first inlet orifice provided in the circumferential wall and the aqueous terminator via a second inlet orifice provided in the circumferential wall, and removing a finely dispersed mixture of the organic phase and of the terminator through an outlet orifice provided in the circumferential wall and feeding it to a phase separation. The process serves to prepare high-reactivity polyisobutenes and/or polyisobutenes with narrow molecular weight distribution.
摘要翻译：本发明涉及通过在路易斯酸催化剂存在下在液态有机相中聚合异丁烯来制备聚异丁烯的方法，通过在具有旋转对称的混合室形成的动态混合器中混合有机相与水性终止剂来终止反应从一个圆周壁和两个端壁以及被驱动使得其在其中旋转的混合转子，有机相通过设置在周壁中的第一入口孔和设置在周向壁中的第二入口孔引入，并通过设置在周壁上的出口孔除去有机相和终止剂的微细分散的混合物并将其送入相分离。该方法用于制备具有窄分子量分布的高反应性聚异丁烯和/或聚异丁烯。

5. 发明授权

US07745554B2 Method for producing a polyisobutene 失效
标题翻译：聚异丁烯的制造方法
公开(公告)号：US07745554B2
公开(公告)日：2010-06-29
申请号：US12089930
申请日：2006-10-13
申请人： Hans Peter Rath , Helmut Mach , Thomas Wettling
发明人： Hans Peter Rath , Helmut Mach , Thomas Wettling
IPC分类号： C08F4/14 , C08F10/10
CPC分类号： C08F110/10 , C08F4/14
摘要： The invention relates to a process for preparing polyisobutene having a mean molecular weight Mn of from 400 to 50 000, in particular from 500 to 10 000, by polymerizing isobutene in the presence of a BF3-containing complex catalyst, wherein the polymerization is carried out at least temporarily in the presence of one or more cyclic ethers.
摘要翻译：本发明涉及通过在含BF 3的络合物催化剂存在下聚合异丁烯来制备平均分子量Mn为400至50,000，特别是500至10000的聚异丁烯的方法，其中进行聚合至少暂时存在一种或多种环醚。

6. 发明授权

US07399404B2 Reduction of the content of compounds containing oxygen and/or nitrogen in material flows containing isobutene 有权
标题翻译：在含有异丁烯的物料流中减少含有氧和/或氮的化合物的含量
公开(公告)号：US07399404B2
公开(公告)日：2008-07-15
申请号：US10556091
申请日：2004-05-14
申请人： Thomas Wettling , Dirk Borchers
发明人： Thomas Wettling , Dirk Borchers
IPC分类号： C07C7/12
CPC分类号： C07C7/13 , C07C11/09
摘要： A process for reducing the content of oxygen-containing and/or nitrogen-containing compounds in streams having an isobutene content of at least 10% by weight, which comprises passing the stream in the liquid state at a temperature T [in K] and a linear velocity v [in cm/min] over a fixed bed of an acid-free zeolite having a mean pore size of from 0.3 to 1.5 nm, where the fixed bed has a length l [in cm] in the flow direction of the stream and T, v and l obey the relationship 2(T−283 K)/10 K·l/v≦500 min, is described. The process avoids the formation of isobutene oligomers.
摘要翻译：一种用于在异丁烯含量为至少10重量％的流中降低含氧和/或含氮化合物的含量的方法，其包括使物流以[K]的温度T和在平均孔径为0.3至1.5nm的无酸沸石的固定床上，在流动方向上的固定床的长度l [cm]，以线速度v [cm / min] 并且T，v和l遵守关系<？in-line-formula description =“In-line Formulas”end =“lead”？> 2（T-283 K）/ 10 K / v <= 500 min，<？in-line-formula description =“In-line Formulas”end =“tail”？>。该方法避免了异丁烯低聚物的形成。

7. 发明授权

US5792884A Preparation of tertiary phosphines 失效
标题翻译：制备叔膦
公开(公告)号：US5792884A
公开(公告)日：1998-08-11
申请号：US170985
申请日：1993-12-21
申请人： Thomas Wettling
发明人： Thomas Wettling
IPC分类号： C07F9/50 , C07F9/02
CPC分类号： C07F9/509
摘要： Tertiary phosphines (I) are prepared by reducing the corresponding phosphine oxides (IIa) or phosphine dihalides (IIb) using silicon or a silicon alloy as reducing agent.
摘要翻译：通过使用硅或硅合金作为还原剂还原相应的氧化膦（IIa）或二卤化膦（IIb）来制备叔膦（I）。

8. 发明授权

US5530147A Selective hydrogenation of aromatic groups in the presence of epoxy groups 失效
标题翻译：在环氧基存在下选择性氢化芳基
公开(公告)号：US5530147A
公开(公告)日：1996-06-25
申请号：US422905
申请日：1995-04-17
申请人： Thomas Wettling , Ludwig Schuster , Jochem Henkelmann
发明人： Thomas Wettling , Ludwig Schuster , Jochem Henkelmann
IPC分类号： B01J23/46 , C07B35/02 , C07D301/00 , C07D303/24 , C08G59/14 , C08G59/68 , C07D303/23
CPC分类号： C07D303/24 , C07D301/00 , C08G59/1405
摘要： A process for the selective hydrogenation of aromatic groups of organic molecules carrying at least one aromatic group and one epoxy group with hydrogen in the presence of a ruthenium-containing catalyst, in which a homogeneous ruthenium catalyst is used which can be prepared by reducing the ruthenium compound with a metal having a redox potential of from -0.75 to 2.5 V, a boron hydride, an aluminum hydride, an aluminum alkyl compound, a lithium alkyl compound, or a lithium aryl compound in the presence of an ether.
摘要翻译：在含钌催化剂的存在下，使用含有钌的催化剂存在下，用氢气携带至少一个芳基和一个环氧基的有机分子的芳族基团的选择性氢化的方法，其中使用均匀的钌催化剂，其可以通过还原钌来制备在乙醚存在下与氧化还原电位为-0.75至2.5V的金属，硼氢化物，氢化铝，烷基铝化合物，烷基锂化合物或锂芳基化合物的化合物。

9. 发明授权

US5274164A Preparation of aryl chloroformates 失效
标题翻译：氯甲酸芳基酯的制备
公开(公告)号：US5274164A
公开(公告)日：1993-12-28
申请号：US975693
申请日：1992-11-13
申请人： Thomas Wettling , Jochem Henkelmann , Irene Troetsch-Schaller , Hermann Koehler
发明人： Thomas Wettling , Jochem Henkelmann , Irene Troetsch-Schaller , Hermann Koehler
IPC分类号： C07C68/02 , C07C69/96
CPC分类号： C07C68/02
摘要： A process for the preparation of aromatic aryl chloroformates of the general formula I ##STR1## in which Ar denotes an aryl radical optionally mono- to penta-substituted by C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.3 -C.sub.8 -alkyl-cycloalkyl, C.sub.1 -C.sub.20 -haloalkyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.1 -C.sub.20 -alkylthio, halo, cyano, C.sub.2 -C.sub.20 -alkylcarbonyloxy, C.sub.3 -C.sub.20 -carboalkoxy, formyl, C.sub.2 -C.sub.20 -dialkylamino, aryl, aryloxy, arylthio, aroyl, C.sub.7 -C.sub.20 -aralkyl, C.sub.7 -C.sub.20 -aralkoxy, arylsulfonyl and/or C.sub.7 -C.sub.20 -aralkylthio and/or optionally mono- or di-substituted by chloroformyl and/or nitro, from phosgene and phenols of the general formula IIAr--OH (II),in which Ar has the meanings stated above and optionally carries one or two hydroxy groups, wherein the reaction is carried out at a temperature of from 60.degree. to 180.degree. C. in the presence of an organic phosphorus compound of the general formula III ##STR2## in which at least one of the radicals R.sup.1, R.sup.2, and R.sup.3 stands, irrespective of the others, for --NR.sup.5 R.sup.6 or --O--R.sup.7 andR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 independently denote C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, halo, aryl, or C.sub.7 -C.sub.20 -aralkyl and R.sup.1 and R.sup.2, R.sup.1 and R.sup.3, R.sup.2 and R.sup.3, and R.sup.5 and R.sup.6 each denote a saturated or unsaturated C.sub.2 -C.sub.5 -alkylene chain,X denotes hydroxy, aryloxy, halo, or an inorganic or organic acid anion,R.sup.4 denotes hydrogen or C.sub.1 -C.sub.20 -alkyl or halo when X stands for halo, aryloxy, or aralkoxy,n is equal to 0 or 1, andR.sup.4 and X can together denote oxygen or sulfur.
摘要翻译：制备通式I（I）的芳族芳基氯甲酸酯的方法，其中Ar表示任选被C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 3 -C 8单取代至五取代的芳基 - 烷基 - 环烷基，C 1 -C 20卤代烷基，C 1 -C 20 - 烷氧基，C 1 -C 20 - 烷硫基，卤素，氰基，C 2 -C 20烷基羰基氧基，C 3 -C 20 - 烷氧基，甲酰基，C 2 -C 20 - 二烷基氨基，芳基，，芳基硫基，芳酰基，C 7 -C 20 - 芳烷基，C 7 -C 20 - 芳烷氧基，芳基磺酰基和/或C 7 -C 20 - 芳烷硫基，和/或任选被氯仿和/或硝基的一般或二取代的光气和酚式II Ar-OH（II），其中Ar具有上述含义并任选地带有一个或两个羟基，其中反应在有机物存在下在60-180℃的温度下进行磷化合物，其中R 1，R 2和R 3中的至少一个与-NR 5 R 6或-O-R 7和R 1，R 2，R 3，R 4不同，其中R 1，R 2和R 3中的至少一个表示， R5，R6，R7独立地表示C1-C20烷基，C2-C20-烯基，卤素，芳基或C7-C20-芳烷基，R1和R2，R1和R3，R2和R3，以及R5和R6各自表示饱和或不饱和C 2 -C 5亚烷基链，X表示羟基，芳氧基，卤素或无机或有机酸阴离子，当X代表卤素，芳氧基或芳烷氧基时，R 4表示氢或C 1 -C 20烷基或卤素，n相等至0或1，R4和X可以一起表示氧或硫。

10. 发明授权

US08697820B2 Process for preparing high-reactivity isobutene homo- or copolymers 有权
标题翻译：制备高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US08697820B2
公开(公告)日：2014-04-15
申请号：US13568421
申请日：2012-08-07
申请人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
发明人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
IPC分类号： C08F4/06 , C08F2/00 , C08F10/00
CPC分类号： C08F110/10 , C08F10/10 , C08F4/00 , C08F4/06 , C08F2500/02 , C08F2500/03
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % by polymerization of isobutene or isobutene-comprising monomer mixtures in the presence of Lewis acids suitable as polymerization catalysts or of complexes which are effective as polymerization catalysts and are formed from Lewis acids and donors, and in the presence of initiators, wherein the initiators used are organic sulfonic acids Z—SO3H in which the variable Z denotes an alkyl radical, haloalkyl radical, cycloalkyl radical, aryl radical or arylalkyl radical.
摘要翻译：通过在适合作为聚合催化剂的路易斯酸存在下异丁烯或含异丁烯的单体混合物的聚合制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键含量的高反应性异丁烯均聚物或共聚物，或者作为聚合催化剂有效并且由路易斯酸和供体形成的络合物，并且在引发剂的存在下，其中所用的引发剂是有机磺酸Z-SO 3 H，其中变量Z表示烷基，卤代烷基，环烷基，芳基或芳基烷基。

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