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    • 6. 发明授权
    • Optical element material and method for producing same
    • 光学元件材料及其制造方法
    • US09574106B2
    • 2017-02-21
    • US14347474
    • 2012-09-25
    • MARUZEN PETROCHEMICAL CO., LTD.
    • Yoshihisa HayashidaTakuro SatsukaTeruyo Ikeda
    • C09D139/04G02B1/12G02B1/10C08F2/50C08F226/12G02B1/04C08F222/10
    • C09D139/04C08F2/50C08F222/1006C08F226/12G02B1/04G02B1/10G02B1/12C08L39/00C08L45/00C08F2220/1883C08F2222/1026C08F226/08C08F2220/301
    • An optical element material which is obtained by curing a resin composition for photoimprinting containing a photocurable monomer (A) of the formula (1) and a photocurable monomer (B) of the formula (2) in a weight ratio of from 30/70 to 87/13, and containing a photopolymerization initiator (C) in a content of from 0.01 to 30 parts by weight per 100 parts by weight of the total weight of the monomer (A) and the monomer (B), and which has a shrinkage on curing of at most 4.5%, and a method for producing it: wherein R1 is —CH═CH2, —CH2CH2—O—CH═CH2, —CH2—C(CH3) ═CH2 or a glycidyl group; R2 and R3 are each independently hydrogen or a C1-4 alkyl group; R4 and R5 are each independently —O—CH═CH2, —O—CH2CH2—O—CH═CH2, —O—CO—CH═CH2, —O—CO—C(CH3)═CH2, —O—CH2CH2—O—CO—CH═CH2, —O—CH2CH2—O—CO—C(CH3)═CH2 or a glycidyl ether group; and R6 and R7 are each independently hydrogen or a C1-4 alkyl group.
    • 本发明提供一种光学元件材料,其特征在于通过固化光密封用树脂组合物得到,其中由式(1)表示的光固化性单体(A)和式(2)表示的光固化性单体(B)的含量重量比为 30/70〜87/13,光聚合引发剂(C)的含量相对于100重量份的光固化性单体(A)和光固化性单体(B)的总计为0.01〜30重量份。 还提供了其制造方法。 式(1)中,R 1为-CH = CH 2,-CH 2 CH 2 -O-CH = CH 2,-CH 2 CH 2 -O-CO-CH = CH 2,-CH 2 CH 2 - O-CO-C(CH 3)= CH 2,-CH 2 -C(CH 3)= CH 2或缩水甘油基; R 2和R 3相同或不同,为氢或C 1-4烷基。 式(2)中,R 4和R 5相同或不同,-O-CH = CH 2,O-CH 2 CH 2 -O-CH = CH 2,-O-CO-CH = CH 2,O -CO-C(CH 3)= CH 2,-O-CH 2 CH 2 -O-CO-CH = CH 2,-O-CH 2 CH 2 -O-CO-C(CH 3)= CH 2或 缩水甘油醚基团。 R 6和R 7相同或不同,为氢或C 1-4烷基。