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1. 发明授权

US09499646B2 Negative resist composition, method of forming resist pattern and complex 有权
标题翻译：抗蚀剂组合物，抗蚀剂图案和复合物的形成方法
公开(公告)号：US09499646B2
公开(公告)日：2016-11-22
申请号：US15153044
申请日：2016-05-12
申请人： TOKYO OHKA KOGYO CO., LTD.
发明人： Naoki Yamashita , Yoshitaka Komuro , Yoshiyuki Utsumi , Daiju Shiono
IPC分类号： C08F30/04 , C07F7/00 , C08G18/22 , C08F4/12 , C08F4/06 , C08F4/16 , C08F299/04 , G03F7/004
CPC分类号： C08F30/04 , C07F7/003 , C08F4/06 , C08F4/12 , C08F4/16 , C08F299/0464 , C08G18/222 , G03F7/004 , G03F7/0042 , G03F7/027 , G03F7/038 , G03F7/2002 , G03F7/30 , G03F7/40
摘要： A negative resist composition including a complex represented by the general formula (1); and a polymerization initiator, in which M represents hafnium (Hf) or zirconium (Zr), X represents a ligand comprising a conjugate base of an acid which has an acid dissociation constant (pKa) of 3.8 or less and has a polymerizable group, Y represents a ligand having no polymerizable group, and n represents an integer of 1 to 4. [MXnY4-n] (1)

2. 发明授权

US09366960B2 Negative resist composition, method of forming resist pattern, and complex 有权
标题翻译：抗蚀剂组合物，形成抗蚀剂图案的方法和复合物
公开(公告)号：US09366960B2
公开(公告)日：2016-06-14
申请号：US14558977
申请日：2014-12-03
申请人： Tokyo Ohka Kogyo Co., Ltd.
发明人： Naoki Yamashita , Yoshitaka Komuro , Yoshiyuki Utsumi , Daiju Shiono
IPC分类号： G03F7/004 , G03F7/038 , G03F7/20 , C08G18/22 , C08F4/06 , G03F7/30 , G03F7/40 , C08F30/04 , C08F299/04
CPC分类号： C08F30/04 , C07F7/003 , C08F4/06 , C08F4/12 , C08F4/16 , C08F299/0464 , C08G18/222 , G03F7/004 , G03F7/0042 , G03F7/027 , G03F7/038 , G03F7/2002 , G03F7/30 , G03F7/40
摘要： A negative resist composition including a complex represented by the general formula (1); and a polymerization initiator. in which M represents hafnium (Hf) or zirconium (Zr), X represents a ligand including a conjugate base of an acid which has an acid dissociation constant (pKa) of 3.8 or less and has a polymerizable group, Y represents a ligand having no polymerizable group, and n represents an integer of 1 to 4. [MXnY4-n] (1)
摘要翻译：包含由通式（1）表示的络合物的负性抗蚀剂组合物; 和聚合引发剂。其中M表示铪（Hf）或锆（Zr），X表示包含酸分解常数（pKa）为3.8以下且具有聚合性基团的酸的共轭碱的配体，Y表示不具有可聚合基团，n表示1〜4的整数。[MXnY4-n]（1）

3. 发明申请

US20150274851A1 PROCESS OF CONTROLLED RADICAL POLYMERIZATION OF BRANCHED POLYACRYLATES 有权
标题翻译：分支聚丙烯酸酯的控制性自由基聚合方法
公开(公告)号：US20150274851A1
公开(公告)日：2015-10-01
申请号：US14736902
申请日：2015-06-11
申请人： Henkel IP & Holding GmbH
发明人： Anthony Francis Jacobine , John Woods , David P. Dworak , Darel Gustafson
IPC分类号： C08F2/38 , C08J5/00 , C08K5/00 , C09J133/08 , C08K3/00 , C08F220/10 , C09D133/08
CPC分类号： C08F2/38 , C08F4/00 , C08F4/06 , C08F4/10 , C08F220/10 , C08F220/18 , C08F2220/1825 , C08F2438/01 , C08J5/00 , C08J2333/08 , C08K3/01 , C08K5/0008 , C08L33/08 , C09D133/08 , C09J133/08 , C09K3/10 , C09K2200/0625 , C08F2220/1808 , C08F2220/286 , C08F2222/1013
摘要： The present invention relates to living radical polymerization processes, reaction products of such processes, and compositions containing such reaction products. More particularly, the invention relates to a living radical polymerization to produce branched polymers, in particular branched polyacrylates.
摘要翻译：本发明涉及活性自由基聚合方法，这些方法的反应产物和含有这种反应产物的组合物。更具体地说，本发明涉及生成支化聚合物，特别是支链聚丙烯酸酯的活性自由基聚合。

4. 发明授权

US09109016B2 Derivatisation of biological molecules 有权
标题翻译：生物分子的衍生化
公开(公告)号：US09109016B2
公开(公告)日：2015-08-18
申请号：US14037777
申请日：2013-09-26
申请人： BIOCOMPATIBLES UK LIMITED
发明人： Stephen James Brocchini , Antony Robert Godwin , Yiqing Tang , Andrew Lennard Lewis
IPC分类号： C07C17/08 , C07K17/08 , A61K47/48 , C08F4/00 , C08F4/06 , C08F30/02 , A61K38/00
CPC分类号： A61K47/48176 , A61K38/00 , A61K38/21 , A61K47/58 , A61K47/60 , C07C323/22 , C07K17/08 , C08F4/00 , C08F4/06 , C08F30/02 , C08F130/02
摘要： The present disclosure relates to a new polymerisation process in which ethylenically unsaturated monomers are polymerised by a living radical polymerisation process in the presence of an initiator and a catalyst. Polymers produced by this new process are also thought to be novel and may be used to derivatise biological molecules to improve their efficacy as therapeutic treatments. A preferred polymer is of formula The polymers are particularly suitable for derivatising proteins, such as interferon-α.
摘要翻译：本公开涉及一种新的聚合方法，其中烯属不饱和单体通过活性自由基聚合方法在引发剂和催化剂存在下聚合。通过这种新方法生产的聚合物也被认为是新的，可用于衍生生物分子以提高其作为治疗疗法的功效。优选的聚合物具有下式聚合物特别适用于衍生化蛋白质，如干扰素-α。

5. 发明申请

US20140107283A1 CONTROLLED RADICAL POLYMERIZATION OF (METH)ACRYLATE MONOMERS 有权
标题翻译：（甲基）丙烯酸酯单体的控制性自由基聚合
公开(公告)号：US20140107283A1
公开(公告)日：2014-04-17
申请号：US13795537
申请日：2013-03-12
申请人： HENKEL CORPORATION
发明人： Qinyan Zhu , David P. Dworak , John G. Woods , Anthony F. Jacobine
IPC分类号： C08F20/18 , C08F20/14
CPC分类号： C08F20/18 , C08F2/38 , C08F4/00 , C08F4/06 , C08F20/14 , C08F220/14 , C08F220/18 , C08F220/20 , C08F220/26 , C08F2438/01
摘要： Living radical polymerization processes, reaction products of such processes, and compositions containing such reaction products are provided. More particularly, a living radical polymerization of (meth)acrylic acid monomers employing having a defined order of introduction of the reactants and/or a specific set of reaction conditions, is provided.
摘要翻译：提供活性自由基聚合方法，这些方法的反应产物和含有这种反应产物的组合物。更具体地，提供了使用具有确定的反应物引入顺序和/或特定反应条件的（甲基）丙烯酸单体的活性自由基聚合。

6. 发明授权

US08013088B2 Cationic polymerization of biological oils 有权
标题翻译：阳离子聚合生物油
公开(公告)号：US08013088B2
公开(公告)日：2011-09-06
申请号：US12400635
申请日：2009-03-09
申请人： Mihail Ionescu , Zoran S. Petrovic
发明人： Mihail Ionescu , Zoran S. Petrovic
IPC分类号： C07C57/03 , C07C57/12 , C08F2/02 , C08F4/12 , C11B3/02 , C11B3/00
CPC分类号： C11C3/00 , C08F4/06 , C08F4/12 , C08F4/20 , C08F220/64
摘要： A polymerization reaction mixture for the cationic polymerization of unsaturated biological oils (e.g. vegetable oils and animals oils) based on the cationic reaction of double bonds initiated by superacids is provided. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).
摘要翻译：提供了基于由超强酸引发的双键的阳离子反应的不饱和生物油（例如植物油和动物油）的阳离子聚合的聚合反应混合物。聚合油的粘度比初始油高约10至200倍，并且具有相对高的不饱和度（比初始油低约10-30％）。

7. 发明授权

US07732549B2 Multi-branched polymer 有权
标题翻译：多支化聚合物
公开(公告)号：US07732549B2
公开(公告)日：2010-06-08
申请号：US10595974
申请日：2004-11-25
申请人： Koichiro Aoyagi , Takeshi Niitani
发明人： Koichiro Aoyagi , Takeshi Niitani
IPC分类号： C08F4/06 , C08F12/16 , C08F20/22
CPC分类号： C08F12/16 , C08F4/06 , C08G83/005
摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.
摘要翻译：本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以与R 3结合形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

8. 发明申请

US20090111957A1 FLUORO-PONYTAILED BIPYRIDINE DERIVATIVES AND THEIR USE AS LIGANDS IN THE METAL-CATALYZED ATRP 审中-公开
标题翻译：氟代膦酰二苯胺衍生物及其作为金属催化ATRP中的配体使用
公开(公告)号：US20090111957A1
公开(公告)日：2009-04-30
申请号：US11930402
申请日：2007-10-31
申请人： Norman Lu , Tsung-Chi Chen
发明人： Norman Lu , Tsung-Chi Chen
IPC分类号： C08F4/06 , C07D401/04 , C07F15/00
CPC分类号： C08F4/06 , C07D213/30 , C08F4/00 , C08F4/80
摘要： The present invention also relates a metal complex complexing with the fluoro-ponytailed bipyridine derivatives, which is represented by the general formula (2): and each Rf is the same or different and represents a fluoro-alkyl group having from 3 to 11 carbon atoms, preferably a perfluoro-alkyl group having from 9 to 11 carbon atoms; X− represents a halogenide such as fluoride, bromide, chloride, or iodide; and M represents a metal selected from the group consisting of Mo, Cr, Re, Ru, Fe, Rh, Ni, Pd, and Cu.
摘要翻译：本发明还涉及与由通式（2）表示的氟 - 马尾二联吡啶衍生物络合的金属络合物：每个Rf相同或不同，表示具有3至11个碳原子的氟代烷基优选具有9-11个碳原子的全氟烷基; X-表示卤化物如氟化物，溴化物，氯化物或碘化物; M表示选自Mo，Cr，Re，Ru，Fe，Rh，Ni，Pd和Cu的金属。

9. 发明申请

US20080281071A1 Cationic polymerization of biological oils 有权
标题翻译：阳离子聚合生物油
公开(公告)号：US20080281071A1
公开(公告)日：2008-11-13
申请号：US11800736
申请日：2007-05-07
申请人： Mihail Ionescu , Zoran S. Petrovic
发明人： Mihail Ionescu , Zoran S. Petrovic
IPC分类号： C08G63/78 , C11C3/00
CPC分类号： C11C3/00 , C08F4/06 , C08F4/12 , C08F4/20 , C08F220/64
摘要： A method for the cationic polymerization of unsaturated biological oils (e.g., vegetable oils and animal oils) based on the cationic reaction of double bonds initiated by superacids is provided. The process occurs under very mild reaction conditions (about 70-110° C. and atmospheric pressure) and with short reaction times. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).
摘要翻译：提供了基于由超强酸引发的双键的阳离子反应的不饱和生物油（例如植物油和动物油）的阳离子聚合的方法。该过程发生在非常温和的反应条件（约70-110℃和大气压）下，反应时间短。聚合油的粘度比初始油高约10至200倍，并且具有相对高的不饱和度（比初始油低约10-30％）。

10. 发明授权

US07423100B2 Polymerization processes 有权
标题翻译：聚合工艺
公开(公告)号：US07423100B2
公开(公告)日：2008-09-09
申请号：US10539013
申请日：2003-12-19
申请人： Michael Francis McDonald , Scott Thomas Milner , Timothy Daniel Shaffer , Robert Norman Webb
发明人： Michael Francis McDonald , Scott Thomas Milner , Timothy Daniel Shaffer , Robert Norman Webb
IPC分类号： C08F2/14 , C08F4/20
CPC分类号： C08F210/12 , C08F2/06 , C08F10/00 , C08F4/06 , C08F4/52 , C08F4/12 , C08F2/14 , C08F2/002 , C08F4/00 , C08F236/08 , C08F2500/04 , C08F2500/03
摘要： The invention provides for polymerization processes to produce polymers utilizing boiling pool reactor systems and diluents including hydrofluorocarbons.
摘要翻译：本发明提供聚合方法以使用沸腾池反应器系统和包括氢氟烃在内的稀释剂来生产聚合物。

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