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1. 发明授权

US08293075B2 Method for the continuous separation by distillation of mixtures that contain morphonline (MO), monoaminodiglycol (ADG), ammonia and water by means of distillation 有权
标题翻译：通过蒸馏连续分离含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法
公开(公告)号：US08293075B2
公开(公告)日：2012-10-23
申请号：US12443581
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： B01D3/14 , C07D295/02
CPC分类号： C07C213/10 , C07D295/023 , C07C217/08
摘要： Processes for the continuous fractional distillation of a mixture containing morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process including: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20, in which water and an organic product are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar; (iii) feeding a bottom fraction from K20 to a third distillation column K30, wherein the column K30 is a dividing wall column (DWC)which preferably has a dividing wall (DW) in the longitudinal direction of the column to form an upper combined column region (1), a lower combined column region (6), an inflow part (2,4) having an enrichment section (2) and a stripping section (4), and also an offtake part (3,5) having an enrichment section (3) and a stripping section (5), with the bottoms from K20 being fed in in the upper or middle third of the inflow part (2,4), based on the number of theoretical plates of the inflow part, ADG and organic products having a boiling point of >190° C. (1.013 bar) being discharge at the bottom, organic products having a boiling point of ≦128° C. (1.013 bar) being discharge at a top and MO being discharge from the middle or lower third of the offtake part (3,5) (side offtake), based on the number of theoretical plates of the offtake part.
摘要翻译：从二甘醇（DEG）与氨的反应中连续分馏含有吗啉（MO），单胺二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在第一蒸馏塔K10顶部; （ii）将底部馏分从K10进料到第二蒸馏塔K20，在第二蒸馏塔K20中，水和有机产物在顶部分离出，顶部温度为45-98℃，压力为范围为0.1至15巴; （iii）从K20向第三蒸馏塔K30供给底部馏分，其中塔K30是分隔壁塔（DWC），其在塔的纵向方向上优选具有分隔壁（DW），以形成上部混合塔区域（1），下部组合柱区域（6），具有浓缩部分（2）和汽提部分（4）的流入部分（2,4），以及具有富集部分（3）和汽提部分（5），其中来自K20的底部基于流入部分的理论塔板的数量，ADG和沸点为> 190℃（1.013巴）的有机产物在底部排出，沸点为＆amp; NlE的有机产物; 128℃（1.013巴）在顶部排出，MO从基于出料部分的理论塔板的数量，出口部分（3,5）（侧面）的中下三分之一。

2. 发明申请

US20110009627A1 REACTOR FOR CARRYING OUT HIGH PRESSURE REACTIONS, METHOD FOR STARTING AND METHOD FOR CARRYING OUT A REACTION 审中-公开
标题翻译：实施高压反应的反应器，起动方法和进行反应的方法
公开(公告)号：US20110009627A1
公开(公告)日：2011-01-13
申请号：US12864540
申请日：2009-01-21
申请人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
发明人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
IPC分类号： B01J19/00 , C07D265/30 , C07C209/04
CPC分类号： B01J8/067 , B01J8/008 , B01J2208/00539 , B01J2208/00796
摘要： The invention relates to a reactor for performing high-pressure reactions, comprising at least one tube (31) whose ends are each conducted through a tube plate (33) and which is bonded to the tube plate (33). The tube plates (33) and the at least one tube (31) are surrounded by an outer jacket, such that an outer space (39) is formed between the tube (31) and the outer jacket. The tube plates (33) each have at least one surface composed of a nickel-base alloy and the at least one tube (31) is in each case welded on to the surface composed of the nickel-base alloy. The surface composed of the nickel-base alloy points in each case in the direction of the particular reactor end. The outer jacket has a thickness which is sufficient to absorb tensile forces which occur between tube (31) and outer jacket owing to a temperature difference in the event of different expansion. The invention further relates to a process for starting up the reactor and for performing an exothermic reaction in the reactor.
摘要翻译：本发明涉及一种用于进行高压反应的反应器，包括至少一个管（31），其端部各自通过管板（33）导通，并连接到管板（33）。管板（33）和至少一个管（31）被外护套围绕，使得在管（31）和外护套之间形成外部空间（39）。管板（33）各自具有由镍基合金构成的至少一个表面，并且至少一个管（31）各自焊接在由镍基合金构成的表面上。由镍基合金组成的表面在每种情况下都指向特定反应器端的方向。外护套的厚度足以吸收由于在不同膨胀的情况下的温度差而在管（31）和外护套之间发生的张力。本发明还涉及一种启动反应器并在反应器中进行放热反应的方法。

3. 发明申请

US20080269426A1 Method for Producing a Polyalkenyl Amine 审中-公开
标题翻译：聚烯基胺的制备方法
公开(公告)号：US20080269426A1
公开(公告)日：2008-10-30
申请号：US11917816
申请日：2006-06-23
申请人： Stefan Bitterlich , Thomas Wettling , Peter Spang , Helmut Schmidtke , Klaus Diehl , Andreas Bode , Matthias Frauenkron , Marc Walter , Erich K. Fehr
发明人： Stefan Bitterlich , Thomas Wettling , Peter Spang , Helmut Schmidtke , Klaus Diehl , Andreas Bode , Matthias Frauenkron , Marc Walter , Erich K. Fehr
IPC分类号： C08F8/30 , C08F8/32
CPC分类号： C10L1/2383 , B01D3/14 , B01D5/0069 , C08F8/00 , C08F8/32 , C10M133/54 , C10M149/02 , C10M2215/26 , C08F10/00 , C08F10/10
摘要： The present invention relates to a process for preparing a polyalkenylamine, in which the solvent used for the reaction is exchanged for a different solvent.
摘要翻译：本发明涉及一种制备聚烯烃的方法，其中用于反应的溶剂被换成不同的溶剂。

4. 发明申请

US20100084257A1 METHOD FOR THE CONTINUOUS SEPARATION OF MIXTURES COMPRISING MORPHOLINE (MO), MONOAMINODIGLYCOL (ADG), AMMONIA AND WATER BY MEANS OF DISTILLATION 有权
标题翻译：通过蒸馏法连续分离包含摩尔（MO），单胺基（ADG），氨和水的混合物的方法
公开(公告)号：US20100084257A1
公开(公告)日：2010-04-08
申请号：US12443563
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Bussmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Bussmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： C07C213/10 , C07D295/02 , B01D3/14 , C07C217/08
CPC分类号： C07D295/027
摘要： Processes for the continuous fractional distillation of a mixture comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process comprising: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20 in which water and organic products are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar, (iii) feeding a bottom fraction from K20 to a third distillation column K30, wherein the column K30 is a dividing wall column (DWC) which preferably has a dividing wall (DW) in the longitudinal direction of the column to form an upper combined column region (1), a lower combined column region (6), an inflow part (2, 4) having an enrichment section (2) and a stripping section (4), and also an offtake part (3, 5) having an enrichment section (3) and a stripping section (5), with the bottoms from K20 being fed in in the upper or middle third of the inflow part (2, 4), based on the number of theoretical plates of the inflow part, ADG and organic products having a boiling point of >190° C. (1.013 bar) being discharged at the bottom, organic products having a boiling point of ≦128° C. (1.013 bar) being discharged at the top and MO being discharged from the middle or lower third of the offtake part (3, 5) (side offtake), based on the number of theoretical plates of the offtake part.
摘要翻译：用于从二甘醇（DEG）与氨的反应连续分馏含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在第一蒸馏塔K10顶部; （ii）将底部馏分从K10进料至第二蒸馏塔K20，其中水和有机产物在顶部分离出，顶部温度为45-98℃，压力范围为 0.1至15巴，（iii）从K20向第三蒸馏塔K30供给底部馏分，其中塔K30是分隔壁塔（DWC），其优选在塔的纵向方向上具有分隔壁（DW）至形成上部组合列区域（1），下部组合列区域（6），具有浓缩部分（2）和剥离部分（4）的流入部分（2,4），以及出口部分（3， 5）具有富集部分（3）和汽提部分（5），其中来自K20的底部在流入部分（2,4）的上部或中部三分之一中被输入，基于理论塔板的数量流入部件，ADG和沸点> 190℃（1.013巴）的有机产物在底部排出，有机原料沸点为＆nlE; 128℃（1.013巴）在顶部排出，MO从出料部（3,5）的中部或下部三分之一（出口侧）排出，基于理论板的出口部分。

5. 发明申请

US20050010057A1 Method for the continuous production of n-methyl-2-pyrrolidone (nmp) 有权
标题翻译：连续生产正甲基-2-吡咯烷酮（nmp）的方法
公开(公告)号：US20050010057A1
公开(公告)日：2005-01-13
申请号：US10495358
申请日：2002-11-15
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
IPC分类号： C07D207/26 , C07D207/267 , C07D207/12
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-methyl-2-pyrrolidone (NMP) by reacting gamma-butyrolactone (GBL) with monomethylamine (MMA) in the liquid phase, wherein GBL and MMA are used in a molar ratio of from 1:1.08 to 1:2 and the reaction is carried out at from 320 to 380° C. and an absolute pressure of from 70 to 120 bar.
摘要翻译：通过使γ-丁内酯（GBL）与一甲胺（MMA）在液相中连续制备N-甲基-2-吡咯烷酮（NMP）的方法，其中GBL和MMA的摩尔比为1:1.08至 1：2，反应在320〜380℃，绝对压力为70〜120巴下进行。

6. 发明授权

US07994350B2 Process for continuously preparing N-ethyl-2-pyrrolidone (NEP) 有权
标题翻译：连续制备N-乙基-2-吡咯烷酮（NEP）的方法
公开(公告)号：US07994350B2
公开(公告)日：2011-08-09
申请号：US12299544
申请日：2007-05-10
申请人： Helmut Schmidtke , Ralph Versch , Silke Simon , Karl Ott , Ronald Drews , Stephanie Mollner
发明人： Helmut Schmidtke , Ralph Versch , Silke Simon , Karl Ott , Ronald Drews , Stephanie Mollner
IPC分类号： C07D207/267
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-ethyl-2-pyrrolidone (NEP) by reacting gamma-butyrolactone (GBL) with monoethylamine (MEA) in the liquid phase, wherein GBL and MEA are used in a molar ratio in the range from 1:1.08 to 1:2 an the reaction is carried out at a temperature in the range from 320 to 420° C. and an absolute pressure in the range from 70 to 120 bar.
摘要翻译：通过在液相中使γ-丁内酯（GBL）与单乙胺（MEA）反应连续制备N-乙基-2-吡咯烷酮（NEP）的方法，其中GBL和MEA的摩尔比范围为1： 1.08至1：2，反应在320至420℃的温度和70至120巴范围内的绝对压力下进行。

7. 发明申请

US20090187030A1 PROCESS FOR CONTINUOUSLY PREPARING N-ETHYL-2-PYRROLIDONE (NEP) 有权
标题翻译：连续制备N-乙基-2-吡咯烷酮（NEP）的方法
公开(公告)号：US20090187030A1
公开(公告)日：2009-07-23
申请号：US12299544
申请日：2007-05-10
申请人： Helmut Schmidtke , Ralph Versch , Silke Simon , Karl Ott , Ronald Drews , Stephanie Mollner
发明人： Helmut Schmidtke , Ralph Versch , Silke Simon , Karl Ott , Ronald Drews , Stephanie Mollner
IPC分类号： C07D207/267
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-ethyl-2-pyrrolidone (NEP) by reacting gamma-butyrolactone (GBL) with monoethylamine (MEA) in the liquid phase, wherein GBL and MEA are used in a molar ratio in the range from 1:1.08 to 1:2 an the reaction is carried out at a temperature in the range from 320 to 420° C. and an absolute pressure in the range from 70 to 120 bar.
摘要翻译：通过在液相中使γ-丁内酯（GBL）与单乙胺（MEA）反应连续制备N-乙基-2-吡咯烷酮（NEP）的方法，其中GBL和MEA的摩尔比范围为1： 1.08至1：2，反应在320至420℃的温度和70至120巴范围内的绝对压力下进行。

8. 发明授权

US07825281B2 Method for producing electronic grade 2,2′-aminoethoxyethanol 有权
标题翻译：生产电子级2,2'-氨基乙氧基乙醇的方法
公开(公告)号：US07825281B2
公开(公告)日：2010-11-02
申请号：US12443226
申请日：2007-09-21
申请人： Helmut Schmidtke , Martin Rudloff
发明人： Helmut Schmidtke , Martin Rudloff
IPC分类号： C07C209/16
CPC分类号： C07C213/02 , C07C217/08
摘要： A process for preparing electronics-grade 2,2′-aminoethyoxyethanol by reacting diethylene glycol with ammonia in the presence of a catalyst in a reactor to give a reaction mixture from which a crude 2,2′-aminoethoxyethanol stream is separated off and is purified further by distillation in a pure column, wherein a sidestream comprising electronics-grade 2,2′-aminoethoxyethanol is taken off from the pure column as a result of the diethylene glycol being passed through a filter which ensures a degree of removal of at least 99% for solid particles having a maximum particle size of ≦1.5 μm before the diethylene glycol is fed into the reactor, is proposed.
摘要翻译：一种通过二甘醇与氨在催化剂存在下在反应器中反应制备电子级2,2'-氨基乙氧基乙醇的方法，得到反应混合物，将粗制的2,2'-氨基乙氧基乙醇流从其中分离出并纯化进一步通过在纯柱中蒸馏，其中由于二甘醇通过过滤器，其中包含电子级2,2'-氨基乙氧基乙醇的侧流从纯柱中取出，确保去除程度至少为99 提出了在将二甘醇进料到反应器中之前，具有最大粒径为＆amp; N1的固体颗粒为1.5μm。

9. 发明授权

US07227029B2 Method for the continuous production of N-methyl-2-pyrrolidone (NMP) 有权
标题翻译：连续生产N-甲基-2-吡咯烷酮（NMP）的方法
公开(公告)号：US07227029B2
公开(公告)日：2007-06-05
申请号：US10495358
申请日：2002-11-15
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
IPC分类号： C07D207/12 , C07D307/20
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-methyl-2-pyrrolidone (NMP) by reacting gamma-butyrolactone (GBL) with monomethylamine (MMA) in the liquid phase, wherein GBL and MMA are used in a molar ratio of from 1:1.08 to 1:2 and the reaction is carried out at from 320 to 380° C. and an absolute pressure of from 70 to 120 bar.
摘要翻译：通过使γ-丁内酯（GBL）与一甲胺（MMA）在液相中连续制备N-甲基-2-吡咯烷酮（NMP）的方法，其中GBL和MMA的摩尔比为1:1.08至 1：2，反应在320〜380℃，绝对压力为70〜120巴下进行。

10. 发明申请

US20070094922A1 Polyalkene amines with improved applicational properties 有权
标题翻译：聚烯烃胺具有改进的应用性能
公开(公告)号：US20070094922A1
公开(公告)日：2007-05-03
申请号：US10550910
申请日：2004-03-31
申请人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
发明人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
IPC分类号： C10L1/22 , C07C211/13
CPC分类号： C10L1/238 , C08F8/32 , C08L39/00 , C09D11/03 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/2383 , C10L1/2387 , C10L10/14 , C10M133/06 , C10M133/08 , C10M133/40 , C10M133/48 , C10M133/50 , C10M133/54 , C10M141/04 , C10M2203/022 , C10M2203/106 , C10M2215/04 , C10M2215/042 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10N2220/023 , C08F10/10
摘要： The present invention relates to polyalkene amine formulations comprising at least one polyalkene amine in a solvent, having improved performance properties, especially improved low temperature properties; a process for preparing such formulations and the use of these formulations in fuel and lubricant compositions, in particular fuels, for improving the intake system-cleaning action of such fuels.
摘要翻译：本发明涉及在溶剂中包含至少一种聚烯烃胺的聚烯烃胺配方，具有改进的性能特性，特别是改进的低温性能; 制备这种制剂的方法以及这些制剂在燃料和润滑剂组合物，特别是燃料中的用途，以改善这种燃料的进气系统清洁作用。

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