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1. 发明授权

US06242630B1 Process for the continuous preparation of 3-halopropylorganosilanes 失效
标题翻译：连续制备3-卤代丙基有机硅烷的方法
公开(公告)号：US06242630B1
公开(公告)日：2001-06-05
申请号：US08908095
申请日：1997-08-11
申请人： Stefan Bade , Uwe Schoen , John Burkhard , Franz-Michael Bollenrath , Norbert Hofmann , Hermann-Josef Korte , Hartwig Rauleder , Uwe Tanger
发明人： Stefan Bade , Uwe Schoen , John Burkhard , Franz-Michael Bollenrath , Norbert Hofmann , Hermann-Josef Korte , Hartwig Rauleder , Uwe Tanger
IPC分类号： C07F708
CPC分类号： C07F7/14 , C07F7/0829 , C07F7/1876
摘要： A process for the continuous preparation of 3-halopropylorganosilanes of the general structure RbH3-a-bXaSiCH2CH2CH2Y (III), where: R is CH3, C2H5, C3H7, OCH3, OC2H5 or OC3H7, X is F, Cl, Br or I, Y is F, Cl, Br or I, and a and b are each one of the numbers 0, 1, 2 or 3 and the sum a+b is 1, 2 or 3, comprising reacting, as starting materials, an allyl halide with a silane carrying at least one H atom, wherein the starting materials are present in stoichiometric amounts or one of the starting materials is present in substoichiometric amounts, wherein the reaction carried out is a partial reaction of from 10% to 80%, on a molar basis, of the starting materials, based on either material, when both are present in stoichiometric amounts, or based on the substoichiometric material.
摘要翻译：连续制备通常结构的3-卤代丙基有机硅烷的方法，其中R为CH 3，C 2 H 5，C 3 H 7，OCH 3，OC 2 H 5或OC 3 H 7，X为F，Cl，Br或I，Y为F，Cl，Br或I，和b分别为数字0,1,2或3中的一个，并且和a + b为1,2或3，包括使烯丙基卤化物与携带至少一个H原子的硅烷作为原料，其中，原料以化学计量的量存在，或者一种起始原料以亚化学计量的量存在，其中进行的反应是基于摩尔的10％至80％的起始原料的部分反应，基于任一材料，当两者都以化学计量的量存在时，或基于亚化学计量的材料。

2. 发明授权

US06222056B1 Process for preparing vinylchlorosilanes 有权
标题翻译：制备乙烯基氯硅烷的方法
公开(公告)号：US06222056B1
公开(公告)日：2001-04-24
申请号：US09556404
申请日：2000-04-24
申请人： Stefan Bade , Hartwig Rauleder , Uwe Schoen , Franz-Michael Bollenrath
发明人： Stefan Bade , Hartwig Rauleder , Uwe Schoen , Franz-Michael Bollenrath
IPC分类号： C07F714
CPC分类号： C07F7/122
摘要： The invention relates to a process for preparing vinylchlorosilanes by thermal non-catalyzed reaction of chlorosilanes with vinyl chloride at from 550 to 700° C., using a ring-gap reactor which includes rapidly cooling the hot reaction gases after they have flowed through the ring-gap space, by quenching them with a liquid.
摘要翻译：本发明涉及一种通过氯代硅烷与氯乙烯在550-700℃下的热非催化反应制备乙烯基氯硅烷的方法，该方法包括一个环流反应器，该反应器包括在热反应气体流过环后快速冷却间隙，用液体淬火。

3. 发明授权

US06291698B1 Process for preparing vinyl chlorosilanes 有权
标题翻译：制备乙烯基氯硅烷的方法
公开(公告)号：US06291698B1
公开(公告)日：2001-09-18
申请号：US09556403
申请日：2000-04-24
申请人： Stefan Bade , Bernt Kesper , Robert Koell , Hartwig Rauleder , Uwe Schoen
发明人： Stefan Bade , Bernt Kesper , Robert Koell , Hartwig Rauleder , Uwe Schoen
IPC分类号： C07F708
CPC分类号： C07F7/122
摘要： The invention relates to a process for preparing vinyl chlorosilanes, that includes thermally and non-catalytically reacting chlorosilane with vinyl chloride at a temperature of 550 to 700° C. by flowing the chlorosilane and vinyl chloride through a ring-gap space in a ring-gap reactor to produce a reaction gas; the ring-gap space having a cross-sectional area and a volume; and, after the flowing, further reacting, adiabatically, the reaction gas in a second zone to produce a hot reaction gas that contains vinylchiorosilane; wherein the second zone has a cross-sectional area that is greater than the cross-sectional area of the ring-gap space; and wherein the second zone has a volume that is in a ratio to the volume of the ring-gap space of 0.15:1 to 1.5:1. The invention also provides an apparatus for carrying out the above process.
摘要翻译：本发明涉及一种制备乙烯基氯硅烷的方法，其包括在550-700℃的温度下使氯代硅烷与氯乙烯进行热和非催化反应，通过使氯代硅烷和氯乙烯通过环 - 间隙反应器产生反应气体; 所述环间隙具有横截面积和体积; 并且在流动之后，绝热地将第二区中的反应气体进行反应，以产生含有乙烯基氯硅烷的热反应气体; 其中所述第二区域具有大于所述环形间隙的横截面面积的横截面面积; 并且其中所述第二区域具有与所述环隙空间的体积的比率为0.15:1至1.5:1的体积。本发明还提供一种用于执行上述过程的装置。

4. 发明授权

US06402961B1 Process for preparing epoxysilanes 有权
标题翻译：制备环氧硅烷的方法
公开(公告)号：US06402961B1
公开(公告)日：2002-06-11
申请号：US09621076
申请日：2000-07-21
申请人： Stefan Bade , Uwe Schoen , Hartwig Rauleder
发明人： Stefan Bade , Uwe Schoen , Hartwig Rauleder
IPC分类号： B01D1508
CPC分类号： C07F7/1892
摘要： A process for preparing epoxysilanes by reacting a hydrogensilane with an allyl glycidyl ether in the presence of a catalyst and working up the crude product obtained, where the catalyst is removed from the crude product and the crude product is subsequently distilled.
摘要翻译：一种通过在催化剂存在下使氢硅烷与烯丙基缩水甘油醚反应来制备环氧硅烷的方法，并处理所得到的粗产物，其中从粗产物中除去催化剂和粗产物。

5. 发明授权

US6100408A Process for preparing 3-glycidyloxypropyltrialkoxysilanes 有权
标题翻译：制备3-缩水甘油氧基丙基三烷氧基硅烷的方法
公开(公告)号：US6100408A
公开(公告)日：2000-08-08
申请号：US246953
申请日：1999-02-09
申请人： Jaroslaw Monkiewicz , Stefan Bade , Uwe Schoen
发明人： Jaroslaw Monkiewicz , Stefan Bade , Uwe Schoen
IPC分类号： B01J23/42 , B01J35/10 , C07B61/00 , C07F7/18 , C07F7/08 , C07D303/02
CPC分类号： C07F7/1876
摘要： The invention relates to a process for preparing 3-glycidyloxypropyltrialkoxysilanes of the general formulaCH.sub.2 (O)CHCH.sub.2 --O--(CH.sub.2).sub.3 Si(OR).sub.3 (I),in which R is an alkyl radical, by reacting allyl glycidyl etherCH.sub.2 (O)CHCH.sub.2 --O--CH.sub.2 CH.dbd.CH.sub.2 (II),with a trialkoxysilane of the general formulaHSi(OR).sub.3 (III),in which R is again an alkyl radical, in a heterogeneous, platinum-catalyzed hydrosilylation reaction, where the catalyst employed is a platinum(0) catalyst on a nonmetallic support.
摘要翻译：本发明涉及一种制备通式CH 2（O）CHCH 2 -O-（CH 2）3 Si（OR）3（I）的3-缩水甘油氧基丙基三烷氧基硅烷的方法，其中R是烷基，烯丙基缩水甘油醚CH2（ O）CHCH 2 -O-CH 2 CH = CH 2（II）与通式为HSi（OR）3（III）的三烷氧基硅烷，其中R再次为烷基，在异质铂催化的氢化硅烷化反应中，其中所使用的催化剂是在非金属载体上的铂（0）催化剂。

6. 发明申请

US20150202590A1 PROCESS FOR PREPARING ALKENYLHALOSILANES AND REACTOR SUITABLE THEREFOR 有权
标题翻译：制备烷基水杨酸的方法及其适用的反应剂
公开(公告)号：US20150202590A1
公开(公告)日：2015-07-23
申请号：US14416989
申请日：2013-05-28
申请人： Stefan Bade , Norbert Schladerbeck
发明人： Stefan Bade , Norbert Schladerbeck
IPC分类号： B01J19/24 , C07F7/12
CPC分类号： B01J19/2415 , B01J2219/00051 , B01J2219/00123 , B01J2219/00162 , B01J2219/00164 , B01J2219/00166 , B01J2219/00245 , C07F7/122
摘要： What is described is a process for preparing alkenylhalosilanes by reacting alkenyl halide selected from the group of vinyl halide, vinylidene halide and allyl halide with halosilane selected from the group of mono-, di- and trihalosilane in the gas phase in a reactor comprising a reaction tube (1) equipped with an inlet (2) at one end of the tube and with an outlet (3) at the other end of the tube, and having a gas inlet device (4) having a plurality of gas feed points (5) which are spaced apart in the direction of the longitudinal axis of the reaction tube (1) and open into the reaction tube (1). To perform the process, mono-, di- or trihalosilane is passed through the inlet (2) into the reaction tube (1) and flows through the reaction tube (1) in the direction of outlet (3), and vinyl halide, vinylidene halide or allyl halide flows through the gas feed points (5) in sections into the gas stream in the interior of the reaction tube (1). The process permits the preparation of alkenylhalosilanes in high yield and with high selectivity. The formation of soot is distinctly lower compared to conventional reactors.The invention also relates to a reactor for performance of gas phase reactions, which is characterized by the presence at least of the following elements: A) reaction tube (1) having B) an inlet (2) at one side of the tube, C) an outlet (3) at the other side of the tube, and D) having a gas inlet device (4) having a plurality of gas feed points (5) which are spaced apart in the direction of the longitudinal axis of the reaction tube (1) and open into the reaction tube (1).
摘要翻译：描述的是通过在气相中将选自乙烯基卤化物，偏二卤乙烯和烯丙基卤化物的烯烃基卤化物与选自单 - ，二 - 和三卤代硅烷的卤代硅烷反应制备烯基卤代硅烷的方法，所述反应器包括反应管（1）在管的一端装有入口（2），并在管的另一端具有出口（3），并且具有气体入口装置（4），其具有多个气体供给点（5 ），其在反应管（1）的纵向轴线的方向上间隔开并进入反应管（1）。为了进行该方法，将单 - ，二 - 或三卤硅烷通过入口（2）进入反应管（1）并沿着出口（3）的方向流过反应管（1），并将乙烯基卤，亚乙烯基卤化物或烯丙基卤化物通过气体供给点（5）以部分流入反应管（1）内部的气流。该方法允许以高产率和高选择性制备链烯基卤代硅烷。与常规反应堆相比，烟灰的形成明显降低。本发明还涉及一种用于气相反应的反应器，其特征在于存在至少以下元素：A）反应管（1），其具有B）管的一侧的入口（2），C ）在所述管的另一侧的出口（3），以及D）具有气体入口装置（4），所述气体入口装置具有多个气体供给点（5），所述多个气体供给点在反应管的纵轴方向上间隔开（1）并通入反应管（1）。

7. 发明授权

US09272258B2 Process for preparing alkenylhalosilanes and reactor suitable therefore 有权
标题翻译：因此制备烯基卤代硅烷和反应器的方法
公开(公告)号：US09272258B2
公开(公告)日：2016-03-01
申请号：US14416989
申请日：2013-05-28
申请人： Stefan Bade , Norbert Schladerbeck
发明人： Stefan Bade , Norbert Schladerbeck
IPC分类号： C07F7/12 , B01J19/24
CPC分类号： B01J19/2415 , B01J2219/00051 , B01J2219/00123 , B01J2219/00162 , B01J2219/00164 , B01J2219/00166 , B01J2219/00245 , C07F7/122
摘要： A process for preparing alkenylhalosilanes by reacting alkenyl halide in the gas phase in a reactor comprising a reaction tube (1) equipped with an inlet (2) at one end of the tube and with an outlet (3) at the other end of the tube, and having a gas inlet device (4) having a plurality of gas feed points (5) that are spaced apart in the direction of the longitudinal axis of the reaction tube (1) and open into the reaction tube (1). The process permits the preparation of alkenylhalosilanes in high yield and with high selectivity. The formation of soot is distinctly lower compared to conventional reactors.
摘要翻译：一种制备烯基卤代硅烷的方法，该方法是在反应器中在气相中使烯基卤化物反应，该反应器包括反应管（1），反应管（1）在管的一端装有入口（2）和管的另一端的出口（3）并具有具有多个气体供给点（5）的气体入口装置（4），所述多个气体供给点在反应管（1）的纵向轴线方向上间隔开并进入反应管（1）。该方法允许以高产率和高选择性制备链烯基卤代硅烷。与常规反应堆相比，烟灰的形成明显降低。

8. 发明授权

US09340560B2 Process for esterifying silicon-halogen compounds in a column and apparatus suitable therefor 有权
公开(公告)号：US09340560B2
公开(公告)日：2016-05-17
申请号：US14767651
申请日：2014-01-16
申请人： Stefan Bade , Norbert Schladerbeck , Andre Nehls
发明人： Stefan Bade , Norbert Schladerbeck , Andre Nehls
IPC分类号： C07F7/18 , C07F7/04 , B01J19/24 , C07F7/08
CPC分类号： C07F7/045 , B01J19/24 , B01J2219/00076 , B01J2219/24 , C07F7/04 , C07F7/08 , C07F7/18 , C07F7/1804 , C07F7/188
摘要： What is described is a process for continuously esterifying halosilanes of the formula I with alcohols of the formula II to give silane esters of the formula III in a single column (1) R1aSiHalb (I) R2—(OH) (II) R1aS—(OR2)b (III) in which R1 is hydrogen or a monovalent organic radical, where any two R1 radicals within a molecule may be different within the scope of the given definitions, Hal is a halogen atom, a plurality of Hal atoms within a molecule may be different within the scope of the given definitions, R2 is a monovalent organic radical, a and b are integers from 0 to 4 and the sum total of a and b is 4, comprising the measures of: i) feeding the total amount of the halosilane of the formula I required for the reaction in liquid form through line (6) into the upper third of the column (1), ii) feeding at least 60% by weight of the alcohol of the formula II required for the reaction in liquid form through line (7) into the upper third of the column (1), iii) feeding the remainder of the alcohol of the formula II required for the reaction in liquid form through line (8) into the lower third of the column (1), iv) conducting the reaction of the halosilane of the formula I with the alcohol of the formula II to give the silane ester of the formula III in the interior of the column (1), the temperature in the interior of the column (1) between line (7) and line (8) being below the boiling temperature of the alcohol of the formula II, v) removing the hydrogen chloride formed in the reaction via the top of the column (1), and vi) removing the esterification product of the formula III formed in the reaction from the bottom of the column (1). The invention also relates to a column (1) for continuously esterifying halosilanes of the above-described formula I with alcohols of the formula II to give silane esters of the formula III, comprising the following elements: A) line (6) which opens into the upper third of the column (1) and which serves to feed in the halosilane of the formula I, B) line (7) which opens into the upper third of the column (1) and which serves to feed in a portion of the alcohol of the formula II required for the reaction, C) line (8) which opens into the lower third of the column (1) and which serves to feed in the remaining portion of the alcohol required for the reaction, D) circulation evaporator (3) which is mounted in the lower third of the column and heats the bottom product present in the column (1), E) line (9) for removing the hydrogen halide formed in the reaction via the top of the column (1), and F) line (10) for removing the esterification product of the formula III formed in the reaction from the bottom of the column (1). The process described allows the preparation of silane esters of the formula III with high selectivity.

9. 发明申请

US20100036146A1 PROCESS FOR PREPARING GLYCIDYLOXYALKYLTRIALKOXYSILANES 有权
标题翻译：制备甘氨酰氧基甲基环氧树脂的方法
公开(公告)号：US20100036146A1
公开(公告)日：2010-02-11
申请号：US12521872
申请日：2007-12-20
申请人： Stefan Bade , Beate Seliger , Norbert Schladerbeck , Joerg Sauer
发明人： Stefan Bade , Beate Seliger , Norbert Schladerbeck , Joerg Sauer
IPC分类号： C07F7/08
CPC分类号： C07F7/1876 , C07F7/0829
摘要： The present invention relates to a process for preparing glycidyloxy-alkylalkoxysilanes of the general formula (I) (R″)O—CnH2nSi(R′)m(OR)3-m (I) in which R and R′ groups are each independently linear or branched alkyl groups having from 1 to 4 carbon atoms, n is 1, 2, 3, 4, 5, 6, 7 or 8 and m is 0, 1, 2 or 3, and R″ is an H2C(O)CH— or H2C(O)CHCH2— group, by reacting (i) a functionalized alkene of the general formula (II) (R″)O—CnH2n-1(II) in which R″ is an H2C(O)CH— or H2C(O)CHCH2— group and n is 1, 2, 3, 4, 5, 6, 7 or 8 with (ii) at least one hydroalkoxy-silane of the general formula (III) HSi(R′)m(OR)3-m (III) in which R and R′ groups are each independently linear or branched alkyl groups having from 1 to 4 carbon atoms and m is 0, 1, 2 or 3, in the presence (iii) of at least one homogeneous catalyst, (iv) of at least one solvent and/or of a diluent and (v) of at least one promoter.
摘要翻译：本发明涉及通式（I）（R“）O-C n H 2n（R'）m（OR）3-m（I）的缩水甘油氧基 - 烷基烷氧基硅烷的制备方法，其中R和R'各自为具有1至4个碳原子的独立的直链或支链烷基，n为1,2,3,4,5,6,7或8，m为0,1,2或3，R“为H 2 C（ O）CH-或H 2 C（O）CHCH 2 - 基，通过使（i）通式（II）的官能化烯烃（R“）O-C n H 2n-1（II）（其中R”是H 2 C O）CH-或H 2 C（O）CHCH 2 - 基，n为1,2,3,4,5,6,7或8，（ii）至少一种通式（III）的氢烷氧基硅烷HSi（R '）m（OR）3-m（III）其中R和R'各自独立地为具有1至4个碳原子的直链或支链烷基，m为0,1,2或3，（iii ）至少一种均相催化剂，（iv）至少一种溶剂和/或稀释剂和（v）至少一种助催化剂。

10. 发明授权

US09718844B2 Process for preparing alkenylhalosilanes and reactor suitable therefor 有权
公开(公告)号：US09718844B2
公开(公告)日：2017-08-01
申请号：US14416952
申请日：2013-05-28
申请人： Stefan Bade , Norbert Schladerbeck
发明人： Stefan Bade , Norbert Schladerbeck
IPC分类号： B01J19/00 , C07F7/14 , B01J19/24 , B01J4/00 , C07F7/12 , B01J19/26
CPC分类号： C07F7/14 , B01J4/002 , B01J19/2415 , B01J19/26 , B01J2219/00051 , B01J2219/00103 , B01J2219/0011 , B01J2219/00123 , B01J2219/00162 , B01J2219/00166 , B01J2219/24 , C07F7/122
摘要： Described is a method for producing alkenyl halosilanes by reacting alkenyl halide selected from the group comprising vinyl halide, vinylidene halide, and allyl halide with halosilane selected from the group comprising monohalosilane, dihalosilane, and trihalosilane in the gas phase in a reactor comprising a reaction tube (1) that has an inlet (2) at one end and an outlet (3) at the other end, said reactor further comprising an annular-gap nozzle (4) that is mounted on the inlet (2), extends into the reaction tube (1), and has a central supply duct (5) for one reactant (7) and a supply duct (6), which surrounds the central supply duct (5), for the other reactant (8). In order to carry out said method, alkenyl halide is injected into the reaction tube (1) through the central supply duct (5), halosilane is injected thereinto through the surrounding supply duct (6), and both substances flow through the reaction tube (1) in the direction of the outlet (3). The described method allows alkenyl halosilanes to be produced at a high yield and with great selectivity. The amount of soot formed is significantly lower than in conventional reactors. The invention also relates to a reactor for carrying out gas-phase reactions, said reactor being characterized by at least the following elements: A) a reaction tube (1) that has B) an inlet (2) at one end, C) an outlet (3) at the other end, and D) an annular-gap nozzle (4) which includes a central supply duct (5) for one reactant (7) and a supply duct (6), which surrounds the central supply duct (5), for another reactant (8), said nozzle being mounted on the inlet (2) and extending into the reaction tube (1).

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