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1. 发明授权

US07365359B2 Organic semiconductor material and organic semiconductor element 失效
标题翻译：有机半导体材料和有机半导体元件
公开(公告)号：US07365359B2
公开(公告)日：2008-04-29
申请号：US10698002
申请日：2003-10-30
申请人： Shinobu Sakurada , Ken Tomino , Hiroki Maeda , Masanori Akada , Jun-ichi Hanna
发明人： Shinobu Sakurada , Ken Tomino , Hiroki Maeda , Masanori Akada , Jun-ichi Hanna
IPC分类号： H01L51/00
CPC分类号： H01L51/0071 , H01L51/0025 , H01L51/0076
摘要： An organic semiconductor material having high charge mobility characteristics and an organic semiconductor element is provided. The organic semiconductor material has rodlike low-molecular liquid crystallinity, including a skeleton structure comprising L 6 π electron aromatic rings, M 10 π electron aromatic rings, and N 14π electron aromatic rings, wherein L, M, and N are each an integer of 0 (zero) to 4 and L+M+N=1 to 4; and a terminal structure attached to both ends of the skeleton structure. The terminal structure can develop liquid crystallinity. The phase angle θ of impedance of the organic semiconductor material is −80°≦θ≦−90° as determined in the measurement of impedance in a frequency f range of 100 Hz≦f≦1 MHz in such a state that the organic semiconductor material in an isotropic phase state is held between a pair of opposed substrates with an interelectrode spacing of 9 μm.
摘要翻译：提供具有高电荷迁移率特性的有机半导体材料和有机半导体元件。有机半导体材料具有棒状低分子液晶性，包括包括L 6π电子芳环，M 10π电子芳环和N 14pi电子芳环的骨架结构，其中L，M和N各自为 0（零）至4，L + M + N = 1至4; 以及附接到骨架结构的两端的端子结构。端子结构可以形成液晶。在100Hz <= f <= 1MHz的频率f范围内的阻抗测量中确定的有机半导体材料的阻抗的相位角θ为-80°θ= -90°，各向同性相状态的有机半导体材料保持在一对相对基板之间，电极间隔为9μm。

2. 发明授权

US07847284B2 Organic semiconductor material, organic semiconductor structure, and organic semiconductor device 有权
标题翻译：有机半导体材料，有机半导体结构和有机半导体器件
公开(公告)号：US07847284B2
公开(公告)日：2010-12-07
申请号：US10508479
申请日：2003-03-26
申请人： Jun-Ichi Hanna , Teppei Shimakawa , Masanori Akada , Hiroki Maeda
发明人： Jun-Ichi Hanna , Teppei Shimakawa , Masanori Akada , Hiroki Maeda
IPC分类号： H01L51/30
CPC分类号： H01L51/0052 , C08K5/0008 , H01L51/0012 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/005 , H01L51/0076 , H01L51/0545 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor material, which can constitute an organic semiconductor layer having homogeneous and a high level of charge transfer characteristics over a large area, and an organic semiconductor structure and an organic semiconductor device utilizing the organic semiconductor material. The organic semiconductor material comprises a polymeric compound and a monomeric compound, the polymeric compound having, in a part of its side chain, a core structure comprising a predetermined π electron ring, the monomeric compound having a core structure comprising a predetermined π electron ring, the monomeric compound having, in at least one of its both ends, a terminal group capable of developing liquid crystallinity.
摘要翻译：提供一种有机半导体材料，其可以构成在大面积上具有均匀和高水平的电荷转移特性的有机半导体层，以及利用有机半导体材料的有机半导体结构和有机半导体器件。有机半导体材料包括聚合化合物和单体化合物，其一部分侧链中的聚合物具有包含预定的＆lt; 电子环，具有包含预定的pgr的核心结构的单体化合物; 在其两端中的至少一个中具有能够显现液晶性的端基的单体化合物。

3. 发明申请

US20050127354A1 Organic semiconductor material, organic semiconductor structure, and organic semiconductor device 有权
标题翻译：有机半导体材料，有机半导体结构和有机半导体器件
公开(公告)号：US20050127354A1
公开(公告)日：2005-06-16
申请号：US10508479
申请日：2003-03-26
申请人： Jun-Ichi Hanna , Teppei Shimakawa , Masanori Akada , Hiroki Maeda
发明人： Jun-Ichi Hanna , Teppei Shimakawa , Masanori Akada , Hiroki Maeda
IPC分类号： C08K5/00 , H01L51/00 , H01L51/05 , H01L51/30 , H01L51/40 , H01L51/42
CPC分类号： H01L51/0052 , C08K5/0008 , H01L51/0012 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/005 , H01L51/0076 , H01L51/0545 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor material, which can constitute an organic semiconductor layer having homogeneous and a high level of charge transfer characteristics over a large area, and an organic semiconductor structure and an organic semiconductor device utilizing the organic semiconductor material. The organic semiconductor material comprises a polymeric compound and a monomeric compound, the polymeric compound having, in a part of its side chain, a core structure comprising a predetermined π electron ring, the monomeric compound having a core structure comprising a predetermined π electron ring, the monomeric compound having, in at least one of its both ends, a terminal group capable of developing liquid crystallinity.
摘要翻译：提供一种有机半导体材料，其可以构成在大面积上具有均匀和高水平的电荷转移特性的有机半导体层，以及利用有机半导体材料的有机半导体结构和有机半导体器件。有机半导体材料包括聚合物和单体化合物，其一部分侧链具有包含预定π电子环的芯结构，所述单体化合物具有包含预定π电子环的核心结构，所述单体化合物在其两端中的至少一个中具有能够显现液晶性的端基。

4. 发明授权

US07102154B2 Organic semiconductor structure, process for producing the same, and organic semiconductor device 有权
标题翻译：有机半导体结构体及其制造方法以及有机半导体装置
公开(公告)号：US07102154B2
公开(公告)日：2006-09-05
申请号：US10502529
申请日：2003-02-07
申请人： Jun-Ichi Hanna , Hiroki Maeda , Masanori Akada
发明人： Jun-Ichi Hanna , Hiroki Maeda , Masanori Akada
IPC分类号： H01L35/24
CPC分类号： H01L51/0076 , H01L51/0012 , H01L51/0052 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0062 , H01L51/0064 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0545 , H01L51/0558 , H01L51/057 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor structure comprising an organic semiconductor layer, which is large in size and homogeneous and has high charge transfer characteristics, a process for producing the same, and an organic semiconductor device. The organic semiconductor structure has, in at least a part thereof, an organic semiconductor layer comprising an aligned liquid crystalline organic semiconductor material. The liquid crystalline organic semiconductor material comprises an organic compound having a core comprising L 6 π electron rings, M 8 π electron rings, N 10 π electron rings, O 12 π electron rings, P 14 π electron rings, Q 16 π electron rings, R 18 π electron rings, S 20 π electron rings, T 22 π electron rings, U 24 π electron rings, and V 26 π electron rings, wherein L, M, N, O, P, Q, R, S, T, U, and V are each an integer of 0 (zero) to 6 and L+M+N+O+P+Q+R+S+T+U+V=1 to 6. The liquid crystalline organic semiconductor material exhibits at least one liquid crystal state at a temperature below the heat decomposition temperature thereof.
摘要翻译：提供了一种有机半导体结构，其包括尺寸大且均匀且具有高电荷转移特性的有机半导体层，其制造方法和有机半导体器件。有机半导体结构在其至少一部分中具有包括取向的液晶有机半导体材料的有机半导体层。液晶有机半导体材料包括具有核心的有机化合物，其包括L 6π电子环，M 8π电子环，N 10π电子环，O 12π电子环，P 14π电子环，Q 16π电子环， R 18π电子环，S 20π电子环，T 22π电子环，U 24π电子环和V 26π电子环，其中L，M，N，O，P，Q，R，S，T， U和V各自为0（零）至6的整数，L + M + N + O + P + Q + R + S + T + U + V = 1至6.液晶有机半导体材料在低于其热分解温度的温度下的至少一种液晶状态。

5. 发明申请

US20060166396A1 Organic semiconductor structure, process for producing the same, and organic semiconductor device 失效
标题翻译：有机半导体结构体及其制造方法以及有机半导体装置
公开(公告)号：US20060166396A1
公开(公告)日：2006-07-27
申请号：US11390667
申请日：2006-03-28
申请人： Jun-ichi Hanna , Hiroki Maeda , Masanori Akada
发明人： Jun-ichi Hanna , Hiroki Maeda , Masanori Akada
IPC分类号： H01L21/00
CPC分类号： H01L51/0076 , H01L51/0012 , H01L51/0052 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0062 , H01L51/0064 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0545 , H01L51/0558 , H01L51/057 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor structure comprising an organic semiconductor layer, which is large in size and homogeneous and has high charge transfer characteristics, a process for producing the same, and an organic semiconductor device. The organic semiconductor structure has, in at least a part thereof, an organic semiconductor layer comprising an aligned liquid crystalline organic semiconductor material. The liquid crystalline organic semiconductor material comprises an organic compound having a core comprising L 6π electron rings, M 8π electron rings, N 10π electron rings, O 12π electron rings, P 14π electron rings, Q 16π electron rings, R 18π electron rings, S 20π electron rings, T 22π electron rings, U 24π electron rings, and V 26π electron rings, wherein L, M, N, O, P, Q, R, S, T, U, and V are each an integer of 0 (zero) to 6 and L+M+N+0+P+Q+R+S+T+U+V=1 to 6. The liquid crystalline organic semiconductor material exhibits at least one liquid crystal state at a temperature below the heat decomposition temperature thereof.
摘要翻译：提供了一种有机半导体结构，其包括尺寸大且均匀且具有高电荷转移特性的有机半导体层，其制造方法和有机半导体器件。有机半导体结构在其至少一部分中具有包括取向的液晶有机半导体材料的有机半导体层。液晶有机半导体材料包括具有芯的有机化合物，其包括L 6pi电子环，M 8pi电子环，N 10pi电子环，O 12pi电子环，P 14pi电子环，Q 16pi电子环，R 18pi电子环，S 20pi电子环，T 22pi电子环，U 24pi电子环和V 26pi电子环，其中L，M，N，O，P，Q，R，S，T，U和V各自为0的整数零）至6和L + M + N + 0 + P + Q + R + S + T + U + V = 1至6.液晶有机半导体材料在低于热的温度下表现出至少一种液晶态分解温度。

6. 发明申请

US20050156161A1 Organic semiconductor structure, process for producing the same, and organic semiconductor device 有权
标题翻译：有机半导体结构体及其制造方法以及有机半导体装置
公开(公告)号：US20050156161A1
公开(公告)日：2005-07-21
申请号：US10502529
申请日：2003-02-07
申请人： Jun-Ichi Hanna , Hiroki Maeda , Masanori Akada
发明人： Jun-Ichi Hanna , Hiroki Maeda , Masanori Akada
IPC分类号： H01L29/786 , H01L35/24 , H01L51/00 , H01L51/30 , H01L51/40
CPC分类号： H01L51/0076 , H01L51/0012 , H01L51/0052 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0062 , H01L51/0064 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0545 , H01L51/0558 , H01L51/057 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor structure comprising an organic semiconductor layer, which is large in size and homogeneous and has high charge transfer characteristics, a process for producing the same, and an organic semiconductor device. The organic semiconductor structure has, in at least a part thereof, an organic semiconductor layer comprising an aligned liquid crystalline organic semiconductor material. The liquid crystalline organic semiconductor material comprises an organic compound having a core comprising L 6 π electron rings, M 8 π electron rings, N 10 π electron rings, O 12 π electron rings, P 14 π electron rings, Q 16 π electron rings, R 18 π electron rings, S 20 π electron rings, T 22 π electron rings, U 24 π electron rings, and V 26 π electron rings, wherein L, M, N, O, P, Q, R, S, T, U, and V are each an integer of 0 (zero) to 6 and L+M+N+O+P+Q+R+S+T+U+V=1 to 6. The liquid crystalline organic semiconductor material exhibits at least one liquid crystal state at a temperature below the heat decomposition temperature thereof.
摘要翻译：提供了一种有机半导体结构，其包括尺寸大且均匀且具有高电荷转移特性的有机半导体层，其制造方法和有机半导体器件。有机半导体结构在其至少一部分中具有包括取向的液晶有机半导体材料的有机半导体层。液晶有机半导体材料包括具有核心的有机化合物，其包括L 6π电子环，M 8π电子环，N 10π电子环，O 12π电子环，P 14π电子环，Q 16π电子环， R 18π电子环，S 20π电子环，T 22π电子环，U 24π电子环和V 26π电子环，其中L，M，N，O，P，Q，R，S，T， U和V各自为0（零）至6的整数，L + M + N + O + P + Q + R + S + T + U + V = 1至6.液晶有机半导体材料在低于其热分解温度的温度下的至少一种液晶状态。

7. 发明授权

US07638795B2 Organic semiconductor structure, process for producing the same, and organic semiconductor device 失效
标题翻译：有机半导体结构体及其制造方法以及有机半导体装置
公开(公告)号：US07638795B2
公开(公告)日：2009-12-29
申请号：US11390667
申请日：2006-03-28
申请人： Jun-ichi Hanna , Hiroki Maeda , Masanori Akada
发明人： Jun-ichi Hanna , Hiroki Maeda , Masanori Akada
IPC分类号： H01L35/24 , H01L51/40
CPC分类号： H01L51/0076 , H01L51/0012 , H01L51/0052 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0062 , H01L51/0064 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0545 , H01L51/0558 , H01L51/057 , Y02E10/549 , Y02P70/521
摘要： There are provided an organic semiconductor structure comprising an organic semiconductor layer, which is large in size and homogeneous and has high charge transfer characteristics, a process for producing the same, and an organic semiconductor device. The organic semiconductor structure has, in at least a part thereof, an organic semiconductor layer comprising an aligned liquid crystalline organic semiconductor material. The liquid crystalline organic semiconductor material comprises an organic compound having a core comprising L 6π electron rings, M 8π electron rings, N 10π electron rings, O 12π electron rings, P 14π electron rings, Q 16π electron rings, R 18π electron rings, S 20π electron rings, T 22π electron rings, U 24π electron rings, and V 26π electron rings, wherein L, M, N, O, P, Q, R, S, T, U, and V are each an integer of 0 (zero) to 6 and L+M+N+O+P+Q+R+S+T+U+V=1 to 6. The liquid crystalline organic semiconductor material exhibits at least one liquid crystal state at a temperature below the heat decomposition temperature thereof.
摘要翻译：提供了一种有机半导体结构，其包括尺寸大且均匀且具有高电荷转移特性的有机半导体层，其制造方法和有机半导体器件。有机半导体结构在其至少一部分中具有包括取向的液晶有机半导体材料的有机半导体层。液晶有机半导体材料包括具有芯的有机化合物，其包括L 6pi电子环，M 8pi电子环，N 10pi电子环，O 12pi电子环，P 14pi电子环，Q 16pi电子环，R 18pi电子环，S 20pi电子环，T 22pi电子环，U 24pi电子环和V 26pi电子环，其中L，M，N，O，P，Q，R，S，T，U和V各自为0的整数零）至6和L + M + N + O + P + Q + R + S + T + U + V = 1至6.液晶有机半导体材料在低于热的温度下显示至少一种液晶态分解温度。

8. 发明授权

US07259390B2 Organic semiconductor material 失效
标题翻译：有机半导体材料
公开(公告)号：US07259390B2
公开(公告)日：2007-08-21
申请号：US10787895
申请日：2004-02-26
申请人： Jun-Ichi Hanna , Hiroaki Iino , Hiroki Maeda
发明人： Jun-Ichi Hanna , Hiroaki Iino , Hiroki Maeda
IPC分类号： H01L29/08 , H01L29/12 , H01L35/24
CPC分类号： C09K19/00 , H01L51/0076
摘要： There is provided a liquid crystalline material, suitable for use as an organic semiconductor material, in which, even when the charge transport distance is long, the charge transport capability is satisfactory, the charge mobility is high, and the dependence of the charge transport properties upon field strength is small. The organic semiconductor material having rodlike low-molecular weight liquid crystallinity comprises: a core structure comprising L 6 π electron rings, M 8 π electron rings, N 10 π electron rings, O 12 π electron rings, P 14 π electron rings, Q 16 π electron rings, R 18 π electron rings, S 20 π electron rings, T 22 π electron rings, U 24 π electron rings, and V 26 π electron rings, wherein L, M, N, O, P, Q, R, S, T, U, and V are each an integer of 0 (zero) to 6 and L+M+N+O+P+Q+R+S+T+U+V=1 to 6; and a terminal structure attached to at least one end of the core structure, the terminal structure being capable of developing liquid crystallinity.
摘要翻译：提供了适合用作有机半导体材料的液晶材料，其中即使电荷传输距离长，电荷传输能力也令人满意，电荷迁移率高，电荷传输性质的依赖性场强很小。具有棒状低分子量液晶性的有机半导体材料包括：包含L 6π电子环，M 8π电子环，N 10π电子环，O 12π电子环，P 14π电子环，Q 16 π电子环，R 18π电子环，S 20π电子环，T 22π电子环，U 24π电子环和V 26π电子环，其中L，M，N，O，P，Q，R， S，T，U和V各自为0（零）至6的整数，L + M + N + O + P + Q + R + S + T + U + V = 1至6; 以及连接到芯结构的至少一端的端子结构，该端子结构能够显现液晶性。

9. 发明授权

US08202759B2 Manufacturing method of organic semiconductor device 失效
标题翻译：有机半导体器件的制造方法
公开(公告)号：US08202759B2
公开(公告)日：2012-06-19
申请号：US12863538
申请日：2009-01-21
申请人： Ken Tomino , Masanao Matsuoka , Tomomi Suzuki , Hiroki Maeda
发明人： Ken Tomino , Masanao Matsuoka , Tomomi Suzuki , Hiroki Maeda
IPC分类号： H01L51/40
CPC分类号： H01L51/0013 , H01L51/003 , H01L51/0076 , H01L51/0545 , H01L51/0558
摘要： The present invention provides a manufacturing method of an organic semiconductor device comprising a step of transferring an organic semiconductor layer to a gate insulation layer by a thermal transfer at a liquid crystal phase transition temperature of a liquid crystalline organic semiconductor material, and the step uses: an organic semiconductor layer-transferring substrate comprising a parting substrate having parting properties, and the organic semiconductor layer formed on the parting substrate and containing the liquid crystalline organic semiconductor material; and a substrate for forming an organic semiconductor device comprising a substrate, a gate electrode formed on the substrate, and the gate insulation layer formed to cover the gate electrode and having alignment properties which are capable of aligning the liquid crystalline organic semiconductor material on a surface of the gate insulation layer.
摘要翻译：本发明提供了一种有机半导体器件的制造方法，其包括通过在液晶有机半导体材料的液晶相变温度下的热转印将有机半导体层转印到栅极绝缘层的步骤，并且该步骤用途：包括具有分离性质的分离基板的有机半导体层转移基板和形成在分型基板上并含有液晶有机半导体材料的有机半导体层; 以及用于形成有机半导体器件的衬底，包括衬底，形成在衬底上的栅极电极和形成为覆盖栅电极并具有能够使液晶有机半导体材料在表面上对准的取向性能的栅极绝缘层的栅极绝缘层。

10. 发明授权

US07935828B2 Organic semiconductor material, organic semiconductor structure and organic semiconductor apparatus 失效
标题翻译：有机半导体材料，有机半导体结构和有机半导体装置
公开(公告)号：US07935828B2
公开(公告)日：2011-05-03
申请号：US11445940
申请日：2006-06-02
申请人： Ken Tomino , Shigeru Sugawara , Hiroki Maeda , Masanao Matsuoka
发明人： Ken Tomino , Shigeru Sugawara , Hiroki Maeda , Masanao Matsuoka
IPC分类号： H01L21/00 , H01L51/30 , C07D513/04
CPC分类号： H01L51/0071 , C09K19/3491 , C09K19/3497 , H01L51/0076 , H01L51/0545 , H01L51/0558 , Y02E10/549
摘要： The present invention is directed to the provision of a novel liquid crystalline organic semiconductor material that is highly stable under an film forming environment and, at the same time, can easily form a film, for example, by coating. The liquid crystalline organic semiconductor material is represented by chemical formula 1 wherein R1 and R2 represent an identical alkyl group having 7 to 20 carbon atoms: There is also provided a liquid crystalline organic semiconductor material characterized by being represented by chemical formula 2 wherein R3 and R4 represent an identical alkyl group having 7 to 20 carbon atoms:
摘要翻译：本发明涉及提供一种在成膜环境下高度稳定的新型液晶有机半导体材料，同时可以容易地通过涂布形成膜。液晶有机半导体材料由化学式1表示，其中R 1和R 2表示相同的具有7至20个碳原子的烷基。还提供了以化学式2表示的液晶有机半导体材料，其中R3和R4 表示具有7至20个碳原子的相同的烷基：

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