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    • 4. 发明申请
    • Silicon single crystal wafer for IGBT and method for manufacturing silicon single crystal wafer for IGBT
    • 用于IGBT的硅单晶晶片和用于IGBT的硅单晶晶片的制造方法
    • US20070193501A1
    • 2007-08-23
    • US11708771
    • 2007-02-20
    • Toshiaki OnoShigeru UmenoWataru SugimuraMasataka Hourai
    • Toshiaki OnoShigeru UmenoWataru SugimuraMasataka Hourai
    • C30B15/00
    • C30B15/00C30B29/06H01L21/261
    • In this silicon single crystal wafer for IGBT, COP defects and dislocation clusters are eliminated from the entire region in the radial direction of the crystal, the interstitial oxygen concentration is 8.5×1017 atoms/cm3 or less, and variation in resistivity within the wafer surface is 5% or less. This method for manufacturing a silicon single crystal wafer for IGBT includes introducing a hydrogen atom-containing substance into an atmospheric gas at a hydrogen gas equivalent partial pressure of 40 to 400 Pa, and growing a single crystal having an interstitial oxygen concentration of 8.5×1017 atoms/cm3 or less at a silicon single crystal pulling speed enabling pulling of a silicon single crystal free of grown-in defects. The pulled silicon single crystal is irradiated with neutrons so as to dope with phosphorous; or an n-type dopant is added to the silicon melt; or phosphorous is added to the silicon melt so that the phosphorous concentration in the silicon single crystal is 2.9×1013 to 2.9×1015 atoms/cm3 and a p-type dopant having a segregation coefficient smaller than that of the phosphorous is added to the silicon melt so that the concentration in the silicon single crystals is 1×1013 to 1×1015 atoms/cm3 corresponding to the segregation coefficient thereof.
    • 在这种用于IGBT的硅单晶晶片中,从晶体的径向的整个区域去除了COP缺陷和位错簇,间隙氧浓度为8.5×10 17原子/ cm 3 以下,晶片表面的电阻率变化为5%以下。 制造用于IGBT的硅单晶晶片的方法包括:将含氢原子的物质以40-400Pa的氢气当量分压引入气氛气体中,并生长间隙氧浓度为8.5×10 5的单晶, 低于17原子/ cm 3以下的硅单晶拉伸速度,使得能够拉伸没有生长缺陷的硅单晶。 将拉制的硅单晶用中子照射以掺入磷; 或者将n型掺杂剂添加到硅熔体中; 或将磷添加到硅熔体中,使得硅单晶中的磷浓度为2.9×10 13 -2.9×10 15原子/ cm 3 / 并且将具有小于磷的偏析系数的p型掺杂剂添加到硅熔体中,使得硅单晶中的浓度为1×10 13至1×10 15 / 对应于其偏析系数的SUP>原子/ cm 3。
    • 9. 发明授权
    • Method for growing silicon single crystal
    • 生长硅单晶的方法
    • US07014704B2
    • 2006-03-21
    • US10455609
    • 2003-06-06
    • Toshiaki OnoTadami TanakaShigeru UmenoEiichi AsayamaHideshi Nishikawa
    • Toshiaki OnoTadami TanakaShigeru UmenoEiichi AsayamaHideshi Nishikawa
    • C30B15/20
    • C30B29/06C30B15/04C30B15/206
    • A method for growing a silicon single crystal used for semiconductor integrated circuit devices, wherein the single crystal is grown by the CZ method at a nitrogen concentration of 1×1013 atoms/cm3–1×1015 atoms/cm3 with a cooling rate of not less than 2.5° C./min at a crystal temperature of 1150° C.–1000° C., in which case, the pulling rate is adjusted such that the outside diameter of a circular region including oxidation-induced stacking faults generated at the center of a wafer which is subjected to the oxidation heat treatment at high temperature is not more than ⅗ of the wafer diameter, wherein the wafer is prepared by slicing the grown single crystal. In the growth method, the concentration of oxygen in the silicon single crystal is preferably not more than 9×1017 atoms/cm3 (ASTM '79). With this method, the silicon single crystal, in which the generation of Grown-in defects can be effectively suppressed, can be produced in a simple process without any increase in the production cost. Moreover, a specification of the oxygen concentration and the application of the outward diffusion treatment are capable of producing a wafer, which is optimally used for monitoring particles.
    • 一种生长用于半导体集成电路器件的硅单晶的方法,其中通过CZ法以1×10 3原子/ cm 3的氮浓度生长单晶。 -1×10 15原子/ cm 3,冷却速率不低于2.5℃/分钟,晶体温度为1150℃-1000℃, 在这种情况下,调整拉伸速度,使得在高温下进行氧化热处理的晶片的中心处产生的氧化诱发堆垛层错的圆形区域的外径不大于 晶片直径,其中通过对生长的单晶进行切片来制备晶片。 在生长方法中,硅单晶中氧的浓度优选不超过9×10 17原子/ cm 3(ASTM '79)。 利用这种方法,可以在简单的工艺中生产出能够有效抑制生成缺陷的硅单晶,而不会增加生产成本。 此外,氧浓度的规格和向外扩散处理的应用能够生产最佳地用于监测颗粒的晶片。