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1. 发明授权

US5171821A Process for producing a phenolate and process for producing an aromatic polyether ketone employing it 失效
标题翻译：生产苯酚的方法和生产使用其的芳族聚醚酮的方法
公开(公告)号：US5171821A
公开(公告)日：1992-12-15
申请号：US359637
申请日：1989-05-31
申请人： Seiichi Nozawa , Hiroshi Noguchi , Fumitoshi Sakaguchi , Yuko Mihara
发明人： Seiichi Nozawa , Hiroshi Noguchi , Fumitoshi Sakaguchi , Yuko Mihara
IPC分类号： C07C45/64 , C07C45/84 , C07C49/83 , C07C205/38 , C07C205/45
CPC分类号： C07C45/84 , C07C45/64
摘要： A process for preparing a metal phenolate of the formula II:Cl--Ar.sub.1 COAr.sub.2 OM (II)wherein each of Ar.sub.1 and Ar.sub.2 which may be the same or different is a bivalent group of the formula: ##STR1## wherein each of R.sup.1 and R.sup.12 is a hydrogen atom, a halogen atom, an alkoxy group, a phenoxy group, an alkyl group, a cycloalkyl group, a phenyl group, an aralkyl group, an acyl group, a nitrile group, a nitro group or an acyloxy group, each of Y and Z is an oxygen atom or a ketone group, and each of n and m is an integer of from 0 to 4, and M is an alkali metal, which comprises reacting a phenol compound of the formula I:Cl--Ar.sub.1 COAr.sub.2 OH (I)wherein Ar.sub.1 and Ar.sub.2 are as defined above, with an alkali metal compound in the presence of water, and then removing water, characterized in that water is azeotropically distilled off together with an organic solvent capable of forming an azeotropic mixture with water.

2. 发明授权

US4977230A Heat-resistant film or sheet 失效
标题翻译：耐热膜或片
公开(公告)号：US4977230A
公开(公告)日：1990-12-11
申请号：US476146
申请日：1990-02-05
申请人： Seiichi Nozawa , Shigeo Utsumi , Michio Nakata
发明人： Seiichi Nozawa , Shigeo Utsumi , Michio Nakata
IPC分类号： B29C55/02 , C08J5/18 , G11B5/73
CPC分类号： C08J5/18 , B29C55/02 , G11B5/7305 , B29K2071/00 , B29L2017/008 , B29L2031/3425 , C08J2371/00
摘要： A heat-resistant film or sheet produced by melt extruding polyether ketone having an intrinsic viscosity of at least 0.4 dl/g, which is obtained by heat treating an unstretched film or sheet which comprises (i) heat-treating to crystallization being not more than 60%, or (ii) uni- or biaxially stretching under specific conditions to an extent in which a stress at 5% elongation in the stretched direction is at least 13 kg/mm.sup.2 ; an initial elastic modulus in the stretched direction is at least 600 kg/mm.sup.2 ; and thermal shrinkages in a lengthwise direction and its vertical direction are not more than 4%.The film or sheet of the present invention is excellent in such properties as heat resistance, mechanical strength and the like, and is suitable for use as a substrate for magnetic recording or electric insulation.
摘要翻译：通过熔融挤出特性粘度为至少0.4dl / g的聚醚酮制成的耐热膜或片材，其通过热处理未拉伸膜或片材获得，所述未拉伸膜或片材包括（i）热处理至结晶不大于 60％，或（ii）在特定条件下的单轴或双轴拉伸至拉伸方向的5％伸长应力至少为13kg / mm2的程度; 拉伸方向的初始弹性模量为至少600kg / mm2; 并且在长度方向上的热收缩和其垂直方向不大于4％。本发明的薄膜或片材的耐热性，机械强度等性质优异，适用于磁记录或电绝缘用基材。

3. 发明授权

US5326849A Method for producing an aromatic poly (thio) ether ketone 失效
标题翻译：芳香族聚（硫代）醚酮的制造方法
公开(公告)号：US5326849A
公开(公告)日：1994-07-05
申请号：US136731
申请日：1993-10-14
申请人： Yukio Takahashi , Norihiko Yoneda , Seiichi Nozawa
发明人： Yukio Takahashi , Norihiko Yoneda , Seiichi Nozawa
IPC分类号： C08G67/00 , C08G61/12 , C08G63/06
CPC分类号： C08G61/12
摘要： A method for producing an aromatic poly(thio)ether ketone having repeating units of the following formula (II): ##STR1## wherein each of R.sup.1 to R.sup.12 is a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group, X is an oxygen atom or a sulfur atom, provided that part of X may be a direct bond, and n is an integer of from 0 to 2, which comprises reacting an aromatic (thio)ether carboxylic acid fluoride of the following formula (I): ##STR2## wherein R.sup.1 to R.sup.12, X and n are as defined above, under pressure in an aprotic organic solvent in the presence of boron trifluoride.
摘要翻译：制备具有下式（II）的重复单元的芳族聚（硫代）醚酮的方法：其中R 1至R 12各自为氢原子，卤素原子，烃基或烷氧基基团，X是氧原子或硫原子，条件是X的一部分可以是直接键，n是0-2的整数，其包括使下式的芳族（硫代）醚羧酸氟化物（I）：在三氟化硼存在下，在非质子有机溶剂中，在压力下，R1至R12，X和n如上定义。

4. 发明授权

US4707536A Catalytic preparation of aromatic polyketone from phosgene and aromatic ether or sulfide 失效
标题翻译：从光气和芳香醚或硫化物催化制备芳香族聚酮
公开(公告)号：US4707536A
公开(公告)日：1987-11-17
申请号：US804615
申请日：1985-12-05
申请人： Norihiko Yoneda , Tsuyoshi Fukuhara , Seiichi Nozawa
发明人： Norihiko Yoneda , Tsuyoshi Fukuhara , Seiichi Nozawa
IPC分类号： C08G61/12 , C08G67/00 , C08G65/00 , C08G83/00
CPC分类号： C08G61/127 , C08G67/00
摘要： Disclosed herein is a process for producing aromatic polyketone, comprising reacting a compound represented by the formula (I): ##STR1## wherein each of R.sup.1 to R.sup.12 represents a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group; X.sup.1 and X.sup.2 respectively represent an oxygen atom or a sulfur atom and n is an integer of from 0 to 5,with phosgene (i) in the presence of a fluoroalkanesulfonic acid or (ii) in hydrogen fluoride in the presence of boron trifluoride at a temperature of from 65.degree. to 90.degree. C.
摘要翻译：本文公开了一种制备芳族聚酮的方法，包括使由式（I）表示的化合物：其中R 1至R 12各自表示氢原子，卤素原子，烃基或烷氧基 ; X1和X2分别表示氧原子或硫原子，n表示0〜5的整数，光气（i）在氟烷基磺酸的存在下，或（ii）在氟化氢中，在三氟化硼存在下，在温度从65℃到90℃

5. 发明授权

US4857626A Wholly aromatic polyester and process for its production 失效
标题翻译：全芳香族聚酯及其生产工艺
公开(公告)号：US4857626A
公开(公告)日：1989-08-15
申请号：US136758
申请日：1987-12-22
申请人： Osamu Kishiro , Atsushi Kasai , Seiichi Nozawa , Hiroshi Kamata
发明人： Osamu Kishiro , Atsushi Kasai , Seiichi Nozawa , Hiroshi Kamata
IPC分类号： C08G63/185 , C08G63/19 , C08G63/60
CPC分类号： C08G63/605 , C08G63/185 , C08G63/19
摘要： A wholly aromatic polyester consisting essentially of:(a) from 2 to 50 equivalent % of a 3,3'-biphenyldicarboxylic acid residue;(b) from 10 to 40 equivalent % of a dicarboxylic acid residue excluding the residue of 3,3'-bisphenyldicarboxylic acid;(c) from 10 to 52 equivalent % of a dioxy compound residue of the formula: ##STR1## wherein R.sup.2 is a group of the formula ##STR2## wherein R.sup.6 is a C.sub.1 -C.sub.4 alkyl group or a phenyl group and n is 0 or an integer up to 4, ##STR3## wherein X is as defined above, ##STR4## wherein X is as defined above, and/or ##STR5## and (d) from 0 to 80 equivalent % of an oxycarboxylic acid residue of the formula: ##STR6## wherein R.sup.3 is a bivalent aromatic hydrocarbon group or R.sup.4 --X--R.sup.5, wherein R.sup.4, R.sup.5 and X are as defined above, said polyester having a melt viscosity of at least 50 poise as measured at 275.degree. C. at 100 sec.sup.-1.

6. 发明授权

US4782132A Process for producing a copolyester 失效
标题翻译：共聚聚酯的制备方法
公开(公告)号：US4782132A
公开(公告)日：1988-11-01
申请号：US853
申请日：1987-01-06
申请人： Seiichi Nozawa , Osamu Kishiro , Atsushi Kasai , Seigo Okumura , Ken Honma , Chieko Muramoto
发明人： Seiichi Nozawa , Osamu Kishiro , Atsushi Kasai , Seigo Okumura , Ken Honma , Chieko Muramoto
IPC分类号： C08G63/60 , C08G63/02 , C08F20/00 , C08G63/16 , C08G63/18
CPC分类号： C08G63/60 , C08G63/605
摘要： A process for producing a copolymeric polyester, which comprises a first step of preparing a copolymeric oligomer by reacting a starting material oligoester or polyester having repeating units of the formula: ##STR1## wherein R.sub.1 is a divalent aromatic hydrocarbon group having from 6 to 10 carbon atoms, a divalent alicyclic hydrocarbon group having from 4 to 20 carbon atoms or/and a divalent aliphatic hydrocarbon group having from 1 to 40 carbon atoms (provided a hydrogen atom in the aromatic ring of the aromatic hydrocarbon group may be substituted by a halogen atom or an alkyl or alkoxy group having from 1 to 4 carbon atoms), and R.sup.2 is a divalent aliphatic hydrocarbon group having from 2 to 40 carbon atoms, a divalent alicyclic hydrocarbon group having from 4 to 20 carbon atoms, or a divalent radical of polyalkylene oxide having a molecular weight of from 80 to 8000, in an amount from 5 to 95 mol % as represented by the amount of the repeating units constituting the oligoester or polyester, with from 5 to 95 mol % of a hydroxycarboxylic acid of the formula:HO--R.sup.3 COOH (B)wherein R.sup.3 is a divalent aromatic hydrocarbon group having from 6 to 20 carbon atoms on its aromatic ring (provided a hydrogen atom in the aromatic ring of the aromatic hydrocarbon group may be substituted by a halogen atom or an alkyl or alkoxy group having from 1 to 4 carbon atoms), a second step of acylating the oligomer by an addition of an acylating agent, and a third step of polymerizing the acylated oligomer under reduced pressure, wherein prior to the completion of the second step, a dihydroxyl compound of the formula:HOR.sup.4 OH (C)wherein R.sup.4 has the same meaning as R.sup.1 in the formula A, or the compound of the formula C and a dicarboxylic acid of the formula:HOOCR.sup.5 COOH (D)wherein R.sup.5 has the same meaning as R.sup.1 in the formula A, are added for reaction.
摘要翻译：一种制备共聚聚酯的方法，其包括通过使具有下式的重复单元的原料低聚酯或聚酯反应制备共聚低聚物的第一步：其中R 1是具有6个碳原子的二价芳族烃基碳原子数为4〜20的二价脂环式烃基和/或碳原子数1〜40的2价脂肪族烃基（芳香族烃基的芳香环中的氢原子可以被卤原子或碳原子数为1〜4的烷基或烷氧基），R 2为碳原子数为2〜40的二价脂肪族烃基，碳原子数为4〜20的二价脂环式烃基或二价分子量为80〜8000的聚环氧烷的基团，以构成低聚酯或p的重复单元的量表示的5〜95摩尔％醇酯，其具有5至95mol％的下式的羟基羧酸：HO-R 3 COOH（B）其中R 3是其芳环上具有6至20个碳原子的二价芳族烃基（在芳族化合物中提供氢原子芳香族烃基的环可以被卤原子或碳原子数为1〜4的烷基或烷氧基取代），通过加成酰化剂使低聚物酰化的第二工序，以及使第酰化低聚物，其中在第二步骤完成之前，式HOR 4 OH（C）的二羟基化合物其中R 4具有与式A中的R 1相同的含义，或式C化合物和二羧酸加入其中R 5具有与式A中的R 1相同含义的下式的HOOCR 5 COOH（D）的酸反应。

7. 发明授权

US4661581A Process for producing aromatic polyether ketones and polythioether ketones 失效
标题翻译：制备芳香族聚醚酮和聚硫醚酮的方法
公开(公告)号：US4661581A
公开(公告)日：1987-04-28
申请号：US656325
申请日：1984-10-01
申请人： Seiichi Nozawa , Michio Nakata
发明人： Seiichi Nozawa , Michio Nakata
IPC分类号： C08G61/12 , C08G67/00 , C08G75/02 , C08G63/62
CPC分类号： C08G61/127 , C08G67/00 , C08G75/024
摘要： A process for producing aromatic polyether ketones and polythioether ketones, which comprises reacting aromatic ethers or thioethers represented by the general formula: ##STR1## where each of R.sup.1 to R.sup.12 is a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group, n is an integer of 0 to 5, and X is an oxygen atom or a sulfur atom, with phosgene in aprotic solvent having a dielectric constant of lower than 20 and a dipole moment of lower than 3.0 in the presence of anhydrous halides of metals of Group III in the periodic table as a catalyst.
摘要翻译：一种制备芳族聚醚酮和聚硫醚酮的方法，其包括使由下列通式表示的芳族醚或硫醚：其中R 1至R 12各自为氢原子，卤素原子，烃基或烷氧基， n为0〜5的整数，X为氧原子或硫原子，在非质子传递溶剂中的光气的介电常数低于20，偶极矩低于3.0，在无水金属卤化物周期表中的III族作为催化剂。

8. 发明授权

US4520208A Aromatic polyester containing phenolphthalein unit and bis-phenol unit 失效
标题翻译：芳香族聚酯含酚酞单元和双酚单元
公开(公告)号：US4520208A
公开(公告)日：1985-05-28
申请号：US505494
申请日：1983-06-17
申请人： Masahiro Hayashi , Seiichi Nozawa , Takashi Oikawa
发明人： Masahiro Hayashi , Seiichi Nozawa , Takashi Oikawa
IPC分类号： C08G63/193 , C07D307/78
CPC分类号： C08G63/193
摘要： An aromatic polyester comprising two structural units represented by the following formulas A and B in a molar ratio of the structural unit A to the structural unit B being from 70:30 to 90:10 or four structural units represented by the following formulas A, B, C and D in a molar ratio of the total of the structural units A and C to the total of the structural units B and D being from 10:90 to 95:5 and the total of the structural units C and D being less than 50 molar %, and having a reduced viscosity .eta.sp/C of from 0.6 to 4 dl/g as measured at 30.degree. C. at a concentration of 1.0 g/dl in a solution of a mixture comprising phenol and tetrachloroethane in a weight ratio of 1:1, ##STR1##
摘要翻译：包含由结构单元A与结构单元B的摩尔比分别由下式A和B表示的两个结构单元的芳族聚酯为70:30至90:10，或由下式A，B表示的四个结构单元 C和D的结构单元A和C的总量与结构单元B和D的总量的摩尔比为10:90至95:5，并且结构单元C和D的总和小于 50摩尔％，并且在30℃下以1.0g / dl的浓度在包含苯酚和四氯乙烷的混合物的溶液中测量的具有0.6-4d / g的比浓粘度eta sp / C的重量比（A）结构单元B：（B）结构单元C：（C）和结构单元D：（D）

9. 发明授权

US4246396A Process for producing polyoxymethylene 失效
标题翻译：生产聚甲醛的方法
公开(公告)号：US4246396A
公开(公告)日：1981-01-20
申请号：US90472
申请日：1979-11-01
申请人： Ikuo Sukegawa , Seiichi Nozawa , Seiichi Mukai , Masaharu Shikama
发明人： Ikuo Sukegawa , Seiichi Nozawa , Seiichi Mukai , Masaharu Shikama
IPC分类号： C08G2/00 , C08G2/06 , C08G2/08 , C08G2/30 , C08K5/49
CPC分类号： C08G2/08 , C08G2/06
摘要： Polyoxymethylene having high molecular weight and high thermal stability is produced by polymerizing formaldehyde in the presence of a specific catalyst and then heating the resulting polyoxymethylene. The specific catalyst is produced by contacting a phosphorus containing compound or an amine (c) with a reaction product obtained by reacting salicylic acid component (b) with an organoaluminum compound (a) having the formula ##STR1## wherein R.sup.1 represents an alkyl or alkoxyl group and R.sup.2 and R.sup.3 respectively represent alkyl or alkoxyl group or a halogen atom.
摘要翻译：具有高分子量和高热稳定性的聚甲醛通过在特定催化剂存在下聚合甲醛，然后加热得到的聚甲醛来制备。通过使含磷化合物或胺（c）与水杨酸组分（b）与具有式（I）的有机铝化合物（a）反应得到的反应产物接触而制备特定催化剂，其中R1表示烷基或烷氧基，R2和R3分别表示烷基或烷氧基或卤素原子。

10. 发明授权

US4158729A Process for producing polyoxymethylene 失效
标题翻译：生产聚甲醛的方法
公开(公告)号：US4158729A
公开(公告)日：1979-06-19
申请号：US891838
申请日：1978-03-30
申请人： Harutaka Kimura , Seiichi Nozawa , Seiichi Mukai , Masaharu Shikama
发明人： Harutaka Kimura , Seiichi Nozawa , Seiichi Mukai , Masaharu Shikama
IPC分类号： C08G2/06 , C08G2/08
CPC分类号： C08G2/06 , C08G2/08
摘要： Polyoxymethylene is produced by polymerizing formaldehyde in the presence of a catalyst comprising a catalytic component of an organoaluminum compound or a complex thereof supported on a modifier of a higher carboxylic acid amide compound.The organoaluminum compound can be in a form of a complex of the organoaluminum compound and a phosphorus compound or an amine.
摘要翻译：聚甲醛是通过在负载在高级羧酸酰胺化合物的改性剂上的有机铝化合物或其配合物的催化剂组分的催化剂存在下聚合甲醛来制备的。

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