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1. 发明授权

US06849667B2 Foam of thermoplastic urethane elastomer composition and process for producing the foam 有权
标题翻译：热塑性聚氨酯弹性体组合物的泡沫和泡沫的制造方法
公开(公告)号：US06849667B2
公开(公告)日：2005-02-01
申请号：US10148998
申请日：2001-10-11
申请人： Ryuuji Haseyama , Masahiko Hashiba , Kaoru Yorita , Shigeo Nishikawa , Yoko Shimada
发明人： Ryuuji Haseyama , Masahiko Hashiba , Kaoru Yorita , Shigeo Nishikawa , Yoko Shimada
IPC分类号： B29C44/34 , C08G18/08 , C08J9/12 , C08G18/28
CPC分类号： C08J9/122 , B29C44/348 , C08G18/14 , C08G2101/00 , C08J2203/08 , C08J2375/04
摘要： The method of the present invention for producing a urethane-based thermoplastic elastomer composition foam comprises the steps of: adding and mixing 0.1 to 30 parts by weight of carbon dioxide (B) to 100 parts by weight of a urethane-based thermoplastic elastomer composition (A) in a molten state, wherein said urethane-based thermoplastic elastomer composition (A) comprises a urethane-based thermoplastic elastomer (A-1) and other thermoplastic elastomer (A-2) in an (A-1)/(A-2) ratio of 20/80 to 99/1 by weight, to form a molten urethane-based thermoplastic elastomer composition (C) which is in a state of a mixture of the urethane-based thermoplastic elastomer composition (A) and the carbon dioxide (B) (gas dissolving step); and lowering a temperature of said molten urethane-based thermoplastic elastomer composition (C) (cooling step). The present invention can produce the urethane-based thermoplastic elastomer foam of stable quality over a range from low foamed product to highly foamed product by adding a given quantity of carbon dioxide in the molten urethane-based thermoplastic elastomer quantitatively and stably. It can also produce the foam excellent in flexibility, thermal insulation and surface appearances. It is also excellent in safety, because of use of carbon dioxide in place of the common foaming agent of fluorochlorohydrocarbon or butane, thus causing no air pollution or destruction of the ozone layer.
摘要翻译：本发明的氨基甲酸酯类热塑性弹性体组合物泡沫体的制造方法包括以下步骤：将0.1〜30重量份的二氧化碳（B）与100重量份的氨基甲酸酯类热塑性弹性体组合物（A-1）/（A-（A-1））中的氨基甲酸乙酯系热塑性弹性体（A-1）和其他热塑性弹性体（A-2） 2）比为20/80〜99/1，形成处于氨基甲酸酯类热塑性弹性体组合物（A）和二氧化碳（A）的混合状态的熔融氨基甲酸酯类热塑性弹性体组合物（C）（B）（气体溶解步骤）; 所述熔融氨基甲酸酯类热塑性弹性体组合物（C）的温度下降（冷却工序）。本发明可以通过添加给定的低发泡产品至高度发泡的产品，从而生产质量稳定的氨基甲酸酯类热塑性弹性体泡沫体定量稳定地熔融氨基甲酸酯类热塑性弹性体中的二氧化碳量。它还可以产生柔韧性，绝热性和表面外观优异的泡沫。由于使用二氧化碳代替氟代氯代烃或丁烷的普通发泡剂，所以安全性也优异，因此不会造成空气污染或破坏臭氧层。

2. 发明授权

US06328916B1 Addition method of supercritical carbon dioxide, and production process of expanded thermoplastic resin product by making use of the addition method 有权
标题翻译：超临界二氧化碳的添加方法，以及通过添加方法生产膨胀热塑性树脂制品的方法
公开(公告)号：US06328916B1
公开(公告)日：2001-12-11
申请号：US09351336
申请日：1999-07-12
申请人： Shigeo Nishikawa , Eiichi Sugihara , Masahiro Takedachi , Kaoru Yorita , Haruo Inoue , Yoko Shimada , Michio Eriguchi
发明人： Shigeo Nishikawa , Eiichi Sugihara , Masahiro Takedachi , Kaoru Yorita , Haruo Inoue , Yoko Shimada , Michio Eriguchi
IPC分类号： B29C4402
CPC分类号： B29C44/348 , B29C44/3446
摘要： This invention provides a method for stably adding a predetermined amount of supercritical carbon dioxide at a fixed delivery rate into a forming machine and also a process for producing an expanded thermoplastic resin product by making use of the addition method. Carbon dioxide is charged from a liquefied carbon dioxide cylinder (1) into a predetermined amount deliverable pump (2) while allowing the carbon dioxide to remain in a liquefied state. When the carbon dioxide is pressurized and delivered by the predetermined amount deliverable pump (2), a delivery pressure of the carbon dioxide is controlled at an optional pressure within a range of from a critical pressure (7.4 MPa) of carbon dioxide to 40 MPa to deliver the carbon dioxide without any fluctuation of the amount of the delivery by setting up the pressure of a pressure control valve (3). The carbon dioxide is heated to a critical temperature (31° C.) of carbon dioxide or higher to convert it into supercritical carbon dioxide. This supercritical carbon dioxide is then added to a molten thermoplastic resin in the forming machine (4).
摘要翻译：本发明提供了一种以固定的输送速率将预定量的超临界二氧化碳稳定地添加到成形机中的方法，以及通过使用添加方法制造发泡热塑性树脂产品的方法。二氧化碳从液化二氧化碳气瓶（1）装入预定量的输送泵（2）中，同时使二氧化碳保持在液化状态。当二氧化碳被预定量的可输送泵（2）加压和输送时，二氧化碳的输送压力被控制在从二氧化碳的临界压力（7.4MPa）到40MPa的范围内的任选压力到通过设置压力控制阀（3）的压力来输送二氧化碳而没有输送量的任何波动。将二氧化碳加热至二氧化碳或更高的临界温度（31℃）以将其转化为超临界二氧化碳。然后将该超临界二氧化碳加入到成形机（4）中的熔融热塑性树脂中。

3. 发明授权

US06303666B1 Process for the production of expanded olefinic thermoplastic elastomer products 有权
标题翻译：生产膨胀型烯烃热塑性弹性体产品的方法
公开(公告)号：US06303666B1
公开(公告)日：2001-10-16
申请号：US09359745
申请日：1999-07-23
申请人： Kaoru Yorita , Eiichi Sugihara , Masahiro Takedachi , Haruo Inoue , Shigeo Nishikawa , Yoko Shimada , Michio Eriguchi , Takanori Sueda , Akira Uchiyama , Yuichi Ito
发明人： Kaoru Yorita , Eiichi Sugihara , Masahiro Takedachi , Haruo Inoue , Shigeo Nishikawa , Yoko Shimada , Michio Eriguchi , Takanori Sueda , Akira Uchiyama , Yuichi Ito
IPC分类号： C08J900
CPC分类号： C08J9/0061 , C08J9/122 , C08J2201/03 , C08J2203/08 , C08J2323/16 , C08J2423/00 , C08L23/02 , C08L23/10 , C08L23/16 , C08L2203/14 , C08L2666/04
摘要： A process is provided for the production of expanded olefinic thermoplastic elastomer product having good external appearance, flexibility and heat resistance. This process features using, as raw materials, a particular olefinic thermoplastic elastomer and carbon dioxide as a blowing agent.
摘要翻译：提供了具有良好的外观，柔韧性和耐热性的膨胀的烯烃类热塑性弹性体制品的制造方法。该方法特征在于使用特定的烯属热塑性弹性体和作为发泡剂的二氧化碳作为原料。

4. 发明授权

US5997781A Injection-expansion molded, thermoplastic resin product and production process thereof 失效
标题翻译：注塑膨胀成型，热塑性树脂制品及其制造方法
公开(公告)号：US5997781A
公开(公告)日：1999-12-07
申请号：US829603
申请日：1997-03-31
申请人： Shigeo Nishikawa , Kaoru Yorita , Kouzo Ichikawa , Haruo Inoue , Michio Eriguchi , Takanori Sueda , Hideo Amemiya
发明人： Shigeo Nishikawa , Kaoru Yorita , Kouzo Ichikawa , Haruo Inoue , Michio Eriguchi , Takanori Sueda , Hideo Amemiya
IPC分类号： B29C44/04 , B29C44/34 , B29C44/42 , C08J9/12 , B29D67/20
CPC分类号： B29C44/348 , B29C44/0415 , B29C44/421 , C08J9/122 , Y02P20/544 , Y10S264/13
摘要： Disclosed is a process for the production of an injection-expansion molded, thermoplastic resin product. The process comprises a gas dissolving step, a cooling step, a metering and injection step, and an expansion controlling step. Specifically, a thermoplastic resin is molten in a continuous plasticator (1), supercritical carbon dioxide and/or nitrogen is added as a blowing agent, and the blowing agent and the thermoplastic resin are formed into a mutually-dissolved state. The resultant molten resin composition is cooled within the plasticator while maintaining a pressure equal to or higher than a critical pressure of the blowing agent. The thus-cooled molten resin composition is metered by an injector (7) and is filled in a mold (8). An internal pressure of the mold is lowered beyond the critical pressure of the blowing agent to produce cell nuclei, whereby the cell diameter is controlled. The blowing agent is maintained in a supercritical state up to the metering and injection step.
摘要翻译：公开了一种用于生产注射膨胀模制的热塑性树脂产品的方法。该方法包括气体溶解步骤，冷却步骤，计量和注入步骤以及膨胀控制步骤。具体地说，热塑性树脂在连续塑化器（1）中熔融，加入超临界二氧化碳和/或氮作为发泡剂，发泡剂和热塑性树脂形成相互溶解状态。将所得熔融树脂组合物在塑化器内冷却，同时保持等于或高于发泡剂临界压力的压力。如此冷却的熔融树脂组合物由注射器（7）计量并填充在模具（8）中。模具的内部压力降低到超过发泡剂的临界压力以产生细胞核，从而控制细胞直径。发泡剂维持在超临界状态直到计量和注射步骤。

5. 发明授权

US5830393A Process for preparing expanded product of thermoplastic resin 失效
标题翻译：制备热塑性树脂膨胀产品的方法
公开(公告)号：US5830393A
公开(公告)日：1998-11-03
申请号：US887323
申请日：1997-07-02
申请人： Shigeo Nishikawa , Kaoru Yorita , Kouzo Ichikawa , Haruo Inoue , Michio Eriguchi , Takanori Sueda , Hideo Amemiya
发明人： Shigeo Nishikawa , Kaoru Yorita , Kouzo Ichikawa , Haruo Inoue , Michio Eriguchi , Takanori Sueda , Hideo Amemiya
IPC分类号： B29C44/34 , B29C44/46 , B29D27/00
CPC分类号： B29C44/461 , B29C44/3446 , B29C44/348 , Y10S264/13
摘要： A process for preparing an expanded product of a thermoplastic resin which includes a gas dissolving step of adding supercritical carbon dioxide and/or nitrogen as an blowing agent to a thermoplastic resin, and melting it in the thermoplastic resin, a cooling step of cooling the resulting molten resin composition under a pressure not less than a critical pressure of the blowing agent, a nuclei forming step of discharging the molten resin composition from a die to lower the pressure to a level not more than the critical pressure, and an expansion controlling step of cooling an expanded product of the thermoplastic resin to a level not more than a glass transition temperature or a crystallization temperature of the resin to control a cell diameter of the expanded product.
摘要翻译：一种制备热塑性树脂的发泡产品的方法，包括将超临界二氧化碳和/或氮气作为发泡剂加入到热塑性树脂中并在热塑性树脂中熔化的气体溶解步骤，冷却步骤，在不低于发泡剂的临界压力的压力下的熔融树脂组合物，将熔融树脂组合物从模具中排出以将压力降低到临界压力以下的成核步骤，以及膨胀控制步骤将热塑性树脂的发泡产品冷却至不超过树脂的玻璃化转变温度或结晶温度的水平，以控制膨胀产品的泡孔直径。

6. 发明申请

US20050214559A1 Molded object obtained by in-mold coating and process for producing the same 失效
标题翻译：通过模内涂布获得的成型体及其制造方法
公开(公告)号：US20050214559A1
公开(公告)日：2005-09-29
申请号：US10525383
申请日：2003-08-21
申请人： Takeshi Minoda , Yuichi Matsuda , Kaoru Yorita , Kenji Yonemochi , Kenji Oota , Etsuo Okahara , Toshio Arai
发明人： Takeshi Minoda , Yuichi Matsuda , Kaoru Yorita , Kenji Yonemochi , Kenji Oota , Etsuo Okahara , Toshio Arai
IPC分类号： B29C37/00 , B29C45/16 , C08J5/00 , B32B27/30 , B32B27/32
CPC分类号： B29C37/0028 , B29C45/1679 , C08J5/00 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： An in-mold coating molded article is obtained by coating the surface of a resin molded product comprising a hydroxyl group-containing polypropylene resin composition (A) with a paint composition for in-mold coating, wherein the composition (A) comprises a polypropylene resin (i), an additive rubber (ii) and optionally a polymer compound (iii) other than the polypropylene resin (i) and the additive rubber (ii), the total hydroxyl value of the polypropylene resin (i), the additive rubber (ii) and the optional polymer compound (iii) is from 1 to 40, the composition (A) has a rubber component content (total of the amount of the additive rubber (ii) and the amount of components soluble in n-decane at 23° C. of the polypropylene resin (i) and the optional polymer compound (iii)) of from 15 to 80% by mass based on 100% by mass of the total amount of the rubber component and the resin component other than the rubber component, the paint composition comprises a vehicle component comprising 10 to 70% by mass of an oligomer having at least two (meth)acrylate groups and 90 to 30% by mass of an ethylenically unsaturated monomer copolymerizable with the oligomer, a (meth)acryl modified chlorinated polyolefin having a chlorine content of from 2 to 40% by mass, an organic peroxide polymerization initiator, and a polyisocyanate compound in a specific proportion. In the process for preparing the article, the article is prepared by injection molding method, injection compression molding method or injection press molding method. Accordingly, there can be provided an in-mold coating molded article such that the paint composition is monolithically formed on the surface of the resin molded product of the composition with good adhesion and a process for preparing the same.
摘要翻译：通过将包含含羟基的聚丙烯树脂组合物（A）的树脂成型体的表面与用于模内涂布的涂料组合物进行涂布而获得模内涂布成型体，其中，组合物（A）含有聚丙烯树脂（i），除了聚丙烯树脂（i）和添加剂橡胶（ii）以外的添加剂橡胶（ii）和任选的高分子化合物（iii），聚丙烯树脂（i），添加剂橡胶 ii）和任选的聚合物化合物（iii）为1至40，组合物（A）的橡胶组分含量（添加剂橡胶（ii）的总量）和可溶于正癸烷的组分的量在23 相对于橡胶成分和除了橡胶成分以外的树脂成分的总量的100质量％，聚丙烯树脂（i）和任选的高分子化合物（iii）的含量为15〜80质量％，所述涂料组合物包含包含10的载体组分至70质量％的具有至少两个（甲基）丙烯酸酯基的低聚物和90〜30质量％的可与低聚物共聚的烯键式不饱和单体，具有氯含量为2〜（甲基）丙烯酸改性氯化聚烯烃 40质量％，有机过氧化物聚合引发剂和特定比例的多异氰酸酯化合物。在制品制备过程中，制品采用注射成型法，注射成型法或注射成型法制备。因此，可以提供一种模内涂布模制品，使得涂料组合物在组合物的树脂模制产品的表面上以良好的粘合力整体形成，以及其制备方法。

7. 发明授权

US07482063B2 Molded object obtained by in-mold coating and process for producing the same 失效
标题翻译：通过模内涂布获得的成型体及其制造方法
公开(公告)号：US07482063B2
公开(公告)日：2009-01-27
申请号：US10525383
申请日：2003-08-21
申请人： Takeshi Minoda , Yuichi Matsuda , Kaoru Yorita , Kenji Yonemochi , Kenji Oota , Etsuo Okahara , Toshio Arai
发明人： Takeshi Minoda , Yuichi Matsuda , Kaoru Yorita , Kenji Yonemochi , Kenji Oota , Etsuo Okahara , Toshio Arai
IPC分类号： B32B25/04 , B32B27/26 , B32B27/30 , B32B27/32 , B32B37/10
CPC分类号： B29C37/0028 , B29C45/1679 , C08J5/00 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： An in-mold coating molded article is obtained by coating the surface of a resin molded product comprising a hydroxyl group-containing polypropylene resin composition (A) with a paint composition for in-mold coating, wherein the composition (A) comprises a polypropylene resin (i), an additive rubber (ii) and optionally a polymer compound (iii) other than the polypropylene resin (i) and the additive rubber (ii), the total hydroxyl value of the polypropylene resin (i), the additive rubber (ii) and the optional polymer compound (iii) is from 1 to 40, the composition (A) has a rubber component content (total of the amount of the additive rubber (ii) and the amount of components soluble in n-decane at 23° C. of the polypropylene resin (i) and the optional polymer compound (iii)) of from 15 to 80% by mass based on 100% by mass of the total amount of the rubber component and the resin component other than the rubber component, the paint composition comprises a vehicle component comprising 10 to 70% by mass of an oligomer having at least two (meth)acrylate groups and 90 to 30% by mass of an ethylenically unsaturated monomer copolymerizable with the oligomer, a (meth)acryl modified chlorinated polyolefin having a chlorine content of from 2 to 40% by mass, an organic peroxide polymerization initiator, and a polyisocyanate compound.
摘要翻译：通过将包含含羟基的聚丙烯树脂组合物（A）的树脂成型体的表面与用于模内涂布的涂料组合物进行涂布而获得模内涂布成型体，其中，组合物（A）含有聚丙烯树脂（i），除了聚丙烯树脂（i）和添加剂橡胶（ii）以外的添加剂橡胶（ii）和任选的高分子化合物（iii），聚丙烯树脂（i），添加剂橡胶 ii）和任选的聚合物化合物（iii）为1至40，组合物（A）的橡胶组分含量（添加剂橡胶（ii）的总量）和可溶于正癸烷的组分的量在23 相对于橡胶成分和除了橡胶成分以外的树脂成分的总量的100质量％，聚丙烯树脂（i）和任选的高分子化合物（iii）的含量为15〜80质量％，所述涂料组合物包含包含10的载体组分至70质量％的具有至少两个（甲基）丙烯酸酯基的低聚物和90〜30质量％的可与低聚物共聚的烯键式不饱和单体，具有氯含量为2〜（甲基）丙烯酸改性氯化聚烯烃 40质量％，有机过氧化物聚合引发剂和多异氰酸酯化合物。

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