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    • 4. 发明授权
    • Reactive dyes, process for their preparation and use thereof
    • 活性染料,其制备方法和用途
    • US4631065A
    • 1986-12-23
    • US767246
    • 1985-08-20
    • Karl SeitzPeter ScheibliHerbert Seiler
    • Karl SeitzPeter ScheibliHerbert Seiler
    • C09B62/085C09B62/02C09B62/165C09B62/17C09B62/245C09B62/25D06P3/00D06P3/66
    • C09B62/02Y10S8/918
    • The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.
    • 本发明涉及式(1)的活性染料,其中D是单偶氮或多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,二苯乙烯,三苯甲烷,呫吨的染料的基团 ,噻吨酮,硝基芳基,萘醌,芘醌或苝四碳酰亚胺系列,R 1和R 2各自独立地为氢或未取代或取代的C 1 -C 4烷基,X 1为未取代或取代的氨基氟三嗪基,X 2为杂环反应性基团 除了未取代或取代的氨基氟三嗪以外,它直接通过-N(R2)桥连接在基团D上。 这些染料特别适用于通过冷垫分批法对纤维素纤维材料进行染色和印花,并提供良好的牢度性能和高着色强度的染色和印花。
    • 5. 发明授权
    • Process for the staining of wood with aqueous wood stains
    • 用木材污渍染色木材的方法
    • US06630002B2
    • 2003-10-07
    • US09850493
    • 2001-05-07
    • Stefan KollerPeter Scheibli
    • Stefan KollerPeter Scheibli
    • D06P362
    • C09D15/00
    • The present invention relates to a process for the staining of wood, which comprises treating the unstained wood with an aqueous preparation comprising a) at least one dye, and b) at least one dye stabilizer of the formula (I) or (II)  in which G1 and G2, independently of one another, are C1-C4alkyl or together are pentamethylene, Z1 and Z2 are methyl, or Z1 and Z2 form a bridging member which is unsubstituted or substituted by an ester, ether, hydroxyl, oxo, cyanohydrin, amido, amino, carboxyl or urethane radical, E is oxyl or hydroxyl, and X is an inorganic or organic anion, and the total number of cations h corresponds to the total number of anions j, to a wood stain comprising a dye and a dye stabilizer of the formula (I) or (II), and to the use of this wood stain for the staining of wood.
    • 本发明涉及木材染色方法,其包括用含有a)至少一种染料的水性制剂处理未染色的木材,和b)至少一种式(I)或(II)的染料稳定剂,其中G 1和 G2彼此独立地是C1-C4烷基或一起是五亚甲基,Z1和Z2是甲基,或Z1和Z2形成未被取代或被酯,醚,羟基,氧代,羟腈,酰氨基,氨基 ,羧基或氨基甲酰基,E是氧基或羟基,X是无机或有机阴离子,并且阳离子总数h对应于阴​​离子总数j,包括染料和染料稳定剂的木材染色剂 式(I)或(II),以及该木材染色剂用于木材染色的用途。
    • 9. 发明授权
    • Reactive disazo dyes which contain two aminofluoro-1,3,5-triazinyl
radicals
    • 含有两个氨基磺酰基-1,3,5-三嗪基的反应性灭菌剂
    • US5073631A
    • 1991-12-17
    • US246031
    • 1988-09-14
    • Peter Scheibli
    • Peter Scheibli
    • C09B62/09D06P1/382
    • C09B62/09
    • Reactive dyes of the formulaX.sub.1 --NH--CH.sub.2).sub.0-1 A--N.dbd.N--M--N.dbd.N--B--CH.sub.2).sub.0-1 NH--X.sub.2 (1)in which M is twice-coupled 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4-sulfonic acid or 2-amino-5-hydroxynaphthalene-7-sulfonic acid, A and B, independently of each other, are each unsubstituted or substituted phenylene or naphthylene, and X.sub.1 and X.sub.2, independently of each other, are each unsubstituted or substituted amino-fluoro-1,3,5-triazinyl, excluding the reactive dyes of German Offenlegungsschrift 2,738,823, are suitable in particular for dyeing and printing cellulose-containing fibre materials and produce, combined with a high dyeing yield, dyeings and prints having good fastness properties.
    • 式X1-NH-CH2)0-1A-N = NMN = NB-CH2)的反应性染料0-1NH-X2(1)其中M是2-氨基-8-羟基萘-3,6-二 二磺酸,1-氨基-8-羟基萘-4,6-二磺酸,1-氨基-8-羟基萘-4-磺酸或2-氨基-5-羟基萘-7-磺酸A和B,独立地 彼此独立地为未取代或取代的亚苯基或亚萘基,X1和X2彼此独立地为未取代或取代的氨基 - 氟-1,3,5-三嗪基,不包括德国Offenlegungsschrift 2,738,823的活性染料是合适的 特别是用于染色和印刷含纤维素的纤维材料并且产生高染色性,染色和具有良好牢度性能的印花。
    • 10. 发明授权
    • Fibre-reactive azo dyes containing vinylsulfonyl groups and further
aliphatic fibre-reactive radicals
    • US4908436A
    • 1990-03-13
    • US921849
    • 1986-10-23
    • Peter Scheibli
    • Peter Scheibli
    • C09B62/006C09B62/44C09B62/47C09B62/507C09B62/51C09B62/513C09B62/523C09B62/78
    • C09B62/4411
    • A reactive dye of the formula ##STR1## or of the formula ##STR2## or of the formula ##STR3## in which D, D.sub.1 and D.sub.2 are each phenylene or naphthylene unsubstituted or substituted by alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, carboxylic acylamino having 1 to 8 carbon atoms, amino, alkylamino having 1 to 4 carbon atoms, phenylamino, N,N-di-.beta.-hydroxyethylamino, N,N-di-.beta.-sulfatoethylamino, sulfobenzylamino, N,N-disulfobenzylamino, alkoxycarbonyl having 1 to 4 carbon atoms in the alkoxy radical, alkylsulfonyl having 1 to 4 carbon atoms, trifluoromethyl, nitro, cyano, halogen, carbamoyl, N-alkylcarbamoyl having 1 to 4 carbon atoms in the alkyl radical, sulfamoyl N-alkylsulfamoyl having 1 to 4 carbon atoms, N-(.beta.-hydroxyethyl)-sulfamoyl, N,N-di-(.beta.-hydroxyethyl)-sulfamoyl, N-phenylsulfamoyl, ureido hydroxyl, carboxyl, sulfomethyl, or sulfo, R.sub.1 is hydrogen or C.sub.1-4 -alkyl unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1-4 -alkoxy, methoxycarbonyl, ethoxycarbonyl, sulfamoyl, sulfato, carboxyl or sulfo, R.sub.2 is (1) hydrogen, (2) alkyl unsubstituted or substituted by halogen, hydroxy, cyano, alkoxy, methoxycarbonyl, ethoxycarbonyl, sulfamoyl, sulferto, carboxy or sulfo, (3) cyclohexyl, (4) phenyl unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine, carboxyl, sulfo or sulfomethyl, or (5) a radical of the formula --alk--SO.sub.2 --Z, E--NH.sub.2, --CH.sub.3, --NH--CO--NH.sub.2, --NH--CO--CH.sub.3 or --NH--CO--CH.sub.2 --OH, wherein alk is C.sub.2-6 --alkylene, Y is --SO.sub.2 --Z, --SO.sub.2 --N(R.sub.1)--Z, --N--(R.sub.1)--SO.sub.2 --Z, --N(R.sub.1)--CO--(CH.sub.2).sub.3-5 SO.sub.2 --Z, --SO.sub.2 --F, --SO.sub.2 CH.sub.2 --CH.dbd.CH.sub.2, --N(R.sub.1)--CO--CBr.dbd.CH.sub.2, --N(R.sub.1)--CO--CHBr--CH.sub.2 Br, --N(R.sub.1)--CO--CCl.dbd.CH.sub.2, --N(R.sub.1)--CO--CHCl--CH.sub.2 Cl, --N(R.sub.1)--CO--CH.sub.2 Cl or --N(R.sub.1)--CO--CH.dbd.CH.sub.2, Z is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --A, A is --OSO.sub.3 H, --SSO.sub.3 H, --OCOCH.sub.3, --OPO.sub.3 H.sub.2, --Cl, --Br or --F, and X is fluorine, chlorine or hydroxyl.