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    • 4. 发明授权
    • Black-dyeing inks and their use
    • US07057024B2
    • 2006-06-06
    • US10060833
    • 2002-01-30
    • Urs LehmannAthanassios TzikasMarcel Frick
    • Urs LehmannAthanassios TzikasMarcel Frick
    • C09B62/04C09B62/095D06P1/382
    • C09D11/32C09B43/16C09B62/04C09B62/4403C09B67/0041C09B67/0046C09D11/17C09D11/18C09D11/328D06P5/30
    • Black-dyeing aqueous inks comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the abovementioned formula (V), (VI), (VII) or (VIII) and one or more radicals of the abovementioned formula (I), (II), (III) or (IV), in which (G)0-2 is 0 to 2 identical or different substituents from the group consisting of substituted or unsubstituted amino, hydroxyl and nitro, L is substituted or unsubstituted amino, R is halogen, C1–C4alkyl, C1–C4alkoxy, C2–C4alkanoylamino, hydroxyl, carboxyl, nitro or cyano, (V)0-2 is 0 to 2 identical or different substituents from the group consisting of halogen, C1–C4alkyl, C1–C4alkoxy, β-sulfatoethylsulfonyl and sulfo, (W)0-1 is an N-acyl radical, if any, n is the number 0, 1, 2 or 3, m is the number 1, 2 or 3 and r and q are the number 0 or 1. The inks according to the invention are distinguished by good black shades without a change in shade in artificial light (metamerism) and an outstanding fastness to light.
    • 5. 发明授权
    • Magenta inks comprising copper complex azo dyes based on 1-naphthol-di- or tri-sulfonic acids
    • 洋红色油墨包含基于1-萘酚二 - 或三磺酸的铜络合偶氮染料
    • US06521032B1
    • 2003-02-18
    • US09669464
    • 2000-09-25
    • Urs LehmannMarcel Frick
    • Urs LehmannMarcel Frick
    • C09D1100
    • C09D11/328C09B45/18C09B62/515C09B67/0041C09B67/0054C09B67/0073C09B69/045
    • Inks comprising a dye of formula (1) wherein X is hydroxy, unsubstituted or hydroxy-substituted C1-C4alkyl, vinyl or a radical —CH2—CH2—Z, wherein Z is a group removable under alkaline conditions or is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24alkylamino unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or unsubstituted or further substituted C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino unsubstituted or substituted in the aryl moiety; morpholino; piperidin-1-yl; or piperazin-1-yl unsubstituted or substituted at the nitrogen atom; or X has the same definitions as Z with the exception of a group removable under alkaline conditions; R is C1-C4alkyl, C1-C4alkoxy or halogen; and m and n are each independently of the other the number 0, 1 or 2; and an organic solvent, yield magenta prints and dyeings having good fastness to light and a high colour brilliance.
    • 油包括式(1)的染料,其中X是羟基,未取代的或羟基取代的C 1 -C 4烷基,乙烯基或基团-CH 2 -CH 2 -Z,其中Z是在碱性条件下可除去的基团或者是未被取代或取代的C 1 -C 24烷氧基 在烷基部分中,其可以通过氧进一步在烷基部分中断; 在苯环中未取代或取代的苯氧基; 在烷基部分未取代或取代的C 1 -C 4烷硫基; 在苯环中未取代或取代的苯硫基; 氨基; 在烷基部分中未被取代或被取代的N-单或N,N-二-C 1 -C 24烷基氨基,其可以在烷基部分中被氧或由-NR 1 - 或其未取代或进一步取代的-NR 1 - C 1 -C 4烷基; C10-C20萜氨基; 在环烷基环中未取代或取代的C 5 -C 7环烷基氨基; 在芳基部分未被取代或取代的苯基或萘基 - 氨基或N-C 1 -C 4烷基-N-苯基 - 或N-C 1 -C 4烷基-N-萘基 - 氨基; 吗啉代 哌啶-1-基; 或在氮原子上被取代或取代的哌嗪-1-基;或X具有与Z相同的定义,除了在碱性条件下可除去的基团; R是C 1 -C 4烷基,C 1 -C 4烷氧基或卤素; 和n和n分别独立于数字0,1或2; 和有机溶剂,产生具有良好的耐光牢度和高色泽的洋红色印花和染色。
    • 7. 发明授权
    • Dye mixtures, 1:2 cobalt complex formazan dyes and their use
    • 染料混合物,1:2钴络合物甲an染料及其用途
    • US06551364B2
    • 2003-04-22
    • US09790782
    • 2001-02-22
    • Urs LehmannMarcel Frick
    • Urs LehmannMarcel Frick
    • D06P110
    • C09B50/00C09B67/0033C09B67/0041Y10S8/918Y10S8/924
    • Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.
    • X为取代或未取代的C 1 -C 8烷基,苯基,萘基,呋喃基或噻吩基,R 1和R 2彼此独立地为甲基的甲an化合物的至少一种1:2钴络合物染料的染料混合物为氢或取代或 未取代的C 1 -C 8烷基,苯基或萘基,m为1至4的数,并且环I,II,III和IV可以与至少一种如权利要求1所定义的式(2)的蒽醌染料一起进一步取代, 或与至少一种含有由所定义的式(3),(4),(5)和(6)的化合物组成的组的两种相同或不同的偶氮化合物的1:2铬或1:2钴配合物染料一起使用。 在权利要求1中;和新颖的1:2钴络合物甲an染料。染料混合物特别适用于染色或印刷天然和合成的聚酰胺纤维材料,获得具有良好牢度的染色或印花。
    • 8. 发明授权
    • Dye mixtures, 1:2 cobalt complex formazan dyes and their use
    • 染料混合物,1:2钴络合物甲an染料及其用途
    • US06428582B1
    • 2002-08-06
    • US08592898
    • 1996-01-29
    • Urs LehmannMarcel Frick
    • Urs LehmannMarcel Frick
    • C09B5000
    • C09B50/00C09B67/0033C09B67/0041
    • Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.
    • X为取代或未取代的C 1 -C 8烷基,苯基,萘基,呋喃基或噻吩基,R 1和R 2彼此独立地为甲基的甲an化合物的至少一种1:2钴络合物染料的染料混合物为氢或取代或未取代的 C 1 -C 8烷基,苯基或萘基,m是1至4的数,并且环I,II,III和IV可以与至少一种如权利要求1所定义的式(2)的蒽醌染料一起进一步取代,或 以及来自包含式(3),(4),(5)和(6)的化合物的两种相同或不同的偶氮化合物的至少一种1:2铬或1:2钴络合物染料,如 权利要求1;和新颖的1:2钴络合物甲an染料。染料混合物特别适用于染色或印刷天然和合成聚酰胺纤维材料,获得具有良好牢度的染色或印花。
    • 9. 发明授权
    • Addition products of acryloylamino-substituted dyes, and the preparation and use thereof
    • 丙烯酰氨基取代染料的添加产物及其制备和应用
    • US06281339B1
    • 2001-08-28
    • US09660846
    • 2000-09-13
    • Urs LehmannMarcel Frick
    • Urs LehmannMarcel Frick
    • C09B62465
    • C09D11/328C09B43/00C09B43/16C09B62/04C09B62/465C09B69/00
    • Monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine dyes comprising at least one structural unit of formula (1) wherein Z is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24-alkylamino, unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino, each unsubstituted or substituted in the aryl moiety; morpholino; piperazin-1-yl or piperidin-1-yl, and X is hydrogen, hydroxy, chlorine or bromine, or X has the meanings given for Z, yield dyeings or prints having good fastness to light and high color brilliance.
    • 包含至少一个式(1)结构单元的单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲az或二恶嗪染料,其中Z是在烷基部分未被取代或取代的C1-C24烷氧基,或在烷基部分中不间断或中断氧 ; 在苯环中未取代或取代的苯氧基; 在烷基部分未取代或取代的C 1 -C 4烷硫基; 在苯环中未取代或取代的苯硫基; 氨基; 在烷基部分未取代或取代的N-单或N,N-二-C 1 -C 24 - 烷基氨基,或在烷基部分中不间断或间断地被氧或由-NR 1 - ,其中R 1是氢或C1- C4烷基; C10-C20萜氨基; 在环烷基环中未取代或取代的C 5 -C 7环烷基氨基; 苯基或萘基 - 氨基或N-C 1 -C 4烷基-N-苯基 - 或N-C 1 -C 4烷基-N-萘基 - 氨基,其各自未被取代或在芳基部分取代; 吗啉代 哌嗪-1-基或哌啶-1-基,X是氢,羟基,氯或溴,或X具有给定的含义,产率染色或具有良好的耐光牢度和高色泽的印花。