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1. 发明授权

US5484915A Sulphonated manganese phthalocyanines and compositions thereof 失效
标题翻译：磺化锰酞菁及其组合物
公开(公告)号：US5484915A
公开(公告)日：1996-01-16
申请号：US268578
申请日：1994-07-06
申请人： Peter Gregory , Stephen J. Reynolds , Raymond L. White
发明人： Peter Gregory , Stephen J. Reynolds , Raymond L. White
IPC分类号： C07D487/22 , C09B47/06 , C09B47/067 , C11D7/32 , D06M13/02 , D06M13/248 , D06M13/256 , D06M13/50 , C09B47/04 , C09B47/24
CPC分类号： C09B47/0675 , C09B47/063
摘要： A substituted phthalocyanine in which at least one of the peripheral carbon atoms in the 1-16 positions of the phthalocyanine nucleus (MnPc) as shown in Formula (1) ##STR1## is linked via an oxygen atom or a sulphur atom to an organic radical, the remaining peripheral carbon atoms being unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof. Compositions comprising one or more compounds of Formula (1) and their use as cleaning materials are also disclosed along with a process for removing stains and/or grime from fabrics using these compositions.
摘要翻译：如式（1）所示的式（1）所示的酞菁核（MnPc）的1-16位中的至少一个外周碳原子的至少一个经由氧原子或硫原子连接的取代酞菁对于有机基团，剩余的外周碳原子是未取代的或被原子或基团的任何组合及其磺化衍生物所取代。还公开了包含一种或多种式（1）化合物及其用作清洁材料的组合物以及使用这些组合物从织物中除去污渍和/或污垢的方法。

2. 再颁专利

USRE36357E Thermal transfer printing: hetero-aromatic azo dye 失效
标题翻译：热转印：杂芳族偶氮染料
公开(公告)号：USRE36357E
公开(公告)日：1999-10-26
申请号：US549292
申请日：1990-07-05
申请人： Peter Gregory , Raymond L. White
发明人： Peter Gregory , Raymond L. White
IPC分类号： C09D11/00 , B41M5/035 , B41M5/124 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B29/033 , C09B29/08 , C09B29/36 , C09B29/44 , C09D11/02 , B41M5/38
CPC分类号： B41M5/388 , C09B29/0025 , C09B29/0809 , C09B29/3643 , C09B29/3695 , Y10S428/913 , Y10S428/914 , Y10S8/922 , Y10T428/31993
摘要： A thermal transfer printing sheet comprising a substrate having a coating comprising at least one azo dye of the formula:A--N.dbd.N--E Iwherein :A is the residue of a diazotizable heteroaromatic amine, A--NH.sub.2, in which A is selected from imidazolyl, pyrazolyl, thiazolyl, benzothiazolyl, isothiazolyl, benzoisothiazolyl, pyridoisothiazolyl and thienyl; andE is the residue of an aromatic coupling component, E--X wherein X is a group displaceable by a diazotized aromatic amine and E is optionally substituted aminophenyl, tetra- hydroquinolinyl, julolidyl or aminoquinolinyl,and a process for the transfer of dye from the transfer sheet to a receiver sheet by the selective application of heat to the transfer sheet while it is contact with the receiver sheet.
摘要翻译：一种热转印片，其包含具有包含至少一种下式的偶氮染料的涂层的基底：AN = N-EI其中：A是可重氮化杂芳族胺A-NH 2的残基，其中A选自咪唑基，吡唑基，噻唑基，苯并噻唑基，异噻唑基，苯并异噻唑基，吡啶并噻唑基和噻吩基; 并且E是芳族偶联组分的残基，EX，其中X是可被重氮化的芳香胺置换的基团，E是任选取代的氨基苯基，四氢喹啉基，高洛勒基或氨基喹啉基，以及用于从转印片转移染料的方法通过在与接收片接触的同时选择性地向转印片施加热量到接收片。

3. 发明授权

US4764178A Thermal transfer printing: hetero-aromatic azo dye 失效
标题翻译：热转印：杂芳族偶氮染料
公开(公告)号：US4764178A
公开(公告)日：1988-08-16
申请号：US896000
申请日：1986-08-13
申请人： Peter Gregory , Raymond L. White
发明人： Peter Gregory , Raymond L. White
IPC分类号： C09D11/00 , B41M5/035 , B41M5/124 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B29/033 , C09B29/08 , C09B29/36 , C09B29/44 , C09D11/02 , C09B29/03
CPC分类号： B41M5/388 , C09B29/0025 , C09B29/0809 , C09B29/3643 , C09B29/3695 , Y10S428/913 , Y10S428/914 , Y10S8/922 , Y10T428/31993
摘要： A thermal transfer printing sheet comprising a substrate having a coating comprising at least one azo dye of the formula:A--N.dbd.N--E Iwherein:A is the residue of a diazotizable heteroaromatic amine, A--NH.sub.2, in which A is selected from imidazolyl, pyrazolyl, thiazolyl, benzothiazolyl, isothiazolyl, benzoisothiazolyl, pyridoisothiazolyl and thienyl; andE is the residue of an aromatic coupling component, E--X wherein X is a group displaceable by a diazotized aromatic amine and E is optionally substituted aminophenyl, tetrahydroquinolinyl, julolidyl or aminoquinolinyl,and a process for the transfer of dye from the transfer sheet to a receiver sheet by the selective application of heat to the transfer sheet while it is contact with the receiver sheet.
摘要翻译：一种热转印片，其包含具有包含至少一种下式的偶氮染料的涂层的涂层：AN = NE I其中：A是可重氮化杂芳族胺A-NH 2的残基，其中A选自咪唑基，吡唑基，噻唑基，苯并噻唑基，异噻唑基，苯并异噻唑基，吡啶并噻唑基和噻吩基; 并且E是芳族偶联组分的残基，EX，其中X是可被重氮化的芳香胺置换的基团，E是任选取代的氨基苯基，四氢喹啉基，高洛勒基或氨基喹啉基，以及用于从转印片转移染料的方法通过在与接收片接触的同时选择性地向转印片施加热量到接收片。

4. 发明授权

US07481522B2 Compositions and inks containing disazo dyes 失效
标题翻译：含有双偶氮染料的组合物和油墨
公开(公告)号：US07481522B2
公开(公告)日：2009-01-27
申请号：US10516496
申请日：2003-06-05
申请人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
发明人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
IPC分类号： G01D11/00
CPC分类号： C09D11/30
摘要： A process for printing an image on a substrate including applying thereto a composition including a liquid medium and a compound of Formula (1) A-N═N-L-N═N-A wherein: each A independently is optionally substituted aryl or heteroaryl; and L is an optionally substituted, optionally metallised 1,8-dihydroxynaphthylene group; provided that: (i) at most one of the groups represented by A has a hydroxy substituent ortho to the —N═N— groups shown in Formula (1); and (ii) Formula (1) is not: Also claimed are compositions for printing, compounds and processes for making the compounds.
摘要翻译：一种在基材上印刷图像的方法，包括向其施涂包含液体介质和式（1）A-N-N-L-N-N-A的化合物的组合物，其中：每个A独立地为任选取代的芳基或杂芳基; 并且L是任选取代的任选金属化的1,8-二羟基萘基; 条件是：（i）由A表示的至多一个基团具有与式（1）所示的-N-N-基邻位的羟基取代基; 和（ii）式（1）不是：还要求的是用于印刷的组合物，化合物和制备该化合物的方法。

5. 发明授权

US5925487A Composition, compound and use 失效
标题翻译：组成，复合和使用
公开(公告)号：US5925487A
公开(公告)日：1999-07-20
申请号：US860491
申请日：1997-06-27
申请人： David Melville Fawkes , Peter Gregory , James Stanley Campbell
发明人： David Melville Fawkes , Peter Gregory , James Stanley Campbell
IPC分类号： C07C65/11 , C07C229/38 , C08K5/09 , C08L101/00 , G03G9/097 , C03G9/097 , C07F3/04 , C07F15/02 , C03G13/08
CPC分类号： G03G9/09775 , C07C229/38 , C07C65/11 , G03G9/09733 , G03G9/09783
摘要： A toner resin composition comprising a toner resin and the metal salt or complex of a carbocyclic hydroxy caboxylic acid containing at least one methylene group optionally substituted by hydroxy or amino such as 4-(N-methyl-N-2-hydroxyethyl)aminomethyl-3-hydroxy-2-naphthoic acid. Iron and zinc salts are preferred.
摘要翻译： PCT No.PCT / GB95 / 02852 Sec。 371日期：1997年6月27日 102（e）日期1997年6月27日PCT提交1995年12月7日PCT公布。公开号WO96 / 20436 日期1996年7月4日一种调色剂树脂组合物，其包含调色剂树脂和含有至少一个任选被羟基或氨基取代的亚甲基的碳环羟基甲醛酸的金属盐或络合物，例如4-（N-甲基-N-2- 羟乙基）氨基甲基-3-羟基-2-萘甲酸。优选铁和锌盐。

6. 发明授权

US5847114A Poly-substituted phthalocyantines 失效
标题翻译：多取代酞菁酮
公开(公告)号：US5847114A
公开(公告)日：1998-12-08
申请号：US548173
申请日：1995-10-25
申请人： Dean Thetford , Peter Gregory
发明人： Dean Thetford , Peter Gregory
IPC分类号： A61K31/40 , A61K31/409 , A61K31/555 , A61K41/00 , A61K51/00 , A61P35/00 , C07D487/22 , C09B47/04 , C09B47/067 , C09B47/18 , C11D3/00 , C11D3/16 , C11D3/39 , C11D3/395 , C11D7/54 , C11D11/00 , D06L3/02
CPC分类号： C07D487/22 , A61K31/40 , C09B47/045 , C09B47/0675 , C09B47/18 , C11D11/0017 , C11D3/0063 , C11D3/168 , C11D3/3932
摘要： The use of substituted phthalocyanines for the generation of singlet oxygen in which at least one of the peripheral carbon atoms in the 1-16 positions of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1): ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; and k is the inverse of 1/2 of the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.
摘要翻译：取代酞菁用于产生其中式（1）的酞菁核的1-16位的末端碳原子（MkPc）中的至少一个的单线态氧：其中：M 选自H，金属，卤素，氧化金属和羟基金属; 并且k是+ E的倒数，f 1的化合价的1/2 + EE; 通过氧原子连接到芳族基团，并且剩余的外围碳原子是未取代的或被原子或基团和磺化衍生物的任何组合取代，条件是酞菁吸收在650nm至800nm的波长的电磁辐射。

7. 发明授权

US5779780A Ink and toner compositions containing a mixture of bis-azo dyes 失效
标题翻译：含有双偶氮染料混合物的油墨和调色剂组合物
公开(公告)号：US5779780A
公开(公告)日：1998-07-14
申请号：US825920
申请日：1997-04-02
申请人： Peter Gregory , John Anthony Taylor
发明人： Peter Gregory , John Anthony Taylor
IPC分类号： C09B62/09 , C09B67/22 , C09D11/00 , D06P5/30 , G03G9/09 , C09D11/02
CPC分类号： C09D11/328 , C09B62/09 , C09B67/0058 , D06P5/30 , G03G9/091
摘要： An ink composition comprising a medium comprising at least one of a low melting point solid, an organic solvent and a mixture of water and one or more water-soluble organic solvent(s); and a mixture of a first, second, third and fourth dye, each of which is of Formula (1) or a salt thereof: ##STR1## wherein: X is a labile or non labile atom or group; A and B are each independently an optionally substituted phenylene group; one or R.sup.1 and R.sup.2 is H and the other is sulpho; one of R.sup.3 and R.sup.4 is H and the other is sulpho; R.sup.5 and R.sup.6 are each independently C.sub.1-4 -alkyl. Also claimed is an ink jet printing process using the inks, a process for ink jet printing textile materials using the inks and a toner containing a mixture of a first, second, third and fourth dyes of the Formula (1).
摘要翻译：一种油墨组合物，其包含包含低熔点固体，有机溶剂和水与一种或多种水溶性有机溶剂的混合物中的至少一种的介质; （1）的第一种，第二种，第三种和第四种染料的混合物或其盐：其中：X是不稳定或非不稳定的原子或基团; A和B各自独立地为任选取代的亚苯基; 一个或R1和R2是H，另一个是磺基; R3和R4之一是H，另一个是磺基; R 5和R 6各自独立地为C 1-4 - 烷基。还要求保护的是使用油墨的喷墨印刷方法，使用该油墨的喷墨印花纺织品的方法和含有式（1）的第一，第二，第三和第四染料的混合物的调色剂。

8. 发明授权

US5756693A Disazo Compound 失效
标题翻译：二唑类化合物
公开(公告)号：US5756693A
公开(公告)日：1998-05-26
申请号：US737613
申请日：1997-01-30
申请人： Ronald Wynford Kenyon , Peter Gregory
发明人： Ronald Wynford Kenyon , Peter Gregory
IPC分类号： B41J2/01 , C09B31/08 , C09D11/00
CPC分类号： C09D11/328 , C09B31/08
摘要： A compound of the Formula (1) and salts thereof: ##STR1## wherein: A is optionally substituted phenyl or optionally substituted naphthyl; R.sup.1 is NR.sup.4 R.sup.5 ; R.sup.2 is H, halo, --COOH, --SO.sub.2 0H, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio; R.sup.3, R.sup.4 & R.sup.5 are each independently H or optionally substituted alkyl; T is H or sulpho; and B is H, optionally substituted alkyl or optionally substituted phenyl; provided that the compound does not contain a piperazinyl group. The compound is suitable for use as a black colorant in ink jet printing inks especially for printing on plain paper.
摘要翻译： PCT No.PCT / GB95 / 01110 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1995年5月17日PCT公布。公开号WO95 / 31505 日期：1995年11月23日一种式（1）化合物及其盐：其中：A为任选取代的苯基或任选取代的萘基; R1为NR4R5; R 2是H，卤素，-COOH，-SO 2 OH，任选取代的烷基，任选取代的烷氧基或任选取代的烷硫基; R 3，R 4和R 5各自独立地为H或任选取代的烷基; T是H或磺基; 且B为H，任选取代的烷基或任选取代的苯基; 条件是该化合物不含哌嗪基。该化合物适合用作喷墨印刷油墨中的黑色着色剂，特别用于在普通纸上印刷。

9. 发明授权

US5730759A Poly-substituted phthalocyanines 失效
标题翻译：聚取代酞菁
公开(公告)号：US5730759A
公开(公告)日：1998-03-24
申请号：US548171
申请日：1995-10-25
申请人： Dean Thetford , Peter Gregory
发明人： Dean Thetford , Peter Gregory
IPC分类号： A61K31/40 , A61K31/409 , A61K31/555 , A61K41/00 , A61K51/00 , A61P35/00 , C07D487/22 , C09B47/04 , C09B47/067 , C09B47/18 , C11D3/00 , C11D3/16 , C11D3/39 , C11D3/395 , C11D7/54 , C11D11/00 , D06L3/02 , D06L3/04
CPC分类号： C07D487/22 , A61K31/40 , C09B47/045 , C09B47/0675 , C09B47/18 , C11D11/0017 , C11D3/0063 , C11D3/168 , C11D3/3932
摘要： The use of substituted phthalocyaines for removing stains from fabrics which comprises treating the stained fabrics with an aqueous composition comprising a phthalocyanine in which at least one of the peripheral carbon atoms in the 1-16 position of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1), ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; and k is the inverse of 1/2 the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.
摘要翻译：使用取代的酞菁素从织物中除去污渍，其中包括用包含酞菁的水性组合物处理染色的织物，其中式（1）的酞菁核的1-16位的至少一个外周碳原子（MkPc）），m H，金属，卤素，氧化金属和羟基金属; 并且k是+ E的倒数，f 1/2 + EE是M的化合价; 通过氧原子连接到芳族基团，并且剩余的外围碳原子是未取代的或被原子或基团和磺化衍生物的任何组合取代，条件是酞菁吸收在650nm至800nm的波长的电磁辐射。

10. 发明授权

US5629417A Phthalocyanines 失效
标题翻译：酞菁
公开(公告)号：US5629417A
公开(公告)日：1997-05-13
申请号：US594412
申请日：1996-01-31
申请人： James S. Campbell , Peter Gregory , Dean Thetford
发明人： James S. Campbell , Peter Gregory , Dean Thetford
IPC分类号： C07D487/22 , C09B47/20 , C09B47/22
CPC分类号： C09B47/20 , C09B47/22
摘要： A phthalocyanine of Formula (1): ##STR1## wherein: M.sub.k PC is a phthalocyanine nucleus of Formula (2): ##STR2## M is a metal atom, a chloro-metal group, and oxy-metal group or hydrogen; k is inverse of 1/2 valency of M; R and R.sup.1 each independently is an organic radical;R.sup.2 is H or optionally substituted alkyl;a is an average value from 15 to 8;b is an average value from 1 to 8; anda+b is from 15 to 16; and sulphonated derivatives thereof and process for their preparation.The phthalocyanines of the present invention are useful for absorbing electro-magnetic radiation from for example a laser source and may be used in a coating for optical data storage disks, or in security applications such as printing banknotes or cheques, or in the preparation of lithographic printing plates or in washing powders to assist in bleaching.
摘要翻译：式（1）的酞菁：式（1）其中：MkPC是式（2）的酞菁核：式（2）M是金属原子，氯 - 金属基和氧 - 金属基团或氢; k为+ E的倒数，为M的1/2 + EE化合价; R和R 1各自独立地为有机基团; R2是H或任选取代的烷基; a是从15到8的平均值; b为1〜8的平均值; a + b为15〜16; 及其磺化衍生物及其制备方法。本发明的酞菁可用于从例如激光源吸收电磁辐射，并且可用于光学数据存储盘的涂层中，或用于诸如印刷纸币或支票的安全应用中，或用于制备光刻印刷板或洗涤粉以帮助漂白。

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