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    • 5. 发明授权
    • Phthalocyanine/ polymer nanocomposite ink for optoelectonics
    • 用于光电子学的酞菁/聚合物纳米复合油墨
    • US09200172B2
    • 2015-12-01
    • US13879795
    • 2010-11-05
    • Xu ZongxiangA. L. Roy Vellaisamy
    • Xu ZongxiangA. L. Roy Vellaisamy
    • C08K5/34C09B47/04H01L21/00C09D11/52B82Y10/00C09B67/46C09B67/08C09B47/067B82Y30/00H01L51/00H01L51/42
    • C09D11/52B82Y10/00B82Y30/00C09B47/0673C09B67/0005C09B67/009H01L51/0036H01L51/0047H01L51/0078H01L51/4253Y02E10/549
    • Aspects describe phthalocyanine (Pc) molecules with peripheral modifications of its core (e.g., alkyl substituents) so that the Pc can self assemble, for example under vacuum sublimation, and form nanocrystals of a size on the order of nanometers. The Pc nanocrystals can be prepared, for example, by a simple vapor deposition method. Further aspects describe a polymer composite ink based Pc nanocrystals in a polymer matrix, which can be formed, for example, under a solution process approach. For example, the polymer matrix can be a different p-type conjugated polymer from the Pc nanocrystals, which are inherently p-type semiconductors. This can increase the film formation ability and charge transport properties of the polymer composite ink. The polymer composite ink can be utilized, for example, in the fabrication of optoelectronic devices, such as photovoltaic devices and/or thin film transistors. The optoelectronic devices can exhibit high power conversion efficiency (PCE), for example 6-7 percent.
    • 方面描述了具有其核心外围修饰(例如烷基取代基)的酞菁(Pc)分子,使得Pc可以例如在真空升华下自组装,并形成大约数量级的纳米晶体。 Pc纳米晶体可以例如通过简单的气相沉积法制备。 另外的方面描述了聚合物基质中的聚合物复合油墨基Pc纳米晶体,其可以例如在溶液工艺方法下形成。 例如,聚合物基质可以是与Pc纳米晶体不同的p型共轭聚合物,其是固有的p型半导体。 这可以增加聚合物复合油墨的成膜能力和电荷传输性能。 聚合物复合油墨可用于例如制造光电器件,例如光伏器件和/或薄膜晶体管。 光电器件可以表现出高功率转换效率(PCE),例如6-7%。